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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Avoid Procuring or Storing 2-Propanol in Opaque White, Clear Containers

One of the most important responsibilities chemical owners at Los Alamos National Laboratory (LANL) have is to ensure the safety of the chemicals they own. An important consideration is how chemicals react to their environment. In the case of 2-propanol, a common solvent found in research laboratories used often in manufacturing and analytical processes, it can develop peroxides with exposure to light. 2-Propanol is classified as a Group B (class 3) peroxide-forming solvent. However, there is a dearth of literature that summarizes the risks surrounding peroxide formation in 2-propanol (IPA), leading to a lack of awareness of these hazards in the chemistry community.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2025

South Pole Lunar Lighting Studies for Driving Exploration on the Lunar Surface

NASA’s Artemis lunar missions will face new exploration challenges due to inherently low sun angles in the lunar south pole region. Whereas the Apollo missions were afforded sunlight for approximately 8 to 50-degrees above the horizon, sunlight for the next lunar missions will only be 1 to 2-degrees about the horizon. With this low angle, long shadows and high contrasts of light and dark areas will be faced by the crew and remote teleop operators while exploring the lunar surface. With this in mind, NASA developed an integrated virtual Lighting and Navigation Simulation to understand these challenges. Two studies have been conducted in this Lunar South Pole environment to evaluate the effects of natural and artificial lighting on driving and navigating a lunar rover across the surface. Early NASA studies, such as this, are used to aid in developing techniques and explore concepts of operations to promote mission success and crew safety. In the Phase One development evaluation, six astronauts were teleported to ten different lighting conditions. For each location, drivers were to drive to an imaginary target approximately 200-meters straight ahead and provide subjective feedback on their ability to drive under the given lighting conditions. Phase Two, a more operational study, four astronauts and a remote operator tested five different Artemis lunar mission scenarios. Results indicated sun direction at such low angles, especially when driving a high speed, can severely impact the crew’s ability to safely drive the rover. In the up-sun situation, with the sun directly in the driver’s eyes and compounded long shadows, the consistent preference among drivers was to initiate a tacking strategy of approximately +/- 20 to 30-degrees to improve visibility. This maneuver does require more time and rover energetics. Conversely, driving down-sun required the crew to tack as well to avoid the shadow of rover blocking the terrain. Less appreciated is how the surrounding landscape is lit. Traveling into shadowed areas, especially while facing a lit terrain beyond the shadowed area, drivers enter at their own risk due to pupil contraction making artificial lights useless. Additionally, the constant transitioning between dark and light areas are mentally taxing to the crew and natural navigational references such as the stars are invisible and therefore unusable. Slope and depth magnitude are very difficult hazards to judge when approaching a shadowed crater. This naturally leads to slower driving speeds than originally anticipated. As for observing scientifically interesting features, assessing them accurately varies greatly by the lighting condition. In most cases, the task can be completed, but the strategy is to use the sun to one’s advantage. Crew workload distribution in the cockpit for driving operations was split amongst crew. The driver primarily focused attention on visual terrain (80%) but referenced displays approximately 20% of the time, while the co-pilot/navigator generally provided directional cues to the driver. These natural lighting conditions present significant challenges for safe rover operations; however, early studies having given investigators a “first-look” into understanding of how operating on the South Lunar Pole can be accomplished.

LTv↗
DOE OSTI2016

Exposure Risks Among Children Undergoing Radiation Therapy: Considerations in the Era of Image Guided Radiation Therapy

Recent improvements in toxicity profiles of pediatric oncology patients are attributable, in part, to advances in the field of radiation oncology such as intensity modulated radiation (IMRT) and proton therapy (IMPT). While IMRT and IMPT deliver highly conformal dose to targeted volumes, they commonly demand the addition of 2- or 3-dimensional imaging for precise positioning—a technique known as image guided radiation therapy (IGRT). In this manuscript we address strategies to further minimize exposure risk in children by reducing effective IGRT dose. Portal X rays and cone beam computed tomography (CBCT) are commonly used to verify patient position during IGRT and, because their relative radiation exposure is far less than the radiation absorbed from therapeutic treatment beams, their sometimes significant contribution to cumulative risk can be easily overlooked. Optimizing the conformality of IMRT/IMPT while simultaneously ignoring IGRT dose may result in organs at risk being exposed to a greater proportion of radiation from IGRT than from therapeutic beams. Over a treatment course, cumulative central-axis CBCT effective dose can approach or supersede the amount of radiation absorbed from a single treatment fraction, a theoretical increase of 3% to 5% in mutagenic risk. In select scenarios, this may result in the underprediction of acute and late toxicity risk (such as azoospermia, ovarian dysfunction, or increased lifetime mutagenic risk) in radiation-sensitive organs and patients. Although dependent on variables such as patient age, gender, weight, body habitus, anatomic location, and dose-toxicity thresholds, modifying IGRT use and acquisition parameters such as frequency, imaging modality, beam energy, current, voltage, rotational degree, collimation, field size, reconstruction algorithm, and documentation can reduce exposure, avoid unnecessary toxicity, and achieve doses as low as reasonably achievable, promoting a culture and practice of “gentle IGRT.”.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2014

SU-E-T-266: Proton PBS Plan Design and Robustness Evaluation for Head and Neck Cancers

Purpose: To describe a newly designed proton pencil beam scanning (PBS) planning technique for radiotherapy of patients with bilateral oropharyngeal cancer, and to assess plan robustness. Methods: We treated 10 patients with proton PBS plans using 2 posterior oblique field (2F PBS) comprised of 80% single-field uniform dose (SFUD) and 20% intensity-modulated proton therapy (IMPT). All patients underwent weekly CT scans for verification. Using dosimetric indicators for both targets and organs at risk (OARs), we quantitatively compared initial plans and verification plans using student t-tests. We created a second proton PBS plan for each patient using 2 posterior oblique plus 1 anterior field comprised of 100% SFUD (3F PBS). We assessed plan robustness for both proton plan groups, as well as a photon volumetric modulated arc therapy (VMAT) plan group by comparing initial and verification plans. Results: The 2F PBS plans were not robust in target coverage. D98% for clinical target volume (CTV) degraded from 100% to 96% on average, with maximum change Δ D98% of −24%. Two patients were moved to photon VMAT treatment due to insufficient CTV coverage on verification plans. Plan robustness was especially weak in the low-anterior neck. The 3F PBS plans, however, demonstrated robust target coverage, which was comparable to the VMAT photon plan group. Doses to oral cavity were lower in the Proton PBS plans compared to photon VMAT plans due to no lower exit dose to the oral cavity. Conclusion: Proton PBS plans using 2 posterior oblique fields were not robust for CTV coverage, due to variable positioning of redundant soft tissue in the posterior neck. We designed 3-field proton PBS plans using an anterior field to avoid long heterogeneous paths in the low neck. These 3-field proton PBS plans had significantly improved plan robustness, and the robustness is comparable to VMAT photon plans.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1973

Apparatus for aiding a pilot in avoiding a midair collision between aircraft

An apparatus for aiding a pilot in avoiding a midair collision between aircraft is described. A protected aircraft carries a transmitter, a transponder, a receiver, and a data processor; and an intruding cooperating aircraft carries a transponder. The transmitter of the protected aircraft continuously transmits a signal to the transponders of all intruding aircraft. The transponder of each of the intruding aircraft adds the altitude of the intruding aircraft to the signal and transmits it back to the receiver of the protected aircraft. The receiver selects only the signal from the most hazardous intruding aircraft and applies it to the data processor. From this selected signal the data processor determines the closing velocity between the protected and intruding aircraft, the range between the two aircraft, their altitude difference and the time to a possible collision.

Schrader, J. H.↗
NASA NTRS2014

NASA's Approach to Critical Risks for Extended Human Space Flight

Planetary Robotic and Human Spaceflight Exploration Humans are exposed to a great variety of hazards in the space environment. These include the effects of weightlessness, radiation, isolation and confinement, altered day-night cycles, and others. These inherent hazards have both physiological and behavioral consequences. The adaptive capabilities of humans in these situations is remarkable, and often exceed our expectations. However, the demanding environment and challenging operational pace can push some of these adaptive processes to their limits. The NASA Human Research Program (HRP) is tasked with mitigating the most serious of these effects on human health, safety, and performance, in long-duration space flight. This can involve the development and deployment of physiological countermeasures, better understanding of the physiological alterations and avoidance of exacerbating situations, inputs to the design of future spacecraft to minimize risks, and in some cases the awareness that some level of risk might have to be accepted based on the resulting consequences and their likelihood. HRP has identified a few areas that are of special concern due to their severity, lack of understanding of underlying causes, or potential for negative impact on health or performance. Some of these areas are visual impairment possibly due to increased intracranial pressure, behavioral and performance problems due to sleep deficits and isolation, and acute and chronic effects of radiation. These problems can, if not addressed, be expected to increase on longer and more distant missions. The evidence from spaceflight, laboratory, and analog studies that supports the selection of the most critical risks will be discussed. Current and planned research programs that address these risks, and their anticipated outcomes, will also be described.

Shelhamer, Mark↗
NASA NTRS2005

SAFER Inspection of Space Shuttle Thermal Protection System

In the aftermath of the space shuttle Columbia accident, it quickly became clear that new methods would need to be developed that would provide the capability to inspect and repair the shuttle's thermal protection system (TPS). A boom extension to the Remote Manipulator System (RMS) with a laser topography sensor package was identified as the primary means for measuring the damage depth in acreage tile as well as scanning Reinforced Carbon- Carbon (RCC) surfaces. However, concern over the system's fault tolerance made it prudent to investigate alternate means of acquiring close range photographs and contour depth measurements in the event of a failure. One method that was identified early was to use the Simplified Aid For EVA Rescue (SAFER) propulsion system to allow EVA access to damaged areas of concern. Several issues were identified as potential hazards to SAFER use for this operation. First, the ability of an astronaut to maintain controlled flight depends upon efficient technique and hardware reliability. If either of these is insufficient during flight operations, a safety tether must be used to rescue the crewmember. This operation can jeopardize the integrity of the Extra-vehicular Mobility Unit (EMU) or delicate TPS materials. Controls were developed to prevent the likelihood of requiring a tether rescue, and procedures were written to maximize the chances for success if it cannot be avoided. Crewmember ability to manage tether cable tension during nominal flight also had to be evaluated to ensure it would not negatively affect propellant consumption. Second, although propellant consumption, flight control, orbital dynamics, and flight complexity can all be accurately evaluated in Virtual Reality (VR) Laboratory at Johnson Space Center, there are some shortcomings. As a crewmember's hand is extended to simulate measurement of tile damage, it will pass through the vehicle without resistance. In reality, this force will push the crewmember away from the vehicle, and could induce a moment which, if strong enough, could saturate the attitude control system in SAFER. This raises the concern that additional propellant will be consumed to maintain controlled flight. To account for this, the fidelity of the Virtual Reality simulation was improved to include the effect of crewmember contact with the vehicle during SAFER flight. In addition, while participating in VR simulations, the subject is in shirt sleeves and sits in a chair. This does not provide a flight-like representation of body position awareness. To prevent inadvertent contact with tile or RCC, other facilities were utilized to establish crew preferences for body attitude and tool configuration. Finally, a study was performed to determine if attitude constraints are needed for the Space shuttle and International Space Station to reduce SAFER flight difficulty.

Scoville, Zebulon C.↗
NASA NTRS2005

Automated Wildfire Detection Through Artificial Neural Networks

We have tested and deployed Artificial Neural Network (ANN) data mining techniques to analyze remotely sensed multi-channel imaging data from MODIS, GOES, and AVHRR. The goal is to train the ANN to learn the signatures of wildfires in remotely sensed data in order to automate the detection process. We train the ANN using the set of human-detected wildfires in the U.S., which are provided by the Hazard Mapping System (HMS) wildfire detection group at NOAA/NESDIS. The ANN is trained to mimic the behavior of fire detection algorithms and the subjective decision- making by N O M HMS Fire Analysts. We use a local extremum search in order to isolate fire pixels, and then we extract a 7x7 pixel array around that location in 3 spectral channels. The corresponding 147 pixel values are used to populate a 147-dimensional input vector that is fed into the ANN. The ANN accuracy is tested and overfitting is avoided by using a subset of the training data that is set aside as a test data set. We have achieved an automated fire detection accuracy of 80-92%, depending on a variety of ANN parameters and for different instrument channels among the 3 satellites. We believe that this system can be deployed worldwide or for any region to detect wildfires automatically in satellite imagery of those regions. These detections can ultimately be used to provide thermal inputs to climate models.

Miller, Jerry↗
NASA NTRS2010

TPSAS-NF1676L-10776-DND

Airborne self-separation (SSEP) among aircraft is proposed as a means for improving air traffic system capacity and safety in the future National Airspace System and for improving the efficiency of flight for all aircraft performing this function. The concept is examined in the U.S. en route domain, in an environment of mixed conventional and SSEP operations. No airspace is set aside for this purpose and the first aircraft equipped to perform the function can receive its benefits. For aircraft operating in the SSEP mode, the Air Navigation Service Provider (ANSP) turns over control and responsibility for all separation tasks to the pilots of SSEP aircraft. This includes separation from all other aircraft, from severe weather hazards and from Special Use Airspace. Connection to the centralized traffic flow management function is retained throughout the flight, however, and compliance with any Required Time of Arrival assignments is maintained. The SSEP function is accomplished in the aircraft through the use of airborne surveillance, data communications and processing equipment, and procedures defined in a new set of operating rules called "Autonomous Flight Rules" (AFR). The technical enablers are Automatic Dependent Surveillance - Broadcast (ADS-B), Traffic Information Service - Broadcast (TIS-B), and Traffic Alert and Collision Avoidance System (TCAS). This briefing presents an overview of the concept.

Frank Bussink↗
NASA NTRS2019

A Comparison of Two Terminal Area Detect and Avoid Well Clear Definitions

Technical requirements are currently under development for a detect and avoid system (DAA) that would support the operation of Unmanned Aircraft Systems (UAS) within the National Airspace System (NAS). Such a system would aid UAS operators in maintaining sufficient separation, or "well clear", from other aircraft in their vicinity. The first set of technical standards for a UAS DAA system (referred to as "Phase 1" requirements) was limited to UAS operations transiting through Class D, E, and G airspace to, or from, Class A (or special-use) airspace. Explicitly out of scope of the Phase 1 requirements was the operation of UAS within terminal airspace in the NAS. Fern, Rorie, Roberts and Monk (2018) explored the application of a Phase 1 DAA system within Class D terminal airspace in a human-in-the-loop simulation. The results of the study demonstrated a poor fit of the Phase 1 DAA well clear (DWC) definition to these terminal operations. The original DWC definition was designed for the en-route environment and could not account for the complex, tightly-choreographed nature of traffic typically found near an airport. The interaction of the en-route DWC definition and the terminal area traffic led to excessive DAA alerting against safely-separated traffic. The frequent alerting quickly degraded pilots' ability to discriminate between encounters where a maneuver was or was not necessary. This resulted in slower response times, higher rates of losses of DAA well clear, and more severe losses of DAA well clear than had been observed in previous DAA research (e.g., Rorie et al., 2017). The current paper reports on a follow-on study to Fern et al. (2018) that tested two DWC definitions designed to accommodate standard terminal area operating procedures, such as traffic in the downwind leg of a VFR traffic pattern while the UAS is on final. The two definitions utilized identical horizontal and vertical thresholds but differed in whether or not Tau (a function that takes into account the closure rate of two aircraft) was included as a part of the DWC hazard zone. The "Tau" DWC candidate definition nominally extended the DWC hazard zone by 15 seconds in the direction of the intruder aircraft, while the "No Tau" DWC candidate definition did not extend the DWC hazard zone. The results of this follow-on study indicated that both candidate definitions improved pilot and DAA system performance relative to Fern et al (2018). Pilot response times and rates of losses of DWC returned to levels comparable to earlier research in the en-route environment. Several important differences between the two DWC candidate definitions, however, are also discussed.

Terminal Area↗
DOE OSTI1994

Nuclear Safety [Vol. 35, No. 1, January-June 1994]

Nuclear Safety is a review journal that covers significant developments in the field of nuclear safety. Its scope includes the analysis and control of hazards associated with nuclear energy, operations involving fissionable materials, and the products of nuclear fission and their effects on the environment. Primary emphasis is on safety in reactor design, construction, and operation; however, the safety aspects of the entire fuel cycle, including fuel fabrication, spent-fuel processing, nuclear waste disposal, handling of radioisotopes, and environmental effects of these operations, are also treated. Table of Contents for this issue follows. GENERAL SAFETY CONSIDERATIONS: THE CHERNOBYL ACCIDENT: 1 Chernobyl Accident Management Actions, A. R Sich 25 The IAEA-ASSET Approach to Avoiding Accidents is to Recognize the Precursors to Prevent Incidents, F. Reisch; ACCIDENT ANALYSIS: 36 A Review of the Available Information on the Triggering Stage of a Steam Explosion, D. F. Fletcher; 58 Analysis and Modeling of Flow-Blockage-Induced Steam Explosion Events in the High-Flux Isotope Reactor, R. P. Taleyarkhan, V. Georgevich, C. W. Nestor, U. Gat, B. L. Lepard, D. H. Cook, J. Freels, S. J. Chang, C. Luttrell, R. C. Gwaltney, and J. Kirkpatrick; 74 An Analysis of Disassembling the Radial Reflector of a Thermionic Space Nuclear Reactor Power System, M. S. El-Genk and D. V. Paramonov; CONTROL AND INSTRUMENTATION: 86 Standards for High-Integrity Software, D. R. Wallace, D. R. Kuhn, L M. Ippolito, and L. Beltracchi; DESIGN FEATURES: 98 Adoption of New Design Features for the Next Generation Nuclear Power Reactors, L. S. Tong; 114 Review of Nuclear Piping Seismic Design Requirements, G. C. Slagis and S. E. Moore; ENVIRONMENTAL EFFECTS: 128 PC-Based Probabilistic Safety Assessment Study for a Geological Waste Repository Placed in a Bedded Salt Formation, S. A. Khan; OPERATING EXPERIENCES: 142 Managing Aging in Nuclear Power Plants: Insights from NRC’s Maintenance Team Inspection Reports, A. Fresco and M. Subudhi; 150 Reactor Shutdown Experience, Compiled by J. W. Cletcher; 153 Selected Safety-Related Events, Compiled by G. A. Murphy; RECENT DEVELOPMENTS: 158 Reports, Standards, and Safety Guides, D. S. Queener; 168 Proposed Rule Changes as of Dec. 31, 1993; ANNOUNCEMENTS: 177 Symposium on Radioactive and Mixed Waste—Risk as a Basis for Waste Classification; 177 1995 Incineration Conference 178 Ninth Power Plant Dynamics Control and Testing Symposium; 174 The Authors

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2015

Likelihood of a marine vessel accident from wind energy development in the Atlantic: Likelihood of shipping accident from wind energy in the Atlantic

Offshore wind energy development is planned for areas off the Atlantic coast. Many of the planned wind development areas fall within traditional commercial vessel routes. In order to mitigate possible hazards to ships and to wind turbines, it is important to understand the potential for increased risk to commercial shipping from the presence of wind farms. Using Automatic Identification System (AIS) data, historical shipping routes between ports in the Atlantic were identified, from Maine to the Florida Straits. The AIS data were also used as inputs to a numerical model that can simulate cargo, tanker and tug/towing vessel movement along typical routes. The model was used to recreate present day vessel movement, as well as to simulate future routing that may be required to avoid wind farms. By comparing the present and future routing of vessels, a risk analysis was carried out to determine the increased marginal risk of vessel collisions, groundings, and allisions with stationary objects, due to the presence of wind farms. The outcome of the analysis showed little increase in vessel collisions or allisions, and a decrease in groundings as more vessels were forced seaward by the wind farms.

commercial shipping↗
DOE OSTI2013

Interplay effects between dose distribution quality and positioning accuracy in total marrow irradiation with volumetric modulated arc therapy

Purpose: To evaluate the dosimetric consequences of inaccurate isocenter positioning during treatment of total marrow (lymph-node) irradiation (TMI-TMLI) using volumetric modulated arc therapy (VMAT).Methods: Four patients treated with TMI and TMLI were randomly selected from the internal database. Plans were optimized with VMAT technique. Planning target volume (PTV) included all the body bones; for TMLI, lymph nodes and spleen were considered into the target, too. Dose prescription to PTV was 12 Gy in six fractions, two times per day for TMI, and 2 Gy in single fraction for TMLI. Ten arcs on five isocenters (two arcs for isocenter) were used to cover the upper part of PTV (i.e., from cranium to middle femurs). For each plan, three series of random shifts with values between −3 and +3 mm and three between −5 and +5 mm were applied to the five isocenters simulating involuntary patient motion during treatment. The shifts were applied separately in the three directions: left–right (L-R), anterior–posterior (A-P), and cranial–caudal (C-C). The worst case scenario with simultaneous random shifts in all directions simultaneously was considered too. Doses were recalculated for the 96 shifted plans (24 for each patient).Results: For all shifts, differences <0.5% were found for mean doses to PTV, body, and organs at risk with volumes >100 cm{sup 3}. Maximum doses increased up to 15% for C-C shifted plans. PTV covered by the 95% isodose decreased of 2%–8% revealing target underdosage with the highest values in C-C direction.Conclusions: The correct isocenter repositioning of TMI-TMLI patients is fundamental, in particular in C-C direction, in order to avoid over- and underdosages especially in the overlap regions. For this reason, a dedicated immobilization system was developed in the authors' center to best immobilize the patient.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2016

Advanced Computational Accident Scenario Modeling for Safety Margin Economic Analysis

The intent of this research is to establish a new tool in the Risk Informed Safety Margin Characterization (RISMC) tool-kit for the fiscal analysis of potential power plant upgrades. This is being done by providing proof-of-concept of the Safety Margin Economic Evaluation (SMEE) methodology of performing cost-benefit analyses of potential Nuclear Power Plant (NPP) upgrades to allow for more data-driven decision making with regards to nuclear safety. To this end, the RAVEN code developed by the Idaho National Laboratory is being used to perform a cost-benefit analysis of several potential power plant safety upgrades to compare the material cost of the upgrades with the probabilistic benefit of avoiding accident scenario consequences to find the most cost effective safety upgrades. Additionally, the MELCOR and MACCS2 codes developed by the Sandia National Laboratory are being used for accident scenario modeling. Evaluating potential NPP upgrades is concluded by doing a detailed cost-benefit analysis of the upgrades. The cost of the upgrade is the direct material cost of implementing, maintaining, and operating the upgrade at an NPP for the projected duration of its lifetime. The benefit of the upgrade is more complex, and is essentially the Risk avoided, where Risk is defined as Consequences multiplied by Probability. Here, Consequences is the economic impact of a severe accident and/or nuclear release and Probability is the likelihood that an NPP upgrade will prevent or mitigate a severe accident, reducing or even eliminating its Consequences. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1997

Pilot Non-Conformance to Alerting System Commands During Closely Spaced Parallel Approaches

Cockpit alerting systems monitor potentially hazardous situations, both inside and outside the aircraft. When a hazard is projected to occur, the alerting system displays alerts and/or command decisions to the pilot. However, pilots have been observed to not conform to alerting system commands by delaying their response or by not following the automatic commands exactly. This non-conformance to the automatic alerting system can reduce its benefit. Therefore, a need exists to understand the causes and effects of pilot non-conformance in order to develop automatic alerting systems whose commands the pilots are more likely to follow. These considerations were examined through flight simulator evaluations of the collision avoidance task during closely spaced parallel approaches. This task provided a useful case-study because the effects of non-conformance can be significant, given the time-critical nature of the task. A preliminary evaluation of alerting systems identified non-conformance in over 40% of the cases and a corresponding drop in collision avoidance performance. A follow-on experiment found subjects' alerting and maneuver selection criteria were consistent with different strategies than those used by automatic systems, indicating the pilot may potentially disagree with the alerting system if the pilot attempts to verify automatic alerts and commanded avoidance maneuvers. A final experiment found supporting automatic alerts with the explicit display of its underlying criteria resulted in more consistent subject reactions. In light of these experimental results, a general discussion of pilot non-conformance is provided. Contributing factors in pilot non-conformance include a lack of confidence in the automatic system and mismatches between the alerting system's commands and the pilots' own decisions based on the information available to them. The effects of non-conformance on system performance are discussed. Possible methods of reconciling mismatches are given, and design considerations for alerting systems which alleviate the problem of non-conformance are provided.

Pritchett, Amy Ruth↗
DOE OSTI2017

Molecular dynamics simulations of stratum corneum lipid mixtures: A multiscale perspective

The lipid matrix of the stratum corneum (SC) layer of skin is essential for human survival; it acts as a barrier to prevent rapid dehydration while keeping potentially hazardous material outside the body. While the composition of the SC lipid matrix is known, the molecular-level details of its organization are difficult to infer experimentally, hindering the discovery of structure-property relationships. To this end, molecular dynamics simulations, which give molecular-level resolution, have begun to play an increasingly important role in understanding these relationships. Furthermore, most simulation studies of SC lipids have focused on preassembled bilayer configurations, which, owing to the slow dynamics of the lipids, may influence the final structure and hence the calculated properties. Self-assembled structures would avoid this dependence on the initial configuration, however, the size and length scales involved make self-assembly impractical to study with atomistic models. Here, we report on the development of coarse-grained models of SC lipids designed to study self-assembly. Building on previous work, we present the interactions between the headgroups of ceramide and free fatty acid developed using the multistate iterative Boltzmann inversion method. Validation of the new interactions is performed with simulations of preassembled bilayers and good agreement between the atomistic and coarse-grained models is found for structural properties. The self-assembly of mixtures of ceramide and free fatty acid is investigated and both bilayer and multilayer structures are found to form. This work therefore represents a necessary step in studying SC lipid systems on multiple time and length scales.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1986

The use of flight test techniques in aircraft accident investigations

Wind shear is a serious safety hazard to commercial aviation. Low level wind shear (downburst) was the cause of the takeoff accident in New Orleans, July 9, 1982, and the landing accident in Dallas, Aug. 2, 1985. Shear layer instability is a common cause of clear air turbulence (CAT) at cruising altitudes. A number of encounters with severe CAT, in which passengers were injured, have recently occurred (Hannibal, MO, April 1981; Morton, WY, July 1982; etc.). Improved accident investigation techniques can lead to a better understanding of the nature of the wind environment associated with downbursts and CAT and to better detection and avoidance procedures. For the past several years, NASA-Ames has worked closely with the National Transportation Safety Board in the investigation of wind related accidents.

Parks, E. K.↗
DOE OSTI2023

Efficient separation and coprecipitation for simplified cathode recycling

Hydrometallurgical recycling of spent lithium-ion batteries is among the most promising recovery approaches. The current hydrometallurgical method for battery recycling faces challenges such as complex separation and precipitation processes, and environmental concerns from the use of caustic inorganic acid and hazardous hydrogen peroxide. Our proposed modified method, namely polyol-metallurgy, uses citric acid in ethylene glycol as dual-function green solution to overcome these obstacles. This bifunctional solution leaches valuable metal ions from cathode materials (e.g., LiCoO 2 ), and then acts as chelating agents to selectively precipitate cobalt through an esterification reaction, without the need for additional precipitation agents. The leaching efficiency of cobalt and lithium reaches 99.55% and 97.65%, respectively, and more than 96% of cobalt could be directly self-precipitated and recovered. Further, the unique characteristics of the dual-function solution also avoids impurities from Al foils and PVDF/carbon black films, enabling the simple separation process. Therefore, the process can be completed in one-pot system with efficient leaching, separation and coprecipitation, making it more efficient and feasible for operation than existing alternatives.

25 ENERGY STORAGE↗