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Silicon particles continuously removed from bottom of fluidizedbed reactor when grown to large size. In reactor, silane (SiH4) flows through bed of small silicon seed particles at temperature of 650 degrees to 700 degrees C. Silane decomposes into silicon vapor and hydrogen gas, and vapor deposits as solid on seed particles. With withdrawal system, reactor operates continuously.
The reliability of scanning laser acoustic microscopy (SLAM) for detecting surface voids in structural ceramic test specimens was statistically evaluated. Specimens of sintered silicon nitride and sintered silicon carbide, seeded with surface voids, were examined by SLAM at an ultrasonic frequency of 100 MHz in the as fired condition and after surface polishing. It was observed that polishing substantially increased void detectability. Voids as small as 100 micrometers in diameter were detected in polished specimens with 0.90 probability at a 0.95 confidence level. In addition, inspection times were reduced up to a factor of 10 after polishing. The applicability of the SLAM technique for detection of naturally occurring flaws of similar dimensions to the seeded voids is discussed. A FORTRAN program listing is given for calculating and plotting flaw detection statistics.
It is shown that primary silicon crystals grow polyhedral in super-eutectic AlSi melts and that phosphorus additives to the melt confirm the strong seeding capacity. Primary silicon exhibits strong dendritic seeding effects in eutectic silicon phases of various silicon alloys, whereas primary aluminum does not possess this capacity. Sodium addition also produces a dendritic silicon network growth in the interior of the sample that is attributed to the slower silicon diffusion velocity during cooling.
A technique for aerosol seeding of gas flows by laser-induced particle formation is demonstrated using a pulsed Nd:YAG laser (1.06 microns) for optical breakdown of a mixture of SF6 and H2 in an inert carrier gas. It is noted that, contrary to the smoke-wire approach, the laser-induced particles form first in zones of high turbulence, since mixing enhances coagulation. The method also allows seeding to be performed in locations hardly accessible otherwise and is mechanically nonintrusive. Finally, a study of the mixture and the breakdown effects indicates that for H2:SF6 ratios between 3:1 and 15:1 the particle formation is only limited by the physics of the gas/particle conversion.
The growth of silicon on seed particles from the pyrolysis of silane in a fluidized bed reactor (FBR) was studied. The grown particles were shown to be crystalline and to have a structure which has been interpreted to indicate growth by chemical vapor deposition as well as by the collection (scavenging) of silicon clusters on seed particle surfaces. Scanning electron microscopy was used to study the product morphology.
It is shown experimentally that the seed metals which can cause cone development on ion bombarded metal targets need not to have a lower sputtering yield as widely believed but rather a higher melting point. By lowering the bombarding ion energy to near sputtering threshold values (less than 100 eV) the growth of genuine single crystal whiskers which point in all directions not related to the direction of ion incidence is observed. It is concluded that (intentional or unintentional) seed cones are the result of an interplay among whisker growth, surface movement of atoms, and the effects of sputtering.
An aerosol reactor system was developed in which large particles of silicon can be grown by silane pyrolysis. To grow particles to sizes larger than one micron, vapor deposition must be used to grow a relatively small number of seed particles. Suppression of nucleation is achieved by limiting the rate of gas phase chemical reactions such that the condensible products of the gas phase chemical reactions diffuse to the surface of the seed particles as rapidly as they are produced. This prevents high degrees of supersaturation and runaway nucleation during the growth process. Particles on the order of 10 microns were grown repeatedly with the present aersol reactor. The nucleation controlled aerosol reactor is, therefore, a suitable system for the production of powders that can readily be separated from the gas by aerodynamic means.
The application of laser anemometry to the measurement of turbomachinery flow fields is reviewed. Choices of optical configuration, seed particle generation, and seed injection techniques are discussed. The modification of experimental facilities to gain optical access is considered. The efficiency of data acquisition schemes is analyzed and issues related to data integrity and error estimation are addressed. Data reduction and analysis techniques for extracting and understanding the flow physics from laser anemometer measurements are presented.
The cooled sting technique used to grow triglycine sulphate (TGS) crystals is investigated. The sting procedure, which achieves supersaturation by cooling the seed crystal mounted on the sting is described and a diagram is provided. Temperature differentials of 1.5 and 1.0 C are optimum for growing (001) and (010) orientation TGS seeds. The data obtained are compared with previous data and good correlation is shown; it is inferred that TGS crystals of any orientation can be grown at a uniform rate of 1 mm/day using this technique.
Small scale magnetic field structures or 'flux ropes' observed in the ionosphere of Venus can be interpreted as the result of a kinematic dynamo process acting on weak seed fields. The seed fields result from the prevailing downward convection of magnetic flux from the vicinity of the ionopause, while small scale fluctuations in the velocity of the ionospheric plasma, which can be caused by collisional coupling to gravity waves in the neutral atmosphere, provide the mechanism by which the field is twisted and redistributed into features of similar scale. This mechanism naturally explains some of the average properties of flux ropes such as the variation of their characteristics with altitude and solar zenith angle. It also elucidates the relationship between the large scale and small scale ionospheric magnetic fields.
The reliability of scanning laser acoustic microscopy (SLAM) for detecting surface voids in structural ceramic test specimens was statistically evaluated. Specimens of sintered silicon nitride and sintered silicon carbide, seeded with surface voids, were examined by SLAM at an ultrasonic frequency of 100 MHz in the as fired condition and after surface polishing. It was observed that polishing substantially increased void detectability. Voids as small as 100 micrometers in diameter were detected in polished specimens with 0.90 probability at a 0.95 confidence level. In addition, inspection times were reduced up to a factor of 10 after polishing. The applicability of the SLAM technique for detection of naturally occurring flaws of similar dimensions to the seeded voids is discussed. A FORTRAN program listing is given for calculating and plotting flaw detection statistics.
Experiments to determine whether plant tissue cultures can be grown in the presence of simulated lunar soil (SLS) and the effect of simulated lunar soil on the growth and morphogenesis of such cultures, as well as the effect upon the germination of seeds and the development of seedlings were carried out . Preliminary results on seed germination and seedling growth of rice and calli growth of winged bean and soybean indicate that there is no toxicity or inhibition caused by SLS. SLS can be used as a support medium with supplements of certain major and micro elements.
Wafer level reliability testing has been nurtured in the DARPA supported workshops, held each autumn since 1982. The seeds planted in 1982 have produced an active crop of very large scale integration manufacturers applying wafer level reliability test methods. Computer Aided Reliability (CAR) is a new seed being nurtured. Users are now being awakened by the huge economic value of the wafer reliability testing technology.
Spatial resolution sufficient for calculation of vorticity.In laser-speckle velocimetry, pulsed or chopped laser beam expanded in one dimension by cylindrical lens to illuminate thin, fan-shaped region of flow measured. Flow seeded by small particles. Lens with optical axis perpendicular to illuminating beam forms image of illuminated particles on photographic plate. Speckle pattern of laser-illuminiated, seeded flow recorded in multiple-exposure photographs and processed to extract data on velocity field. Technique suited for study of vortical flows like those about helicopter rotor blades or airplane wings at high angles of attack.
Conditions are optimized for maximum yield and quality of wheat to be used in a controlled environment life support system (CELSS) in a Lunar or Martian base or a spacecraft. With yields of 23 to 57 g/sq m/d of edible biomass, a minimum size for a CELSS would be between 12 and 30 sq m per person, utilizing about 600 W/sq m of electrical energy for artificial light. Temperature, irradiance, photoperiod, carbon dioxide levels, humidity, and wind velocity are controlled in growth chambers. Nutrient solutions (adjusted for wheat) are supplied to the roots via a recirculating system that controls pH by adding HNO3 and controlling the NO3/NH4 ratio in solution. A rock-wool plant support allows direct seeding and densities up to 10,000 plants sq m. Densities up to 2000 plants/sq m appear to increase seed yield. Biomass production increases almost linearily with increasing irradiance from 400 to 1700 micromol/sq m/s of photosynthetic photon flux, but the efficiency of light utilization decreases over this range. Photoperiod and temperature both have a profound influence on floral initiation, spikelet formation, stem elongation, and fertilization.
The present optimization study for maximum yield and quality conditions in the lunar or Martian Controlled Environment Life Support System (CELSS)-based growth of wheat has determined that, for 23-57 g/sq m per day of edible biomass, minimum CELSS size must be of the order of 12-30 sq m/person. About 600 W/sq m of electricity would be consumed by the artificial lighting required; temperature, irradiance, photoperiod, CO2 levels, humidity, and wind velocity are all controlled. A rock wool plant support allows direct seeding, and densities of up to 10,000 plants/sq m. Densities of up to 2000 plants/sq m appear to increase seed yields.
A technology for crystal growth, which overcomes certain shortcomings of other techniques, is developed and its applicability to proteins is examined. There were several unknowns to be determined: the design of the apparatus for suspension of crystals of varying (growing) diameter, control of the temperature and supersaturation, the methods for seeding and/or controlling nucleation, the effect on protein solutions of the temperature oscillations arising from the circulation, and the effect of the fluid shear on the suspended crystals. Extensive effort was put forth to grow lysozyme crystals. Under conditions favorable to the growth of tetragonal lysozyme, spontaneous nucleation could be produced but the number of nuclei could not be controlled. Seed transfer techniques were developed and implemented. When conditions for the orthorhombic form were tried, a single crystal 1.5 x 0.5 x 0.2 mm was grown (after in situ nucleation) and successfully extracted. A mathematical model was developed to predict the flow velocity as a function of the geometry and the operating temperatures. The model can also be used to scaleup the apparatus for growing larger crystals of other materials such as water soluble non-linear optical materials. This crystal suspension technology also shows promise for high quality solution growth of optical materials such as TGS and KDP.
A method for describing the probability of initiating flashover discharges across dielectric surfaces is presented in which a transport coefficient for electron multiplication similar to the Townsend coefficient used for gas discharges is defined. The coefficient is a function of the scaling parameter (charge released from the cathode)/(cathode-anode separation) and is also a measure of the growth of the sheath on the dielectric surface resulting from electron scattering. Results are discussed as to when the source of seed electrons does not necessarily depend upon field emission at the cathode-vacuum-dielectric triple point. For these conditions, there is a different functional dependence of flashover probability on voltage and geometry than when field emission provides the seed electrons. As a result, criteria previously used to predict flashover discharges may not apply.