Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “grain shape”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Microstructure and Thermal History of Metal Particles in CH Chondrites

Fe-Ni metal particles with smooth Ni, Co, and Cr zoning patterns, 8-13 wt.% Ni in the center of the particle to 3-5 wt% Ni at the rim, have been identified in several CR-clan (CH, Bencubbinlike, and CR) chondrites. These zoning patterns are broadly consistent with an origin by gas-solid condensation in the solar nebula at temperatures between approximately 1500 to 1300 K and fast cooling rates, 2 to 25 K/day. Apparently, this condensate metal was not melted during chondrule formation or affected significantly in the solid-state by alteration during parent body processing. Consideration of diffusional redistribution of Ni, Co, Cr and siderophile elements have further constrained the calculated condensation temperatures and cooling rates of the zoned condensates. These condensate metals have irregular shapes and vary in size from 50 to 350 m as revealed in some detail by optical and SEM techniques. In addition to zoned condensate particles, other types of metal particles have been observed. These include zoned condensates with exsolution-precipitates, unzoned homogeneous metal with no exsolution precipitates, unzoned metal exhibiting exsolution precipitates and high Ni metal grains.

Goldstein, J. I.↗
NASA NTRS2012

Keck/NIRC2 Imaging of the Warped, Asymmetric Debris Disk Around HD 32297

We present Keck/NIRC2 Ks band high-contrast coronagraphic imaging of the luminous debris disk around the nearby, young A star HD 32297 resolved at a projected separation of r = 0.3-2.5 arcse (approx 35-280 AU). The disk is highly warped to the north and exhibits a complex, "wavy" surface brightness profile interior to r approx 110 AU, where the peaks/plateaus in the profiles are shifted between the NE and SW disk lobes. The SW side of the disk is 50 - 100% brighter at r = 35 - 80 AU, and the location of its peak brightness roughly coincides with the disk's mm emission peak. Spectral energy distribution modeling suggests that HD 32297 has at least two dust populations that may originate from two separate belts likely at different locations, possibly at distances coinciding with the surface brightness peaks. A disk model for a single dust belt including a phase function with two components and a 5-10 AU pericenter offset explains the disk's warped structure and reproduces some of the surface brightness profile's shape (e.g. the overall "wavy" profile, the SB peak/plateau shifts) but more poorly reproduces the disk's brightness asymmetry. Although there may be alternate explanations, agreement between the SW disk brightness peak and disk's peak mm emission is consistent with an overdensity of very small, sub-blowout-sized dust and large, 0.1-1 mm-sized grains at approx 45 AU tracing the same parent population of planetesimals. New near-IR and submm observations may be able to clarify whether even more complex grain scattering properties or dynamical sculpting by an unseen planet are required to explain HD 32297's disk structure.

Currie, Thayne↗
DOE OSTI2023

Mycorrhizal status and host genotype interact to shape plant nutrition in field grown maize ( Zea mays ssp. mays )

Arbuscular mycorrhizal fungi (AMF) establish symbioses with the major cereal crops, providing plants with increased access to nutrients while enhancing their tolerance to toxic heavy metals. However, not all plant varieties benefit equally from this association. In this study, we used quantitative trait loci (QTL) mapping to evaluate the combined effect of host genotypic variation (G) and AMF across 141 genotypes on the concentration of 20 mineral elements in the leaves and grain of field grown maize (Zea mays spp. mays). Our mapping design included selective incorporation of a castor AMF-incompatibility mutation, allowing estimation of AMF, QTL and QTLxAMF effects by comparison of mycorrhizal and non-mycorrhizal plants. Overall, AMF compatibility was associated with higher concentrations of boron (B), copper (Cu), molybdenum (Mo), phosphorus (P), selenium (Se) and zinc (Zn) and lower concentrations of arsenic (As), iron (Fe), magnesium (Mg), manganese (Mn), potassium (K) and strontium (Sr). In addition to effects on individual elements, pairwise correlation matrices for element concentration differed between mycorrhizal and non-mycorrhizal plants. We mapped 22 element QTLs, including 18 associated with QTLxAMF effects that indicate plant genotype-specific differences in the impact of AMF on the host ionome. Although there is considerable interest in AMF as biofertilizers, it remains challenging to estimate the impact of AMF in the field. Our design illustrates an effective approach for field evaluation of AMF effects. Furthermore, we demonstrate the capacity of the ionome to reveal host genotype-specific variation in the impact of AMF on plant nutrition.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2012

The Evolution of Friction Stir Welding Theory at Marshall Space Flight Center

From 1995 to the present the friction stir welding (FSW) process has been under study at Marshall Space Flight Center (MSFC). This is an account of the progressive emergence of a set of conceptual tools beginning with the discovery of the shear surface, wiping metal transfer, and the invention of a kinematic model and making possible a treatment of both metallurgical structure formation and process dynamics in friction stir welding from a unified point of view. It is generally observed that the bulk of the deformation of weld metal around the FSW pin takes place in a very narrow, almost discontinuous zone with high deformation rates characteristic of metal cutting. By 1999 it was realized that this zone could be treated as a shear surface like that in simple metal cutting models. At the shear surface the seam is drawn out and compressed and pressure and flow conditions determine whether or not a sound weld is produced. The discovery of the shear surface was followed by the synthesis of a simple 3- flow kinematic model of the FSW process. Relative to the tool the flow components are: (1) an approaching translational flow at weld speed V, (2) a rotating cylindrical plug flow with the angular velocity of the tool , and (3) a relatively slow ring vortex flow (like a smoke ring) encircling the tool and driven by shoulder scrolls and pin threads. The rotating plug flow picks up an element of weld metal, rotates it around with the tool, and deposits it behind the tool ( wiping metal transfer ); it forms plan section loops in tracers cut through by the tool. Radially inward flow from the ring vortex component retains metal longer in the rotating plug and outward flow expels metal earlier; this interaction forms the looping weld seam trace and the tongue and groove bimetallic weld contour. The radial components of the translational and ring vortex flows introduce parent metal intrusions into the small grained nugget material close to the tool shoulder; if this feature is pronounced, nugget collapse may result. Certain weld features, in particular internal banding seen in transverse section as onion rings and associated surface ridges called tool marks , have long implied an oscillation flow component, but have only recently been attributed in the literature to tool eccentricity. Rotating plug shape, typically a hollow cylinder flared at the end where it sticks to the shoulder, varies as pressure distribution on the tool determines where sticking occurs. Simplified power input estimates balanced against heat loss estimates give reasonable temperature estimates, explain why the power requirement changes hardly at all over a wide range of RPM s, and yield isotherms that seem to fall along boundaries of parameter windows of operation.

Nunes, Arthur C.↗
NASA NTRS1983

Nuclear track records in the Abee enstatite chondrite

A determination of preatmospheric mass and a delineation of cosmic ray exposure history are made, through the study of nuclear track records in 14 samples taken from different locations of an Abee enstatite chondrite cut slab. Measured track densities in different samples range from 10,000 to 1,000,000/sq cm. Excess tracks of fissiogenic origin were found near the grain edges and across cleavage planes in eight enstatite grains out of the 300 analyzed. The track data rule out preirradiation of any of the analyzed samples with shielding of less than a few tens of cm. The isotrack density contours on the plane of the slab imply an asymmetric ablation of the Abee chondrite during its atmospheric transit. A sphere of about 30 cm radius approximates the preatmospheric shape and size of the Abee meteorite, which underwent a 70% mass loss during ablation.

Goswami, J. N.↗
NASA NTRS1994

Further analysis of remnants found in LDEF and Mir impact craters

This study is the further investigation of space-exposed samples recently recovered from the American satellite LDEF and the Franco-Soviet Mir 'Aragatz' experiment. Some interesting impact features have been selected as examples to demonstrate various findings. Part of the objective of the experiments was to determine the nature and origin of particles in low earth orbit (LEO). Observations show that the 'multiple foil detectors' appear to be an effective way of retaining impactor residues of larger particles. They provide a 'witness' foil that shows the shape and dimensions of the impacting particle. Several low-velocity (less than 4 km/s) oblique craters containing significant quantities of impactor residue have been identified. Energy dispersive spectrometer (EDS) analyses of the residues show evidence of micrometeoroid and debris compositions. Similarities between the meteoroid signatures and those of Brownlee particles have been noted. Evidence of at least two different grain compositions in one impacting particle is shown. The discovery of debris impacts on the trailing edge of LDEF demonstrates that artificial debris may be found, not just in circular orbits, but also in elliptical orbits.

Berthoud, S. Lucinda↗
DOE OSTI2022

(Towards) DNS of a Laboratory Lean CH4/H2 Low-Swirl Flame Impinging on an Inclined Wall

Due to downsizing trends, flame-wall interaction (FWI) is increasingly prominent in gas turbines (GTs). FWI has direct consequences on flame stabilization and pollutant emissions, but it is not well understood in turbulent flows representative of GTs. We present results from a direct numerical simulation (DNS) of a turbulent CH4/H2 model GT low-swirl laboratory-scale flame interacting with an inclined wall. The results from the laboratory flame include simultaneous measurements of velocity using stereo particle imaging velocimetry and OHxCH2O planar laser induced fluorescence. The adaptive-mesh refinement solver PeleLMeX is used, with 24-species, 105-reaction reduced Aramco chemical kinetics mechanism. The premixed fuel-air mixture consists of hydrogen-enriched methane with 70% hydrogen volume fraction and 0.4 equivalence ratio. The inflow is prescribed to match experimental measurements at the burner exit. Karlovitz and turbulent Reynolds numbers are 300 and 400, respectively. The simulation and experimental results show excellent agreement. The flame features a bowl-shape stabilization, with a corrugated, continuous flame front at the leading edge, followed by fragmented reaction zones downstream. A large diffuse cloud of CH2O is formed downstream of the quenching point. The simulation results indicate that the cloud of CH2O is the result of incomplete methane combustion, with CH2O "leaking" from the locally quenched reaction zones.The DNS provides fine-grain resolution of turbulence-flame-wall interaction that cannot be captured with experimental measurements. With access to the entire solution vector at each cell of the computational domain, the local quenching.

flame-wall interactions↗
NASA NTRS2008

Analysis of Lunar Highland Regolith Samples from Apollo 16 Drive Core 64001/2 and Lunar Regolith Simulants - An Expanding Comparative Database

We present modal data from QEMSCAN(registered TradeMark) beam analysis of Apollo 16 samples from drive core 64001/2. The analyzed lunar samples are thin sections 64002,6019 (5.0-8.0 cm depth) and 64001,6031 (50.0-53.1 cm depth) and sieved grain mounts 64002,262 and 64001,374 from depths corresponding to the thin sections, respectively. We also analyzed lunar highland regolith simulants NU-LHT-1M, -2M, and OB-1, low-Ti mare simulants JSC-1, -lA, -1AF, and FJS-1, and high-Ti mare simulant MLS-1. The preliminary results comprise the beginning of an internally consistent database of lunar regolith and regolith simulant mineral and glass information. This database, combined with previous and concurrent studies on phase chemistry, bulk chemistry, and with data on particle shape and size distribution, will serve to guide lunar scientists and engineers in choosing simulants for their applications. These results are modal% by phase rather than by particle type, so they are not directly comparable to most previously published lunar data that report lithic fragments, monomineralic particles, agglutinates, etc. Of the highland simulants, 08-1 has an integrated modal composition closer than NU-LHT-1M to that of the 64001/2 samples, However, this and other studies show that NU-LHT-1M and -2M have minor and trace mineral (e.g., Fe-Ti oxides and phosphates) populations and mineral and glass chemistry closer to these lunar samples. The finest fractions (0-20 microns) in the sieved lunar samples are enriched in glass relative to the integrated compositions by approx.30% for 64002,262 and approx.15% for 64001,374. Plagioclase, pyroxene, and olivine are depleted in these finest fractions. This could be important to lunar dust mitigation efforts and astronaut health - none of the analyzed simulants show this trend. Contrary to previously reported modal analyses of monomineralic grains in lunar regolith, these area% modal analyses do not show a systematic increase in plagiociase/pyroxene as size fraction decreases.

Schrader, Christian M.↗
DOE OSTI2025

Production of Creep-Resistant FeCrAl-ODS

Four ODS FeCrAl alloys with base alloy composition Fe-16Cr-4Al-2Mo-0.2Y (wt.%) were mechanically alloyed with minor additions of CeO 2 and Y 2 O 3 additions and were successfully extruded into rectangular-shaped bars. Two oxide compositions were explored, which were designated NC with oxide addition of 0.5CeO 2 plus 0.2Yin solution of the base alloy powder and PC with additions of 0.5CeO 2 and 0.7Y 2 O 3 to elevate the O level. The microstructure of both alloys revealed by SEM and EBSD to consist of very small grains with sizes of ~450-520 nm and weak texture components. Sub-size tensile specimens fabricated from both alloys were tensile tested from room temperature to 800ºC. The results for both alloys from room temperature to 400ºC showed very high strengths, but low ductilities, especially uniform strain. From 500ºC to 800ºC, the strengths decreased rapidly, and the ductilities increased significantly. The reason for the rapid decreases in tensile strengths above 500ºC for both alloys is not clear, but will require advanced characterization techniques including atom probe tomography, to determine the size and number density of the nano-size oxide particles, and TEM/EFTEM, for investigating the dispersion of nano-size oxide particles on grain boundaries to assess the Zener grain boundary pinning effect, which will hinder grain coarsening at high temperatures that may enhance the Hall Petch strengthening mechanism.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Creation of Multi-Principal Element Alloy NiCoCr Nanostructures via Nanosecond Laser-Induced Dewetting

The multi-principal element alloy nanoparticles (MPEA NPs), a new class of nanomaterials, present a highly rewarding opportunity to explore new or vastly different functional properties than the traditional mono/bi/multimetallic nanostructures due to their unique characteristics of atomic-level homogeneous mixing of constituent elements in the nanoconfinements. Here, in this paper, the successful creation of NiCoCr nanoparticles, a well-known MPEA system is reported, using ultrafast nanosecond laser-induced dewetting of alloy thin films. Nanoparticle formation occurs by spontaneously breaking the energetically unstable thin films in a melt state under laser-induced hydrodynamic instability and subsequently accumulating in a droplet shape via surface energy minimization. While NiCoCr alloy shows a stark contrast in physical properties compared to individual metallic constituents, i.e., Ni, Co, and Cr, yet the transient nature of the laser-driven process facilitates a homogeneous distribution of the constituents (Ni, Co, and Cr) in the nanoparticles. Using high-resolution chemical analysis and scanning nanodiffraction, the environmental stability and grain arrangement in the nanoparticles are further investigated. Thermal transport simulations reveal that the ultrashort (≈100 ns) melt-state lifetime of NiCoCr during the dewetting event helps retain the constituent elements in a single-phase solid solution with homogenous distribution and opens the pathway to create the unique MPEA nanoparticles with laser-induced dewetting process.

36 MATERIALS SCIENCE↗
NASA NTRS2012

Constraining the Origin of Impact Craters on Al Foils from the Stardust Interstellar Dust Collector

Preliminary examination (PE) of the aerogel tiles and Al foils from the Stardust Interstellar Dust Collector has revealed multiple impact features. Some are most likely due to primary impacts of interstellar dust (ISD) grains, and others are associated with secondary impacts of spacecraft debris, and possibly primary impacts of interplanetary dust particles (IDPs) [1, 2]. The current focus of the PE effort is on constraining the origin of the individual impact features so that definitive results from the first direct laboratory analysis of contemporary ISD can be reported. Because crater morphology depends on impacting particle shape and composition, in addition to the angle and direction of impact, unique particle trajectories are not easily determined. However, elemental analysis of the crater residues can distinguish real cosmic dust from the spacecraft debris, due to the low cosmic abundance of many of the elements in the spacecraft materials. We present here results from the elemental analysis of 24 craters and discuss the possible origins of 4 that are identified as candidate ISD impacts

Stroud, Rhonda M.↗
DOE OSTI2023

Martini 3 Coarse-Grained Force Field for Cholesterol

Cholesterol plays a crucial role in biomembranes by regulating various properties, such as fluidity, rigidity, permeability, and organization of lipid bilayers. The latest version of the Martini model, Martini 3, offers significant improvements in interaction balance, molecular packing, and inclusion of new bead types and sizes. However, the release of the new model resulted in the need to reparameterize many core molecules, including cholesterol. Here, we describe the development and validation of a Martini 3 cholesterol model, addressing issues related to its bonded setup, shape, volume, and hydrophobicity. In conclusion, the proposed model mitigates some limitations of its Martini 2 predecessor while maintaining or improving the overall behavior.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1987

Light echoes - Type II supernovae

Type II supernovae (SNs) light curves show a remarkable range of shapes. Data have been collected for the 12 Type II SNs that have light curve information for more than four months past maximum. Contrary to previous reports, it is found that (1) the decay rate after 100 days past maximum varies by almost an order of magnitude and (2) the light curve shapes are not bimodally distributed, but actually form a continuum. In addition, it is found that the extinctions to the SNs are related to the light curve shapes. This implies that the absorbing dust is local to the SNs. The dust is likely to be part of a circumstellar shell emitted by the SN progenitor that Dwek (1983) has used to explain infrared echoes. The optical depth of the shell can get quite large. In such cases, it is found that the photons scattered and delayed by reflection off dust grains will dominate the light curve several months after peak brightness. This 'light echo' offers a straightforward explanation of the diversity of Type II SN light curves.

Schaefer, Bradley E.↗
NASA NTRS1985

Mechanical testing of large thallium doped sodium iodide single crystals

The findings of mechanical tests performed on five thallium-doped sodium iodide NaI(Tl) crystals are presented. These crystals are all in the shape of circular flat plates, 20.0 in. in diameter an d0.5 in. thick. The test setup, testing procedure, and the test data are presented. Large crystals exhibit a high degree of material plasticity, as well as a much higher strength than previously anticipated, on the order of 500 psi. Also revealed from the testing is the fact that crystal with a large number of grain boundaries developed less plasticity, and therefore less permanent deformation, than those with fewer grain boundaries.

Lee, H. M.↗
NASA NTRS1990

Towards a circumstellar silicate mineralogy

This paper reviews the formation, composition, and spectroscopy of circumstellar silicate grains. It is argued that 'clean' silicates (and oxides) are formed close to the stellar photosphere, but because of their low NIR absorptivity, these grains float with the gas in the pulsating photosphere until, at large distances from the stellar surface, enough Fe(2+) is incorporated (i.e., 'dirty' silicates) for radiation pressure to drive a dusty outflow. The silicate chemical condensation sequence is reviewed with emphasis on kinetics rather than thermodynamics, and likely condensates are identified. IRAS LRS spectra of tenuous dust shells show considerable variations in the shape of the 10-micron feature and at least 5 independent spectral components are indicated. These are compared with laboratory spectra and (preliminary) identifications are proposed.

Tielens, A. G. G. M.↗
DOE OSTI2024

Visualizing the Internal Nanocrystallinity of Calcite Due to Nonclassical Crystallization by 3D Coherent X–Ray Diffraction Imaging

The internal crystallinity of calcite is investigated for samples synthesized using two approaches: precipitation from solution and the ammonium carbonate diffusion method. Scanning electron microscopy (SEM) analyses reveal that the calcite products precipitated using both approaches have a well–defined rhombohedron shape, consistent with the euhedral crystal habit of the mineral. The internal structure of these calcite crystals is characterized using Bragg coherent diffraction imaging (BCDI) to determine the 3D electron density and the atomic displacement field. BCDI reconstructions for crystals synthesized using the ammonium carbonate diffusion approach have the expected euhedral shape, with internal strain fields and few internal defects. In contrast, the crystals synthesized by precipitation from solution have very complex external shapes and defective internal structures, presenting null electron density regions and pronounced displacement field distributions. These heterogeneities are interpreted as multiple crystalline domains, created by a nonclassical crystallization mechanism, where smaller nanoparticles coalescence into the final euhedral particles. The combined use of SEM, X–ray diffraction (XRD), and BCDI allows for structurally differentiating calcite crystals grown with different approaches, opening new opportunities to understand how grain boundaries and internal defects alter calcite reactivity.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Sequence-defined Pareto frontier of a copolymer structure

The correlations between the sequence of monomers in a macromolecule and its three-dimensional (3D) structure is a grand challenge in polymer science. The properties and functions of macromolecules depend on their 3D shape that has appeared to be dictated by their monomer sequence. However, the progress towards understanding the sequence–structure-property correlations and their utilization in materials engineering are slow because it is almost impossible to characterize an astronomically large number of possible sequences of a copolymer using traditional experimental and simulation methods. To address this problem, here, we combine evolutionary computing and coarse-grained molecular dynamics (CGMD) simulation and study the sequence-structure correlations of a model AB-type copolymer in a solution and assess the impact of sequence on the packing density in its bulk phase. The CGMD-based evolutionary algorithm (EA) screens the sequence space of a single chain copolymer efficiently and identifies a wide range of single-molecule structures including extremal radii of gyration. The data are utilized to estimate the Pareto front of the structure-space of a binary copolymer as a function of its composition. The monomer packings in single-molecule solution phase and multimolecular bulk phase are found to be identical. Finally, this work highlights the opportunities of sequence-specific control of macromolecular structure for designing target materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗