Air Quality Implications of Using Ammonia as a Renewable Fuel: How Low Can NO x Emissions Go?
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
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Constraining low redshift [C II ] emission by cross-correlating FIRAS and BOSS data
ABSTRACT We perform a tomographic cross-correlation analysis of archival FIRAS data and the BOSS galaxy redshift survey to constrain the amplitude of [C II] 2P3/2 → 2P1/2 fine structure emission. Our analysis employs spherical harmonic tomography (SHT), which is based on the angular cross-power spectrum between FIRAS maps and BOSS galaxy over-densities at each pair of redshift bins, over a redshift range of 0.24 < z < 0.69. We develop the SHT approach for intensity mapping, where it has several advantages over existing power spectral estimators. Our analysis constrains the product of the [C II] bias and [C II] specific intensity, $b_{\rm [C \small{\rm II}]}I_{\rm [C \small{\rm II}]}$, to be <0.31 MJy/sr at z ≈ 0.35 and <0.28 MJy/sr at z ≈ 0.57 at $95{{\ \rm per\ cent}}$ confidence. These limits are consistent with most current models of the [C II] signal, as well as with higher-redshift [C II] cross-power spectrum measurements from the Planck satellite and BOSS quasars. We also show that our analysis, if applied to data from a more sensitive instrument such as the proposed PIXIE satellite, can detect pessimistic [C II] models at high significance.
79 ASTRONOMY AND ASTROPHYSICS↗
Recent observations of the very low frequency interplanetary radio emission
Observations of radio emissions in the frequency range of 2 to 3 kHz have been made in the distant heliosphere by the Voyager 1 and 2 plasma wave instruments. Based primarily on wideband observations made periodically throughout the cruise phases of the missions the radio emission, first observed in 1982, appears to have been present almost continuously since 1983. The spectrum is complex, usually showing two peaks, one near 2 and another near 3 kHz. Occasionally, only one of the peaks is observed. A possible source for the radio emissions is the terminal shock in the outer heliosphere.
Kurth, W. S.↗
Low energy gamma ray emission from the Cygnus OB2 association
According to our newly developed model of gamma-ray emission from chaotic early-type stellar winds, we predict the combined gamma-ray flux from the circumstellar winds of many very luminous early-type stars in the Cyg OB2 association can be detectable by the Energetic Gamma Ray Experiment Telescope (EGRET) (and maybe also by OSSE) on CGRO. Due to different radiation mechanisms, the gamma-ray spectrum from stellar winds can be quite different from that of CYG X-3; this spectral difference and the time-variation of Cyg X-3 flux will help to distinguish the gamma-ray components from different sources in this small region, which is spatially unresolvable by CGRO.
Chen, Wan↗
Timing analysis of low-energy gamma ray emission from galactic compact objects using the Gamma Ray Observatory
The principal goal of our phase 1 investigation was the development of techniques and data analysis tools for pulsar searches and timing. After the launch of the Compton Observatory, we received from the Burst and Transient Source Experiment (BATSE) team one day of discriminator large area (DISCLA) data for use in the development and testing of data analysis techniques. Using this first day of data for testing and optimizing our timing tools we detected four x-ray binary pulsars, Vela X-1, Cen X-3, 4U 0115+63, and GX 301-2. Subsequently, we received four more days of data, allowing us to test our timing tools with data from a variety of days. In summary, using the tools we developed based on the first day of data that we received, we have detected 8 pulsars in 5 days of data, or roughly one quarter of the approximately 30 known x-ray binary pulsars. In addition to the pulsars listed above, we detected GX 1+4, 4U 1626-67, OAO 1657-415, and Her X-1. Many of the data analysis tools that we developed have been ported to MSFC and are being used for the analysis of BATSE data. This appendix describes some of the timing tools and presents preliminary pulse period and phase profile results.
Prince, Thomas A.↗
Evaluating the Detection Efficiency of VHF Lightning Emissions Observed in Low-Earth Orbit
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lightning↗
Peculiarities of spectra of induced emission of polymethine dye solutions at low temperatures
Results from studying the induced emission spectra with monochromatic excitation (superluminescent regime) within a temperature range of 300 K - 5.2 K are presented. The significant feature of such operations is the appearance of quasi-lines whose minimum width is realized at 4.2 K. The frequency distribution of the quasi-lines unambiguously characterizes the dye investigated. When interpreting these results, the idea of an inhomogeneous broadening of the polymethine dye spectra in the solution being studied experimentally was used for the first time. The quasi-lines observed are interpreted as a manifestation of the electron vibration structure of singlet states of a complex molecule.
Melishchuk, M. V.↗
Status of Technological Advancements for Reducing Aircraft Gas Turbine Engine Pollutant Emissions
Combustor test rig results indicate that substantial reductions from current emission levels of carbon monoxide (CO), total unburned hydrocarbons (THC), oxides of nitrogen (NOx), and smoke are achievable by employing varying degrees of technological advancements in combustion systems. Minor to moderate modifications to existing conventional combustors produced significant reductions in CO and THC emissions at engine low power (idle/taxi) operating conditions but did not effectively reduce NOx at engine full power (takeoff) operating conditions. Staged combusiton techniques were needed to simultaneously reduce the levels of all the emissions over the entire engine operating range (from idle to takeoff). Emission levels that approached or were below the requirements of the 1979 EPA standards were achieved with the staged combustion systems and in some cases with the minor to moderate modifications to existing conventional combustion systems. Results from research programs indicate that an entire new generation of combustor technology with extremely low emission levels may be possible in the future.
Rudey, R. A.↗
Attenuation of sound in a low Mach number nozzle flow
The energy conversion mechanisms which govern the emission of low frequency sound from an axisymmetric jet pipe of arbitrary nozzle contraction ratio in the case of low Mach number nozzle flow are discussed. The energy of the incident sound which flows through the nozzle is used to maintain two distinct characteristic disturbances in the exterior fluid. First, there is the emitted radiation which has the directivity equivalent to that of a monopole-dipole combination. Second, essentially incompressible vortex waves are induced on the jet by vortex shedding from the lip of the nozzle and may involve the excitation of instability modes. Two linearized analytical models are examined to determine the partition of the emitted energy between the radiation field and the vortex waves. One of these is an exact linear theory in which the jet boundary is treated as a vortex sheet. The second model assumes that the width of the mean shear layer of the jet cannot be neglected. The results are discussed with reference to recent nozzle attenuation measurements.
Howe, M. S.↗
Flame Tube NOx Emissions Using a Lean-Direct-Wall-Injection Combustor Concept
A low-NOx emissions combustor concept has been demonstrated in flame tube tests. A lean-direct injection concept was used where the fuel is injected directly into the flame zone and the overall fuel-air mixture is lean. In this concept the air is swirled upstream of a venturi section and the fuel is injected radially inward into the air stream from the throat section using a plain-orifice injector. Configurations have two-, four-, or six-wall fuel injectors and in some cases fuel is also injected from an axially located simplex pressure atomizer. Various orifice sizes of the plain-orifice injector were evaluated for the effect on NOx. Test conditions were inlet temperatures up to 8 1 OK, inlet pressures up to 2760 kPa, and flame temperatures up to 2100 K. A correlation is developed relating the NOx emissions to inlet temperature, inlet pressure, fuel-air ratio and pressure drop. Assuming that 15 percent of the combustion air would be used for liner cooling and using an advanced engine cycle, for the best configuration, the NOx emissions using the correlation is estimated to be <75 percent of the 1996 ICAO standard.
Tacina, Robert R.↗
High-energy emission in gamma-ray bursts
Between February 1980 and August 1983 the Gamma-Ray Spectrometer on the Solar Maximum Mission Satellite (SMM) detected 72 events identified as being of cosmic origin. These events are an essentially unbiased subset of all gamma-ray bursts. The measured spectra of these events show that high energy (greater than 1 MeV) emission is a common and energetically important feature. There is no evidence for a general high-energy cut-off or a distribution of cut-offs below about 6 MeV. These observations imply a limit on the preferential beaming of high energy emission. This constraint, combined with the assumption of isotropic low energy emission, implies that the typical magnetic field strength at burst radiation sites is less than 1 x 10 to the 12th gauss.
Matz, S. M.↗
Techno-economic assessment of emissions mitigation technologies for post-combustion CO2 capture using AMP/PZ
Minimizing the environmental impacts of amine-based post-combustion carbon capture technologies is essential for meeting environmental permitting regulations and ensuring public acceptance. Experimental test campaigns at the CO₂ capture pilot plant in Niederaussem using CESAR1 demonstrated that integrating available emission abatement technologies can significantly reduce the concentration of amines and degradation products in CO₂-depleted flue gas to below the detection limit of an infrared spectrometer. The study confirmed that proprietary dry bed technology (OEASE Aerozone™) or a second water wash can lower AMP and PZ emissions to below 1 mg/Nm³. However, to achieve very low NH₃ emissions below 2 mg/Nm³, an acid or other chemically active wash downstream of the water wash is required. A configuration with a dry bed or a double water wash results in a carbon capture cost (CCC) of 44 €/tCO₂, and a CO₂ avoided cost (CAC) of 86 €/tCO₂. A configuration with an acid wash increases the CCC to 47 €/tCO₂ and the CAC to 90 €/tCO₂ due to the amine losses in the acid waste and its treatment.
CO2 capture↗
Low energy X-ray emission from five galaxy cluster sources
We report the detection of soft (0.2-2.5 keV) X-ray emission from several known cluster X-ray sources using the low energy detectors of the HEAO 1 A-2 experiment. Soft X-ray emission was observed from five clusters - the Centaurus cluster, Abell 2147, SC 1329-314, Abell 2319, and Abell 133. Spectral parameters estimated from the soft X-ray fluxes are inconsistent with those reported at higher energies for the Centaurus cluster, Abell 2147, and SC 1329-314, indicating the presence of more than one spectral component in these clusters. No evidence for more than one component was found for either Abell 2319 or Abell 133. The temperature of Abell 133 is constrained to be less than 2 x 10 to the 7th K, making it the coolest X-ray cluster yet detected.
Reichert, G.↗
The ultraviolet emission properties of five low-redshift active galactic nuclei at high signal-to-noise ratio and spectral resolution
We analyze the ultraviolet (UV) emission line and continuum properties of five low-redshift active galactic nuclei (four luminous quasars: PKS 0405-123, H1821 + 643, PG 0953 + 414, and 3C 273, and one bright Seyfert 1 galaxy: Mrk 205). The HST spectra have higher signal-to-noise ratios (typically approximately 60 per resolution element) and spectral resolution (R = 1300) than all previously published UV spectra used to study the emission characteristics of active galactic nuclei. We include in the analysis ground-based optical spectra covering H beta and the narrow (O III) lambda lambda 4959, 5007 doublet. New results are obtained and presented.
Laor, Ari↗
Development of Methane Emissions Model to Assess Fuel Recovery Potential at Gas Well Sites Using On Site Compression
The U.S. natural gas production and consumption has increased 85.5% since 2005 primarily due to the unconventional production methods of horizontal drilling and hydraulic fracturing. Natural gas used as a fuel has a lower greenhouse gas (GHG) footprint than coal and petroleum due to lower Carbon Dioxide (CO2) emissions when combusted. However, the “greener” benefit to natural gas may be negated by leaks in production and transmission systems. Methane (CH4), the primary hydrocarbon in natural gas, has an estimated Global Warming Potential (GWP) of 28-36 over 100 years, meaning it can absorb 28-36 more energy than CO2 which has a GWP of 1.0. Natural gas well sites are prone to methane emissions, or leaks and irregular gas releases, vented to atmosphere throughout production and transmission. The U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) has recently granted West Virginia University (WVU) funding under agreement DE-FOA-0002005, to “Advance technologies to mitigate methane emissions and increase the efficiency of the natural gas transportation infrastructure”. As part of this funding WVU was tasked with identifying and quantifying sources of methane emissions at unconventional well sites, processing this data, and developing a system to recapture these emissions. A 0-D Simulink model was developed, utilizing standardized methodologies, data from previously conducted studies, as well as collected data from well sites in the Marcellus shale play region. The model was developed to predict emission rates from various components at natural gas well sites as well as the potential to utilize these emissions as fuel for the natural gas powered compressor engines on-site. This model was utilized to run high, medium, and low cases for four identified emission sources, engine size, pneumatic controller count, liquid level production which dictates tank emissions, and compressor packing vent emissions. Due to discrepancies in transient tank emission data, a high and low emission factor for tanks was used, resulting in two sets of 81 executed cases, and 162 unique cases of total site emissions and potential for fuel consumption. Each of the cases were run over 86,400 seconds at a 1 Hz, representative of a full 24 hour day of operation. The fuel consumption offset an average of 557% of fuel consumption on an energy density basis across all 81 cases with the high tank emission factor with a maximum offset of 2334%. The fuel consumption offset was an average of 82.9% for all 81 cases with the low tank emission factor with a maximum offset of 337%. This study highlights flaws in the use of publicly available methane number calculations to determine natural gas’s suitability as an engine fuel as well as the lack of public data for transient liquid storage tank emissions.
03 NATURAL GAS↗
Raindrop Signature from Microwave Radiometer over Deserts
Rainfall estimates from spaceborne microwave radiometers form the foundation of global precipitation datasets. Since the beginning of the satellite microwave rainfall estimation era in the1980s, the primary signature leveraged over land for these estimates has been the brightness temperature (TB) depression due to ice particle scattering. Contrary to this practice, time series analyses based on observations from two spaceborne radars and two spaceborne radiometers reveal a TB increase due to raindrop emission as the primary cloud particle signature over desert terrain. Low surface emissivity supports the use of liquid raindrop emission as the primary signature over desert surfaces. In these regions, the surface rain rate better correlates with the liquid raindrop emission signal than with the scattering induced by ice further aloft, suggesting a new potential for improving rainfall estimation over deserts by exploiting the liquid raindrop emission signature.
Yalei You↗
Optimization of a Residential Air Source Heat Pump using Refrigerants with GWP <150 for Improved Performance and Reduced Emission
Using low-GWP refrigerants can reduce the Green House Gas (GHG) emission of heat pump systems. Heat exchangers and compressors are the key components and have a prominent impact on system performance, significant research is devoted to reducing the cost of the heat exchangers while achieving the same or better system performance with refrigerant charge reduction.To better understand the environmental impacts of optimized systems with low-GWP refrigerants, Life Cycle Climate Performance (LCCP) evaluation method was used to evaluate the direct and indirect emissions of the system over the course of its lifetime from manufacturing to disposal. The DOE/ORNL Heat Pump Design Model (HPDM) is used to evaluate the performance of heat pumps. Multi-objective optimizations using Particle Swarm Optimization (PSO) algorithm are performed on a 3-ton R410A residential air source heat pump on market. Seven R410A alternatives, i.e., R32, R454B, R454C, R455A, R457A, R1234yf and R1234ze(E) are investigated. The last five fluids have GWP lower than 150.As a result, 5.5%-12.8% seasonal energy efficiency ratio 2 (SEER2) improvement is achieved, and the optimized systems reduce life cycle CO2 emission by 8.5%-28.6% with GWP lower than 150 refrigerants. The optimal heat exchangers can fit into the original R410A fan-coil units; therefore, the proposed design method establishes a production and installation path to produce cost-effective low-GWP heat pumps easily accepted by end users.
Li, Zhenning↗
Acoustic emission characteristics of copper alloys under low-cycle fatigue conditions
The acoustic emission (AE) characteristics of pure copper, zirconium-copper, and several copper alloys were determined to develop nondestructive evaluation schemes of thrust chambers through AE techniques. The AE counts rms voltages, frequency spectrum, and amplitude distribution analysis evaluated AE behavior under fatigue loading conditions. The results were interpreted with the evaluation of wave forms, crack propagation characteristics, as well as scanning electron fractographs of fatigue-tested samples. AE signals at the beginning of a fatigue test were produced by a sample of annealed alloys. A sample of zirconium-containing alloys annealed repeatedly after each fatigue loading cycle showed numerous surface cracks during the subsequent fatigue cycle, emitting strong-burst AE signals. Amplitude distribution analysis exhibits responses that are characteristic of certain types of AE signals.
Krampfner, Y.↗