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NASA NTRS2016

A Compilation of Global Bio-Optical in Situ Data for Ocean-Colour Satellite Applications

A compiled set of in situ data is important to evaluate the quality of ocean-colour satellite-data records. Here we describe the data compiled for the validation of the ocean-colour products from the ESA Ocean Colour Climate Change Initiative (OC-CCI). The data were acquired from several sources (MOBY, BOUSSOLE, AERONET-OC, SeaBASS, NOMAD, MERMAID, AMT, ICES, HOT, GePCO), span between 1997 and 2012, and have a global distribution. Observations of the following variables were compiled: spectral remote-sensing reflectances, concentrations of chlorophyll a, spectral inherent optical properties and spectral diffuse attenuation coefficients. The data were from multi-project archives acquired via the open internet services or from individual projects, acquired directly from data providers. Methodologies were implemented for homogenisation, quality control and merging of all data. No changes were made to the original data, other than averaging of observations that were close in time and space, elimination of some points after quality control and conversion to a standard format. The final result is a merged table designed for validation of satellite-derived ocean-colour products and available in text format. Metadata of each in situ measurement (original source, cruise or experiment, principal investigator) were preserved throughout the work and made available in the final table. Using all the data in a validation exercise increases the number of matchups and enhances the representativeness of different marine regimes. By making available the metadata, it is also possible to analyse each set of data separately. The compiled data are available at doi:10.1594PANGAEA.854832 (Valente et al., 2015).

Valente, Andre↗
NASA NTRS2019

A Compilation of Global Bio-Optical in Situ Data for Ocean-Colour Satellite Applications – Version Two

A global compilation of in situ data is useful to evaluate the quality of ocean-colour satellite data records. Here we describe the data compiled for the validation of the ocean-colour products from the ESA Ocean Colour Climate Change Initiative (OC-CCI). The data were acquired from several sources (including, inter alia, MOBY, BOUSSOLE, AERONETOC, SeaBASS, NOMAD, MERMAID, AMT, ICES, HOT, GeP&CO) and span the period from 1997 to 2018. Observations of the following variables were compiled: spectral remote-sensing reflectances, concentrations of chlorophyll-a, spectral inherent optical properties, spectral diffuse attenuation coefficients and total suspended matter. The data were from multi-project archives acquired via open internet services or from individual projects, acquired directly from data providers. Methodologies were implemented for homogenisation, quality control and merging of all data. No changes were made to the original data, other than averaging of observations that were close in time and space, elimination of some points after quality control and conversion to a standard format. The final result is a merged table designed for validation of satellite-derived ocean-colour products and available in text format. Metadata of each in situ measurement (original source, cruise or experiment, principal investigator) were propagated throughout the work and made available in the final table. By making the metadata available, provenance is better documented, and it is also possible to analyse each set of data separately. This paper also describes the changes that were made to the compilation in relation to the previous version (Valente et al., 2016). The compiled data are available at https://doi.org/10.1594/PANGAEA.898188.

Andre Valente↗
NASA NTRS2016

Monitoring Orbital Precession of EO-1 Hyperion With Three Atmospheric Correction Models in the Libya-4 PICS

Spaceborne spectrometers require spectral-temporal stability characterization to aid in validation of derived data products. Earth Observation 1 (EO-1) began orbital precession in 2011 after exhausting onboard fuel resources. In the Libya-4 pseudo-invariant calibration site (PICS), this resulted in a progressive shift from a mean local equatorial crossing time of approximately10:00 A.M. in 2011 to approximately 8:30 A.M. in late 2015. Here, we studied precession impacts to Hyperion surface reflectance products using three atmospheric correction approaches from 2004 to 2015. Combined difference estimates of surface reflectance were less than 5 percent in the visible near infrared (VNIR) and less than 10 percent for most of the shortwave infrared (SWIR). Combined coefficient of variation estimates in the VNIR ranged from 0.025 to 0.095, and in the SWIR it ranged from 0.025 to 0.06, excluding bands near atmospheric absorption features. Reflectances produced with different atmospheric models were correlated (R squared) in VNIR from 0.25 to 0.94 and in SWIR from 0.12 to 0.88 (p value (calculated probability) less than 0.01). The uncertainties in all the models increased with a terrain slope up to 15 degrees and selecting dune flats could reduce errors. We conclude that these data remain a valuable resource over this period for sensor intercalibration despite orbital decay.

Neigh, Christopher S. R.↗
NASA NTRS1988

Analysis of algorithms for the retrieval of rain-rate profiles from a spaceborne dual-wavelength radar

The ability to retrieve rain-rate profiles from a dual-wavelength spaceborne radar system operating at 13.6 and 35 GHz is analyzed. The fundamental problem of extracting either the attenuation and/or the reflectivity from the backscatter echo, which contains both contributions, is addressed. Three algorithms, the backscatter, the attenuation coefficient, and the dual-wavelength methods, are examined. These algorithms are tested using four rain-rate profiles derived from radar measurements. In particular, measured (true) values are compared with calculated (retrieved) rain rates applying the algorithms with superimposed uncertainties assuming a suggested spaceborne dual-wavelength radar system. Error values of rain rates are determined where these values reflect failure of the assumptions utilized in the derivation of the algorithms, rain backscatter noise, and instrument noise. It is concluded that no single technique gives rise to a panacea in the making of accurate rain measurements and that difficulties exist with each method.

Goldhirsh, Julius↗
NASA NTRS1975

Signature extension for sun angle, volume 1

The author has identified the following significant results. Within a restricted zenith sun angle range of 35 - 50 degrees, it was empirically observed that canopy reflectance is mainly Lambertian. Reflectance changes with crop stage were simple shifts in scale in the sun angle range. It was noted that sun angle variations depend on canopy characteristics. Effects of the vegetative canopy were most pronounced at the larger solar zenith angles (20 %). The linear sun angle correction coefficients demonstrate a dependency on both crop stage (15-20 %) and crop type (10-20 %). The use of canopy reflectance modeling allowed for the generation of a simulated data set over an extremely broad envelope of sun angles.

Smith, J. A.↗
NASA NTRSDate not supplied

Additional Characterization of Sonoran Pics in Support of A Stable Multi-Sensor Geostationary Imager Record

The Sonoran Desert is the most utilized Pseudo Invariant Calibration Site (PICS) located in the Americas for post-launch radiometer drift monitoring and sensor pair radiometric scaling. The Sonoran Desert is located near the US Arizona and Mexican border with an elevation of 37 m. The site has small spatial and angular variations; however, soil moisture can cause short- term periodic reflectance fluctuations. The NASA Clouds and the Earth’s Radiant Energy System (CERES) project utilizes the site to validate the GOES East and West imager calibration coefficients derived from inter-calibrating GOES with MODIS. Because the daily local noon angular solar and viewing angles repeat every year over the site, a daily exoatmospheric radiance model (DERM) can be constructed over the lifetime of a well-calibrated GOES sensor. DERM based on a well-calibrated GOES imager can then be used to determine the calibration coefficients of successive GOES imagers to provide a stable multi-sensor GOES imager record. This will ensure that the GOES retrieved clouds and derived broadband fluxes can be used to infer the regional diurnal cycle in between Terra and Aqua CERES measurements to accurately compute the daily mean regional fluxes and clouds over the 20-year CERES SYN1deg product. Although the Sonoran Desert surface reflectance and atmospheric column vary seasonally, the inter-annual variability of the seasonal cycle is small, but it adds noise to the resulting DERM calibration coefficients. We seek to reduce the uncertainty of the DERM approach by improving the clear-sky filtering and correlating the observed interannual reflectance variability with atmospheric parameters, such as precipitable water, ozone concentration, and aerosol optical depth. The additional characterization of the Sonoran Desert site DERM for both the GOES East and West positions should improve the accuracy of the CERES SYN1deg product clouds and fluxes.

Prathana Khakurel↗
NASA NTRS1995

Extinction coefficient (1 micrometer) properties of high-altitude clouds from solar occultation measurements (1985-1990): Evidence of volcanic aerosol effect

The properties of the 1-micrometer volume extinction coefficient of two geographically different high-altitude cloud systems have been examined for the posteruption period (1985-1990) of the April 1982 El Chichon volcanic event with emphasis on the effect of volcanic aerosols on clouds. These two high-altitude cloud systems are the tropical clouds in the tropopause region observed by the Stratospheric Aerosol and Gas Experiment (SAGE) 2 and the polar stratospheric clouds (PSCs) sighted by the Stratospheric Aerosol Measurement (SAM) 2. The results indicate that volcanic aerosols alter the frequency distributions of these high-altitude clouds in such a manner that the occurrence of clouds having high extinction coefficients (6 x 10(exp -3) - 2 x 10(exp -2)/km) is suppressed, while that of clouds having low extinction coefficients (2 x 10(exp -3) - 6 x 10(exp -2)/km) is enhanced. This influence of the volcanic aerosols appears to be opposite to the increase in the extinction coefficient of optically thick clouds observed by the Earth Radiation Budget Experiment (ERBE) during the initial posteruption period of the June 1991 Pinatubo eruption. A plausible explanation of this difference, based on the Mie theory, is presented. As a consequence of the Mie theory, the effective radius of most, if not all, of the high-altitude clouds, measured by the SAGE series of satellite instruments must be less than about 0.8 micrometers. This mean cloud particle size implied by the satellite extinction-coefficient data at a single wavelength (1 micrometer) is further substantiated by the particle size analysis based on cloud extinction coefficient at two wavelengths (0.525 and 1.02 micrometers) obtained by the SAGE 2 observations. Most of the radiation measured by ERBE is reflected by cloud systems comprised of particles having effective radii much greater than 1 micrometer. A reduction in the effective radius of these clouds due to volcanic aerosols is expected to increase their extinction-coefficient values, opposite the effect observed by SAGE 2 and SAM 2. This work further illustrates the capability of the solar occultation satellite sensor to provide particulate extinction-coefficient measurements important to the study of the aerosol-cloud interactions. It is important to examine the variations of the extinction coefficient of these two high-altitude cloud systems for the posteruption years of the Pinatubo volcanic event for further evidence of the impact of volcanic aerosols on high-altitude clouds.

Wang, Pi-Huan↗
NASA NTRS2015

Improved Discrete Ordinate Solutions in the Presence of an Anisotropically Reflecting Lower Boundary: Upgrades of the DISORT Computational Tool

A successor version 3 of DISORT (DISORT3) is presented with important upgrades that improve the accuracy, efficiency, and stability of the algorithm. Compared with version 2 (DISORT2 released in 2000) these upgrades include (a) a redesigned BRDF computation that improves both speed and accuracy, (b) a revised treatment of the single scattering correction, and (c) additional efficiency and stability upgrades for beam sources. In DISORT3 the BRDF computation is improved in the following three ways: (i) the Fourier decomposition is prepared "off-line", thus avoiding the repeated internal computations done in DISORT2; (ii) a large enough number of terms in the Fourier expansion of the BRDF is employed to guarantee accurate values of the expansion coefficients (default is 200 instead of 50 in DISORT2); (iii) in the post processing step the reflection of the direct attenuated beam from the lower boundary is included resulting in a more accurate single scattering correction. These improvements in the treatment of the BRDF have led to improved accuracy and a several-fold increase in speed. In addition, the stability of beam sources has been improved by removing a singularity occurring when the cosine of the incident beam angle is too close to the reciprocal of any of the eigenvalues. The efficiency for beam sources has been further improved from reducing by a factor of 2 (compared to DISORT2) the dimension of the linear system of equations that must be solved to obtain the particular solutions, and by replacing the LINPAK routines used in DISORT2 by LAPACK 3.5 in DISORT3. These beam source stability and efficiency upgrades bring enhanced stability and an additional 5-7% improvement in speed. Numerical results are provided to demonstrate and quantify the improvements in accuracy and efficiency of DISORT3 compared to DISORT2.

Lin, Z.↗
NASA NTRS1992

Predicting equilibrium states with Reynolds stress closures in channel flow and homogeneous shear flow

Turbulent channel flow and homogeneous shear flow have served as basic building block flows for the testing and calibration of Reynolds stress models. A direct theoretical connection is made between homogeneous shear flow in equilibrium and the log-layer of fully-developed turbulent channel flow. It is shown that if a second-order closure model is calibrated to yield good equilibrium values for homogeneous shear flow it will also yield good results for the log-layer of channel flow provided that the Rotta coefficient is not too far removed from one. Most of the commonly used second-order closure models introduce an ad hoc wall reflection term in order to mask deficient predictions for the log-layer of channel flow that arise either from an inaccurate calibration of homogeneous shear flow or from the use of a Rotta coefficient that is too large. Illustrative model calculations are presented to demonstrate this point which has important implications for turbulence modeling.

Abid, R.↗
NASA NTRS1993

Predicting equilibrium states with Reynolds stress closures in channel flow and homogeneous shear flow

Turbulent channel flow and homogeneous shear flow have served as basic building block flows for the testing and calibration of Reynolds stress models. A direct theoretical connection is made between homogeneous shear flow in equilibrium and the log-layer of fully-developed turbulent channel flow. It is shown that if a second-order closure model is calibrated to yield good equilibrium values for homogeneous shear flow it will also yield good results for the log-layer of channel flow provided that the Rotta coefficient is not too far removed from one. Most of the commonly used second-order closure models introduce an ad hoc wall reflection term in order to mask deficient predictions for the log-layer of channel flow that arise either from an inaccurate calibration of homogeneous shear flow or from the use of a Rotta coefficient that is too large. Illustrative model calculations are presented to demonstrate this point which has important implications for turbulence modeling.

Abid, R.↗
NASA NTRS1980

Reducing the error of geoid undulation computations by modifying Stokes' function

The truncation theory as it pertains to the calculation of geoid undulations based on Stokes' integral, but from limited gravity data, is reexamined. Specifically, the improved procedures of Molodenskii et al. are shown through numerical investigations to yield substantially smaller errors than the conventional method that is often applied in practice. In this improved method, as well as in a simpler alternative to the conventional approach, the Stokes' kernel is suitably modified in order to accelerate the rate of convergence of the error series. These modified methods, however, effect a reduction in the error only if a set of low-degree potential harmonic coefficients is utilized in the computation. Consider, for example, the situation in which gravity anomalies are given in a cap of radius 10 deg and the GEM 9 (20,20) potential field is used. Then, typically, the error in the computed undulation (aside from the spherical approximation and errors in the gravity anomaly data) according to the conventional truncation theory is 1.09 m; with Meissl's modification it reduces to 0.41m, while Molodenskii's improved method gives 0.45 m. A further alteration of Molodenskii's method is developed and yields an RMS error of 0.33 m. These values reflect the effect of the truncation, as well as the errors in the GEM 9 harmonic coefficients. The considerable improvement, suggested by these results, of the modified methods over the conventional procedure is verified with actual gravity anomaly data in two oceanic regions, where the GEOS-3 altimeter geoid serves as the basis for comparison. The optimal method of truncation, investigated by Colombo, is extremely ill-conditioned. It is shown that with no corresponding regularization, this procedure is inapplicable.

Jekeli, C.↗
NASA NTRS1980

Tribological properties of sputtered MoS sub 2 films in relation to film morphology

Thin sputter deposited MoS2 films in the 2000 to 6000 A thickness range have shown excellent lubricating properties, when sputtering parameters and substrate conditions are properly selected and precisely controlled. The lubricating properties of sputtered MoS2 films are strongly influenced by their crystalline-amorphous structure, morphology and composition. The coefficient of friction can range from 0.04 which is effective lubrication to 0.4 which reflects an absence of lubricating properties. Visual screening and slight wiping of the as-sputtered MoS2 film can identify the integrity of the film. An acceptable film displays a black-sooty surface appearance whereas an unacceptable film has a highly reflective, gray surface and the film is hard and brittle.

Spalvins, T.↗
NASA NTRS1989

State-of-the-art fiber optics for short distance frequency reference distribution

A number of recently developed fiber-optic components that hold the promise of unprecedented stability for passively stabilized frequency distribution links are characterized. These components include a fiber-optic transmitter, an optical isolator, and a new type of fiber-optic cable. A novel laser transmitter exhibits extremely low sensitivity to intensity and polarization changes of reflected light due to cable flexure. This virtually eliminates one of the shortcomings in previous laser transmitters. A high-isolation, low-loss optical isolator has been developed which also virtually eliminates laser sensitivity to changes in intensity and polarization of reflected light. A newly developed fiber has been tested. This fiber has a thermal coefficient of delay of less than 0.5 parts per million per deg C, nearly 20 times lower than the best coaxial hardline cable and 10 times lower than any previous fiber-optic cable. These components are highly suitable for distribution systems with short extent, such as within a Deep Space Communications Complex. Here, these new components are described and the test results presented.

Lutes, G. F.↗
NASA NTRS2012

Acoustics Reflections of Full-Scale Rotor Noise Measurements in NFAC 40- by 80-Foot Wind Tunnel

The objective of current research is to identify the extent of acoustic time history distortions due to wind tunnel wall reflections. Acoustic measurements from the recent full-scale Boeing-SMART rotor test (Fig. 2) will be used to illustrate the quality of noise measurement in the NFAC 40- by 80-Foot Wind Tunnel test section. Results will be compared to PSU-WOPWOP predictions obtained with and without adjustments due to sound reflections off wind tunnel walls. Present research assumes a rectangular enclosure as shown in Fig. 3a. The Method of Mirror Images7 is used to account for reflection sources and their acoustic paths by introducing mirror images of the rotor (i.e. acoustic source), at each and every wall surface, to enforce a no-flow boundary condition at the position of the physical walls (Fig. 3b). While conventional approach evaluates the "combined" noise from both the source and image rotor at a single microphone position, an alternative approach is used to simplify implementation of PSU-WOPWOP for this reflection analysis. Here, an "equivalent" microphone position is defined with respect to the source rotor for each mirror image that effectively renders the reflection analysis to be a one rotor, multiple microphones problem. This alternative approach has the advantage of allowing each individual "equivalent" microphone, representing the reflection pulse from the associated wall surface, to be adjusted by the panel absorption coefficient illustrated in Fig. 1a. Note that the presence of parallel wall surfaces requires an infinite number of mirror images (Fig. 3c) to satisfy the no-flow boundary conditions. In the present analysis, up to four mirror images (per wall surface) are accounted to achieve convergence in the predicted time histories

Barbely, Natasha Lydia↗
NASA NTRS2018

Remote Sensing of CDOM, CDOM Spectral Slope, and Dissolved Organic Carbon in the Global Ocean

A Global Ocean Carbon Algorithm Database (GOCAD) has been developed from over 500 oceanographic field campaigns conducted worldwide over the past 30 years including in situ reflectances and coincident satellite imagery, multi- and hyperspectral Chromophoric Dissolved Organic Matter (CDOM) absorption coefficients from 245–715 nm, CDOM spectral slopes in eight visible and ultraviolet wavebands, dissolved and particulate organic carbon (DOC and POC, respectively), and inherent optical, physical, and biogeochemical properties. From field optical and radiometric data and satellite measurements, several semi-analytical, empirical, and machine learning algorithms for retrieving global DOC, CDOM, and CDOM slope were developed, optimized for global retrieval, and validated. Global climatologies of satellite-retrieved CDOM absorption coefficient and spectral slope based on the most robust of these algorithms lag seasonal patterns of phytoplankton biomass belying Case 1 assumptions, and track terrestrial runoff on ocean basin scales. Variability in satellite retrievals of CDOM absorption and spectral slope anomalies are tightly coupled to changes in atmospheric and oceanographic conditions associated with El Niño Southern Oscillation (ENSO), strongly covary with the multivariate ENSO index in a large region of the tropical Pacific, and provide insights into the potential evolution and feedbacks related to sea surface dissolved carbon in a warming climate. Further validation of the DOC algorithm developed here is warranted to better characterize its limitations, particularly in mid-ocean gyres and the southern oceans.

Dissolved organic carbon↗
NASA NTRS1980

Visible spectral reflectance measurements /0.33-1.1 microns/ of the Galilean satellites at many orbital phase angles

One hundred eighty-seven reflectance spectra (0.33-1.10 microns) of the Galilean satellites have been obtained. Solar phase angle color correction coefficients were derived and the spectra corrected to a solar phase of 6 deg. Solar phase angle coefficients beyond 0.55 micron are presented for the first time. The spectra as a function of orbital phase angle are presented in the form of images to display hemispheric spectral variations. Io and Europa are redder on their trailing hemispheres while Callisto is redder on its leading hemisphere. Ganymede shows small longitudinal color variations despite the complex albedo structure visible in Voyager images. Comparisons of these data with previous measurements reveal that most differences can be attributed to the solar calibration. Reflectance measurements of Io at 0.73 micron observed 8.5 years apart show a 6% global reflectance decrease. However, it is difficult to unambiguously attribute this particular decrease in reflectance to a change in Io's surface composition.

Mcfadden, L. A.↗
NASA NTRS1995

Shock Tube and Modeling Study of the H + O2 = OH + O Reaction over a Wide Range of Composition, Pressure, and Temperature

The rate coefficient of the reaction H + 02 = OH + 0 was determined using OH laser absorption spectroscopy behind reflected shock waves over the temperature range 1050-2500 K and the pressure range 0.7-4.0 atm. Eight mixtures and three stoichiometries were used. Two distinct and independent criteria were employed in the evaluation of k(sub 1). Our recommended expression for k(sub 1) is k(sub 1) = 7.13 x 10(exp 13)exp(-6957 K/T) cm(exp 3)mol(exp -1)s(exp -1) with a statistical uncertainty of 6%. A critical review of recent evaluations of k(sub 1) yields a consensus expression given by k(sub 1) = 7.82 x 10(exp 13)exp(-7105 K/7) cm(exp 3)mol(exp -1)s(exp -1) over the temperature range 960-5300 K. We do not support a non-Arrhenius rate coefficient expression, nor do we find evidence of composition dependence upon the determination of k(sub 1).

Ryu, Si-Ok↗
NASA NTRS2012

Calibration of VIIRS F1 Sensor Fire Detection Band Using lunar Observations

Visible Infrared Imager Radiometer Suite (VIIRS) Fight 1 (Fl) sensor includes a fire detection band at roughly 4 microns. This spectral band has two gain states; fire detection occurs in the low gain state above approximately 345 K. The thermal bands normally utilize an on-board blackbody to provide on-orbit calibration. However, as the maximum temperature of this blackbody is 315 K, the low gain state of the 4 micron band cannot be calibrated in the same manner as the rest of the thermal bands. Regular observations of the moon provide an alternative calibration source. The lunar surface temperature has been recently mapped by the DIVINER sensor on the LRO platform. The periodic on-board high gain calibration along with the DIVINER surface temperatures was used to determine the emissivity and solar reflectance of the lunar surface at 4 microns; these factors and the lunar data are then used to fit the low gain calibration coefficients of the 4 micron band. Furthermore, the emissivity of the lunar surface is well known near 8.5 microns due to the Christiansen feature (an emissivity maximum associated with Si-O stretching vibrations) and the solar reflectance is negligible. Thus, the 8.5 micron band is used for relative calibration with the 4 micron band to de-trend any temporal variations. In addition, the remaining thermal bands are analyzed in a similar fashion, with both calculated emissivities and solar reflectances produced.

McIntire, Jeff↗