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At least 577 records · Page 32

A novel addition polyimide adhesive

An addition polyimide adhesive, LARC 13, was developed which shows promise for bonding both titanium and composites for applications which require service temperatures in excess of 533 K. The LARC 13 is based on an oligomeric bis nadimide containing a meta linked aromatic diamine. The adhesive melts prior to polymerization due to its oligomeric nature, thereby allowing it to be processed at 344 kPa or less. Therefore, LARC 13 is ideal for the bonding of honeycomb sandwich structures. After melting, the resin thermosets during the cure of the nadic endcaps to a highly crosslinked system. Few volatiles are evolved, thus allowing large enclosed structures to be bonded. Preparation of the adhesive as well as bonding, aging, and testing of lap shear and honeycomb samples are discussed.

St.clair, T. L.↗

Characterization of a thermoplastic polyimidesulfone

The detailed characterization of an experimental thermoplastic polyimidesulfone adhesive based on 3,3 prime-diaminodiphenylsulfone and 3,3 prime,4,4 prime-benzophenone tetracarboxylic dianhydride was studied. Model compounds were also examined. Thermal cyclization of the amide-acid to the imide was studied by a variety of techniques including DSC, TGA, MS, in situ diffuse reflectance-FTIR, and flow mearsurement. Characterizations were continued during the processing of adhesive tapes and the fabrication, bonding, and testing of lap shear specimens. Results provide fundamental insights into the role of cure chemistry, and the effects of residual solvent and volatile produces on processing and performance. These insights and the resulting chemical models should lead to more efficient processing cycles for these and other related thermoplastic adhesive systems.

Dezern, J. F.↗

Optimal disturbance suppression with application to wind shear

A novel quadratic cost function composed of stochastic and deterministic contributions is used in the design of a digital flight control system for a small commercial jet with wind shear present. The optimal output feedback control design is configured to suppress the effect of the wind shear disturbance and maintain closed loop stability. A new algorithm is presented for finding the feedback gain. A proportional-integral control design with wind shear suppression is tested in a detailed nonlinear simulation of a commercial jet during the landing approach.

Broussard, J. R.↗

Process optimization of a thermoplastic polyimidesulphone

The detailed characterization of an experimental thermoplastic polyimidesulfane adhesive based on 3,3 prime-diaminodiphenylsulfone and 3,3 prime,4,4 prime-benzophenone tetracarboxylic dianhydride was studied. Model compounds were also examined. Thermal cyclization of the amide-acid to the imide was studied by a variety of techniques including DSC, TGA, MS, in situ diffuse reflectance-FTIR, and flow measurement. Characterizations were continued during the processing of adhesive tapes and the fabrication, bonding, and testing of lap shear specimens. Results provide fundamental insights into the role of cure chemistry, and the effects of residual solvent and volatile produces on processing and performance. These insights and the resulting chemical models should lead to more efficient processing cycles for these and other related thermoplastic adhesive systems.

Dezern, J. F.↗

SEM/XPS analysis of fractured adhesively bonded graphite fibre surface resin-rich/graphite fibre composites

Samples of graphite fiber-reinforced polyimide were fabricated allowing the resin to accumulate at the composite surface. These surface resin-rich composites were then bonded together and tested for lap shear strength both before and after thermal aging. Lap shear strength did not appear to show a significant improvement over that previously recorded for resin-poor samples and was shown to decrease with increasing aging time and temperature.

Devilbiss, T. A.↗

Mechanical properties of 2D and 3D braided textile composites

The purpose of this research was to determine the mechanical properties of 2D and 3D braided textile composite materials. Specifically, those designed for tension or shear loading were tested under static loading to failure to investigate the effects of braiding. The overall goal of the work was to provide a structural designer with an idea of how textile composites perform under typical loading conditions. From test results for unnotched tension, it was determined that the 2D is stronger, stiffer, and has higher elongation to failure than the 3D. It was also found that the polyetherether ketone (PEEK) resin system was stronger, stiffer, and had higher elongation at failure than the resin transfer molding (RTM) epoxy. Open hole tension tests showed that PEEK resin is more notch sensitive than RTM epoxy. Of greater significance, it was found that the 3D is less notch sensitive than the 2D. Unnotched compression tests indicated, as did the tension tests, that the 2D is stronger, stiffer, and has higher elongation at failure than the RTM epoxy. The most encouraging results were from compression after impact. The 3D braided composite showed a compression after impact failure stress equal to 92 percent of the unimpacted specimen. The 2D braided composite failed at about 67 percent of the unimpacted specimen. Higher damage tolerance is observed in textiles over conventional composite materials. This is observed in the results, especially in the 3D braided materials.

Norman, Timothy L.↗

Numerical simulations of solar disturbances and their interplanetary consequences

Time-dependent MHD numerical simulations are used to study responses of the solar atmosphere and interplanetary medium to simulated solar disturbances. A number of 2D and 3D examples of coronal mass ejection (CME) simulations and some current controversies concerning the basic processes of CME initiation are discussed. Footpoint shearing motion is tested to determine whether it can provide a reasonable mechanism for CME development from arch filament configurations. Possible interplanetary consequences to CME-like disturbances are demonstrated by using 3D simulations to determine the dynamic response of the solar wind to a plasmoid injection from an eruptive filament or prominence. The possibility that a plasmoid may be generated in the interplanetary medium by a solar-generated shock that propagates through a heliospheric current sheet is discussed. Application of the 3D model for the interpretation of interplanetary scintillation observations is addressed.

Dryer, M.↗

An instrumented fastener for shear force measurements in joints

A preliminary investigation has been conducted on instrumented fasteners for use as sensors to measure the shear loads transmitted by individual fasteners installed in double-splice joints. Calibration and load verification tests were conducted for instrumented fasteners installed at three fastener torque levels. Results from calibration tests show that the shear strains obtained from the instrumented fasteners vary linearly with the applied load and that the instrumented fasteners can be effectively used to measure shear loads transmitted by individual fasteners installed in double-splice joints. Tests were also conducted with three instumented fasteners installed in a typical double-splice joint. The test results showed that the load distribution between individual fasteners is dependent on the location of the fastener in the joint and the fastener torque level.

Sawyer, J. W.↗

Lightweight Carbon-Carbon High-Temperature Space Radiator

A document summarizes the development of a carbon-carbon composite radiator for dissipating waste heat from a spacecraft nuclear reactor. The radiator is to be bonded to metal heat pipes and to operate in conjunction with them at a temperature approximately between 500 and 1,000 K. A goal of this development is to reduce the average areal mass density of a radiator to about 2 kg/m(exp 2) from the current value of approximately 10 kg/m(exp 2) characteristic of spacecraft radiators made largely of metals. Accomplishments thus far include: (1) bonding of metal tubes to carbon-carbon material by a carbonization process that includes heating to a temperature of 620 C; (2) verification of the thermal and mechanical integrity of the bonds through pressure-cycling, axial-shear, and bending tests; and (3) construction and testing of two prototype heat-pipe/carbon-carbon-radiator units having different radiator areas, numbers of heat pipes, and areal mass densities. On the basis of the results achieved thus far, it is estimated that optimization of design could yield an areal mass density of 2.2 kg/m (exp 2) close to the goal of 2 kg/m(exp 2).

Miller, W.O.↗

Phenylethynyl Terminated Imide (PETI) Composites Made by High Temperature Vartm

The use of composites as primary structures on aerospace vehicles has increased dramatically over the past decade. As these advanced structures increase in size and complexity, their production costs have grown significantly. A major contributor to these manufacturing costs is the requirement of elevated pressures, during high temperature processing, to create fully consolidated composite parts. Recently, NASA Langley has licensed a series of low viscosity Phenyl Ethynyl Terminated Imide, PETI, oligomers that possess a wide processing window to allow for Resin Transfer Molding, RTM, processing. These resins, PETI-8 and PETI-330, demonstrate void fractions of approx.1% under elevated pressure consolidation. However, when used with a standardized thermal curing cycle in a High Temperature Vacuum Assisted RTM (HT-VARTM) process, they display undesirable void contents in excess of 7%. It was determined previously that under the thermal cycles used for laminate fabrication, the phenylethynyl endcap underwent degradation leading to volatile evolution. Modifications to the processing cycle used in the laminate fabrication have reduced the void content significantly (typically less than 3%) for carbon fiber biaxially woven fabric. For carbon fiber uniaxial fabric, void contents of less than 2% have been obtained using both PETI-8 and PETI-330. The resins were infused into carbon fiber preforms at 260 C and cured between 316 C and 371 C. Photomicrographs of the panels were taken and void contents were determined by acid digestion. Mechanical properties of the panels were determined at both room and elevated temperatures. These include short beam shear and flexure tests. The results of this work are presented herein.

Ghose, Sayata↗

Characterization of Hybrid CNT Polymer Matrix Composites

Carbon nanotubes (CNTs) have been studied extensively since their discovery and demonstrated at the nanoscale superior mechanical, electrical and thermal properties in comparison to micro and macro scale properties of conventional engineering materials. This combination of properties suggests their potential to enhance multi-functionality of composites in regions of primary structures on aerospace vehicles where lightweight materials with improved thermal and electrical conductivity are desirable. In this study, hybrid multifunctional polymer matrix composites were fabricated by interleaving layers of CNT sheets into Hexcel® IM7/8552 prepreg, a well-characterized toughened epoxy carbon fiber reinforced polymer (CFRP) composite. The resin content of these interleaved CNT sheets, as well as ply stacking location were varied to determine the effects on the electrical, thermal, and mechanical performance of the composites. The direct-current electrical conductivity of the hybrid CNT composites was characterized by in-line and Montgomery four-probe methods. For [0](sub 20) laminates containing a single layer of CNT sheet between each ply of IM7/8552, in-plane electrical conductivity of the hybrid laminate increased significantly, while in-plane thermal conductivity increased only slightly in comparison to the control IM7/8552 laminates. Photo-microscopy and short beam shear (SBS) strength tests were used to characterize the consolidation quality of the fabricated laminates. Hybrid panels fabricated without any pretreatment of the CNT sheets resulted in a SBS strength reduction of 70 percent. Aligning the tubes and pre-infusing the CNT sheets with resin significantly improved the SBS strength of the hybrid composite To determine the cause of this performance reduction, Mode I and Mode II fracture toughness of the CNT sheet to CFRP interface was characterized by double cantilever beam (DCB) and end notch flexure (ENF) testing, respectively. Results are compared to the control IM7/8552 laminate.

Grimsley, Brian W.↗

Flow Behavior of Particulate Pine Forest Residues and Corn Stover: A Comparison of Experiments and Simulations

Feeding and handling problems have been recognized as a major contributor to low production of renewable cellulosic ethanol in the US, which achieved only 7% of nameplate capacity in 2016. In this work we compare the flow behavior of pine forest residues and corn stover at various particle sizes and moisture contents in instrumented pilot-scale hopper tests and instrumented shear testers to continuum finite element method (FEM) and discrete element method (DEM) models. The shear testers include a Schulze ring shear tester, a custom large Peschl-style tester, and a modified Johanson direct shear tester. In addition to measurements of normal force and torque, the shear testers are also instrumented with arrays of pressure transducers. Modeling approaches include a Drucker-Prager model, a micropolar hypoelasticity model, and DEM simulations employing non-spherical, deformable particles. Results from physical experiments indicate that continuum elastoplastic models, such as Drucker-Prager models, do not account for the full complexity of biomass flow, and that more advanced rheological models are better able to predict nuances of the flow behavior, especially the compressive stress field.

09 BIOMASS FUELS↗

Shear fatigue crack growth - A literature survey

Recent studies of shear crack growth are reviewed, emphasizing test methods and data analyses. The combined mode I and mode II elastic crack tip stress fields are considered. The development and design of the compact shear specimen are described, and the results of fatigue crack growth tests using compact shear specimens are reviewed. The fatigue crack growth tests are discussed and the results of inclined cracks in tensile panels, center cracks in plates under biaxial loading, cracked beam specimens with combined bending and shear loading, center-cracked panels and double edge-cracked plates under cyclic shear loading are examined and analyzed in detail.

Liu, H. W.↗

Polymer matrix and graphite fiber interface study

Hercules AS4 graphite fiber, unsized, or with EPON 828, PVA, or polysulfone sizing, was combined with three different polymer matrices. These included Hercules 3501-6 epoxy, Hercules 4001 bismaleimide, and Hexcel F155 rubber toughened epoxy. Unidirectional composites in all twelve combinations were fabricated and tested in transverse tension and axial compression. Quasi-isotropic laminates were tested in axial tension and compression, flexure, interlaminar shear, and tensile impact. All tests were conducted at both room temperature, dry and elevated temperature, and wet conditions. Single fiber pullout testing was also performed. Extensive scanning electron microphotographs of fracture surfaces are included, along with photographs of single fiber pullout failures. Analytical/experimental correlations are presented, based on the results of a finite element micromechanics analysis. Correlations between matrix type, fiber sizing, hygrothermal environment, and loading mode are presented. Results indicate that the various composite properties were only moderately influenced by the fiber sizings utilized.

Adams, D. F.↗

Methodology for Mechanical Property Testing on Fuel Cladding Using an Expanded Plug Wedge Test

To determine the tensile properties of irradiated fuel cladding in a hot cell, a simple test was developed at ORNL and is described fully in US Patent Application 20060070455, Expanded plug method for developing circumferential mechanical properties of tubular materials. This method is designed for testing fuel rod cladding ductility in a hot cell utilizing an expandable plug to stretch a small ring of irradiated cladding material. The specimen strain is determined using the measured diametrical expansion of the ring. This method removes many complexities associated with specimen preparation and testing. The advantages are the simplicity of measuring the test component assembly in the hot cell and the direct measurement of specimen strain. It was also found that cladding strength could be determined from the test results. The basic approach of this test method is to apply an axial compressive load to a cylindrical plug of polyurethane (or other materials) fitted inside a short ring of the test material to achieve radial expansion of the specimen. The diameter increase of the specimen is used to calculate the circumferential strain accrued during the test. The other two basic measurements are total applied load and amount of plug compression (extension). A simple procedure is used to convert the load circumferential strain data from the ring tests into material pseudo-stress-strain curves. However, several deficiencies exist in this expanded-plug loading ring test, which will impact accuracy of test results and introduce potential shear failure of the specimen due to inherited large axial compressive stress from the expansion plug test. First of all, the highly non-uniform stress and strain distribution resulted in the gage section of the clad. To ensure reliable testing and test repeatability, the potential for highly non-uniform stress distribution or displacement/strain deformation has to be eliminated at the gage section of the specimen. Second, significant compressive stresses were induced by clad bending deformation due to a clad bulging effect (or the barreling effect). The barreling effect caused very large localized shear stress in the clad and left testing material at a high risk of shear failure. The above combined effects will result in highly non-conservative predictions both in strength and ductility of the tested clad, and the associated mechanical properties as well. To overcome/mitigate the mentioned deficiencies associated with the current expansion plug test, systematic studies have been conducted. Through detailed parameter investigation on specific geometry designs, careful filtering of material for the expansion plug, as well as adding newly designed parts to the testing system, a method to reconcile the potential non-conservatism embedded in the expansion plug test system has been discovered. A modified expansion plug testing protocol has been developed based on the method. In order to closely resemble thin-wall theory, a general procedure was also developed to determine the hoop stress $\sigma_\theta$ in the tested ring specimen. A scaling factor called $\chi$-factor is defined to correlate the ring load F ring into hoop stress $\sigma_\theta$, and written as $\sigma_\theta = \chi \frac{F_{ring}} {tl}$. The generated stress-strain curve agrees very well with tensile test data in both the elastic and plastic regions.

expansion plug test↗

Solid Cylinder Torsion for Large Shear Deformation and Failure of Engineering Materials

Using a thin-walled tube torsion test to characterize a material’s shear response is a well-known technique; however, the thin walled specimen tends to buckle before reaching large shear deformation and failure. An alternative technique is the surface stress method (Nadai 1950; Wu et al. J Test Eval 20:396–402, 1992), which derives a shear stress-strain curve from the torque-angular displacement relationship of a solid cylindrical bar. The solid bar torsion test uniquely stabilizes the deformation which allows us to control and explore very large shear deformation up to failure. However, this method has rarely been considered in the literature, possibly due to the complexity of the analysis and experimental issues such as twist measurement and specimen uniformity.

42 ENGINEERING↗

Feeding properties and behavior of hammer- and knife-milled pine

This work reports the rheological characterization of hammer and knife-milled lodgepole pine materials as a function of grind size and moisture content. Characterizations included particle size and shape distributions, bulk density, compressibility at 10 kPa uniaxial pressure, elastic recovery from 10 kPa uniaxial pressure, shear strength, effective angle of internal friction, arching in a custom hopper, and feeding performance in volumetric and gravimetric auger feeders. Particle analysis indicates that the width and length distributions of the 3 mm hammer-milled and the 6 mm knife-milled materials are quite similar, and that all the materials have relatively short aspect ratios (< 4). Compressibility and elastic recovery both increased with increasing moisture content with both values increasing more than 10% and the effect being most severe for the 3 mm grind. Adding 3 kPa of pressure increased the critical arching width for all hopper arching tests, except for the 25 mm grind material with 20% MC, for which the critical arching width actually decreased with increased pressure. Interestingly, for materials with smaller particle sizes, the volumetric feed rate tends to decrease as moisture increases even though the density of the material increases with moisture content and the auger speeds are the same. Time variability of volumetric feed rate increased dramatically with increasing particle size but the impact of moisture content was not as clear. For nearly all tests, gravimetric auger feeding resulted in better feeding control and substantially decreased time variability in the material feed rate. These tests show that material feed rate and volumetric auger feed rate variability are dependent upon material shear strength, bulk density, and particle size. Shear tests indicate that material strength generally decreased with increasing particle size, although the impact of moisture was not entirely consistent.

09 BIOMASS FUELS↗

Test and analysis of Celion 3000/PMR-15, graphite/polyimide bonded composite joints: Summary

Standard single lap, double lap and symmetric step lap bonded joints of Celion 3000/PMR-15 graphite/polyimide composite were evaluated. Composite to composite and composite to titanium joints were tested at 116K (-250 F), 294K (70 F) and 561K (550 F). Joint parameters evaluated were lap length, adherend thickness, adherend axial stiffness, lamina stacking sequence and adherend tapering. Tests of advanced joint concepts were also conducted to establish the change in performance of preformed adherends, scalloped adherends and hybrid systems. Special tests were conducted to establish material properties of the high temperature adhesive, designated A7F, used for bonding. Most of the bonded joint tests resulted in interlaminar shear or peel failures of the composite. There were very few adhesive failures. Average test results agree with expected performance trends for the various test parameters. Results of finite element analyses and of test/analysis correlations are also presented.

Cushman, J. B.↗