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At least 577 records · Page 32

Colloidal Quantum Dot Solar Cells: Progressive Deposition Techniques and Future Prospects on Large-area Fabrication

Colloidally grown nanosized semiconductors yield extremely high-quality optoelectronic materials. Many examples have pointed to near perfect photoluminescence quantum yields, meaning non-radiative optical processes (losses) can be completely suppressed allowing for technology-leading materials as high purity color centers in display technology and emitters in LEDs. Furthermore, because of high chemical yield, and improved understanding of the surfaces, these materials, particularly colloidal quantum dots (QDs) can also be ideal candidates for other optoelectronic applications. Given the strong drive toward carbon neutrality and limiting climate change, electricity from solar photovoltaics will play a large role in the power generation sector. QDs have been developed and shown dramatic improvements over the past 15 years as photoactive materials in photovoltaics and have unique potential with various innovative deposition properties which could lead to exceptionally low-cost and high-performance devices. Once the key issues related to charge transport in optically thick arrays are addressed, QD-based photovoltaic technology could become a better candidate for practical application. In this article, w e show how the possibilities of different deposition techniques could bring QD-based solar cells to the industrial level and discuss the challenges for perovskite QD solar cells in particular, to achieve large-area fabrication for further advancing technology to solve pivotal energy and environmental issues.

14 SOLAR ENERGY↗

Pathways Toward Efficient and Durable Anion Exchange Membrane Water Electrolyzers Enabled By Electro‐Active Porous Transport Layers

Abstract Green hydrogen, produced via water electrolysis using renewable electricity, will play a crucial role in decarbonizing industrial and heavy‐duty transportation sectors. Anion exchange membrane water electrolyzers (AEMWEs) can overcome many of the performance and cost limitations of incumbent technologies, however, still suffer from durability challenges due to oxidative instability of anion‐exchange ionomers. Herein, the use of an electro‐active porous transport layer as anode (PTL‐electrode) is demonstrated to enable efficient and durable AEMWEs. The stainless‐steel PTL‐electrodes are shown to have superior performance and durability compared to traditional catalyst layers containing ionomer and nanoparticle catalysts. An AEMWE cell operating at 2 A cm −2 for over 600 h exhibited a degradation rate of just 5 µV h −1 . During operation, the surface composition of the stainless steel transforms into a mixture of iron and nickel oxyhydroxides, contributing to enhanced oxygen‐evolution reaction activity. The combination of experimental work and modeling elucidates how the bulk structure of the PTL‐electrode offers an additional design dimension to further improve electrolyzer performance. Lastly, a surface modification strategy is applied to a PTL‐electrode to achieve an even higher performing AEMWE (2.3 vs 2.0 A cm −2 at 1.8 V). Overall, this work lays out pathways toward more efficient, durable, and affordable AEMWEs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Magnetic dynamics with Weyl fermions

Transport of charge and valley (axial) degrees of freedom coupled to order-parameter dynamics in magnetic Weyl semimetals is studied in the framework of nonequilibrium thermodynamics. In addition to the established valley-related transport anomalies that are rooted in band-structure topology, we construct dissipative couplings between the three dynamic constituents of the system driven out of equilibrium by electromagnetic perturbations. We show how the valley degree of freedom mediates an effective coupling between the charge and magnetic sectors of the system, through a combination of the chiral anomaly, on the electric side, and the Onsager-paired valley torque and pumping, on the magnetic side. This work complements previous studies of magnetic Weyl semimetals by a more systematic analysis of collective dissipation. We discuss several concrete examples of the valley-mediated current-driven magnetic instabilities and charge pumping, and extend the theory to the antiferromagnetic case.

36 MATERIALS SCIENCE↗

Energy Sector Position, Navigation, and Time Cybersecurity Profile

The Pacific Northwest National Laboratory has developed this positioning, navigation, and timing (PNT) profile for the Energy Sector at the request of the U.S. Department of Energy. The Department of Energy is the sector-specific agency for the Energy Sector and is responsible for providing guidance in the form of this PNT Profile, per Executive Order 13905, Strengthening National Resilience Through Responsible Use of Positioning, Navigation, and Timing Services (Executive Office of the President 2020) issued February 18, 2020. Executive Order 13905 directed the National Institute of Standards & Technology to develop a PNT Profile that is broadly applicable to all sectors and to serve as a foundation for sector-neutral guidance, NISTIR 8323 Foundational PNT Profile: Applying the Cybersecurity Framework for the Responsible Use of Positioning, Navigation, and Timing (PNT) Services. This document builds on NISTIR 8323 to identify and serve as the required Energy Sector specific guidance. For purposes of this PNT Profile, Energy Sector precise time is 0.5 µs (microseconds) to 1 µs accuracy. Currently, the electricity subsector has systems that use this level of precision time, but the oil and natural gas subsector currently does not. While the electricity subsector uses precision timing, it does not use positioning and/or navigation at this level of accuracy. For this reason, this PNT Profile will focus on only precise time for the electricity subsector.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Price Formation in Zero-Carbon Electricity Markets: The Role of Hydropower

In April 2019, Water Power Technologies Office (WPTO) launched the HydroWIRES Initiative to understand, enable, and improve hydropower and pumped storage hydropower’s (PSH’s) contributions to reliability, resilience, and integration in the rapidly evolving U.S. electricity system. The unique characteristics of hydropower, including PSH, make it well suited to provide a range of storage, generation flexibility, and other grid services to support the cost-effective integration of variable renewable resources. The U.S. electricity system is rapidly evolving, bringing both opportunities and challenges for the hydropower sector. While increasing deployment of variable renewables such as wind and solar have enabled low-cost, clean energy in many U.S. regions, it has also created a need for resources that can store energy or quickly change their operations to ensure a reliable and resilient grid. Hydropower (including PSH) is not only a supplier of bulk, low-cost, renewable energy but also a source of large-scale flexibility and a force multiplier for other renewable power generation sources. Realizing this potential requires innovation in several areas: understanding value drivers for hydropower under evolving system conditions, describing flexible capabilities and associated tradeoffs associated with hydropower meeting system needs, optimizing hydropower operations and planning, and developing innovative technologies that enable hydropower to operate more flexibly.

13 HYDRO ENERGY↗

Enabling the Electrification of Offshore Activities – Co-Demonstration of Next-Generation Autonomous Offshore Power System and Resident, Uncrewed Mobile and Static Assets at PacWave Wave Energy Test Site

Oceans cover two-thirds of the earth's surface and form the world's biggest and best – yet largely untapped – battery. Ocean waves have more energy density than other renewables, including wind, solar, and biomass, and have the potential to supply 4x the world's annual energy consumption (Masterson, 2022; Zic, 2020). In addition to the impact wave energy can have on decarbonizing and diversifying the electric grid, it offers a significant value proposition in the emerging blue economy sector (LiVecchi et al, 2019). The blue economy consists of industries operating offshore, including shipping, oil and gas, defense and security, aquaculture, and research. These industries require bringing people and energy on site to perform daily work, but current energy costs in the blue economy are extremely high. Here, the prevailing processes are complex, including shore dependencies and fuel transportation logistics. Few alternatives for reliable power generation exist, with the most prominent being high cost and high carbon emissions diesel generation. Because of this lack of affordable, reliable power, the trends of electrification, digitization, and automation that have led to substantial innovation and improvements in the terrestrial economy over the last two decades are slow to come to the blue economy.

16 TIDAL AND WAVE POWER↗

Quantifying the Sensitive Parameters of the New Energy Vehicles in China

To achieve carbon neutrality by 2060, the Chinese government has put effort into decarbonizing the transportation sector. Consequently, China elaborated a new energy vehicle strategy promoting the production of electric vehicles and expanding into hydrogen (H2) vehicle technologies including fuel cell electric vehicles and H2 internal combustion engine vehicles. The Transportation Energy Analysis Model (TEAM) projects the market penetration as well as energy demand and greenhouse gas emissions in China up to 2050. By integrating the Monte Carlo simulation, this study tests the robustness of TEAM and investigates the key parameters that will shape passenger vehicle sales and emissions in the future. The results show that fuel cell cost, H2 price, and battery cost are the most sensitive parameters for H2 vehicle technologies.

Saafi, Mohamed Ali↗

Vertical motions of the midlatitude F2 layer during magnetospheric substorms.

Use of ground-based ionosonde records from midlatitude stations during winter nights to study vertical motions of the F2 layer associated with magnetospheric substorms. The results show that during substorms the F2 layer is lifted upward in the premidnight sector and pushed downward in the postmidnight sector. These motions are interpreted in terms of E x B drifts, the electric field being eastward on the eveningside and westward on the morningside. The results emphasize the importance of substorm effects on the midlatitude F region and the potential of ground-based hf sounding techniques in studying magnetospheric substorms.

Park, C. G.↗

Satellite studies of magnetospheric substorms on August 15, 1968. III - Some features of magnetospheric convection.

New details of unsteady magnetospheric convection and gradual erosion of the plasmasphere during a weak magnetic storm are revealed in the light of presented ground data and OGO-4 and OGO-5 data for August 13-15, 1968. These new findings suggest that westward electric fields of the order of 0.5 mv/m were present in the midnight sector during the substorms studied.

Carpenter, D. L.↗

High-altitude observations of an intense inverted V event

Inverted-V events which generally occur in the pre-midnight sector over the auroral zone are frequently associated with reversals in the convection electric field. Such a reversal is observed by the University of Iowa quasispherical LEPEDEA on board ISEE 1 at an altitude of 13 RE on May 1, 1978. The bulk of the plasma shows a large shear over a five-minute interval. The associated change in the convection electric field is 5.1 mV/m. Large values of the field-aligned current are simultaneously detected. The potential structure appears to extend to the satellite location. Using a theoretical model, the field-aligned current due to the electric field discontinuity has been calculated. The magnitude of the parallel potential drop and width of the inverted-V region agree well with observation.

Huang, C. Y.↗

Sustainable Campus with PEV and Microgrid

Market penetration of electric vehicles (EVs) is gaining momentum, as is the move towards increasingly distributed, clean and renewable electricity sources. EV charging shifts a significant portion of transportation energy use onto building electricity meters. Hence, integration strategies for energy-efficiency in buildings and transport sectors are of increasing importance. This paper focuses on a portion of that integration: the analysis of an optimal interaction of EVs with a building-serving transformer, and coupling it to a microgrid that includes PV, a fuel cell and a natural gas micro-turbine. The test-case is the Nanyang Technological University (NTU), Singapore campus. The system under study is the Laboratory of Clean Energy Research (LaCER) Lab that houses the award winning Microgrid Energy Management System (MG-EMS) project. The paper analyses three different case scenarios to estimate the number of EVs that can be supported by the building transformer serving LaCER. An approximation of the actual load data collected for the building into different time intervals is performed for a transformer loss of life (LOL) calculation. The additional EV loads that can be supported by the transformer with and without the microgrid are analyzed. The numbers of possible EVs that can be charged at any given time under the three scenarios are also determined. The possibility of using EV fleet at NTU campus to achieve demand response capability and intermittent PV output leveling through vehicle to grid (V2G) technology and building energy management systems is also explored.

Singh, Reshma↗

Ground-based studies of ionospheric convection associated with substorm expansion

The instantaneous patterns of electric fields and currents in the high-latitude ionosphere are deduced by combining satellite and radar measurements of the ionospheric drift velocity, along with ground-based magnetometer observations for October 25, 1981. The period under study was characterized by a relatively stable southward interplanetary magnetic field (IMF), so that the obtained electric field patterns do reflect, in general, the state of sustained and enhanced plasma convection in the magnetosphere. During one of the satellite passes, however, an intense westward electrojet caused by a substorm intruded into the satellite (DE2) and radar (Chatanika, Alaska) field of view in the premidnight sector, providing a unique opportunity to differentiate the enhanced convection and substorm expansion fields. The distributions of the calculated electric potential for the expansion and maximum phases of the substorm show the first clear evidence of the coexistence of two physically different systems in the global convection pattern. The changes in the convection pattern during the substorm indicate that the large-scale potential distributions are indeed of general two-cell patterns representing the southward IMF status, but the night-morning cell has two positive peaks, one in the midnight sector and the other in the late morning hours, corresponding to the substorm expansion and the convection enhancement, respectively.

Kamide, Y.↗

Cyber-Informed Engineering (CIE) Power Generation Guide [Slides]

This guide offers suggestions for applying CIE principles to technologies used to generate electric power. It addresses issues of design, implementation, and maintenance, preemptively addressing cybersecurity threats to electric generation. The intended audience for this guide includes practitioners across the energy and cybersecurity sectors, such as energy industry professionals (e.g., engineers, system designers, operators, and researchers) and cybersecurity experts (e.g., communication system designers, information technology/operational technology [IT/OT] administrators, and penetration testers).

13 HYDRO ENERGY↗

Integrated energy-water-land nexus planning in the Colorado River Basin (Argentina)

Integrated energy-water-land (EWL) planning promotes synergies and avoids conflicts in ways that sector-specific planning approaches cannot. Many important decisions that influence emerging EWL nexus issues are implemented at regional (e.g., large river basin, electricity grid) and sub-regional (e.g., small river basin, irrigation district) scales. However, actual implementation of integrated planning at these scales has been limited. Simply collecting and visualizing data and interconnections across multiple sectors and sub-regions in a single modeling platform is a unique endeavor in many regions. This study introduces and applies a novel approach to linking together multiple sub-regions in a single platform to characterize and visualize EWL resource use, EWL system linkages within and among sub-regions, and the EWL nexus implications of future policies and investments. This integrated planning methodology is applied in the water-stressed Colorado River Basin in Argentina, which is facing increasing demands for agricultural and fossil fuel commodities. Guided by stakeholders, this study seeks to inform basin planning activities by characterizing and visualizing (1) the basin’s current state of EWL resources, (2) the linkages between sectors within and among basin sub-regions, and (3) the EWL nexus implications of planned future agricultural development activities. Results show that water scarcity, driven in part by human demands that have historically reached 60% of total surface water supply, poses a substantial constraint to economic development in the basin. The Colorado basin has the potential to serve as a testbed for crafting novel and generalizable sub-regional EWL planning approaches capable of informing the EWL planning dialogue globally.

54 ENVIRONMENTAL SCIENCES↗

Electric Medium- and Heavy-Duty Vehicle Charging Infrastructure Attributes and Development

Although more established for light-duty vehicles (LDVs), advancements in electric vehicle (EV) charging technology are being made in the medium- and heavy-duty (MD/HD) sector. Progress is also being made with the electrification of MD/HD vehicles, including transit buses, school buses, MD trucks, and HD trucks. The diverse set of operational requirements and duty cycles for each vocation, as well as the range in the size of fleets, present unique charging and infrastructure requirements. This report focuses on charging requirements for MD/HD vehicles and synergies with LDV infrastructure. This analysis leans toward the qualitative rather than quantitative because relevant model inputs are in development and will not be established for a few years, as EV deployments are more mature in the LDV sectors than MD/HD. The report begins with an overview of MD/HD vehicle classes and types of charging, including depot and residential charging, among others (Section 2). Section 3 analyzes the home bases (overnight dwell locations) of existing MD/HD vehicles, with an emphasis on depot and residential home bases, and discusses implications for charging infrastructure. Section 4 discusses the key characteristics for determining if, when, and where MD/HD vehicles can leverage LDV charging infrastructure rather than requiring dedicated chargers. These considerations include electricity demand, connectors, physical space requirements, payment considerations, and impacts on the grid. Section 5 summarizes shared characteristics for MD/HD vehicles that are appropriate for near-term electrification and includes a summary of the outlook of the electric MD/HD vehicle market. The conclusion (Section 6) summarizes the report's findings and outlines areas for future research.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Batteries Annual Progress Report (FY2019)

The Vehicle Technologies Office (VTO) of the Department of Energy (DOE) conducts research and development (R&D) on advanced transportation technologies that would reduce the nation’s use of imported oil and would also lead to reductions in harmful emissions. Technologies supported by VTO include electric drive components such as advanced energy storage devices (primarily batteries), power electronics and electric drive motors, advanced structural materials, energy efficient mobility systems, advanced combustion engines, and fuels. VTO is focused on funding early-stage high-reward/high-risk research to improve critical components needed for more fuel efficient (and cleaner-operating) vehicles. One of the major VTO objectives is to enable U.S. innovators to rapidly develop the next generation of technologies that achieve the cost, range, and charging infrastructure necessary for the widespread adoption of plug-in electric vehicles (PEVs). An important prerequisite for the electrification of the nation’s light duty transportation sector is development of more cost-effective, longer lasting, and more abuse-tolerant PEV batteries. One of the ultimate goals of this research, consistent with the current vehicle electrification trend, is an EV which can provide the full driving performance, convenience, and price of an internal combustion engine (ICE) vehicle. To achieve this, VTO has established the following overarching goal (Source: FY2021 Congressional Budget Justification1): …identify new battery chemistry and cell technologies with the potential to reduce the cost of electric vehicle battery packs by more than half, to less than $100/kWh (ultimate goal is $60/kWh battery cell cost), increase range to 300 miles, and decrease charge time to 15 minutes or less by 2028. VTO works with key U.S. automakers through the United States Council for Automotive Research (USCAR) – an umbrella organization for collaborative research consisting of Fiat Chrysler Automobiles (FCA), the Ford Motor Company, and General Motors. Collaboration with automakers through the partnership known as U.S. Driving Research and Innovation for Vehicle Efficiency and Energy Sustainability (U.S. DRIVE) attempts to enhance the relevance and the success potential of its research portfolio. VTO competitively selects projects for funding through funding opportunity announcements (FOAs). Directly-funded work at the national laboratories are awarded competitively through a lab-call process. During the past year, VTO continued R&D in support of PEVs. Stakeholders for VTO R&D include universities, national laboratories, other government agencies and industry (including automakers, battery manufacturers, material suppliers, component developers, private research firms, and small businesses). This document summarizes the progress of VTO battery R&D projects supported during the fiscal year 2019 (FY 2019).

25 ENERGY STORAGE↗

Potential Adoption and Benefits of Co-Optimized Multimode Engines and Fuels for U.S. Light-Duty Vehicles

Exploring a diverse portfolio of technologies for decarbonization is crucial to understanding the potential impacts of different technological solutions and their associated environmental implications. Using high-octane, high-sensitivity biofuel blends in co-optimized multimode engines can increase engine efficiency and reduce vehicle emissions. Here, the multimode engine research focuses on the benefits of light-duty vehicle engines, which can operate in multiple modes depending on the vehicle's load. Low-temperature combustion can improve efficiency and reduce emissions (such as those from oxides of nitrogen and particulate matter) during low-load operation, while spark ignition performance is maintained in high-load operation. These advanced engines can be optimized to run on blends of biobased fuels. This analysis models scenarios for potential market adoption of co-optimized multimode vehicles fueled by three different bioblendstocks: ethanol, isopropanol, and isobutanol. An integrated modeling approach is used to forecast the energy and environmental impacts of the deployment of co-optimized multimode vehicles and fuels in the light-duty sector over the 2020-to-2050 time horizon. The multidisciplinary approach combines vehicle sales modeling, system dynamics modeling of the biorefining industry, and life cycle assessment to estimate the emissions and energy benefits. The models consider market forces such as consumer preferences for vehicle attributes, biofuel supply and demand dynamics subject to biorefinery capacity build-out and bioresource constraints, and forecasted changes to the U.S. bulk energy system over time. Market adoption of co-optimized vehicles is evaluated across a wide parameter space for incremental vehicle cost and engine efficiency improvement. This analysis reveals that the deployment of co-optimized multimode fuels and vehicles results in up to a 5% reduction in annual sector-wide life cycle greenhouse gas (GHG) emissions by 2050, relative to a business-as-usual scenario, but is also indicates environmental trade-offs, such as higher life cycle water-use. Emission benefits could potentially increase beyond 2050, as the new technologies penetrate the market and gain a foothold. Results also show that, under certain circumstances, vehicles with engines co-optimized for use with high-octane, high-sensitivity biofuel blends can be cost-competitive with conventional gasoline, while reducing GHG emissions. Our modeling results indicate that co-optimized multimode fuels and engines can be strategically leveraged in tandem with electrification to decarbonize the light-duty sector. Co-optimized vehicles could play a role in the early years of the time horizon, while electric vehicles (EVs) could become more competitive in the later years, highlighting the complementary benefits of these technologies for GHG reductions.

Oke, Doris↗

Electric Vehicle Lithium-Ion Battery Life Cycle Management

There is no question that electric vehicles (EVs), which are key for addressing climate change impacts from the transportation sector, are quickly gaining popularity and availability. With limits and other challenges related to the supply of critical battery minerals, maximizing the use of EV batteries and ensuring recovery of battery minerals is imperative. Therefore, proper end-of-life-cycle management (reuse and recycling) of these batteries must be part of the EV ecosystem from the perspective of both the supply chain and environmental footprint. Second use of batteries for energy storage systems extends the initial life of these resources and provides a buffer until economical material recovery facilities are in place. Although there are multiple pathways to recycling and recovery of materials, new recovery technologies are moving toward commercially available hydrometallurgy and promising direct recycling, which analysis has shown has the lowest overall carbon footprint. Strategically locating these plants close to battery collection further reduces transportation and thus recycling and recovering costs. Proper life cycle management could alleviate future lithium-ion battery materials supply chains for EVs. Governments and other stakeholders around the world have started initiatives and proposed regulations to address the challenges associated with life cycle management of EV lithium batteries. Finally, as manufacturers are increasingly faced with the likelihood of such extensive regulatory requirements, attention should be given to new designs, sales, and service models that can reduce life cycle management costs.

25 ENERGY STORAGE↗