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At least 577 records · Page 32

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NASA NTRS1988

Experimental results on atomic oxygen corrosion of silver

The results of an experimental study of the reaction kinetics of silver with atomic oxygen in 10 degree increments over the temperature range of 0 to 70 C is reported. The silver specimens, of the order of 10,000 A in thickness, were prepared by thermal evaporation onto 3 inch diameter polished silicon wafers. There were later sliced into pieces having surface areas of the order of 1/4 to 1/2 square inch. Atomic oxygen was generated by a gas discharge in a commercial plasmod asher operating in the megahertz frequency range. The sample temperature within the chamber was controlled by means of a thermoelectric unit. Exposure of the silver specimens to atomic oxygen was incremental, with oxide film thickness measurements being carried out between exposures by means of an automated ellipsometer. For the early growth phase, the data can be described satisfactorily by a logarithmic growth law: the oxide film thickness increases as the logarithm of the exposure time. Furthermore, the oxidation process is thermally activated, the rate increasing with increasing temperature. However, the empirical activation energy parameter deduced from Arrhenius plots is quite low, being of the order of 0.1 eV.

Fromhold, Albert T.↗

NASA NTRS1989

Atomic oxygen effects on spacecraft materials: The state of the art of our knowledge

In the flight materials exposure data base extensive quantitative data is available from limited exposures in a narrow range of orbital environments. More data is needed in a wider range of environments as well as longer exposure times. Synergistic effects with other environmental factors; polar orbit and higher altitude environments; and real time materials degradation data is needed to understand degradation kinetics and mechanism. Almost no laboratory data exists from high fidelity simulations of the LEO environment. Simulation and test system are under development, and the data base is scanty. Theoretical understanding of hyperthermal atom surface reactions in the LEO environment is not good enough to support development of reliable accelerated test methods. The laser sustained discharge, atom beam sources are the most promising high fidelity simulation-test systems at this time.

Koontz, Steven L.↗

NASA NTRS1989

Space nuclear reactor shields for manned and unmanned applications

Missions which use nuclear reactor power systems require radiation shielding of payload and/or crew areas to predetermined dose rates. Since shielding can become a significant fraction of the total mass of the system, it is of interest to show the effect of various parameters on shield thickness and mass for manned and unmanned applications. Algorithms were developed to give the thicknesses needed if reactor thermal power, separation distances, and dose rates are given as input. The thickness algorithms were combined with models for four different shield geometries to allow tradeoff studies of shield volume and mass for a variety of manned and unmanned missions. Shield design tradeoffs presented in this study include the effects of: higher allowable dose rates; radiation hardened electronics; shorter crew exposure times; shield geometry; distance of the payload and/or crew from the reactor; and changes in the size of the shielded area. Specific NASA missions that were considered in this study include unmanned outer planetary exploration, manned advanced/evolutionary space station, and advanced manned lunar base.

Mckissock, Barbara I.↗

NASA NTRS1989

Impact of heterogeneous reactions on stratospheric chemistry of the Arctic

The possible depletion of ozone due to heterogeneous reactions occurring in Arctic polar stratospheric clouds (PSCs) is fundamentally different from the Antarctic situation. PSCs in the Arctic are relatively short-lived and occur over limited regions of the Arctic stratosphere. The Arctic situation is examined using a model which calculates photochemical processes as a function of longitude in air circulating with fixed velocity around the pole at fixed pressure level and latitude. The model allows sunlight to vary diurnally and PSCs to occur in specified subregions of the domain. Measurements of chemical species including HCl, ClO, NO2 and HNO3 downwind from a PSC should show obvious changes compared to measurements in air unaffected by clouds. These species concentrations are found to be sensitive to sticking coefficients, cloud characteristics including particle number density and surface area, and to the PSC exposure time.

Douglass, Anne R.↗

NASA NTRS1989

Reduced reactivity to air on HF-treated YBa2Cu3O(7-x)surfaces

Treatment of YBa2Cu3O(7-x) films with a nonaqueous solution of HF in absolute ethanol results in the formation of an oxyfluoride with relative Y:Ba:Cu concentrations of 1:4:3 on the surface, as determined by X-ray photoelectron spectroscopy. The passivation properties of chemically treated films were tested by monitoring the growth of the high binding energy O 1s peak, associated with nonsuperconducting surface species, as a function of air exposure time, for both HF-treated and untreated films. The native oxyfluoride is shown to reduce the reactivity of the superconductor to air.

Vasquez, R. P.↗

NASA NTRS1989

Deformation and fracture of single-crystal and sintered polycrystalline silicon carbide produced by cavitation

An investigation was conducted to examine the deformation and fracture behavior of single-crystal and sintered polycrystalline SiC surfaces exposed to cavitation. Cavitation erosion experiments were conducted in distilled water at 25 C by using a magnetostrictive oscillator in close proximity (1 mm) to the surface of SiC. The horn frequency was 20 kHz, and the double amplitude of the vibrating disk was 50 microns. The results of the investigation indicate that the SiC (0001) surface could be deformed in a plastic manner during cavitation. Dislocation etch pits were formed when the surface was chemically etched. The number of defects, including dislocations in SiC (0001) surface, increased with increasing exposure time to cavitation. The presence of intrinsic defects such as voids in the surficial layers of the sintered polycrystalline SiC determined the zones at which fractured grains and fracture pits (pores) were generated. Single-crystal SiC had superior erosion resistance to that of sintered polycrystalline SiC.

Miyoshi, Kazuhisa↗

NASA NTRS1990

Preparation Of High-Temperature Reactive Oligomers

Very reactive materials form very-heat-stable polymers. Recent research directed toward synthesis of polyimides soluble in common organic solvents, melt-processable, and thermally curable without evolution of volatile by-products. Diels-Alder polymerization yields compounds that maintain integrities and toughnesses during long exposure times at high temperatures. High-temperature polymers synthesized by use of technique. Films and perhaps fibers fabricated from prepolymer in solution. Major potential at this stage of research limited to aerospace applications.

Ottenbrite, Raphael M.↗

NASA NTRS1989

Display interface concepts for automated fault diagnosis

An effort which investigated concepts for displaying dynamic system status and fault history (propagation) information to the flight crew is described. This investigation was performed by developing several candidate display formats and then conducting comprehension tests to determine those characteristics that made one format preferable to another for presenting this type of information. Twelve subjects participated. Flash tests, or limited time exposure tests, were used to determine the subjects' comprehension of the information presented in the display formats. It was concluded from the results of the comprehension tests that pictographs were more comprehensible than both block diagrams and text for presenting dynamic system status and fault history information, and that pictographs were preferred over both block diagrams and text. It was also concluded that the addition of this type of information in the cockpit would help the crew remain aware of the status of their aircraft.

Palmer, Michael T.↗

NASA NTRS1989

Bis(4-(3,4-dimethylenepyrrolidyl)-phenyl) methane

It is the primary object of the present invention to prepare high temperature polymeric materials, especially linear aromatic polyimides, which maintain their integrity and toughness during long exposure times at elevated temperatures. According to the present invention, this object is achieved, and the attending benefits are obtained, by first providing the bis(exocyclodiene) bis(4-(3,4-dinethylene pyrrolidyl) phenyl) methane, which is formed from the monomer N-phenyl 3,4-dimethylene pyrrolidine. This bis-(exocyclodiene) undergoes Diels-Alder reaction with a bismaleimide without the evolution of gaseous by-products, to form the aromatic polyimide.

Ottenbrite, Raphael M.↗

NASA NTRS1988

Photon degradation of AlGaAs/GaAs solar cells

The behavior of GaAs solar cells after photon illumination for a prolonged exposure time is presented. More than 55 OMCVD AlGaAs/GaAs solar cells were exposed for over 400 h to AM0 photons at 28 C in three separate, well-controlled runs. Significant degradation of solar cell efficiency was observed in two out of three runs. Although noticeable losses in the open-circuit voltage, fill factor, and maximum power were observed, no change in the short-circuit current was found. In one of the runs, no change was seen in either the test cells or the control cells. Each cell in this run was protected with a coverglass. The cells in this run had thicker buffer layers and thinner window layers than the cells in the other two runs.

Anspaugh, Bruce↗

NASA NTRS1989

Ellipsometric study of Al2O3/Ag/Si and SiO2/Ag/quartz ashed in an oxygen plasma

The growth of silver oxide (proposed as a potentially useful protective coating for space environment) on a silver mirror coated with an Al2O3 or a SiO2 protective layer was investigated using the monolayer-sensitive variable angle of incidence spectroscopic ellipsometry technique. The samples were exposed to a pure oxygen plasma in a plasma asher, and the silver oxide growth was monitored as a function of the exposure time. It was found that atomic oxygen in the asher penetrated through the SiO2 or Al2O3 coatings to convert the silver underneath to silver oxide, and that the quantity of the silver oxide formed was proportional to the ashing time. The band gap of silver oxide was determined to be 1.3 eV. A schematic diagram of the variable angle of incidence spectroscopic ellipsometer is included.

De, Bhola N.↗

NASA NTRS1990

Space nuclear reactor shields for manned and unmanned applications

Mckissock, Barbara I.↗

NASA NTRS1990

Oxidation characteristics of Ti-25Al-10Nb-3V-1Mo intermetallic alloy

Static oxidation kinetics of the super-alpha 2 titanium-aluminide alloy Ti-25Al-10Nb-3V-1Mo (at. percent) were investigated in air over the temperature range of 650 to 1000 C using thermogravimetric analysis. The oxidation kinetics were complex at all exposure temperatures and displayed up to three distinct oxidation rates. Breakaway oxidation occurred after long exposure times at high temperatures. Oxidation products were determined using x ray diffraction techniques, electron microprobe analysis, and energy dispersive x ray analysis. Oxide scale morphology was examined by scanning electron microscopy of the surfaces and cross sections of oxidized specimens. The oxides during the parabolic stages were compact and multilayered, consisting primarily of TiO2 doped with Nb, a top layer of Al2O3, and a thin bottom layer of TiN. The transition between the second and third parabolic stage was found to be linked to the formation of a TiAl layer at the oxide-metal interface. Porosity was formed during the third stage, causing degradation of the oxide and the beginning of breakaway oxidation.

Wallace, Terryl A.↗

NASA NTRS1990

Bis (4-(3,4-dimethylene-pyrrolidyl)-phenyl) methane

The primary objective is to prepare high temperature polymeric materials, especially linear aromatic polyimides, which maintain their integrity and toughness during long exposure times at elevated temperatures. The attained benefits are obtained by first providing the bis (exocyclodiene) bis (4-(3,4-dimethylene-pyrrolidyl)-phenyl) methane, which is a novel material formed from the monomer N-phenyl-3,4-dimethylene-pyrrolidine. This compound undergoes Diels-Alder reaction with a bismaleimide, without the evolution of gaseous by-products, to form the aromatic polyimide bis (4-(3,4-dimethylene-pyrrolidyl)-phenyl) methane.

Ottenbrite, Raphael M.↗

NASA NTRS1990

IUE observations of comets P/Brorsen-Metcalf and Okazaki-Levy-Rudenko

Comet P/Brorsen-Metcalf (1989c) was observed with the International Ultraviolet Explorer (IUE) on several dates from 27 July 1989 through 5 August 1989; comet Okazaki-Levy-Rudenko (1989r) was observed in low dispersion with IUE on 2 and 22 December 1989. The water production rates for P/Brorsen-Metcalf were derived from OH measurements using the vectorial model of Festou (1981). Included also are the water production rates for Okazaki-Levy-Rudenko. Two estimates of the water production rate from the O I emission around 1304 A(octogons) are included. The ultraviolet continuum was not reliably measurable in comet P/Brorsen-Metcalf in most of the spectra, but Afp is approximately 30 cm for 2 August. For the comet Okazaki-Levy-Rudenko, an Afp = 50 cm was derived for 22 December. Both comets have very little dust compared to other recently observed comets. The ratio of CS to water production rates are presented. Relative to water, both comets had less CS than P/Halley in the same range of heliocentric distances. The CS production rates were obtained from a Haser model, assuming a short-lived parent (CS2). Because the dynamic range of the IUE spectrographs are limited, not all species can be measured in each spectrum. The P/Brorsen-Metcalf spectra from 31 July and 3 August were obtained from the NSSDC Archives. Due to the observing technique used for these spectra, the exposure time and hence, the brightnesses and derived quantities have a small uncertainty associated with them.

Roettger, E. E.↗

NASA NTRS1991

Stellar photometry with the Hubble Space Telescope Wide-field/Planetary camera - A progress report

The prospects for the use of the Wide-Field/Planetary Camera (WFPC) for stellar photometry are described. The large halos of the point-spread function (PSF) resulting from spherical aberration and from spatial, temporal, and color variations of the PSF are the main limitations to accurate photometry. Degradations caused by crowding are exacerbated by the halos of the PSF. An attempt is made to quantify these effects and determine the current accuracy of stellar photometry with the WFPC. In realistic cases, the brighter stars in crowded fields have 0.09 mag errors; fainter stars have larger errors depending on the degree of crowding. It is shown that measuring Cepheids in Virgo Cluster galaxies is not currently possible without inordinate increases in exposure times.

Holtzman, Jon A.↗

NASA NTRS1990

Neptune encounter - Guidance and control's finest hour

The Voyager 2 technology had to be stretched significantly to confront the challenges posed by the environment of Neptune. Little was known about Neptune's characteristics because of its great distance from the sun; and its reduced light levels required longer exposure time. Thus, it was necessary to reduce the spacecraft limit cycle; this was made more difficult by the trajectory selected, which caused high spacecraft-to-target rates (these rates dictated the use of image motion compensation). Another challenge faced by Voyager 2 was the need to perform all the required image motion compensation with a limited quantity of attitude control computer and command computer memory, together with a limited quantity of tape recorder resources. This made necessary a new concept of real-time image motion compensation.

Miller, Maurine↗

NASA NTRS1990

Environmental interactions on Space Station

This paper describes the key environment/system interactions associated with the Space Station and its companion polar platform and defines the range of test environments that will need to be simulated. These environments include the neutral atmosphere, the ionospheric plasma, natural and man-made particulates, the ambient magnetic field, the South Atlantic Anomaly, and the ram/wake environment. The system/environment interactions include glow, oxygen erosion, drag, radiation effects, induced electric fields, high-voltage solar-array effects, and EMC/EMI associated with plasma/neutral gas operations. The Space Station and its associated systems pose unique demands on the ability to simulate these effects; synergistic effects require multiple environments to be simulated simultaneously, and the long life requirements require proper scaling of the exposure time. The analysis of specific effects and the calibration or improvement of ground test techniques will likely require in situ evaluation. Qualification and acceptance testing, because of cost and the impractically of extensive on-orbit analysis/modification, will likely remain ground test objectives except in very rare cases.

Garrett, Henry B.↗