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At least 577 records · Page 32

Determination of the thermal stability of perfluoroalkylethers

The thermal decomposition temperatures of several commercial and custom synthesized perfluoroalkylether fluids were determined with a computerized tensimeter. In general, the decomposition temperatures of the commercial fluids were all similar and significantly higher than those for custom synthesized fluids. Correlation of the decomposition temperatures with the molecular structures of the primary components of the commercial fluids revealed that the stability of the fluids is not affected by intrinsic factors such as carbon chain length, branching, or cumulated difluoroformal groups. Instead, correlation with extrinsic factors revealed that the stability may be limited by the presence of small quantities of thermally unstable material and/or chlorine-containing material arising from the use of chlorine-containing solvents during synthesis. Finally, correlation of decomposition temperatures with molecular weights for Demnum and Krytox fluids supports a chain cleavage reaction mechanism for Demnum fluids and an unzipping reaction mechanism for Krytox fluids.

Helmick, Larry S.↗

Modifications to the three-component classification algorithm for SAR data

Previously, a scattering model was used to classify SAR data as due to three mechanisms: surface or odd-bounce scattering; double-bounce scattering; and volume scattering. A Bragg rough-surface model was used for odd-bounce scattering, and two reflecting surfaces, as in a dihedral corner reflector, represented the double-bounce scattering mechanism. A random collection of infinitely thin cylinders was used to model the volume scattering contribution. It was assumed that the cylinders are uniformly oriented in all directions. In this work, modifications are made to the above model, which include specifying a preferred orientation for the cylinders representing branches and using thin cylinders of finite thickness as opposed to infinitely thin ones. In the first case, the preferred orientation is represented by a probability density function in the form of a dirac delta function. For the second case, small argument asymptotic expansions of Bessel functions are used to express the volume scattering contributions in terms of quantities containing the average radius of the cylinders. Since in each case the number of unknowns exceeds that of equations, simplifying assumptions are made. The solutions are applied to multifrequency polarimetric SAR data to obtain the new unknowns in addition to the relative contributions of each scattering mechanism. Several results are presented. It is found that the calculated percentage of each mechanism does not change significantly compared to the original model; however, additional information is gained about the scatterers.

Moghaddam, M.↗

The Right Amount of Glue: Technologies and Standards Relevant to a Future Solar-Terrestrial Data Environment

In order to meet the challenge of developing a new system science, we will need to employ technology that enables researchers to access data from fields with which they are at least initially unfamiliar as well as from sources they use more regularly. At the same time, the quantity of data to be obtained by missions such as the Solar Dynamics Observatory demands ease and simplicity of data access. These competing demands must in turn fit within severely constrained funding for data analysis in such projects. Based on experience in only a single discipline but with a diversity of data types and sources, we will give examples of technology that have made a significant difference in the way people do science. Similarly, we will show how adoption of a well-documented data format has made it easier for one community to search, reduce, and analyze data. We will also describe a community-supported data reduction and analysis software tree with useful features. We will attempt to generalize the lessons learned in these instances to features the broader, solar-terrestrial community might find compelling, while avoiding overdesign of a common data environment.

Gurman, J. B.↗

Relationship between LIBS Ablation and Pit Volume for Geologic Samples: Applications for in situ Absolute Geochronology

In planetary sciences, in situ absolute geochronology is a scientific and engineering challenge. Currently, the age of the Martian surface can only be determined by crater density counting. However this method has significant uncertainties and needs to be calibrated with absolute ages. We are developing an instrument to acquire in situ absolute geochronology based on the K‐Ar method. The protocol is based on the laser ablation of a rock by hundreds of laser pulses. Laser Induced Breakdown Spectroscopy (LIBS) gives the potassium content of the ablated material and a mass spectrometer (quadrupole or ion trap) measures the quantity of 40Ar released. In order to accurately measure the quantity of released 40Ar in cases where Ar is an atmospheric constituent (e.g., Mars), the sample is first put into a chamber under high vacuum. The 40Arquantity, the concentration of K and the estimation of the ablated mass are the parameters needed to give the age of the rocks. The main uncertainties with this method are directly linked to the measures of the mass (typically some μg) and of the concentration of K by LIBS (up to 10%). Because the ablated mass is small compared to the mass of the sample, and because material is redeposited onto the sample after ablation, it is not possible to directly measure the ablated mass. Our current protocol measures the ablated volume and estimates the sample density to calculate ablated mass. The precision and accuracy of this method may be improved by using knowledge of the sample's geologic properties to predict its response to laser ablation, i.e., understanding whether natural samples have a predictable relationship between laser energy deposited and resultant ablation volume. In contrast to most previous studies of laser ablation, theoretical equations are not highly applicable. The reasons are numerous, but the most important are: a) geologic rocks are complex, polymineralic materials; b) the conditions of ablation are unusual (for example, variable vacuum pressure), and c) the ablation is made with hundreds of successive laser pulses. In this work, we aim to understand the effects that occur on LIBS spectra when a homogeneous rock or a mineral is ablated under high vacuum. Understanding these effects is important to define best practices for LIBS measurements and may lead to improved measurement (or possibly prediction) of the ablated volume. We will describe our laboratory approach and first results, and discuss its utility for situ absolute geochronology campaigns.

Devismes, D.↗

MSFC Skylab Apollo Telescope Mount summary mission report

A summary of the Apollo Telescope Mount (ATM) performance during the 8.5-month Skylab mission is presented. A brief description of each ATM system, system performance summaries, discussion of all significant ATM anomalies which occurred during the Skylab mission, and, in an appendix, a summary of the Skylab ATM Calibration Rocket Project (CALROC) are provided. The text is supplemented and amplified by photographs, drawings, curves, and tables. The report shows that the ATM not only met, but exceeded premission performance criteria, and that participation of man in space for this scientific investigation greatly enhanced the quality and quantity of the data attained.

Morse, A. R.↗

SEAPAK user's guide, version 2.0. Volume 1: System description

The SEAPAK is a user interactive satellite data analysis package that was developed for the processing and interpretation of Nimbus-7/Coastal Zone Color Scanner (CZCS) and the NOAA Advanced Very High Resolution Radiometer (AVHRR) data. Significant revisions were made to version 1.0 of the guide, and the ancillary environmental data analysis module was expanded. The package continues to emphasize user friendliness and user interactive data analyses. Additionally, because the scientific goals of the ocean color research being conducted have shifted to large space and time scales, batch processing capabilities for both satellite and ancillary environmental data analyses were enhanced, thus allowing large quantities of data to be ingested and analyzed in background.

Mcclain, Charles R.↗

A fundamental study of suction for Laminar Flow Control (LFC)

This report covers the period forming the first year of the project. The aim is to experimentally investigate the effects of suction as a technique for Laminar Flow Control. Experiments are to be performed which require substantial modifications to be made to the experimental facility. Considerable effort has been spent developing new high performance constant temperature hot-wire anemometers for general purpose use in the Fluid Mechanics Laboratory. Twenty instruments have been delivered. An important feature of the facility is that it is totally automated under computer control. Unprecedently large quantities of data can be acquired and the results examined using the visualization tools developed specifically for studying the results of numerical simulations on graphics works stations. The experiment must be run for periods of up to a month at a time since the data is collected on a point-by-point basis. Several techniques were implemented to reduce the experimental run-time by a significant factor. Extra probes have been constructed and modifications have been made to the traverse hardware and to the real-time experimental code to enable multiple probes to be used. This will reduce the experimental run-time by the appropriate factor. Hot-wire calibration drift has been a frustrating problem owing to the large range of ambient temperatures experienced in the laboratory. The solution has been to repeat the calibrations at frequent intervals. However the calibration process has consumed up to 40 percent of the run-time. A new method of correcting the drift is very nearly finalized and when implemented it will also lead to a significant reduction in the experimental run-time.

Watmuff, Jonathan H.↗

Synoptic/planetary-scale interactions and blocking over the North Atlantic Ocean

The central theme of this project has been the diagnosis of blocking anticyclogenesis and the corresponding interactions with synoptic-scale circulations. To that end an extensive investigation of the dynamics and energetics of a major blocking anticyclone and two upstream cyclones, all of which occurred over the North Atlantic Ocean and the United States in January 1979, was undertaken. Data for the study were provided by Goddard Laboratory for Atmospheres (GLA) 4 LAT by 5 LON FGGE analyses. The methodology has primarily focused on the diagnosis of circulation forcing mechanisms using the modified forms (referred to as the extended forms) of the height tendency and Zwack-Okossi equations developed by our research group. Calculations use routine second-order finite differencing with boundary layer fraction and sensible heating and latent heat release represented as parameterized quantities. Of particular interest are the latent heat release estimates, which combine convectional parameterized values with estimates derived from satellite IR data. The latter were obtained using an algorithm derived by Dr. Franklin R. Robertson of NASA's Marshall Space Flight Center. Results are contained in project reports, theses and publications identified in previous review summaries and reports, and publications listed at the end of this summary. Significant accomplishments in the past year are presented.

Smith, Phillip J.↗

Conceptual design of the 7 megawatt Mod-5B wind turbine generator

Similar to MOD-2, the MOD-5B wind turbine generator system is designed for the sole purpose of providing electrical power for distribution by a major utility network. The objectives of the MOD-2 and MOD-5B programs are essentially identical with one important exception; the cost-of-electricity (COE) target is reduced from 4 cent/Kwhr on MOD-2 to 3 cent/Kwhr on MOD-5B, based on mid 1977 dollars and large quantity production. The MOD-5B concept studies and eventual concept selection confirmed that the program COE targets could not only be achieved but substantially bettered. Starting from the established MOD-2 technology as a base, this achievement resulted from a combination of concept changes, size changes, and design refinements. The result of this effort is a wind turbine system that can compete with conventional power generation over significant geographical areas, increasing commercial market potential by an order of magnitude.

Douglas, R. R.↗

An imaging photoemission polarimeter for soft X-rays

Results of investigations are reviewed to assess the polarization dependence of photoemission in the optical, UV, and soft X-ray bands, as well as present a design for an imaging photoelectric polarimeter. Data regarding the effect of the dependence in the soft X-ray band are emphasized including the quantity of photons produced by each X-ray. The phase shift encountered in some experiments indicates that a third axis is present; the importance of the phase shift in understanding the vectoral photoeffect is emphasized. Measurements of the pulse height show that this measure is proportional to the number of electrons photoemitted by the incident X-ray. The development of X-ray polarimeters can be significantly improved as a result of the study of polarization sensitivity in the photoelectric effect. The design of a photoelectric polarimeter is presented, and the potential uses for the instrument include measuring the polarization of supernova remnants, AGN, and black hole candidates.

Kaaret, Philip↗

Pulmonary function in microgravity

We report the successful collection of a large quantity of human resting pulmonary function data on the SLS-1 mission. Preliminary analysis suggests that cardiac stroke volumes are high on orbit, and that an adaptive reduction takes at least several days, and in fact may still be in progress after 9 days on orbit. It also suggests that pulmonary capillary blood volumes are high, and remain high on orbit, but that the pulmonary interstitium is not significantly impacted. The data further suggest that the known large gravitational gradients of lung function have only a modest influence on single breath tests such as the SBN washout. They account for only approximately 25% of the phase III slope of nitrogen, on vital capacity SBN washouts. These gradients are only a moderate source of the cardiogenic oscillations seen in argon (bolus gas) and nitrogen (resident gas), on such tests. They may have a greater role in generating the normal CO2 oscillations, as here the phase relationship to argon and nitrogen reverses in microgravity, at least at mid exhalation in those subjects studied to date. Microgravity may become a useful tool in establishing the nature of the non-gravitational mechanisms that can now be seen to play such a large part in the generation of intra-breath gradients and oscillations of expired gas concentration. Analysis of microgravity multibreath nitrogen washouts, single breath washouts from more physiological pre-inspiratory volumes, both using our existing SLS-1 data, and data from the upcoming D-2 and SLS-2 missions, should be very fruitful in this regard.(ABSTRACT TRUNCATED AT 250 WORDS).

manned↗

Feasibility Study of SDAS Instrumentation's Ability to Identify Mobile Launcher (ML)/Crawler-Transporter (CT) Modes During Rollout Operations

The Space Launch System (SLS) and its Mobile Launcher (ML) will be transported to the launch pad via the Crawler-Transporter (CT) system. Rollout (i.e., transportation) loads produce structural loads on the integrated SLS/Orion Multi-Purpose Crew Vehicle (MPCV) launch vehicle which are of a concern with respect to fatigue. As part of the risk reduction process and in addition to the modal building block test approach that has been adopted by the SLS Program, acceleration data will be obtained during rollout for use in modal parameter estimation. There are several occurrences where the ML/CT will be transported either into the Vertical Assembly Building (VAB) or to the launch pad and back without the SLS stack as part of the Kennedy Space Center (KSC) Exploration Ground Systems (EGS) Integrated Test and Checkout (ITCO). NASA KSC EGS has instrumentation installed on both the ML and CT to record data during rollout, at the launch pad, and during liftoff. The EGS instrumentation on the ML, which includes accelerometers, is referred to as the Sensor Data Acquisition System (SDAS). The EGS instrumentation on the CT, which also includes accelerometers, is referred to as the CT Data Acquisition System (CTDAS). The forces and accelerations applied to the ML and CT during a rollout event will be higher than any of the planned building block modal tests. This can be very beneficial in helping identify nonlinear behavior in the structure. Developing modal parameters from the same test hardware in multiple boundary conditions and under multiple levels of excitation is a key step in developing a well correlated FEM. The purpose of this study was three fold. First, determine the target modes of the ML/CT in its rollout configuration. Second, determine if the test degrees of freedom (DOF) corresponding to the layout of the SDAS/CTDAS accelerometers (i.e. position and orientation) is sufficient to identify the target modes. Third, determine if the Generic Rollout Forcing Functions (GRFF's) is sufficient for identifying the ML/CT target modes accounting for variations in CT speed, modal damping, and sensor/ambient background noise levels. The finding from the first part of this study identified 28 target modes of the ML/CT rollout configuration based upon Modal Effective Mass Fractions (MEFF) and engineering judgement. The finding from the second part of this study showed that the SDAS/CTDAS accelerometers (i.e. position and orientation) are able to identify a sufficient number of the target modes to support model correlation of the ML/CT FEM. The finding from the third part of this study confirms the GRFFs sufficiently excite the ML/CT such that varying quantities of the defined target modes should be able to be extracted when utilizing an Experimental Modal Analysis (EMA) Multi-Input Multi-Output (MIMO) analysis approach. An EMA analysis approach was used because Operational Modal Analysis (OMA) tools were not available and the GRFFs were sufficiently uncorrelated. Two key findings from this third part of the study are that the CT speed does not show a significant impact on the ability to extract the modal parameters and that keeping the ambient background noise observed at each accelerometer location at or below 30 µgrms is essential to the success of this approach.

Winkel, James P.↗

Studies related to the development of the Viking 1975 labeled release experiment

The labeled release life detection experiment on the Viking 1975 Mars mission is based on the concept that microorganisms will metabolize radioactive organic substrates in a nutrient medium and release radioactive carbon dioxide. Several experiments, using laboratory equipment, were carried out to evaluate various aspects of the concept. Results indicate: (1) label is released by sterilization-treated soil, (2) substantial quantities of label are retained in solution under basic conditions, (3) the substrate used, as well as position of label in the molecule, affect release of label, (4) label release is depressed by radiolytic decomposition of substrates, and (5) About 100,000 organisms are required to produce a detectable response. These results, suggest additional areas for testing, add to the data base for interpretation of flight results, and have significance for broader application of this technique for assessing microbial activity.

Devincenzi, D. L.↗

Pioneer Venus data analysis for the retarding potential analyzer

This report describes the data analysis and archiving activities, analysis results, and instrument performance of the orbiter retarding potential analyzer (ORPA) flown on the Pioneer Venus Orbiter spacecraft during the period, Aug. 1, 1988 to Sept. 30, 1993. During this period, the periapsis altitude of the Orbiter spacecraft descended slowly from 1900 km altitude, at which altitude the spacecraft was outside the Venus ionosphere, to approximately 130 km altitude in Oct. 1992 at which time communication with the spacecraft ceased as a result of entry of the spacecraft into the Venus atmosphere. The quantity of ORPA data returned during this reporting period was greatly reduced over that recovered in the previous years of the mission because of the reduced power capability of the spacecraft, loss of half of the onboard data storage, and partial failure of the ORPA. Despite the reduction in available data, especially ionospheric data, important scientific discoveries resulted from this extended period of the Pioneer Venus mission. The most significant discovery was that of a strong solar cycle change in the size of the dayside ionosphere and the resulting shutoff of flow of dayside ions into the nightside hemisphere. The large, topside O+ F2 ionospheric layer observed during the first three years of the Pioneer Venus mission, a period of solar cycle maximum activity, is absent during the solar cycle minimum activity period.

Knudsen, William C.↗

ROSAT HRI observations of Magellanic Cloud supernova remnants

Analysis of deep ROSAT high resolution imager (HRI) observations of two oxygen-rich supernova remnants (SNR's) in the Magellanic Clouds is described. For N132D, I exploit the limited spectral information provided by the HRI to investigate arcsecond scale spectral variations. I find that there is a region of harder X-ray emission near the southern limb and regions of softer emission near the center and northwestern limb. The remnant is believed to be interacting with a molecular cloud and the harder emission to the south is explained as a result of increased absorption along the line-of-sight there. I argue that the softer emission comes from X-ray emitting material with an enhanced abundance of oxygen. For the second SNR, E0102.2 72.2, the spatial structure is investigated in detail using two-dimensional image fitting techniques. Evidence is found for a ring-like and a spherically symmetric shell-like component both of which were modeled as homogeneous regions. In addition, a significant fraction of the observed flux (approximately 11 percent) must come from a resolved clumped component. A comparison with optical and radio imagery is made to provide a physical basis for the components identified in the X-ray analysis. The mass of X-ray emitting gas in the remnant is estimated and a value of approximately 75 M(solar mass) was determined. The dominant uncertainty on this quantity is the extent of unresolved clumping in the X-ray gas. Such clumping would tend to reduce the mass estimate by f(exp 1/2), where f is the mean volume filling factor of the gas.

Hughes, John P.↗

The kinetic and available potential energy budget of a winter extratropical cyclone system

The energy budget of an extratropical cyclone system which traversed North America and intensified through the period January 9-11, 1975 is presented. The objectives of the study are: (1) to document the complete energy budget of a significant winter cyclone event, and (2) to comment on the significance of latent heat release (LHR) in the cyclone's evolution. Results reveal an overall increase in both kinetic (K) and available potential energy (A). K increases are accounted for by boundary flux convergence of K, while A increases are due to generation by LHR and K to A conversion. In addition, the general A increase is accompanied by a 24 h oscillation that is explained largely by the flux quantity in the A budget equation and is correlated with a similar fluctuation in the K to A conversion. LHR does not appear to be critical in the development of this cyclone system. Rather, LHR acts to increase the intensity of the event. It is hypothesized that the direct influence that LHR had on the deepening cyclone's reduced mass was augmented by an indirect influence, in which pre-existing dry dynamical forcing was enhanced by diabatic heating, thus leading to accelerated cyclone development at a later time.

Smith, P. J.↗

Two-phase measurements of a spray in the wake of a bluff body

The dynamics of spray drop interaction with the turbulent, recirculating wake of a flat disk bluff body were investigated using a phase Doppler particle analyzer to determine drop size and velocity and the gas-phase velocity. Detailed measurements obtained included spray drop size, axial and radial velocity, angle of trajectory, and size-velocity correlations. The gas-phase velocity was determined from seeding of the two-phase flow. Results showed dramatic differences in drop behavior for various size classes when interacting with the turbulent flow field. Small drops were quickly entrained and recirculated, while initially, the larger drops continued in the general direction of the spray cone. Further downstream, significant numbers of large drops recirculated, generating a bifurcated size-velocity correlation. These lateral convections and streamwise accelerations and decelerations strongly influenced the number density along with size and velocity distributions. The complex interaction of the spray with the turbulent air-flow points out the need for spatially-resolved measurements that determine drop behavior for individual size classes, rather than characterizing a spray only via simple integral quantities such as the Sauter mean diameter.

Rudoff, R. C.↗

Condensational growth and trace species scavenging in stratospheric sulfuric acid/water aerosol droplets

Stratospheric aerosols play a significant role in the environment. The composition of aerosols is believed to be a liquid solution of sulfuric acid and water with numerous trace species. Of these trace species, ozone in particular was recognized as being very important in its role of shielding the environment from harmful ultraviolet radiation. Also among the trace species are HCl and ClONO2, the so called chlorine reservoir species and various oxides of nitrogen. The quantity of stratospheric aerosol and its particle size distribution determines, to a large degree, the chemistry present in the stratosphere. Aerosols experience 3 types of growth: nucleation, condensation, and coagulation. The application of condensation investigations to the specific problem of stratospheric aerosols is discussed.

Tompson, Robert V., Jr.↗