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At least 577 records · Page 32

Progress in Atmospheric Carbon Monitoring Using NASA's GEOS Model and Data from the OCO and GOSAT Missions

NASA's Global Modeling and Assimilation Office (GMAO) produces a variety of carbon products based the synthesis of satellite remote sensing data and outputs of the Goddard Earth Observing System (GEOS). This includes bottom-up surface fluxes due to fossil fuel emissions, biomass burning, terrestrial biospheric exchange, and ocean exchangeconstrained by measurements of nighttime lights, fire radiative power, normalized difference vegetation index, and ocean color. These fluxes are the basis of top-down estimates of carbon concentrations and fluxes. In particular, the GMAO system processes retrievals of column carbon dioxide (XCO2) from GOSAT and OCO-2 to produce a high-resolution, long-term global analysis of CO2 in three dimensions every 6 hours. Here, we discuss the potential applications of such products for satellite intercomparison and evaluation against independent, non-coincident data. We also highlight the ability to provide monthly global atmospheric growth rates inferred from the assimilated CO2 concentration product. Finally, we discuss the challenges facing such products including bias correction and the estimation and analysis of model transport errors.

Weir, B.↗

Use of long-lived radon daughters as indicators of exchange between the free troposphere and the marine boundary layer

Fluxes and exchange coefficients are derived for the transport of Sr-90, Pb-210, Bi-210, and Po-210 between the free troposphere and the marine boundary layer and between the boundary layer and the sea surface. Radionuclide concentrations previously measured near Hawaii are used in the derivations. Values obtained for the free troposphere/boundary layer exchange coefficient (expressed as a piston velocity) were 185, 228 and 203 m/d for Pb-210, Bi-210, and Sr-90, respectively. The magnitude of the local sea-surface source of Po-210 is also determined.

Kritz, M. A.↗

Airspace Technology Demonstration 2 (ATD-2) Integrated Surface and Airspace Simulation - Experiment Plan

This presentation describes the objectives and high level setup for the human-in-the-loop simulation of the integrated surface and airsapce simulation of the ATD-2 Integrated Arrival, Departure, Surface (IADS) system. The purpose of the simulation is to evaluate the functionality of the IADS system, including tactical surface scheduler, negotiation of departure times for the flights under Traffic Management Initiatives (TMIs), and data exchange between ATC Tower and airline Ramp. The same presentation was presented to serve the experiment review prior to the simulation.

Surface↗

Chemistry of the global troposphere - Fluorocarbons as tracers of air motion

Winds and convective mixing from a general circulation model of the atmosphere have been applied in a chemical tracer model (CTM) to simulate the global distribution and temporal variability of chlorofluorocarbons (CFCs). The seasonal cycle in moist convection, with maximum activity over continents in summer, leads to an annual cycle in the surface concentration of CFCs. Emissions are retained in the lowest levels of the atmosphere during winter, and surface concentrations peak near sources. In this season, CFCs from European sources are carried by low-level winds into the Arctic. During summer, vertical exchange is more efficient, and pollutants are transported more rapidly to the middle atmosphere. Consequently, concentrations of CFCs during summer are relatively low near the surface and elevated in the middle troposphere. Time series analysis of data from Adrigole, Ireland, indicates that the model accurately simulates long-range transport of air pollution. The model reproduces global distributions and trends for CFC-11 and CFC-12 observed by the ALE experiment; however, subgrid diffusion must be introduced into the model in order to reproduce the observed interhemispheric gradient. Interhemispheric exchange occurs mainly in the upper tropical troposphere, producing a profile which increases with altitude in the Southern Hemisphere, in agreement with observations. The distribution of CFCs is such that it is necessary to apply important corrections to observations at surface stations in order to derive global distributions.

Prather, Michael↗

Transport effects due to particle erosion mechanisms

Various processes can erode the surfaces of planetary ring particles. Recent estimates for Saturn's rings suggest that a centimeter-thick surface layer could be eroded from an isolated ring particle in less than 1000 yr by meteoroid impacts alone. The atoms, molecules, and chips ejected from ring particles by erosion will arc across the rings along elliptical orbits. For moderate ring optical depths, ejecta will be absorbed or inelastically scattered upon reintersecting the ring plane. Continuous exchange of ejecta between different ring regions can lead to net radial transport of mass and angular momentum, to changes in particle sizes, and to the buildup of chip regoliths several centimeters deep on the surfaces of ring particles. Because most of the erosional ejecta are not lost but merely exchanged over short distances, the net erosion rate of the surfaces of these ring particles will be much less than that estimated for an isolated particle. Numerical solutions for time-dependent ballistic transport under various assumptions suggest pile-up and spillover effects especially near regions of preexisting high optical depth contrast, such as the inner edges of A and B rings. Global redistribution could be significant over billions of years. Other features in planetary ring systems may be influenced by ballistic transport.

Durisen, R. H.↗

Reducing distortion and internal forces in truss structures by member exchanges

Manufacturing errors in the length of members or joint diameters of large truss reflector backup structures may result in unacceptable large distortion errors or member forces. However, it may be possible to accurately measure these length or diameter errors. The present work suggests that a member and joint placement strategy may be used to reduce distortion errors and internal member forces. A member and joint exchange algorithm is used to demonstrate the potential of this approach on several 102-member and 660-member truss reflector structures. It is shown that it is possible to simultaneously reduce the rms of the surface error and the rms of member forces by two orders of magnitude by member and joint exchanges.

Greene, William H.↗

Reducing distortion and internal forces in truss structures by member exchanges

Manufacturing errors in the length of members or joint diameters of large truss reflector backup structures may result in unacceptable large distortion errors or member forces. However, it may be possible to accurately measure these length or diameter errors. The present work suggests that a member and joint placement strategy may be used to reduce distortion errors and internal member forces. A member and joint exchange algorithm is used to demonstrate the potential of this approach on several 102-member and 660-member truss reflector structures. It is shown that it is possible to simultaneously reduce the rms of the surface error and the rms of member forces by two orders of magnitude by member and joint exchanges.

Greene, William H.↗

Assessment of Microbiologically Influenced Corrosion Potential in the International Space Station Internal Active Thermal Control System Heat Exchanger Materials: A 6-Momths Study

The fluid in the Internal Active Thermal Control System (IATCS) of the International Space Station (ISS) is water based. The fluid in the ISS Laboratory Module and Node 1 initially contained a mix of water, phosphate (corrosion control), borate (pH buffer), and silver sulfate (Ag2SO4) (microbial control) at a pH of 9.5+/-0.5. Over time, the chemistry of the fluid changed. Fluid changes included a pH drop from 9.5 to 8.3 due to diffusion of carbon dioxide (CO2) through Teflon(reistered Trademark) (DuPont) hoses, increases in dissolved nickel (Ni) levels, deposition of silver (Ag) to metal surfaces, and precipitation of the phosphate (PO4) as nickel phosphate (NiPO4). The drop in pH and unavailability of a antimicrobial has provided an environment conducive to microbial growth. Microbial levels in the fluid have increased from >10 colony-forming units (CFUs)/100 ml to 10(exp 6) CFUs/100 ml. The heat exchangers in the IATCS loops are considered the weakest point in the loop because of the material thickness (=7 mil). It is made of a Ni-based braze filler/CRES 347. Results of a preliminary test performed at Hamilton Sundstrand indicated the possibility of pitting on this material at locations where Ag deposits were found. Later, tests have confirmed that chemical corrosion of the materials is a concern for this system. Accumulation of micro-organisms on surfaces (biofilm) can also result in material degradation and can amplify the damage caused by the chemical corrosion, known as microbiologically influenced corrosion (MIC). This paper will discuss the results of a 6-mo test performed to characterize and quantify the damage from microbial accumulation on the surface of the ISS/ATCS heat exchanger materials. The test was designed to quantify the damage to the materials under worst-case conditions with and without micro-organisms present at pH 8.3 and 9.5.

Roman, Monsi C.↗

Possible surface reactions on Mars - Implications for Viking biology results

The results of two of the three biology experiments carried out on the Viking Mars landers have been simulated. The mixture of organic compounds labeled with carbon-14 used on Mars released carbon dioxide containing carbon-14 when reacted with a simulated Martian surface and atmosphere exposed to ultraviolet light (labeled release experiment). Oxygen was released when metal peroxides or superoxides were treated with water (gas exchange experiment). The simulations suggest that the results of these two Viking experiments can be explained on the basis of reactions of the Martian surface and atmosphere.

Ponnamperuma, C.↗

Airspace Technology Demonstration 2 (ATD-2) Phase 1 Concept of Use (ConUse)

This document presents an operational Concept of Use (ConUse) for the Phase 1 Baseline Integrated Arrival, Departure, and Surface (IADS) prototype system of NASA's Airspace Technology Demonstration 2 (ATD-2) sub-project, which began demonstration in 2017 at Charlotte Douglas International Airport (CLT). NASA is developing the IADS system under the ATD-2 sub-project in coordination with the Federal Aviation Administration (FAA) and aviation industry partners. The primary goal of ATD-2 sub-project is to improve the predictability and the operational efficiency of the air traffic system in metroplex environments, through the enhancement, development, and integration of the nation's most advanced and sophisticated arrival, departure, and surface prediction, scheduling, and management systems. The ATD-2 effort is a five-year research activity through 2020. The initial phase of the ATD-2 sub-project, which is the focus of this document, will demonstrate the Phase 1 Baseline IADS capability at CLT in 2017. The Phase 1 Baseline IADS capabilities of the ATD-2 sub-project consists of: (a) Strategic and tactical surface scheduling to improve efficiency and predictability of airport surface operations, (b) Tactical departure scheduling to enhance merging of departures into overhead traffic streams via accurate predictions of takeoff times and automated coordination between the Airport Traffic Control Tower (ATCT, or Tower) and the Air Route Traffic Control Center (ARTCC, or Center), (c) Improvements in departure surface demand predictions in Time Based Flow Management (TBFM), (d) A prototype Electronic Flight Data (EFD) system provided by the FAA via the Terminal Flight Data Manager (TFDM) early implementation effort, and (e) Improved situational awareness and demand predictions through integration with the Traffic Flow Management System (TFMS), TBFM, and TFDM (3Ts) for electronic data integration and exchange, and an on-screen dashboard displaying pertinent analytics in real-time. The surface scheduling and metering element of the capability is consistent with the Surface CDM Concept of Operations published in 2014 by the FAA Surface Operations Directorate.1 Upon successful demonstration of the Phase 1 Baseline IADS capability, follow-on demonstrations of the matured IADS traffic management capabilities will be conducted in the 2018-2020 timeframe. At the end of each phase of the demonstrations, NASA will transfer the ATD-2 sub-project technology to the FAA and industry partners.

integrated arrival↗

Estimation of the average exchanges in momentum and latent heat between the atmosphere and the oceans with Seasat observations

Ocean-surface momentum flux and latent heat flux are determined from Seasat-A data from 1978 and compared with ship observations. Momentum flux was measured using the Seasat-A scatterometer system (SASS) heat flux, with the scanning multichannel MW radiometer (SMMR). Ship measurements were quality selected and averaged to increase their reliability. The fluxes were computed using a bulk parameterization technique. It is found that although SASS effectively measures momentum flux, variations in atmospheric stability and sea-surface temperature cause deviations which are not accounted for by the present data-processing algorithm. The SMMR-latent-heat-flux algorithm, while needing refinement, is shown to given estimations to within 35 W/sq m in its present form, which removes systematic error and uses an empirically determined transfer coefficient.

Liu, W. T.↗

Measurement of emissivity of industrial surfaces using a simple method

To detect emissivity, the drop in temperature of the sample undergoing radiation exchange with the wall in an evacuated space is measured over a given period. In this manner, emissivities of various synthetic resin lacquers, metals, and metallic coatings were measured. Once the emissivity is known, the same method can be used to detect specific heat and the head condition of gases.

Dallmeyer, H.↗

Remotely-Sensed Regional-Scale Evapotranspiration of a Semi-Arid Great Basin Desert and its Relationship to Geomorphology, Soils, and Vegetation

Landsat thematic mapper data are used to estimate instantaneous regional-scale surface water and energy fluxes in a semi-arid Great Basin desert of the western United States. Results suggest that it is possible to scale from point measurements of environmental state variables to regional estimates of water and energy exchange. This research characterizes the unifying thread in the classical climate-topography-soil-vegetation relation -the surface water and energy balance-through maps of the partitioning of energy throughout the landscape. The study was conducted in Goshute Valley of northeastern Nevada, which is characteristic of most faulted graben valleys of the Basin and Range Province of the western United States. The valley comprises a central playa and lake plain bordered by alluvial fans emanating from the surrounding mountains. The distribution of evapotranspiration (ET) is lowest in the middle reaches of the fans where the water table is deep and plants are small, resulting in low evaporation and transpiration. Highest ET occurs in the center of the valley, particularly in the playa, where limited to no vegetation occurs, but evaporation is relatively high because of a shallow water table and silty clay soil capable of large capillary movement. Intermediate values of ET are associated with large shrubs and is dominated by transpiration.

Laymon, C.↗

Evaluation of geophysical parameters measured by the Nimbus-7 microwave radiometer for the TOGA Heat Exchange Project

The data distributed by the National Space Science Data Center on the Geophysical parameters of precipitable water, sea surface temperature, and surface-level wind speed, measured by the Scanning Multichannel Microwave Radiometer (SMMR) on Nimbus-7, are evaluated with in situ measurements between Jan. 1980 and Oct. 1983 over the tropical oceans. In tracking annual cycles and the 1982-83 E1 Nino/Southern Oscillation episode, the radiometer measurements are coherent with sea surface temperatures and surface-level wind speeds measured at equatorial buoys and with precipitable water derived from radiosonde soundings at tropical island stations. However, there are differences between SMMR and in situ measurements. Corrections based on radiosonde and ship data were derived supplementing correction formulae suggested in the databook. This study is the initial evaluation of the data for quantitative description of the 1982-83 E1 Nino/Southern Oscillation episode. It paves the way for determination of the ocean-atmosphere moisture and latent heat exchanges, a priority of the Tropical Ocean and Global Atmosphere (TOGA) Heat Exchange Program.

Liu, W. Timothy↗

Surfactant Facilitated Spreading of Aqueous Drops on Hydrophobic Surfaces

Microgravity technologies often require aqueous phases to spread over nonwetting hydrophobic solid surfaces. Surfactants facilitate the wetting of water on hydrophobic surfaces by adsorbing on the water/air and hydrophobic solid/water interfaces and lowering the surface tensions of these interfaces. The tension reductions decrease the contact angle, which increases the equilibrium wetted area. Hydrocarbon surfactants; (i.e., amphiphiles with a hydrophobic moiety consisting of an extended chain of (aliphatic) methylene -CH2- groups attached to a large polar group to give aqueous solubility) are capable of reducing the contact angles on surfaces which are not very hydrophobic, but do not reduce significantly the contact angles of the very hydrophobic surfaces such as parafilm, polyethylene or self assembled monolayers. Trisiloxane surfactants (amphiphiles with a hydrophobe consisting of methyl groups linked to a trisiloxane backbone in the form of a disk ((CH3)3-Si-O-Si-O-Si(CH3)3) and an extended ethoxylate (-(OCH2CH2)a-) polar group in the form of a chain with four or eight units) can significantly reduce the contact angle of water on a very hydrophobic surface and cause rapid and complete (or nearly complete) spreading (termed superspreading). The overall goal of the research described in this proposal is to establish and verify a theory for how trisiloxanes cause superspreading, and then use this knowledge as a guide to developing more general hydrocarbon based surfactant systems which superspread. We propose that the trisiloxane surfactants superspread because their structure allows them to strongly lower the high hydrophobic solid/aqueous tension when they adsorb to the solid surface. When the siloxane adsorbs, the hydrophobic disk parts of the molecule adsorb onto the surface removing the surface water. Since the cross-sectional area of the disk is larger than that of the extended ethoxylate chain, the disks can form a space-filling mat on the surface which removes a significant amount of the surface water. In this presentation, we report the results of measurements of the molecular packing and rates of kinetic exchange of the trisiloxane surfactants at the air/water interface in order to confirm our picture of trisiloxane packing, and provide additional insight into the superspreading process. We used the pendant bubble technique as a Langmuir trough to measure the trisiloxane equation of state which relates the tension to the surface concentration. From these measurements we obtain accurate values for the maximum packing density. We find that trisiloxanes with 4 and 8 ethoxylate groups have the same maximum packing concentration, indicating that the maximum packing is controlled by the cross section of the head group. For trisiloxanes with larger than eight ethoxylates, the maximum packing increases with ethoxylate number, indicating that the disposition of the ethoxylate chain (i.e., its effective size) is controlling. This supports our picture of superspreading: The superspreading ability of trisiloxanes decreases considerably for trisiloxanes with larger than eight ethoxylates; the packing measurements indicate that for the higher ethoxylate number trisiloxanes, the compact nonpolar head groups are pushed apart by the ethoxylate chain. They leave spaces of surface water on adsorption and do not lower the solid tension as much as their lower chain analogues. Finally the report measurements of the dynamic tension reduction accompanying the adsorption of trisiloxanes onto an initially clean interface using the pendant bubble technique, and we obtain from these relaxations, the equation of state and a mass transfer model, the rate constants for kinetic exchange. We find that the rate constants for desorption of trisiloxanes are generally much slower than for analogous aliphatic polyethoxylate surfactants with identical ethoxylate chain lengths. When an aqueous drop of a superspreader solution is placed on a hydrophobic surface and begins to spread, the lower desorption rates allows the tension at the drop center to remain reduced relative to the tension of the expanding periphery, thus strengthening Marangoni forces which can assist the spreading. Marangoni forces can be especially significant in the case of superspreaders because their maximum equilibrium reduction in tension is several dynes/cm lower than for aliphatic surfactants.

Kumar, Nitin↗

Semiempirical energy surface for H sub 3

Semiempirical potential energy surface generation for triatomic hydrogen from London equation by evaluating Coulomb and exchange integrals taking into account effective orbital overlap

Salomon, M.↗