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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Supernova neutrino signals based on long-term axisymmetric simulations

ABSTRACT We study theoretical neutrino signals from core-collapse supernova (CCSN) computed using axisymmetric CCSN simulations that cover the post-bounce phase up to ∼4 s. We provide basic quantities of the neutrino signals such as event rates, energy spectra, and cumulative number of events at some terrestrial neutrino detectors, and then discuss some new features in the late phase that emerge in our models. Contrary to popular belief, neutrino emissions in the late phase are not always steady, but rather have temporal fluctuations, the vigour of which hinges on the CCSN model and neutrino flavour. We find that such temporal variations are not primarily driven by proto-neutron star convection, but by fallback accretion in exploding models. We assess the detectability of these temporal variations, and find that IceCube is the most promising detector with which to resolve them. We also update fitting formulae first proposed in our previous paper for which the total neutrino energy emitted at the CCSN source is estimated from the cumulative number of events in each detector. This will be a powerful technique with which to analyse real observations, particularly for low-statistics data.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1981

Determination of wind tunnel constraint effects by a unified pressure signature method. Part 2: Application to jet-in-crossflow

The development of an improved jet-in-crossflow model for estimating wind tunnel blockage and angle-of-attack interference is described. Experiments showed that the simpler existing models fall seriously short of representing far-field flows properly. A new, vortex-source-doublet (VSD) model was therefore developed which employs curved trajectories and experimentally-based singularity strengths. The new model is consistent with existing and new experimental data and it predicts tunnel wall (i.e. far-field) pressures properly. It is implemented as a preprocessor to the wall-pressure-signature-based tunnel interference predictor. The supporting experiments and theoretical studies revealed some new results. Comparative flow field measurements with 1-inch "free-air" and 3-inch impinging jets showed that vortex penetration into the flow, in diameters, was almost unaltered until 'hard' impingement occurred. In modeling impinging cases, a 'plume redirection' term was introduced which is apparently absent in previous models. The effects of this term were found to be very significant.

Hackett, J. E.↗
NASA NTRS1999

Soil Organic Carbon and Below Ground Biomass: Development of New GLOBE Special Measurements

A scientific consensus is building that changes in the atmospheric concentrations of radiatively active gases are changing the climate (IPCC, 1990). One of these gases CO2 has been increasing in concentration due to additions from anthropogenic sources that are primarily industrial and land use related. The soil contains a very large pool of carbon, estimated at 1550 Gt (Lal 1995) which is larger than the atmospheric and biosphere pools of carbon combined (Greenland, 1995). The flux between the soil and the atmosphere is very large, 60 Pg C/yr (Lal 1997), and is especially important because the soil can act as either a source or a sink for carbon. On any given landscape, as much as 50% of the biomass that provides the major source of carbon can be below ground. In addition, the movement of carbon in and out of the soil is mediated by the living organisms. At present, there is no widespread sampling of soil biomass in any consistent or coordinated manner. Current large scale estimates of soil carbon are limited by the number and widely dispersed nature of the data points available. A measurement of the amount of carbon in the soil would supplement existing carbon data bases as well as provide a benchmark that can be used to determine whether the soil is storing carbon or releasing it to the atmosphere. Information on the below ground biomass would be a valuable addition to our understanding of net primary productivity and standing biomass. The addition of these as special measurements within GLOBE would be unique in terms of areal extent and continuity, and make a real contribution to scientific understanding of carbon dynamics.

Levine, Elissa↗
NASA NTRS1999

Tropical Rainfall Measuring Mission

Tropical rainfall affects the lives and economics of a majority of the Earth's population. Tropical rain systems, such as hurricanes, typhoons, and monsoons, are crucial to sustaining the livelihoods of those living in the tropics. Excess rainfall can cause floods and great property and crop damage, whereas too little rainfall can cause drought and crop failure. The latent heat release during the process of precipitation is a major source of energy that drives the atmospheric circulation. This latent heat can intensify weather systems, affecting weather thousands of kilometers away, thus making tropical rainfall an important indicator of atmospheric circulation and short-term climate change. Tropical forests and the underlying soils are major sources of many of the atmosphere's trace constituents. Together, the forests and the atmosphere act as a water-energy regulating system. Most of the rainfall is returned to the atmosphere through evaporation and transpiration, and the atmospheric trace constituents take part in the recycling process. Hence, the hydrological cycle provides a direct link between tropical rainfall and the global cycles of carbon, nitrogen, and sulfur, all important trace materials for the Earth's system. Because rainfall is such an important component in the interactions between the ocean, atmosphere, land, and the biosphere, accurate measurements of rainfall are crucial to understanding the workings of the Earth-atmosphere system. The large spatial and temporal variability of rainfall systems, however, poses a major challenge to estimating global rainfall. So far, there has been a lack of rain gauge networks, especially over the oceans, which points to satellite measurement as the only means by which global observation of rainfall can be made. The Tropical Rainfall Measuring Mission (TRMM), jointly sponsored by the National Aeronautics and Space Administration (NASA) of the United States and the National Space Development Agency (NASDA) of Japan, provides visible, infrared, and microwave observations of tropical and subtropical rain systems.The satellite observations are complemented by ground radar and rain gauge measurements to validate satellite rain estimation techniques. Goddard Space Flight Center's involvement includes the observatory, four instruments, integration and testing of the observatory, data processing and distribution, and satellite operations. TRMM has a design lifetime of three years. Data generated from TRMM and archived at the GDAAC are useful not only for hydrologists, atmospheric scientists, and climatologists, but also for the health community studying infectious diseases, the ocean research community, and the agricultural community.

Source record↗
NASA NTRS2003

A Chandra X-Ray Study of NGC 1068 IL the Luminous X-Ray Source Population

We present an analysis of the compact X-ray source population in the Seyfert 2 galaxy NGC 1068, imaged with a approx. 50 ks Chandra observation. We find a total of 84 compact sources on the S3 chip, of which 66 are located within the 25.0 B-mag/arcsec isophote of the galactic disk of NGC 1068. Spectra have been obtained for the 21 sources with at least 50 counts and modeled with both multicolor disk blackbody and power-law models. The power-law model provides the better description of the spectrum for 18 of these sources. For fainter sources, the spectral index has been estimated from the hardness ratio. Five sources have 0.4 - 8 keV intrinsic luminosities greater than 10(exp 39)ergs/ s, assuming that their emission is isotropic and that they are associated with NGC 1068. We refer to these sources as intermediate-luminosity X-ray objects (ISOs). If these five sources are X-ray binaries accreting with luminosities that are both sub-Eddington and isotropic, then the implied source masses are approx greater than 7 solar mass, and so they are inferred to be black holes. Most of the spectrally modeled sources have spectral shapes similar to Galactic black hole candidates. However, the brightest compact source in NGC 1068 has a spectrum that is much harder than that found in Galactic black hole candidates and other ISOs. The brightest source also shows large amplitude variability on both short-term and long-term timescales, with the count rate possibly decreasing by a factor of 2 in approx. 2 ks during our Chundra observation, and the source flux decreasing by a factor of 5 between our observation and the grating observations taken just over 9 months later. The ratio of the number of sources with luminosities greater than 2.1 x 10(exp 38) ergs/s in the 0.4 - 8 keV band to the rate of massive (greater than 5 solar mass) star formation is the same, to within a factor of 2, for NGC 1068, the Antennae, NGC 5194 (the main galaxy in M51), and the Circinus galaxy. This suggests that the rate of production of X-ray binaries per massive star is approximately the same for galaxies with currently active star formation, including "starbursts."

Smith, David A.↗
NASA NTRS2004

Latent Heating from TRMM Satellite Measurements

Rainfall production is the fundamental variable within the Earth's hydrological cycle because it is both the principal forcing term in surface water budgets and its energetics corollary, latent heating, is the principal source of atmospheric diabatic heating. Latent heat release itself is a consequence of phase changes between the vapor, liquid, and frozen states of water. The properties of the vertical distribution of latent heat release modulate large-scale meridional and zonal circulations within the tropics - as well as modifying the energetic efficiencies of midlatitude weather systems. This paper focuses on the retrieval of latent heat release from satellite measurements generated by the Tropical Rainfall Measuring Mission (TRMM) satellite observatory, which was launched in November 1997 as a joint American-Japanese space endeavor. Since then, TRMM measurements have been providing an accurate four-dimensional account of rainfall over the global tropics and sub-tropics, information which can be used to estimate the space-time structure of latent heating across the Earth's low latitudes. The paper examines how the observed TRMM distribution of rainfall has advanced an understanding of the global water and energy cycle and its consequent relationship to the atmospheric general circulation and climate via latent heat release. A set of algorithm methodologies that are being used to estimate latent heating based on rain rate retrievals from the TRMM observations are described. The characteristics of these algorithms and the latent heating products that can be generated from them are also described, along with validation analyses of the heating products themselves. Finally, the investigation provides an overview of how TRMM-derived latent heating information is currently being used in conjunction with global weather and climate models, concluding with remarks intended to stimulate further research on latent heating retrieval from satellites.

Tao, Wei-Kuo↗
NASA NTRS2018

Survey of Methods to Predict Controller Workload for Real-Time Monitoring of Airspace Safety

The Real Time Safety Monitoring (RTSM) approach allows for assessment and prediction of the safety margin in the National Airspace System (NAS) to help preempt incidents and accidents, rather than having to reactively mitigate them. In RTSM, the NAS is modeled using state variables, and safety metrics are defined in terms of these state variables. The safety metrics have been classified as weather-related, airspace-related, and human-related. Many of the formulated human-related safety metrics need an estimate of the controller workload for their computation. However, this computation is not trivial. Hence, in this report, we perform a literature survey to identify the different factors that enable the computation of controller workload and categorize these factors. Next, we describe studies undertaken to determine a minimal set of factors that pro- vide a correct assessment of controller workload. Lastly, we survey approaches for evaluating how well the selected factors correlate with the controllers' subjective assessment of their workload. Based on this survey, we present factors beneficial to computing and predicting controller workload in real time, and discuss the status of data sources necessary for these computations.

National Airspace System↗
NASA NTRS2021

Tonlé Sap Food Security and Agriculture: Evaluating the Effects of Land Use and Hydrological Change on Ecosystem Vitality using Remotely-Sensed Data in the Tonlé Sap Lake Basin

Tonlé Sap Lake, the largest lake in Southeast Asia, is a critical source of fish and freshwater resources for the region. The health of this freshwater system is under pressure from accelerating dam construction, intensifying agriculture, deforestation, and changing climate patterns, forcing tradeoffs between immediate food security and the long-term vitality and productivity of the ecosystem. Efficient freshwater system monitoring is crucial to navigating these challenges. In collaboration with Conservation International, the Cambodian Ministry of Water Resources and Meteorology, and the Tonlé Sap Authority, we developed and tested remotely-sensed proxies for sub-indicators of the Freshwater Health Index (FHI), which is typically calculated using in situ datasets. We used landcover datasets derived from Landsat 5 Thematic Mapper (TM), Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), PROBA-V Vegetation sensor (VGT), Sentinel-2 Multispectral Imager (MSI), Advanced Very High Resolution Radiometer (AVHRR), and Envisat Medium Resolution Imaging Spectrometer (MERIS) as inputs to calculate land cover naturalness and bank modification. Additionally, we created a lake-level time series using a collection of altimetry data sources to estimate deviation from natural flow. We observed a decrease in landcover naturalness and a breakdown in the volume and regularity of annual lake levels from 2000-2020, reflecting increased pressure on water supply and agricultural productivity. At least 8% of forested areas in the basin were lost and rice harvest intensity increased over the course of the study period. These results will help our partners make informed decisions regarding freshwater management. Furthermore, our remotely-sensed FHI analysis can be replicated in other regions, providing decision makers with a snapshot of freshwater health in data-scarce environments.

Marco Vallejos↗
DOE OSTI2023

The miniJPAS survey: AGN and host galaxy coevolution of X-ray-selected sources

Studies indicate strong evidence of a scaling relation in the local Universe between the supermassive black hole mass (MBH) and the stellar mass of their host galaxies (M * ). They even show similar histories across cosmic times of their differential terms: the star formation rate (SFR) and black hole accretion rate (BHAR). However, a clear picture of this coevolution is far from being understood. We selected an X-ray sample of active galactic nuclei (AGN) up to z = 2.5 in the miniJPAS footprint. Their X-ray to infrared spectral energy distributions (SEDs) have been modeled with the CIGALE code, constraining the emission to 68 bands, from which 54 are the narrow filters from the miniJPAS survey. For a final sample of 308 galaxies, we derived their physical properties, such as their M * , SFR, star formation history (SFH), and the luminosity produced by the accretion process of the central BH (L AGN ). For a subsample of 113 sources, we also fit their optical spectra to obtain the gas velocity dispersion from the broad emission lines and estimated the M BH . We calculated the BHAR in physical units depending on two radiative efficiency regimes. We find that the Eddington ratios (λ Edd ) and its popular proxy (L X /M * ) have a difference of 0.6 dex, on average, and a KS test indicates that they come from different distributions. Our sources exhibit a considerable scatter on the MBH - M * scaling relation, which can explain the difference between λ Edd and its proxy. We also modeled three evolution scenarios for each source to recover the integral properties at z = 0. Using the SFR and BHAR, we show a notable diminution in the scattering between MBH - M * . For the last scenario, we considered the SFH and a simple energy budget for the AGN accretion, and we retrieved a relation similar to the calibrations known for the local Universe. Our study covers ~1 deg 2 in the sky and is sensitive to biases in luminosity. Nevertheless, we show that, for bright sources, the link between the differential values (SFR and BHAR) and their decoupling based on an energy limit is the key that leads to the local M BH - M * scaling relation. In the future, we plan to extend this methodology to a thousand degrees of the sky using JPAS with an X-ray selection from eROSITA, to obtain an unbiased distribution of BHAR and Eddington ratios.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2016

Using Unmanned Air Systems to Monitor Methane in the Atmosphere

Methane is likely to be an important contributor to global warming, and our current knowledge of its sources, distributions, and transport is insufficient. It is estimated that there could be from 7.5 to 400 billion tons carbon-equivalent of methane in the arctic region, a broad range that is indicative of the uncertainty within the Earth Science community. Unmanned Air Systems (UASs) are often used for combat or surveillance by the military, but they also have been used for Earth Science field missions. In this study, we will analyze the utility of the NASA Global Hawk and the Aurora Flight Sciences Orion UASs compared to the manned DC-8 aircraft for conducting a methane monitoring mission. The mission will focus on the measurement of methane along the boundaries of Arctic permafrost thaw and melting glaciers. The use of Long Endurance UAS brings a new range of possibilities including the ability to obtain long- term and persistent observations and to significantly augment methane measurements/retrievals collected by satellite. Furthermore, we discuss the future of long endurance UAS and their potential for science applications in the next twenty to twenty-five years.

Clow, Jacqueline↗
DOE OSTI2023

The Seismic Signature of a High-Energy Density Physics Laboratory and Its Potential for Measuring Time-Dependent Velocity Structure

The Z Machine at Sandia National Laboratories is a pulsed power facility for high-energy density physics experiments that can shock materials to extreme temperatures and pressures through a focused energy release of up to ~ 25 MJ in < 100 nanoseconds. It has been in operation for more than two decades and conducts up to ~ 100 experiments, or “shots,” per year. Based on a set of 74 known shot times from 2018, we determined that Z Machine shots produce detectable ~ 3–17 Hz ground motion 12 km away at the Albuquerque Seismological Laboratory, New Mexico (ANMO), borehole seismograph, with peak signal at ~ 7 Hz. The known shot waveforms were used to create a three-component template, leading to the detection of 2339 Z Machine shots since 1998 through single-station cross-correlation. Local seismic magnitude estimates range from local magnitude (M L ) —2 to —1.3 and indicate that only a small fraction of the shot energy is transmitted by seismic phases observable at 12 km distance. The most recent major facility renovation, which was intended to decrease mechanical dissipation, is associated with an abrupt decrease in observed seismic amplitudes at ANMO despite stable maximum shot energy. The highly repetitive impulsive sources are well suited to coda-wave interferometry to investigate time-dependent velocity structures. Relative velocity variations (dv/v) show an annual cycle with amplitude of ~ 0.2%. Local minima are observed in the late spring, and dv/v increases through the summer monsoon rainfall, possibly reflecting patchy saturation as rainfall infiltrates near the eastern edge of the Albuquerque basin. Importantly, the cumulative results demonstrate that forensic seismology can provide insight into long-term operation of facilities such as pulsed-power laboratories, and that their recurring signals may be valuable for studies of time-dependent structure

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1994

Structural analysis of airborne flux estimates over a region

Aircraft-based observations of turbulence fields of velocity, moisture, and temperature are used to study coherent turbulent structures that dominate turbulent transfer of moisture and heat above three different eco-systems. Flux traces are defragmented, to reconstruct the presumed full size (along the sampled transect) of these structures, and flux traces are simplified by elimination of those that contribute negligibly to the flux estimate. Structures are analyzed in terms of size, spatial distribution, and contribution to the flux, in the four 'quadrant' modes of eddy-covariance transfer (excess up/down and deficit up/down). The effect of nonlinear detrending of moisture and temperature data on this 'structural analysis,' over surfaces with heterogeneous surface wetness, is also examined. Results over grassland, wetland, and moist and dry agricultural land, show that nonlinear detrending may provide a more physically realistic description of structures. Significant differences are observed between structure size and associated relative flux contribution, between moist and dry areas, with smaller structures playing a more important role over the moist areas. Structure size generally increases with height, as spatial reorganization from smaller structures into larger ones takes place. This coincides with a gradual loss of surface 'signature' (position and clustering of plumes above localized source areas). The data are expected to provide a basis for an eventual statistical description of boundary-layer transfer events , and help to interpret the link between boundary-layer transfer and hydrological surface conditions.

Caramori, Paulo↗
NASA NTRS2016

FTIR Analysis of Water in Pyroxene and Plagioclase in ALH 84001 and Nakhlites

Determining the volatile budget of the interior of Mars is crucial for our understanding of that planet's formation, geodynamics, cooling history and the origin of its volcanism and atmosphere as well as its potential for life. Surficial water is evident from spacecraft and rover data in polar caps and the atmosphere, in the presence of river channels, and in the detection of water-bearing minerals. Meteorites, however, are our best candidates for estimating the amount of water present at depth, even if all are crustal samples. The last 10 years have seen a blooming of studies measuring water and halogens in Martian meteorites. The bulk of these studies target phosphate, a typically late-stage phase in the igneous Martian meteorites that potentially would concentrate incompatible element hydrogen (H quantified traditionally as "water", i.e., H2O concentrations in weight) near the end of the crystallization sequence. However, determining the amount of water, F, and Cl in the magma from which a phosphate crystallized from is not straightforward and in most instances not possible. On the other hand, phosphates have turned out to be very useful in identifying hydrothermal processes that could have added water while or after the magma flowed and crystallized. Another caveat of analyzing Martian meteorite phases for water is that shocked phases such as maskelynite and impact melts appear to have incorporated water from the Martian atmosphere, as evidenced by high H isotope ((delta)D) signatures, and therefore their water concentrations cannot be interpreted in terms of deep planetary processes. The best candidates for estimating the water content of the Martian interior have been melt inclusions (glass or amphibole-bearing) which the enclosing mineral (usually olivine) would have prevented from exchanging volatiles with the surroundings after crystallization. Even some of these, however, have high (delta)D, meaning they were affected by H exchange via impact events or with crustal reservoirs or hydrothermal fluids. Here, nominally anhydrous minerals (pyroxene, olivine, plagioclase, or maskelynite) in orthopyroxenite ALH 84001 and selected nakhlites are analyzed for water and major elements, in order to determine 1) whether they contain any water; 2) if they do, what controls its distribution (crystallization, degassing, hydrothermal or impact processes); and 3) if any of these measurements can be used to infer the water contents of the parent magma and their mantle sources. A shock-reverberation experiment was also performed on terrestrial orthopyroxenes (opx) to simulate the heavily shocked conditions of ALH 84001 (> 31 GPa [17]).

Peslier, A. H.↗
DOE OSTI2024

Photometric redshifts probability density estimation from recurrent neural networks in the DECam local volume exploration survey data release 2

Photometric wide-field surveys are imaging the sky in unprecedented detail. These surveys face a significant challenge in efficiently estimating galactic photometric redshifts while accurately quantifying associated uncertainties. In this work, we address this challenge by exploring the estimation of Probability Density Functions (PDFs) for the photometric redshifts of galaxies across a vast area of 17,000 square degrees, encompassing objects with a median 5 σ point-source depth of g = 24.3, r = 23 . 9 , i = 23.5, and z = 22.8 mag. Our approach uses deep learning, specifically integrating a Recurrent Neural Network architecture with a Mixture Density Network, to leverage magnitudes and colors as input features for constructing photometric redshift PDFs across the whole DECam Local Volume Exploration (DELVE) survey sky footprint. Subsequently, we rigorously evaluate the reliability and robustness of our estimation methodology, gauging its performance against other well-established machine learning methods to ensure the quality of our redshift estimations. Our best results constrain photometric redshifts with the bias of − 0 . 0013 , a scatter of 0.0293, and an outlier fraction of 5.1%. These point estimates are accompanied by well-calibrated PDFs evaluated using diagnostic tools such as Probability Integral Transform and Odds distribution. We also address the problem of the accessibility of PDFs in terms of disk space storage and the time demand required to generate their corresponding parameters.We present a novel Autoencoder model that reduces the size of PDF parameter arrays to one-sixth of their original length, significantly decreasing the time required for PDF generation to one-eighth of the time needed when generating PDFs directly from the magnitudes.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1993

Comprehensive investigation of HgCdTe metalorganic chemical vapor deposition

The principal objective of this experimental and theoretical research program was to explore the possibility of depositing high quality epitaxial CdTe and HgCdTe at very low pressures through metalorganic chemical vapor deposition (MOCVD). We explored two important aspects of this potential process: (1) the interaction of molecular flow transport and deposition in an MOCVD reactor with a commercial configuration, and (2) the kinetics of metal alkyl source gas adsorption, decomposition and desorption from the growing film surface using ultra high vacuum surface science reaction techniques. To explore the transport-reaction issue, we have developed a reaction engineering analysis of a multiple wafer-in-tube ultrahigh vacuum chemical vapor deposition (UHV/CVD) reactor which allows an estimate of wafer or substrate throughput for a reactor of fixed geometry and a given deposition chemistry with specified film thickness uniformity constraints. The model employs a description of ballistic transport and reaction based on the pseudo-steady approximation to the Boltzmann equation in the limit of pure molecular flow. The model representation takes the form of an integral equation for the flux of each reactant or intermediate species to the wafer surfaces. Expressions for the reactive sticking coefficients (RSC) for each species must be incorporated in the term which represents reemission from a wafer surface. The interactions of MOCVD precursors with Si and CdTe were investigated using temperature programmed desorption (TPD) in ultra high vacuum combined with Auger electron spectroscopy (AES). These studies revealed that diethyltellurium (DETe) and dimethylcadmium (DMCd) adsorb weakly on clean Si(100) and desorb upon heating without decomposing. These precursors adsorb both weakly and strongly on CdTe(111)A, with DMCd exhibiting the stronger interaction with the surface than DETe.

Raupp, Gregory B.↗
NASA NTRS2019

Goddard Latent Heating (LH) Retrieval Algorithm

Rainfall production is a fundamental process within the Earth's hydrological cycle because it represents both a principal forcing term in surface water budgets, and its energetics corollary, latent heating, is the principal source of atmospheric diabatic heating. Latent heat release itself is a consequence of phase changes between the vapor, liquid, and frozen states of water. The properties of the vertical distribution of latent heat release modulate large-scale meridional and zonal circulations within the Tropics - as well as modify the energetic efficiencies of mid-latitude weather systems. This paper highlights the retrieval of latent heat release from satellite measurements generated by the Tropical Rainfall Measuring Mission (TRMM) and Global Precipitation Mission (GPM) satellite observatory, which were launched in November 1997 and February 2014, respectively. Both TRMM and GPM measurements have been providing an accurate four-dimensional account of rainfall over the global Tropics and mid-latitudes: information that can be used to estimate the space-time structure of latent heating. Two sets of latent heating retrieval algorithm methodologies (Goddard Convective-Stratiform or CSH, and Japan Spectral Latent Heating or SLH) have been developed to estimate latent heating based on rain rate profile retrievals obtained from TRMM and GPM measurements. The CSH algorithm will be described followed by a discussion its improvements and performance against the combined derived surface ran rates. We will also present the CSH retrieved LH for TRMM and GPM.

Tao, Wei-Kuo↗
NASA NTRS2019

Latent Heating Algorithm

Rainfall production is a fundamental process within the Earth's hydrological cycle because it represents both a principal forcing term in surface water budgets, and its energetics corollary, latent heating, is the principal source of atmospheric diabatic heating. Latent heat release itself is a consequence of phase changes between the vapor, liquid, and frozen states of water. The properties of the vertical distribution of latent heat release modulate large-scale meridional and zonal circulations within the Tropics - as well as modify the energetic efficiencies of mid-latitude weather systems. This paper highlights the retrieval of latent heat release from satellite measurements generated by the Tropical Rainfall Measuring Mission (TRMM) and Global Precipitation Measurement (GPM) Mission satellite observatory, which were launched in November 1997 and February 2014, respectively. Both TRMM and GPM measurements have been providing an accurate four-dimensional account of rainfall over the global Tropics and mid-latitudes: information that can be used to estimate the space-time structure of latent heating.Two sets of latent heating (LH) retrieval algorithm methodologies (Goddard Convective-Stratiform Heating or CSH, and Japan's Spectral Latent Heating or SLH) have been developed to estimate latent heating based on rain rate profile retrievals obtained from TRMM and GPM measurements. The differences and similarities between the CSH and SLH algorithm designs will be presented. The presentation then will provide the results of LH structures derived from the TRMM and GPM. At the end of presentation, the further research on latent heating retrieval from satellites will be discussed.

Tao, Wei-Kuo↗
DOE OSTI2022

Psilocybin: crystal structure solutions enable phase analysis of prior art and recently patented examples

Psilocybin {systematic name: 3-[2-(dimethylamino)ethyl]-1 H -indol-4-yl dihydrogen phosphate} is a zwitterionic tryptamine natural product found in numerous species of fungi known for their psychoactive properties. Following its structural elucidation and chemical synthesis in 1959, purified synthetic psilocybin has been evaluated in clinical trials and has shown promise in the treatment of various mental health disorders. In a recent process-scale crystallization investigation, three crystalline forms of psilocybin were repeatedly observed: Hydrate A, Polymorph A, and Polymorph B. The crystal structure for Hydrate A was solved previously by single-crystal X-ray diffraction. This article presents new crystal structure solutions for the two anhydrates, Polymorphs A and B, based on Rietveld refinement using laboratory and synchrotron X-ray diffraction data, and density functional theory (DFT) calculations. Utilizing the three solved structures, an investigation was conducted via Rietveld method (RM) based quantitative phase analysis (QPA) to estimate the contribution of the three different forms in powder X-ray diffraction (PXRD) patterns provided by different sources of bulk psilocybin produced between 1963 and 2021. Over the last 57 years, each of these samples quantitatively reflect one or more of the hydrate and anhydrate polymorphs. In addition to quantitatively evaluating the composition of each sample, this article evaluates correlations between the crystal forms present, corresponding process methods, sample age, and storage conditions. Furthermore, revision is recommended on characterizations in recently granted patents that include descriptions of crystalline psilocybin inappropriately reported as a single-phase `isostructural variant.' Rietveld refinement demonstrated that the claimed material was composed of approximately 81% Polymorph A and 19% Polymorph B, both of which have been identified in historical samples. In this article, we show conclusively that all published data can be explained in terms of three well-defined forms of psilocybin and that no additional forms are needed to explain the diffraction patterns.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗