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At least 577 records · Page 32

Signatures of Cooper pair dynamics and quantum-critical superconductivity in tunable carrier bands

Different superconducting pairing mechanisms are markedly distinct in the underlying Cooper pair kinematics. Quantum-critical soft modes drive pairing interactions in which the pair scattering processes are highly collinear and can be classified into two categories: forward scattering and backscattering. Conversely, in conventional phonon mechanisms, Cooper pair scattering is of a generic noncollinear character. In this study, we present a method to discern the kinematic type by observing the evolution of superconductivity while adjusting the Fermi surface geometry. To demonstrate our approach, we utilize the recently reported phase diagrams of untwisted graphene multilayers. Our analysis connects the emergence of superconductivity at “ghost crossings” of Fermi surfaces in distinct valleys to the pair kinematics of a backscattering type. Together with the observed nonmonotonic behavior of superconductivity near its onset (sharp rise followed by a drop), it lends strong support to a particular quantum-critical superconductivity scenario in which pairing is driven by intervalley coherence fluctuations. These findings offer direct insights into the genesis of pairing in these systems, providing compelling evidence for the electron–electron interactions driving superconductivity. More broadly, our work highlights the potential of tuning bands via ghost crossings as a promising means of boosting superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Structure in the nucleus of NGC 1068 at 10 microns

New 8-13 micron array camera images of the central kiloparsec of Seyfert 2 galaxy NGC 1068 resolve structure that is similar to that observed at visible and radio wavelengths. The images reveal an infrared source which is extended and asymmetric, with its long axis oriented at P.A. 33 deg. Maps of the spatial distribution of 8-13 micron color temperature and warm dust opacity are derived from the multiwavelength infrared images. The results suggest that there exist two pointlike luminosity sources in the central region of NGC 1068, with the brighter source at the nucleus and the fainter one some 100 pc to the northeast. This geometry strengthens the possibility that the 10 micron emission observed from grains in the nucleus is powered by a nonthermal source. In the context of earlier visible and radio studies, these results considerably strengthen the case for jet-induced star formation in NGC 1068.

Tresch-Fienberg, R.↗

Structure in the nucleus of NGC 1068 at 10 microns

New 8 to 13 micron array camera images of the central kiloparsec of Seyfert 2 galaxy NGC 1068 resolve structure that is similar to that observed at visible and radio wavelengths. The images reveal an infrared source which is extended and asymmetric, with its long axis oriented at P.A. 33 deg. Maps of the spatial distribution of 8 to 13 micron color temperature and warm dust opacity are derived from the multiwavelength infrared images. The results suggest that there exist two pointlike luminosity sources in the central regions of NGC 1068, with the brighter source at the nucleus and the fainter one some 100 pc to the northeast. This geometry strengthens the possibility that the 10 micron emission observed from grains in the nucleus is powered by a nonthermal source. In the context of earlier visible and radio studies, these results considerably strengthen the case for jet induced star formation in NGC 1068.

Tresch-Fienberg, R.↗

The Plasma Wave Environment of Europa

The Galileo spacecraft has executed nine close flybys of Jupiter's moon Europa for which plasma wave observations were obtained. This paper presents an analysis of the observations from these flybys taking into consideration the variable geometry of the trajectories in an attempt to characterize the general plasma-wave environment associated with the interaction of the Jovian magnetosphere with the moon. A wide variety of plasma-wave phenomena are found to be associated with this interaction. While there are apparently temporal variations which complicate the analysis, a crude model of the distribution of these phenomena around Europa is derived. Primarily on the upstream side of Europa, and working inward to the moon, electron-cyclotron harmonics are first observed, followed by a region within about two Europa radii of the moon with whistler-mode hiss or chorus, and culminating in a region closest to the moon where a band at the upper hybrid resonance frequency is sometimes enhanced over its ambient intensity. The wake region is approximately two Europa radii across and comprises a broadband, highly variable, and bursty electrostatic phenomenon. Upon closer inspection, these bursty emissions appear as solitary structures similar to those in Earth's auroral zone and plasma sheet boundary layer. In addition to the survey of wave phenomena in the vicinity of Europa, we provide density profiles derived primarily from the upper hybrid resonance frequency which is readily apparent throughout most of each of the flybys. Finally, we suggest that the whistler mode, electron cyclotron harmonic, and upper hybrid resonance emissions are driven by some combination of factors including variations in the magnetic field near Europa and the loss and production of plasma at Europa as a result of the interaction of the Jovian magnetosphere with the moon. By analogy with studies of the ion and electron holes and broadband electrostatic noise at Earth and Jupiter, we argue that the electrostatic solitary structures in the wake are associated with currents and beams coupling Europa to Jupiter's ionosphere.

Kurth, W. S.↗

Th 2 O – , Th 2 Au – , and Th 2 AuO 1,2 – Anions: Photoelectron Spectroscopic and Computational Characterization of Energetics and Bonding

The observation and characterization of the anions: Th 2 O – , Th 2 Au – , and Th 2 AuO 1,2 – is reported. These species were studied through a synergetic combination of anion photoelectron spectroscopy and ab initio correlated molecular orbital theory calculations at the CCSD(T) level with large correlation-consistent basis sets. To better understand the energetics and bonding in these anions and their corresponding neutrals, a range of smaller diatomic to tetratomic species were studied computationally. Correlated molecular orbital theory calculations at the CCSD(T) level showed that in most of these cases, there are close-lying anions and neutral clusters with different geometries and spin states and are consistent with the experimentally observed spectra. Thus, comparison of experimentally determined and computationally predicted vertical detachment energies and electron affinities for different optimized geometries and spin states shows excellent agreement to within 0.1 eV. The structures for both the neutrals and anions have a significant ionic component to the bonding because of the large electron affinity of the Au atom and modest ionization potentials for Th 2 , Th 2 O, and Th 2 O 2 . The analysis of the bonding for the Th–Th bonds from the molecular orbitals is consistent with this ionic model. The results show that there is a wide variation in the bond distance from 2.7 to 3.5 Å for the Th–Th bonds all of which are less than twice the atomic radius of Th of 3.6 Å. The bond distances encompass bond orders from 4 to 0. Furthermore, there can be different bond orders for the same bond distance depending on the nature of the ionic bonding suggesting that one may not be able to correlate the bond order with the bond distance in these types of clusters. In addition, the presence of an Au atom may provide a unique probe of the bonding in such clusters because of its ability to accept an electron from clusters with modest ionization potentials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Energetic Electrons Accelerated and Trapped in a Magnetic Bottle above a Solar Flare Arcade

Where and how flares efficiently accelerate charged particles remains an unresolved question. Recent studies revealed that a “magnetic bottle” structure, which forms near the bottom of a large-scale reconnection current sheet above the flare arcade, is an excellent candidate for confining and accelerating charged particles. However, further understanding its role requires linking the various observational signatures to the underlying coupled plasma and particle processes. Here we present the first study combining multiwavelength observations with data-informed macroscopic magnetohydrodynamics and particle modeling in a realistic eruptive flare geometry. The presence of an above-the-loop-top magnetic bottle structure is strongly supported by the observations, which feature not only a local minimum of magnetic field strength but also abruptly slowing plasma downflows. It also coincides with a compact above-the-loop-top hard X-ray source and an extended microwave source that bestrides the flare arcade. Spatially resolved spectral analysis suggests that nonthermal electrons are highly concentrated in this region. Our model returns synthetic emission signatures that are well matched to the observations. The results suggest that the energetic electrons are strongly trapped in the magnetic bottle region due to turbulence, with only a small fraction managing to escape. The electrons are primarily accelerated by plasma compression and facilitated by a fast-mode termination shock via the Fermi mechanism. Our results provide concrete support for the magnetic bottle as the primary electron acceleration site in eruptive solar flares. They also offer new insights into understanding the previously reported small population of flare-accelerated electrons entering interplanetary space.

79 ASTRONOMY AND ASTROPHYSICS↗

From +I to +IV, Alkalis to Actinides: Capturing Cations across the Periodic Table with Keggin Polyoxometalate Ligands

Coordination chemistry trends across the periodic table are often difficult to probe experimentally due to limitations in finding a versatile but consistent chelating platform that can accommodate various elements without changing its coordination mode. Herein, we present new metal/ligand systems covering a wide range of ionic radii, charges, and elements. Five different ligands derived from the Keggin structure (HBW 11 O 39 8– , PW 11 O 39 7– , SiW 11 O 39 8– , GeW 11 O 39 8– , and GaW 11 O 39 9– ) were successfully crystallized with six different cations (Na + , Sr 2+ , Ba 2+ , La 3+ , Ce 4+ , and Th 4+ ) and characterized by single-crystal X-ray diffraction. Twenty-five new compounds were obtained by using Cs + as the counterion, yielding a consistent base formula of Cs x [M(XW 11 O 39 ) 2 ]·nH 2 O. Despite having a similar first-coordination sphere geometry (i.e., 8-coordinated), the nature of the central cation was found to impact the long-range geometry of the complexes. This unique crystallographic data set shows that, despite the traditional consensus, the local geometry of the cation (i.e., metal–oxygen bond distance) is not enough to depict the full impact of the complexed metal ion. The bending and twisting of the complexes, as well as ligand–ligand distances, were all impacted by the nature of the central cation. We also observed that counterions play a critical role by stabilizing the geometry of the M(XW 11 ) 2 complex and directing complex–complex interactions in the lattice. We also define certain structural limits for this type of complex, with the large Ba 2+ ion seemingly approaching those limits. Finally, this study thus lays the foundation for capturing the coordination chemistry of other rarer elements across the periodic table such as Ra 2+ , Ac 3+ , Bk 4+ , Cf 3+ , etc.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermal Comptonization and Disk Thermal Reprocessing in NGC3516

We present an application of the thermal Comptonization/disk reprocessing model recently proposed by Zdziarski, Lubiniski, and Smith. We show that the absence of strong optical variations in the presence of strong concurrent X-ray variations, similar to those found by Hubble Space Telescope (HST)/Rossi X-Ray Timing Explorer (RXTE) monitoring observations of NGC 3516, can be explained by changing the geometry of the Comptonizing plasma rather than the accretion disk itself. The total X-ray luminosity of the Comptonizing plasma must decrease as its spatial extent increases. In contrast, the disk inner radius must be roughly fixed in order not to produce optical/ultraviolet color variations stronger than observed. By including emission due to internal viscous dissipation in the disk, we can roughly match the optical and X-ray flux levels and variability amplitudes seen from NGC 3516 during the HST/RXTE campaign.

Chiang, James↗

On the geodetic applications of simultaneous range-differencing to LAGEOS

The possibility of improving the accuracy of geodetic results by use of simultaneously observed ranges to Lageos, in a differencing mode, from pairs of stations was studied. Simulation tests show that model errors can be effectively minimized by simultaneous range differencing (SRD) for a rather broad class of network satellite pass configurations. The methods of least squares approximation are compared with monomials and Chebyshev polynomials and the cubic spline interpolation. Analysis of three types of orbital biases (radial, along- and across track) shows that radial biases are the ones most efficiently minimized in the SRC mode. The degree to which the other two can be minimized depends on the type of parameters under estimation and the geometry of the problem. Sensitivity analyses of the SRD observation show that for baseline length estimations the most useful data are those collected in a direction parallel to the baseline and at a low elevation. Estimating individual baseline lengths with respect to an assumed but fixed orbit not only decreases the cost, but it further reduces the effects of model biases on the results as opposed to a network solution. Analogous results and conclusions are obtained for the estimates of the coordinates of the pole.

Pablis, E. C.↗

Quasi-linear velocity space diffusion of heavy cometary pickup ions on bispherical diffusion characteristics

We consider an ion transport equation describing the source, convection, adiabatic acceleration, and quasi-linear velocity diffusion of cometary pickup ions. The equation is solved numerically along solar wind plasma flow lines for the environment of Comet Halley, to obtain distributions at positions on the Giotto spacecraft trajectory which may be compared with observations. We obtain full two-dimensional (pitch angle and velocity) numerical distributions which show pitch angle scattering about the wave scattering centers at +/- V(A), where V(A) is the Alfven wave speed in the solar wind frame. Peak ion phase-space densities approximately follow the bispherical shell geometry. The energy distributions F(v) agree well with Giotto observations at lower v, but in the high-energy tail there is evidence possibly for the first-order Fermi acceleration mechanism taking place in the Comet Halley foreshock region.

Huddleston, D. E.↗

Multiple Asteroid Systems: Dimensions and Thermal Properties from Spitzer Space Telescope and Ground-based Observations

We collected mid-IR spectra from 5.2 to 38 microns using the Spitzer Space Telescope Infrared Spectrograph of 28 asteroids representative of all established types of binary groups. Photometric light curves were also obtained for 14 of them during the Spitzer observations to provide the context of the observations and reliable estimates of their absolute magnitudes. The extracted mid-IR spectra were analyzed using a modified standard thermal model (STM) and a thermophysical model (TPM) that takes into account the shape and geometry of the large primary at the time of the Spitzer observation. We derived a reliable estimate of the size, albedo, and beaming factor for each of these asteroids, representing three main taxonomic groups: C, S, and X. For large (volume-equivalent system diameter Deq > 130 km) binary asteroids, the TPM analysis indicates a low thermal inertia (Lambda < or = approx.100 J/1/2 s/K/sq m2) and their emissivity spectra display strong mineral features, implying that they are covered with a thick layer of thermally insulating regolith. The smaller (surface-equivalent system diameter Deff < 17 km) asteroids also show some emission lines of minerals, but they are significantly weaker, consistent with regoliths with coarser grains, than those of the large binary asteroids. The average bulk densities of these multiple asteroids vary from 0.7-1.7 g/cu cm (P-, C-type) to approx. 2 g/cu cm (S-type). The highest density is estimated for the M-type (22) Kalliope (3.2 +/- 0.9 g/cu cm). The spectral energy distributions (SEDs) and emissivity spectra, made available as a supplement document, could help to constrain the surface compositions of these asteroids.

Marchis, F.↗

Improved Lunar Irradiance Model Using Multiyear MODIS Lunar Observations

The Moderate Resolution Imaging Spectroradiometer (MODIS) instruments on board the Terra and Aqua spacecrafts were launched on December 18, 1999, and May 4, 2002, respectively. One of the features of the MODIS instruments is the ability to perform observations of the lunar surface from its space view (SV) port. This event is scheduled approximately once a month via a spacecraft roll maneuver, which enables the lunar phase to be confined to within 1° for each instrument. The Moon is considered to be an extremely stable reference to monitor the long-term radiometric stability of the reflective solar bands (RSB). Each MODIS instrument can also view the Moon for about four months in a year without a roll maneuver. This is caused by the intrusion of the Moon in the SV. The lunar phase angles of these unscheduled lunar observations are distributed over a wide range varying from approximately 50° to 80° for Terra MODIS and from about -80° to -50° for Aqua MODIS, where the positive phase angle refers to a waning Moon, while the negative phase angle corresponds to a waxing Moon. Together, the scheduled and unscheduled lunar observations are used to monitor the long-term radiometric stability of the RSB. Of the several challenges involved in the modeling of the lunar optical properties, such as its absolute brightness, a number of optical and view geometry effects need to be considered. These effects are much easier to characterize for the scheduled observations due to confinement of the lunar phase angles compared to those for the unscheduled intrusions of the Moon in the SV. Nevertheless, it is still a challenge to remove the view geometry effect in the calibration coefficients derived from the scheduled lunar observations and even more challenging for the unscheduled lunar intrusions. In this work, the lunar absolute irradiance is modeled using known attributes and from the lunar observations by the two MODIS instruments from the time period between the years 2005 and 2012.

Calibration↗

MODIS Aerosol Optical Depth Bias Adjustment Using Machine Learning Algorithms

To monitor the earth atmosphere and its surface changes, satellite based instruments collect continuous data. While some of the data is directly used, some others such as aerosol properties are indirectly retrieved from the observation data. While retrieved variables (RV) form very powerful products, they don't come without obstacles. Different satellite viewing geometries, calibration issues, dynamically changing atmospheric and earth surface conditions, together with complex interactions between observed entities and their environment affect them greatly. This results in random and systematic errors in the final products.

Albayrak, Arif↗

1999-2003 Shortwave Characterizations of Earth Radiation Budget Satellite (ERBS)/Earth Radiation Budget Experiment (ERBE) Broadband Active Cavity Radiometer Sensors

From October 1984 through May 2005, the NASA Earth Radiation Budget Satellite (ERBS/ )/Earth Radiation Budget Experiment (ERBE)ERBE nonscanning active cavity radiometers (ACR) were used to monitor long-term changes in the earth radiation budget components of the incoming total solar irradiance (TSI), earth-reflected TSI, and earth-emitted outgoing longwave radiation (OLR). From September1984 through September 1999, using on-board calibration systems, the ERBS/ERBE ACR sensor response changes, in gains and offsets, were determined from on-orbit calibration sources and from direct observations of the incoming TSI through calibration solar ports at measurement precision levels approaching 0.5 W/sq m , at satellite altitudes. On October 6, 1999, the onboard radiometer calibration system elevation drive failed. Thereafter, special spacecraft maneuvers were performed to observe cold space and the sun in order to define the post-September 1999 geometry of the radiometer measurements, and to determine the October 1999-September 2003 ERBS sensor response changes. Analyses of these special solar and cold space observations indicate that the radiometers were pointing approximately 16 degrees away from the spacecraft nadir and on the anti-solar side of the spacecraft. The special observations indicated that the radiometers responses were stable at precision levels approaching 0.5 W/sq m . In this paper, the measurement geometry determinations and the determinations of the radiometers gain and offset are presented, which will permit the accurate processing of the October 1999 through September 2003 ERBE data products at satellite and top-of-the-atmosphere altitudes.

Lee, Robert B., III↗

Durability of plasma sprayed Thermal Barrier Coatings with controlled properties part Ⅱ: Effects of geometrical curvature

The present investigation elucidates the effects of substrate curvature on the durability of Air Plasma Sprayed (APS) Thermal Barrier Coatings (TBCs). Traditionally, planar disk specimens are utilized in Furnace Cycle Testing (FCT). In most cases, delamination is initiated at the disk's free edge and then propagates along the TBC-bond coat interface. However, in turbine components (e.g., blades/vanes), they lack significant free edges and the coatings are deposited on non-flat surfaces of varying radii of curvature. These geometrical discrepancies imply significant differences in the stress states as compared to planar disk specimens. Therefore, the part geometry inevitably affects the TBC failure mechanisms in the turbine system, and consequently influences TBC durability. Nevertheless, these effects have not been fully explored in the past, despite the anecdotal knowledge which suggests the leading edge of turbine blades to be one of the most common failure/spallation locations. Here in this study, representative TBC systems were deposited onto superalloy disks with flat substrate and rods with curved substrate. The experimental results from FCT suggest TBC durability on rods is significantly lower than when sprayed on disks. Furthermore, the durability of TBCs on rods appears to increase with higher porosity, which is contradictory to reported trends for TBCs on disks. In addition, the effects of various bond coats are not consistent with those observed in disks. To clarify the underlying effects of curved geometries, detailed stress analyses were performed. They revealed a state of thermal stresses which is unique to curved geometries. It was found that TBC on rods experience tensile radial stresses as well as tensile hoop stresses during the cooling. These stresses result in a complex interplay in failure processes in rods, which explains the different observed trends in the durability from those obtained with disks.

36 MATERIALS SCIENCE↗

Radio and X-ray observations of the gamma-ray bright quasar PKS 0528+134

We present a study of the z = 2.07 quasar PKS 0528+134, which has been detected as an extraordinarily luminous gamma-ray source. Its radio properties are highly variable in both total and polarized flux density. Milliarcsecond-scale maps from global very long base interferometry (VLBI) experiments, an X-ray spectrum from ROSAT Position Sensitive Proportional Counter (PSPC) observations, and light curves in total flux density and polarization are used to investigate the geometry, radiation mechanism, and physical environment of the emission region in the source. The VLBI images reveal a bent jet extending toward the northeast on parsec scales, with less intense knots of emission appearing on the opposite side of the brightest spot. The position of the core usually found in such sources is unclear. The polarization angle is stable despite strong variability in polarized flux density and indicates that the magnetic field is aligned with the jet axis as defined by our 8.4 GHz image. The ROSAT X-ray flux density of PKS 0528+134 in 1991 March is measured to be 1.6 micro Jy at 1 keV, with a very steep spectral (`energy') index sigma(sub x) approximately equal to 2.2. The X-ray observations reveal the presence of cold gas along the line of sight significantly in excess of that present in the Galaxy. A strong radio flare began within two months of the first observation of a high flux of gamma-rays from PKS 0528+134 by Hunter et al. Using the geometry and spectral chacateristics determined by our VLBI observations, a synchrotron self-Compton calculation indicates that relativistic bulk motion is required in PKS 0528+134, with an estimated Doppler beaming factor delta approximately greater than 4.3, similar to the value delta approximately greater than 7 required to explain the low optical depth of the gamma-rays to photon-photon pair production. We suggest that the core activity of PKS 0528+134 is sporadic in nature, with the nonthermal outburst starting in 1991 representing a violent period involving ejection of relativistic plasma along a compact jet pointed almost directly toward us.

Zhang, Yun Fei↗

Specimen Size and Geometry Effects on the Master Curve Fracture Toughness Measurements of EUROFER97 and F82H Steels

EUROFER97 and F82H are two leading reduced-activation ferritic-martensitic (RAFM) steels for fusion blanket applications. Exposure to the harsh environment of fusion reactors can result in severe degradation of materials fracture toughness (FT). Thus, the post-irradiation evaluation of FT is critical to understanding the material behavior. Due to the space constraint of irradiation facilities, the development of small specimen test techniques (SSTT) is necessary to evaluate the performance of irradiated materials. In this study, we evaluated the specimen size and geometry effects on the ductile-to-brittle transition FT of EUROFER97 batch-3 and F82H-BA12 steels. The specimen thicknesses ranged from 1.65 to 12.7 mm and the geometries included 1.65 mm bend bar, 4 mm mini-compact tension (miniCT), and 0.5T compact tension (CT) specimens. Fracture toughness testing and evaluations were performed using the Master Curve method in the ASTM E1921-19 standard. After size correction to 1T size using the Master Curve method, no specimen size effect was observed between the 4 mm miniCT and 0.5T CT specimens for the Master Curve reference temperature T0Q, while the bend bars yielded a higher T0Q. A strong effect of fatigue precrack front straightness on T0Q for 0.5T CT specimens was observed. The minimum number of specimens needed for each specimen geometry has been determined.

Chen, Xiang↗

Discovery of Strongly Variable X-Ray Polarization in the Neutron Star Low-Mass X-Ray Binary Transient XTE J1701−462

Context. After about 16 years since its first outburst, the transient neutron star low-mass X-ray binary XTE J1701−462 turned on again in September 2022, allowing for the first study of its X-ray polarimetric characteristics by a dedicated observing program with the Imaging X-ray Polarimeter Explorer (IXPE). Aims. Polarimetric studies of XTE J1701−462 have been expected to improve our understanding of accreting weakly magnetized neutron stars, in particular, the physics and the geometry of the hot inner regions close to the compact object. Methods. The IXPE data of two triggered observations were analyzed using time-resolved spectroscopic and polarimetric techniques, following the source along its Z-track of the color–color diagram. Results. During the first pointing on 2022 September 29, an average 2–8 keV polarization degree of (4.6 ± 0.4)% was measured, the highest value found up to now for this class of sources. Conversely, only a ∼0.6% average degree was obtained during the second pointing ten days later. Conclusions. The polarimetric signal appears to be strictly related to the higher energy blackbody component associated with the boundary layer (BL) emission and its reflection from the inner accretion disk, and it is as strong as 6.1% and 1.2% (> 95% significant) above 3–4 keV for the two measurements, respectively. The variable polarimetric signal is apparently related to the spectral characteristics of XTE J1701−462, which is the strongest when the source was in the horizontal branch of its Z-track and the weakest in the normal branch. These IXPE results provide new important observational constraints on the physical models and geometry of the Z-sources. Here, we discuss the possible reasons for the presence of strong and variable polarization among these sources.

XTEJ1701↗