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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32

Use of NASA Near Real-Time and Archived Satellite Data to Support Disaster Assessment

NASA's Short‐term Prediction Research and Transition (SPoRT) Center partners with the NWS to provide near realtime data in support of a variety of weather applications, including disasters. SPoRT supports NASA's Applied Sciences Program: Disasters focus area by developing techniques that will aid the disaster monitoring, response, and assessment communities. SPoRT has explored a variety of techniques for utilizing archived and near real‐time NASA satellite data. An increasing number of end‐users - such as the NWS Damage Assessment Toolkit (DAT) - access geospatial data via a Web Mapping Service (WMS). SPoRT has begun developing open‐standard Geographic Information Systems (GIS) data sets via WMS to respond to end‐user needs.

McGrath, Kevin M.↗

Load‐balanced and locality‐aware scheduling for data‐intensive workloads at extreme scales

Summary Data‐driven programming models such as many‐task computing (MTC) have been prevalent for running data‐intensive scientific applications. MTC applies over‐decomposition to enable distributed scheduling. To achieve extreme scalability, MTC proposes a fully distributed task scheduling architecture that employs as many schedulers as the compute nodes to make scheduling decisions. Achieving distributed load balancing and best exploiting data locality are two important goals for the best performance of distributed scheduling of data‐intensive applications. Our previous research proposed a data‐aware work‐stealing technique to optimize both load balancing and data locality by using both dedicated and shared task ready queues in each scheduler. Tasks were organized in queues based on the input data size and location. Distributed key‐value store was applied to manage task metadata. We implemented the technique in MATRIX, a distributed MTC task execution framework. In this work, we devise an analytical suboptimal upper bound of the proposed technique, compare MATRIX with other scheduling systems, and explore the scalability of the technique at extreme scales. Results show that the technique is not only scalable but can achieve performance within 15% of the suboptimal solution. Copyright © 2015 John Wiley & Sons, Ltd.

Wang, Ke↗

Engineering the solid oxide fuel cell electrocatalyst infiltration technique for industrial use

We explore various parameters for infiltrating La 0.6 Sr 0.4 CoO 3-δ (LSCo) into the La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ (LSCF) – Ce 0.8 Sm 0.2 O 2 (SDC) cathode of a planar solid oxide fuel cell (SOFC) using an automated solution dispensing technique for commercial deployment of infiltrated SOFCs by industry. Substrate temperature, chelating agent concentration, and surfactant type were explored to develop a 1-step infiltration process for delivering 8–10 weight percent of LSCo electrocatalyst to the cathode active layer. Finally, the results confirm increased fuel cell performance and durability by optimizing the infiltrate solution for increased transport into the cathode's microstructure.

25 ENERGY STORAGE↗

Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode

A molecular-level understanding of the reactions that occur at the lithium-metal anode/electrolyte interphase is essential to improve the performance of Li–O2 batteries. Experimental and computational techniques are applied to explore the reactivity of tri(ethylene glycol)-substituted trimethylsilane (1NM3), a siloxane-based ether electrolyte, at the lithium-metal anode. In situ/ex situ X-ray diffraction and Fourier-transform infrared spectroscopy studies provide evidence of the formation of lithium hydroxide and lithium carbonates at the anode upon gradual degradation of the metallic lithium anode and the solvent molecules in the presence of oxygen. Density functional calculations performed to obtain a mechanistic understanding of the reductive decomposition of 1NM3 indicate that the decomposition does not require any apparent barrier to produce lithium hydroxide and lithium carbonates when the reduced 1NM3 solvent molecules interact with the oxygen crossing over from the cathode. This study indicates that degradation may be more significant in the case of the 1NM3 solvent, compared to linear ethers such as tetraglyme or dioxalone, because of its relatively high electron affinity. Also, both protection of the lithium metal and prevention of oxygen crossover to the anode are essential for minimizing electrolyte and anode decomposition.

Environmental Molecular Sciences Laboratory↗

Traverse Planning Experiments for Future Planetary Surface Exploration

The purpose of the investigation is to evaluate methodology and data requirements for remotely-assisted robotic traverse of extraterrestrial planetary surface to support human exploration program, assess opportunities for in-transit science operations, and validate landing site survey and selection techniques during planetary surface exploration mission analog demonstration at Haughton Crater on Devon Island, Nunavut, Canada. Additionally, 1) identify quality of remote observation data sets (i.e., surface imagery from orbit) required for effective pre-traverse route planning and determine if surface level data (i.e., onboard robotic imagery or other sensor data) is required for a successful traverse, and if additional surface level data can improve traverse efficiency or probability of success (TRPF Experiment). 2) Evaluate feasibility and techniques for conducting opportunistic science investigations during this type of traverse. (OSP Experiment). 3) Assess utility of remotely-assisted robotic vehicle for landing site validation survey. (LSV Experiment).

Hoffman, Stephen J.↗

Application of multiple criteria decision methods in space exploration initiative design and planning

Fellowship activities were directed towards the identification of opportunities for application of the Multiple Criteria Decision Making (MCDM) techniques in the Space Exploration Initiative (SEI) domain. I identified several application possibilities and proposed demonstration application in these three areas: evaluation and ranking of SEI architectures, space mission planning and selection, and space system design. Here, only the first problem is discussed. The most meaningful result of the analysis is the wide separation between the two top ranked architectures, indicating a significant preference difference between them. It must also be noted that the final ranking reflects, to some extent, the biases of the evaluators and their understanding of the architecture.

Masud, Abu S. M.↗

Multifunctional application of nanoscratch technique to characterize cementitious materials

This study aims to further explore the multifunctional applicability of nanoscratch technique to cementitious materials for comprehensive characterization. Based on the investigation of deformation, applied force, and fracture toughness of hardened cement paste during scratching, the methods of phase identification, fracture toughness of individual phase, and the interfacial transition zone (ITZ) thickness quantification were proposed and discussed. After redefining the vertical loading rate of scratching, the slope of the square scratching depth vs. scratching length is recognized as a reliable parameter to distinguish the individual phases for the first time. A fracture toughness-based method is proposed to quantify the thickness of ITZ between clinker and hydrates. Meanwhile, the applicability of phase identification by the scratch method is discussed for different transverse scratching speeds and the vertical loading rates. The findings will benefit the investigation and mechanism understanding of cementitious materials at the microscale by utilizing nanoscratch technique.

36 MATERIALS SCIENCE↗

Mirror-smooth surfaces and repair of defects in superconducting RF cavities by mechanical polishing

Mechanical techniques for polishing the inside surface of niobium superconducting radio-frequency (SRF) cavities have been systematically explored. By extending known techniques to fine polishing, mirror-like finishes were produced, with <15 nm RMS (root mean square) roughness over 1 mm2 scan area. This is an order of magnitude less than the typical roughness produced by the electropolishing of niobium cavities. The extended mechanical polishing (XMP) process was applied to several SRF cavities which exhibited equator defects that caused quench at <20 MV m-1 and were not improved by further electropolishing. Cavity optical inspection equipment verified the complete removal of these defects, and minor acid processing, which dulled the mirror finish, restored performance of the defective cells to the high gradients and quality factors measured for adjacent cells when tested with other harmonics. This innate repair feature of XMP could be used to increase manufacturing yield. Excellent superconducting properties resulted after initial process optimization, with quality factor Q of 3 × 1010 and accelerating gradient of 43 MV m-1 being attained for a single-cell TESLA cavity, which are both close to practical limits. Several repaired nine-cell cavities also attained Q > 8 × 109 at 35 MV m-1, which is the specification for the International Linear Collider. Future optimization of the process and pathways for eliminating requirements for acid processing are also discussed.

43 PARTICLE ACCELERATORS↗

Calibration of the spin-scan ozone imager aboard the dynamics Explorer 1 satellite

The calibration technique, which contains the calibrated backscattered radiance values necessary for performing the calibrations, is presented. The calibration constants for September to October 1981 to determine total columnar ozone from the Spin-Scan Ozone Imager (SOI), which is a part of the auroral imaging instrumentation aboard the Dynamics Explorer 1 Satellite, are provided. The precision of the SOI-derived total columnar ozone is estimated to be better than 2.4 percent. Linear regression analysis was used to calculate correlation coefficients between total columnar ozone obtained from Dobson ground stations and SOI which indicate that the SOI total columnar ozone determination is equally accurate for clear or cloudy weather conditions.

Bressette, Walter E.↗

High-throughput manufacturing of epitaxial membranes from a single wafer by 2D materials-based layer transfer process

Layer transfer techniques have been extensively explored for semiconductor device fabrication as a path to reduce costs and to form heterogeneously integrated devices. These techniques entail isolating epitaxial layers from an expensive donor wafer to form freestanding membranes. However, current layer transfer processes are still low-throughput and too expensive to be commercially suitable. Here we report a high-throughput layer transfer technique that can produce multiple compound semiconductor membranes from a single wafer. We directly grow two-dimensional (2D) materials on III–N and III–V substrates using epitaxy tools, which enables a scheme comprised of multiple alternating layers of 2D materials and epilayers that can be formed by a single growth run. Each epilayer in the multistack structure is then harvested by layer-by-layer mechanical exfoliation, producing multiple freestanding membranes from a single wafer without involving time-consuming processes such as sacrificial layer etching or wafer polishing. Moreover, atomic-precision exfoliation at the 2D interface allows for the recycling of the wafers for subsequent membrane production, with the potential for greatly reducing the manufacturing cost.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Target development using the method of High-Intensity Vibrational Powder Plating (HIVIPP) at the Center for Accelerator Target Science (CATS) at Argonne National Laboratory (ANL)

One of the primary goals of the Center for Accelerator Target Science (CATS) is to provide targets and foils in support of the ATLAS User Facility and the Low-Energy community at large. While a wide array of target production techniques are available at CATS, new methods that must be explored invariably arise. One such technique, the High-Intensity Vibrational Powder Plating (HIVIPP), was first reported in 1997 by Isao Sugai. It was developed to produce targets and stripper foils that were difficult to make by standard methods. At Argonne National Laboratory (ANL), we have successfully constructed and tested a simple system for this purpose. We have produced targets of carbon and titanium on various metal backings using the HIVIPP method. We are currently in the exciting phase of exploring the production of other elements, including isotopically enriched and radioactive material. This work is in progress and will be further detailed with specific examples.

47 OTHER INSTRUMENTATION↗

Hydrothermal Exploration Best Practices and Geothermal Knowledge Exchange on OpenEI

Though exploring for hydrothermal resources is not new, advances in exploration technologies and the pursuit of less visible resources have created a need to outline exploration best practices. This multi-year study outlines 21 geothermal exploration regions in the Western United States. These regions were developed based on the U.S. Geological Survey (USGS) physiographic regions, then adjustedto fit geothermal parameters such as differences in geologic regime, structure, heat source, surface effects (weather, vegetation patterns, groundwater flow), and other relevant factors. Literature searches were conducted in each of these 21 regions for the application of field reconnaissance, geochemical, geophysical and remote sensing techniques. At this time, data from more than 250 referenceshave been cataloged in U.S. Department of Energy's (DOE) OpenEnergy Information (OpenEI, http://en.openei.org) website, which allows industry to access data information and run analyses on specific data attributes. The platform also allows updates, edits, and additions from the public so that the dataset can be expanded as industry's knowledge grows. In addition to the literature survey,interviews were conducted with exploration experts with both geothermal and oil-and-gas industry experience to identify the exploration challenges and best practices for the exploration regions. This paper defines and describes the geothermal regions developed for this study, describes how exploration techniques contribute to hydrothermal analyses (structural, petrologic, temperature, andhydrologic), and defines the exploration hurdles and best practices for each region. The results of the study and accompanying data sets on OpenEI will be available through the National Geothermal Data System.

15 GEOTHERMAL ENERGY↗

Descriptor Aided Bayesian Optimization for Many-Level Qualitative Variables With Materials Design Applications

Abstract Engineering design often involves qualitative and quantitative design variables, which requires systematic methods for the exploration of these mixed-variable design spaces. Expensive simulation techniques, such as those required to evaluate optimization objectives in materials design applications, constitute the main portion of the cost of the design process and underline the need for efficient search strategies—Bayesian optimization (BO) being one of the most widely adopted. Although recent developments in mixed-variable Bayesian optimization have shown promise, the effects of dimensionality of qualitative variables have not been well studied. High-dimensional qualitative variables, i.e., with many levels, impose a large design cost as they typically require a larger dataset to quantify the effect of each level on the optimization objective. We address this challenge by leveraging domain knowledge about underlying physical descriptors, which embody the physics of the underlying physical phenomena, to infer the effect of unobserved levels that have not been sampled yet. We show that physical descriptors can be intuitively embedded into the latent variable Gaussian process approach—a mixed-variable GP modeling technique—and used to selectively explore levels of qualitative variables in the Bayesian optimization framework. This physics-informed approach is particularly useful when one or more qualitative variables are high dimensional (many-level) and the modeling dataset is small, containing observations for only a subset of levels. Through a combination of mathematical test functions and materials design applications, our method is shown to be robust to certain types of incomplete domain knowledge and significantly reduces the design cost for problems with high-dimensional qualitative variables.

Engineering↗

ACTS advanced system concepts and experimentation

Over the course of the first two years of experimentation with the Advanced Communications Technology Satellite (ACTS), many different K/Ka-band applications-oriented experiments will be conducted and evaluated for their commercial viability. In addition, the technological developments and advanced systems concepts associated with the various terminals and the satellite itself will also be examined. Beyond these existing experiments and the current terminal developments, many other new and exciting experiment ideas and advanced system concepts exist. With the additional use of ACTS for the last two years of its lifetime, many of these ideas could be explored. In the mobile satellite communications arena, a particular applications-oriented concept that has yet to be developed is a maritime-mobile experiment. Applications of K/Ka-band mobile satcom technologies to the pleasure cruise industry could provide similar communications services as those that are being developed for the broadband aeronautical experiments. A second applications-oriented experiment that could be of interest is the development of a hybrid satellite-cellular system experiment. In such an experimental system, a mobile K/Ka-band satellite service would extend the coverage of the already existing cellular network. Many new system concepts and terminal developments could also be accomplished. The initial characterization of the K/Ka-band mobile satellite communications propagation channel and evaluation of the currently existing rain compensation algorithms (RCA's) could lead to a second generation RCA development that would improve the overall ACTS Mobile Terminal (AMT) performance. In addition, the development of an enhanced modem to be used with the AMT that utilizes CDMA spread spectrum would also improve the overall terminal efficiency and provide a greater commercial potential for K/Ka-band applications. Other techniques worthy of further exploration and evaluation include the development of new Doppler estimation algorithms and demodulation techniques such as pseudo-coherent demodulation. The possibility of exploring these new and exciting experiment and conceptual ideas, as well as many others, with an extended ACTS satellite lifetime, are examined.

Abbe, Brian S.↗

Continued development of the radio science technique as a tool for planetary and solar system exploration

A possible alternative to a spacecraft monostatic radar system for surface studies of Titan is introduced. The results of a short study of the characteristics of a bistatic radar investigation of Titan's surface, presented in terms of the Voyager 1 flyby and a proposed Galileo orbiter of Saturn are outlined. The critical factors which need to be addressed in order to optimize the radio occultation technique for the study of clouds and cloud regions in planetary atmospheres are outlined. Potential improvements in the techniques for measuring small-scale structures in planetary atmospheres and ionospheres are addressed. The development of a technique for vastly improving the radial resolution from the radio occultation measurements of the rings of Saturn is discussed.

Source record↗

Rapid High-Resolution Analysis of Polysaccharide-Lignin Interactions in Secondary Plant Cell Walls Using Proton-Detected Solid-State NMR

The plant secondary cell wall, a complex matrix composed of cellulose, hemicellulose, and lignin, is crucial for the mechanical strength and water-proofing properties of plant tissues, and serves as a primary source of biomass for biorenewable energy and biomaterials. Structural analysis of these polymers and their interactions within the secondary cell wall has been heavily relying on 13 C-based solid-state NMR techniques. In this study, we explore the application of 1 H-detected solid-state NMR techniques for rapid, high-resolution structural characterization of polysaccharides and lignin, demonstrated on the stems of hardwood eucalyptus. We explored the use of synthesized 2D spectra to resolve central 1 H resonances and the combined application of 3D hCCH and hCHH experiments for complete resonance assignment and unambiguous identification of lignin-carbohydrate interactions. Our findings emphasize the central role of acetylated three-fold xylan conformers, rather than two-fold, in stabilizing the carbohydrate-lignin interface, with glucuronic acid sidechains in eucalyptus glucuronoxylan colocalizing with lignin, revised cellulose-lignin interactions involving uncoated microfibril surfaces, and pectin-lignin interactions indicative of early-stage lignification. These results present a novel approach for rapid structural analysis of lignocellulosic biomaterials without the need for solubilization or extraction.

09 BIOMASS FUELS↗

Mathematical analysis techniques for modeling the space network activities

The objective of the present work was to explore and identify mathematical analysis techniques, and in particular, the use of linear programming. This topic was then applied to the Tracking and Data Relay Satellite System (TDRSS) in order to understand the space network better. Finally, a small scale version of the system was modeled, variables were identified, data was gathered, and comparisons were made between actual and theoretical data.

Foster, Lisa M.↗