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At least 577 records · Page 32

The potential impact on atmospheric ozone and temperature of increasing trace gas concentrations

The response of the atmosphere to emissions of chlorofluorocarbons (CFCs) and other chlorocarbons, and to increasing concentrations of other radiatively active trace gases such as CO2, CH4, and N2O is calculated by a coupled chemical-radiative transport one-dimensional model. It is shown that significant reductions in the ozone concentration and in the temperature are expected in the upper stratosphere as a result of increasing concentrations of active chlorine produced by photodecomposition of the CFCs. The ozone content is expected to increase in the troposphere, as a consequence of increasing concentrations of methane and nitrogen oxides. Due to enhanced greenhouse effects, the Earth's surface should warm up by several degrees. The amplitude and even the sign of future changes in the ozone column are difficult to predict as they are strongly scenario-dependent. An early detection system to prevent noticeable ozone changes as a result of increasing concentrations of source gases should thus be based on a continuous monitoring of the ozone amount in the upper stratosphere rather than on measurements of the ozone column only. Measurements of NOx, Clx, and HOx are also required for unambiguous trend detection and interpretation.

Brasseur, G.↗

Trace element differences between Archean, Proterozoic and Phanerozoic crustal components: Implications for crustal growth processes

Critical to models for continental crust growth and recycling are the processes through which crustal growth takes place. In particular, it is important to know whether these processes have changed fundamentally with time in response to the earth's thermal evolution, and whether the crustal compositions generated are compatible with crustal remobilization, crustal recycling, or represent primary additions. There are some significant and consistent differences in the major and trace element compositions of crustal components with time which have important implications for crustal growth processes. These will be illustrated with reference to Archean rocks from a number of shield areas, Proterozoic granitoids from Australia and elsewhere, Palaeozoic granitoids from Australia and Scotland, and Mesozoic - recent granitoids from present continental margin belts. Surprisingly some rather simple and consistent patterns energy using this technique. There are then significant differences in compositions of granitoid crustal additions throughout geological time, with a particular type of granitoid apparently dominating a particular time period. This implies that the tectonic processes giving rise to granite generation have changed in response to the earth's thermal evolution.

Tarney, J.↗

Stratospheric trace gases in the spring 1986 Antarctic atmosphere

The atmospheric absorption features of over 500 infrared solar spectra recorded at McMurdo Station have been analyzed to determine the vertical column abundances of trace gases crucial to understanding of the 'ozone hole' phenomenon. The techniques used to retrieve the column abundances are described. Results are reported for ozone, nitrogen species, and halogen sinks and reservoirs.

Farmer, C. B.↗

The potential impact on atmospheric ozone and temperature of increasing trace gas concentrations

The response of the atmosphere to emission of chlorofluorocarbons and other chlorocarbons and to increasing concentrations of other radiatively active trace gases is calculated using a coupled, one-dimensional, time-dependent chemical-radiative-transport model. The model predicts future changes in the ozone content and in the temperature based on several possible time-dependent scenarios of future atmospheric emissions. The sensitivity of the atmospheric responses to the values adopted for parameters such as the eddy diffusion coefficient for vertical transport and the atmospheric budget of nitrogen oxides is estimated and discussed.

Brasseur, Guy↗

Concentrations of ethane (C2H6) in the lower stratosphere and upper troposphere and acetylene (C2H2) in the upper troposphere deduced from Atmospheric Trace Molecule Spectroscopy/Spacelab 3 spectra

This paper reports the results of the spectroscopic analysis of C2H6 and C2H2 absorption spectra obtained by the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument flown on the Shuttle as part of the Spacelab 3 mission. The spectra were recorded during sunset occultations occurring between 25 deg N and 31 deg N latitudes, yielding volume-mixing ratio profiles of C2H6 in the lower stratosphere and the upper troposphere, and an upper tropospheric profile of C2H2. These results compare well with previous in situ and remote sounding data obtained at similar latitudes and with model calculations. The results demonstrate the feasibility of the ATMOS instrument to sound the lower atmosphere from space.

Rinsland, C. P.↗

Trace constituents in the mesosphere

The paper examines recent composition measurements, the large-scale distributions of trace constituents, and the interpretation of these global patterns in the light of the current understanding of chemistry and transport. Attention is given to results from the following space missions: the Nimbus 7 LIMS and SAMS experiments; the SMM UV spectrometer solar occultation experiment; the SME UVS and AGS experiments; and the Spacelab 1 solar occultation experiment. A brief summary of measurements and their implications is presented for three long-lived species, CO, NO, and H2O. The reactive or short-lived species OH and O3 are also examined.

Thomas, Gary E.↗

Measurement of stratospheric trace constituent distributions from balloon-borne far infrared observations

FIR limb thermal emission spectra obtained from balloon-borne measurements made as a part of the Balloon Intercomparison Campaign (BIC) have been analyzed for retrieval of stratospheric trace-constituent distributions. The measurements were made with a high-resolution Michelson interferometer and covered the 15-180/cm spectral range with an unapodized spectral resolution of 0.0033/cm. The retrieved vertical profiles of O3, H2O, HDO, HCN, CO, and isotopes of O3 are presented. The results are compared with the BIC measurements for O3 and H2O made from the same balloon gondola and with other published data. A comparison of the simultaneously retrieved profiles for several gases with the published data shows good agreement and indicates the validity of the FIR data and retrieval techniques and the accuracy of the inferred profiles.

Abbas, M. M.↗

Irregular and diurnal variability in asynoptic measurements of stratospheric trace species

The consequences of irregular and diurnal variability on the interpretation of asynoptic measurements of stratospheric trace species are explored. In particular, the fidelity with which the continuous behavior may be recovered from discrete asynoptic measurements is examined. Dynamically created tracer variability in the form of an advected space-time random process is discussed. Diagnostics such as power spectra and time-mean fields are derived asynoptically and compared with the true behavior. Diurnal variations of a photochemically active species are considered, describing variability in terms of a solar waveform which propagates through a latitudinal envelope. Several diagnostics of the behavior are derived asynoptically and compared with the true variability.

Salby, Murry L.↗

Tracing structural optima as a function of available resources by a homotopy method

Optimization problems are typically solved by starting with an initial estimate and proceeding iteratively to improve it until the optimum is found. The design points along the path from the initial estimate to the optimum are usually of no value. The present work proposes a strategy for tracing a path of optimum solutions parameterized by the amount of available resources. The paper specifically treats the optimum design of a structure to maximize its buckling load. Equations for the optimum path are obtained using Lagrange multipliers, and solved by a homotopy method. The solution path has several transitions from unimodal to bimodal solutions. The Lagrange multipliers and second-order optimality conditions are used to detect branching points and to switch to the optimum solution path. The procedure is applied to the design of a foundation which supports a column for maximum buckling load. Using the total available foundation stiffness as a homotopy parameter, a set of optimum foundation designs is obtained.

Haftka, Raphael T.↗

Balloon-borne measurements of middle atmosphere aerosols and trace gases in Antarctica

This paper reviews data on in situ balloon-borne measurements on stratospheric ozone concentrations and aerosol contents obtained prior to 1986, along with the measurements obtained in 1986 during the National Ozone Expedition. The data indicate that the phenomenon of ozone depletion appears to be shaped spatially and temporally by dynamical stratospheric phenomena. In terms of Antarctic stratospheric research, it appears that the most important problems at the moment involve delineating the springtime ozone depletion through accurate in situ measurements of temperature, trace gas, and particle size (in addition to remote sensing from space).

Hofmann, D. J.↗

Tracing Rays In A Solar Power System

OFFSET is ray-tracing computer code for analysis of optics of solar collector. Code models distributions of solar flux within receiver cavity, produced by reflections from collector. Developed to model mathematically offset solar collector of solar dynamic electric power system being developed for Space Station Freedom. Used to develop revised collector-facet concept of four groups of toroidally contoured facets. Also used to develop methods for tailoring distribution of flux incident on receiver. Written in FORTRAN 77 (100 percent).

Jefferies, Kent↗

Mechanical Device Traces Parabolas

Mechanical device simplifies generation of parabolas of various focal lengths. Based on fundamental geometrical construction of parabola. Constancy of critical total distance enforced by maintaining cable in tension. Applications of device include design of paraboloidal antennas, approximating catenaries on drawings of powerlines or long-wire antennas, and general tracing of parabolas on drawings.

Soper, Terry A.↗

Tracing Rays In Laser-Fringe Anemometers

"OPTMAIN" is simple ray-tracing computer code developed to quantify refractive effects that result when laser-fringe anemometer used to observe flows through window. Code calculates changes for four different types of windows: flat-plate windows, simple cylindrical windows, "general" axisymmetric windows, and smooth general-surface windows. Written in FORTRAN IV.

Owen, Karl↗

Volatile/mobile trace elements in meteoritic, non-lunar basalts: Guides to Martian sample contents

A variety of genetic processes on or in extraterrestrial objects can be examined by study of volatile/mobile trace elements. Doubtless, considerable efforts will be expended on determining these elements in returned Martian samples. The purpose is to estimate levels of such elements expected to be present in returned Martian samples. Some ideas about Martian genesis were already advanced from the volatile/mobile element contents in SNC meteorites, assuming that Mars was their parent body. Even is Mars and the SNC meteorite parent body are identical, compositional ranges for returned Martian samples should exceed those of SNC meteorites. It is expected, therefore, that Martian samples returned from locations other than Polar regions will have indigenous volatile/mobile element contents within howardite-diogenite ranges. Elements with strong lithophile tendences may be more abundant, as they are in many lunar samples. Most of these elements should be at ppb levels except for Co, Ga, Zn, and Rb, which should lie at ppm levels. If Martian volcanism was accompanied by fumarolic emanations, it should be reflected in occasional huge enrichments of mobile trance elements, as in lunar meteorite Y 791197. During collection and transport Earthward, samples must be contained under conditions appropriate to ppb concentrations. Materials must be used that will not cause contamination which occurred during the Apollo program, where indium from seals contaminated many samples.

Lipschutz, M. E.↗

A search for biogenic trace gases in the atmosphere of Mars

The detection of certain trace gases in the atmosphere of Mars may serve as a possible indicator of microbial life on the surface of Mars. Candidate biogenic gases include methane CH4, ammonia NH3, nitrous oxide N2O, and several reduced sulfur species. Chemical thermodynamic equilibrium and photochemical calculations preclude the presence of these gases in any measurable concentrations in the atmosphere of Mars in the absence of biogenic production. A search for these gases utilizing either high resolution (spectral and spatial) spectroscopy from a Mars orbiter, such as the Observer, and or in situ measurements from a Mars lander or rover, is proposed.

Levine, Joel S.↗

Reversal electron attachment ionizer for detection of trace species

An in-line reversal electron, high-current ionizer capable of focusing a beam of electrons to a reversal region and executing a reversal of the electrons, such that the electrons possess zero kinetic energy at the point of reversal, may be used to produce both negative and positive ions. A sample gas is introduced at the point of electron reversal for low energy electron-(sample gas) molecule attachment with high efficiency. The attachment process produces negative ions from the sample gas, which includes species present in trace (minute) amounts. These ions are extracted efficiently and directed to a mass analyzer where they may be detected and identified. The generation and detection of positive ions is accomplished in a similar fashion with minimal adjustment to potentials applied to the apparatus.

Bernius, Mark T.↗

Atmospheric Trace Molecule Spectroscopy (ATMOS)

The Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment is a space-borne investigation designed to obtain fundamental information related to the chemistry and physics of the earth's upper atmosphere (20 to 120 km altitude). The instrument, a high resolution (0.01/cm) interferometric spectrometer, measures the atmospheric absorption of solar radiation over the wavelength range from 2 to 16 micrometers, a spectral band which encompasses active transitions of all of the molecular species of current importance in upper atmospheric studies. There are two major aspects to the experiment: (1) the determination of the detailed compositional structure of the stratosphere and mesosphere, and its global, seasonal, and long-term variability; and (2) the study of the partitioning of absorbed solar energy at levels in the atmosphere characterized by dissociation of many of the constituents and by the breakdown of thermodynamic equilibrium. Characteristics of ATMOS are given. This experiment will be part of the atmospheric science research payload flown on the Atmospheric Laboratory for Applications and Science (ATLAS 1) NASA mission planned for late 1990.

Farmer, C. B.↗

Global budget of stratospheric trace constituents (GLOBUS). MAP/GLOBUS 1983: A review

MAP/GLOBUS 1983 was a project for the study of stratospheric trace gases and dynamics. A respective field campaign was performed in September/October 1983 in Western Europe. A large number of measurements were taken by instruments based on the ground, on airplane, balloons, and satellite. The structure of the campaign is described, and a survey of the results are given.

Offermann, D.↗