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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Optimal Membrane Cascade Design for Critical Mineral Recovery Through Logic-based Superstructure Optimization

Critical minerals and rare earth elements play an important role in our climate change initiatives, particularly in applications related with energy storage. Here, we use discrete optimization approaches to design a process for the recovery of Lithium and Cobalt from battery recycling, through membrane separation. Our contribution involves proposing a Generalized Disjunctive Programming (GDP) model for the optimal design of a multistage diafiltration cascade for Li-Co separation. By solving the resulting nonconvex mixed-integer nonlinear program model to global optimality, we investigated scalability and solution quality variations with changes in the number of stages and elements per stage. Results demonstrate the computational tractability of the nonlinear GDP formulation for design of membrane separation processes while opening the door for decom-position strategies for multicomponent separation cascades. Future work aims to extend the GDP formulation to account for stage installation and explore various decomposition techniques to enhance solution efficiency.

Ovalle, Daniel↗
NASA NTRS1980

Latitude-dependent sensitivity to stationary perturbations in simple climate models

The steady-state zonally averaged climate is perturbed by adding a latitude-dependent heat source to an energy balance equation of the simplified Budyko-Sellers type. The latitude of the ice edge, which is attached to an isotherm, becomes dependent on the strength of the perturbation. This dependence is given in terms of the well-known iceline-solar constant relation, and the latitude dependence of the perturbed temperature field is then uniquely determined. The exact analytical solution is linearized and expressed in terms of a superposition of line sources at various latitudes. The main features are: (1) The total temperature response is a sum of the direct effect of the perturbation and an indirect ice-albedo effect proportional to the solar ice-edge sensitivity; and (2) the indirect feedback effect produces an enhanced response in polar latitudes.

Salmun, H.↗
NASA NTRS1984

Climate studies with a multilayer energy balance model. III - Climatic impact of stratospheric volcanic aerosols

A multilayer energy balance model is applied in an examination of the sensitivity of climate to stratospheric aerosols induced by volcanic eruptions. Zonally and annually averaged quantities are considered, with ocean and land temperatures computed separately and the atmosphere below the 200 mb level divided into eight layers of 24 sublayers each. The aerosol is assumed to form in the 150-200 mb range. Aerosol parameters for radiative transfer calculations are reflection in the solar spectral region and absorption in the solar and IR regions. A 75 percent aqueous solution of sulfuric acid is assumed for the aerosols. The sensitivity of the hemispherically averaged surface temperature is enhanced 37 percent, with a 20 percent uncertainty, when the thermal IR radiation is excluded. The solar radiation enhances the surface temperatures to a higher degree than the thermal radiation. The maximum response to the evenly distributed aerosols is in the 60-70 deg N latitudes and propagates, weakening, to lower latitudes.

Chou, M.-D.↗
DOE OSTI2022

Autonomous Energy Management Software System for Small Commercial Buildings in Support of Decarbonization (Abstract)

The primary goal for the project is to develop and validate an autonomous energy management software (AEMS) system that will continuously optimize small commercial building operations by minimizing energy consumption and cost, providing a solution for maximizing decarbonization benefits from electrification of buildings. The work will leverage vast experience of Pacific Northwest National Laboratory (PNNL) research and development staff who have over two decades of experience in developing and successfully transferring software technologies to the private sector. This solution will be jointly developed with Intellimation LLC who plans to use it to scale their building energy efficiency offering. The project plan will include collaboratively working with Intellimation to package a set of solutions into the AEMS system, validate and demonstrate their capability, and value proposition through field demonstrations. If the deployment of the AEMS system optimizes RTUs’ set points, schedules, setbacks and optimal start and results in energy consumption reduction of 20%, the technical potential savings is approximately 675 trillion Btus of site energy savings and 2,000 trillion Btus of source energy. It will also result in carbon reductions of approximately 2.4 MMTCO2 and contribute to the climate change mitigation plans of many cities and states across the United States. Additional cost savings and emissions reduction are possible from management of peak electricity demand. The primary outcome will be an AEMS system that can be deployed at scale on small commercial buildings to improve operating efficiency.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Methane Hydrates in Alaska

This paper was prepared for the National Petroleum Council's Study on Natural Gas GHG Emissions. Natural gas is the largest primary energy produced in the United States and its use is growing. Yet getting this gas to homes and businesses creates greenhouse gas emissions. That’s why reducing emissions from America’s natural gas is an urgent priority that requires collaborative solutions. The National Petroleum Council brought together a diverse group of stakeholders with the expertise to analyze this complex issue and identify ways to reduce natural gas GHG emissions for all future supply and demand scenarios. The result: actionable consensus on ensuring a lower-emission natural gas system. The study’s research charts a course forward to meaningfully reduce emissions from the natural gas system, contributing significantly to the United States’ ability to achieve its climate goals. The report concludes that through the implementation of existing policies, voluntary commitments, technologies, and market mechanisms, a 63% reduction in methane emissions can be achieved by 2030. The report went further to identify an additional pathway that methane emissions decrease by 70% and carbon dioxide emissions reduce by 33% through 2050.

03 NATURAL GAS↗
NASA NTRS2005

Automated Image Registration Using Morphological Region of Interest Feature Extraction

With the recent explosion in the amount of remotely sensed imagery and the corresponding interest in temporal change detection and modeling, image registration has become increasingly important as a necessary first step in the integration of multi-temporal and multi-sensor data for applications such as the analysis of seasonal and annual global climate changes, as well as land use/cover changes. The task of image registration can be divided into two major components: (1) the extraction of control points or features from images; and (2) the search among the extracted features for the matching pairs that represent the same feature in the images to be matched. Manual control feature extraction can be subjective and extremely time consuming, and often results in few usable points. Automated feature extraction is a solution to this problem, where desired target features are invariant, and represent evenly distributed landmarks such as edges, corners and line intersections. In this paper, we develop a novel automated registration approach based on the following steps. First, a mathematical morphology (MM)-based method is used to obtain a scale-orientation morphological profile at each image pixel. Next, a spectral dissimilarity metric such as the spectral information divergence is applied for automated extraction of landmark chips, followed by an initial approximate matching. This initial condition is then refined using a hierarchical robust feature matching (RFM) procedure. Experimental results reveal that the proposed registration technique offers a robust solution in the presence of seasonal changes and other interfering factors. Keywords-Automated image registration, multi-temporal imagery, mathematical morphology, robust feature matching.

Plaza, Antonio↗
NASA NTRS2011

NASA World Wind: Infrastructure for Spatial Data

The world has great need for analysis of Earth observation data, be it climate change, carbon monitoring, disaster response, national defense or simply local resource management. To best provide for spatial and time-dependent information analysis, the world benefits from an open standards and open source infrastructure for spatial data. In the spirit of NASA's motto "for the benefit of all" NASA invites the world community to collaboratively advance this core technology. The World Wind infrastructure for spatial data both unites and challenges the world for innovative solutions analyzing spatial data while also allowing absolute command and control over any respective information exchange medium.

Hogan, Patrick↗
NASA NTRS2022

Adaptations of Endolithic Communities to Abrupt Environmental Changes in A Hyper-Arid Desert

The adaptation mechanisms of microbial communities to natural perturbations remain relatively unexplored, particularly in extreme environments. The extremophilic communities of halite (NaCl) nodules from the hyper-arid core of the Atacama Desert are self-sustained and represent a unique opportunity to study functional adaptations and community dynamics with changing environmental conditions. We transplanted halite nodules to different sites in the desert and investigated how their taxonomic, cellular, and biochemical changes correlated with water availability, using environmental data modeling and metagenomic analyses. Salt-in strategists, mainly represented by haloarchaea, significantly increased in relative abundance at sites characterized by extreme dryness, multiple wet/dry cycles, and colder conditions. The functional analysis of metagenome-assembled genomes (MAGs) revealed site-specific enrichments in archaeal MAGs encoding for the uptake of various compatible solutes and for glycerol utilization. These findings suggest that opportunistic salt-in strategists took over the halite communities at the driest sites. They most likely benefited from metabolites newly released in the environment by the death of microorganisms least adapted to the new conditions. The observed changes were consistent with the need to maximize cellular bioenergetics when confronted with lower water availability and higher salinity, providing valuable information on microbial community adaptations and resilience to climate change.

Atacama↗
DOE OSTI2023

Application of Particle Accelerators to Mitigate Energy and Climate Change Problems Facing America

Reliable CO 2 -free baseload power is needed to address ever-increasing demands for electricity while minimizing adverse climate change. Diversified power supply provided by solar, wind, geothermal, and nuclear reactors can displace the use of fossil fuels. The United States (U.S.) is taking a new look at nuclear power as a source of electrical energy and the nuclear industry is proposing new approaches which may minimize capital costs. However, nuclear power comes with a variety of technical problems. Chief among those is managing the used fuel from nuclear reactors. No long-term, practicable solution to this problem is available. The lack of progress on a comprehensive waste management strategy restricts growth in the nuclear power industry and minimizes the role that nuclear energy may serve as part of a zero-carbon future (Bahr, 2021). According to the Nuclear Waste Policy Act of 1982, as amended, the U.S. Government has possession of the used reactor fuel and incurs large annual storage fees paid to utilities to store and safeguard the accumulated used fuel. In effect, short term on-site storage of nuclear waste is the current waste management plan. The amount of used reactor fuel in the U.S. is approximately 80,000 metric tons. While no geologic repository exists within the U.S., the potential site at Yucca Mountain, NV would accommodate 70,000 metric tons, which fails to meet current and future needs. Given the technical and political challenges associated with establishing a single geological storage site, it is necessary for the U.S. to implement technologies that improve the suitability of geological storage by reducing the volume and radiotoxicity of stored material. No extant technology meets this need. Accelerator driven waste burners have been proposed as a scalable method to process used nuclear fuel, however considerable technical challenges remain which impede commercialization. Innovations in design require investigation of novel materials, development of accurate models and simulations, and a comprehensive assessment of safety and performance. This proposal elaborates how LANL is uniquely positioned to make key contributions to this area of research.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Direct Air Capture of CO 2 via Reactive Crystallization

Atmospheric CO 2 removal using engineered chemical processes, aka direct air capture (DAC), has become an essential component of our available portfolio for mitigating climate change. Here we describe a promising approach to DAC based on reactive crystallization of atmospheric CO 2 (RC-DAC) with aqueous guanidine and amino acid. Compared to the previously studied phase-changing DAC processes involving initial CO 2 absorption by an aqueous alkaline solvent followed by carbonate crystallization in a second step, RC-DAC combines the CO 2 absorption and carbonate crystallization into a single step. Thus, as the insoluble carbonate salts are removed from solution by crystallization, more CO 2 is pulled from the air into solution, further driving the DAC process. The RC-DAC was performed in a household humidifier as the air–liquid contactor, which can handle solid–liquid slurries effectively. The crystallization was monitored in situ by pH measurements, real-time imaging with a microscope probe, and by Raman spectroscopy, and ex situ by NMR spectroscopy, powder X-ray diffraction, and total inorganic carbonate analysis. Further, the investigation provided a detailed mechanistic picture of the RC-DAC process, involving formation of carbamate and carbonate anions in solution, followed by sequential crystallization of different guanidinium carbonate phases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Perspectives on AI Architectures and Codesign for Earth System Predictability

Abstract Recently, the U.S. Department of Energy (DOE), Office of Science, Biological and Environmental Research (BER), and Advanced Scientific Computing Research (ASCR) programs organized and held the Artificial Intelligence for Earth System Predictability (AI4ESP) workshop series. From this workshop, a critical conclusion that the DOE BER and ASCR community came to is the requirement to develop a new paradigm for Earth system predictability focused on enabling artificial intelligence (AI) across the field, laboratory, modeling, and analysis activities, called model experimentation (ModEx). BER’s ModEx is an iterative approach that enables process models to generate hypotheses. The developed hypotheses inform field and laboratory efforts to collect measurement and observation data, which are subsequently used to parameterize, drive, and test model (e.g., process based) predictions. A total of 17 technical sessions were held in this AI4ESP workshop series. This paper discusses the topic of the AI Architectures and Codesign session and associated outcomes. The AI Architectures and Codesign session included two invited talks, two plenary discussion panels, and three breakout rooms that covered specific topics, including 1) DOE high-performance computing (HPC) systems, 2) cloud HPC systems, and 3) edge computing and Internet of Things (IoT). We also provide forward-looking ideas and perspectives on potential research in this codesign area that can be achieved by synergies with the other 16 session topics. These ideas include topics such as 1) reimagining codesign, 2) data acquisition to distribution, 3) heterogeneous HPC solutions for integration of AI/ML and other data analytics like uncertainty quantification with Earth system modeling and simulation, and 4) AI-enabled sensor integration into Earth system measurements and observations. Such perspectives are a distinguishing aspect of this paper. Significance Statement This study aims to provide perspectives on AI architectures and codesign approaches for Earth system predictability. Such visionary perspectives are essential because AI-enabled model-data integration has shown promise in improving predictions associated with climate change, perturbations, and extreme events. Our forward-looking ideas guide what is next in codesign to enhance Earth system models, observations, and theory using state-of-the-art and futuristic computational infrastructure.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1984

Ocean modelling on the CYBER 205 at GFDL

At the Geophysical Fluid Dynamics Laboratory, research is carried out for the purpose of understanding various aspects of climate, such as its variability, predictability, stability and sensitivity. The atmosphere and oceans are modelled mathematically and their phenomenology studied by computer simulation methods. The present state-of-the-art in the computer simulation of large scale oceans on the CYBER 205 is discussed. While atmospheric modelling differs in some aspects, the basic approach used is similar. The equations of the ocean model are presented along with a short description of the numerical techniques used to find their solution. Computational considerations and a typical solution are presented in section 4.

Cox, M.↗
DOE OSTI2022

Understanding the Hydrogeochemical Response of a Mountainous Watershed Using Integrated Surface‐Subsurface Flow and Reactive Transport Modeling

Abstract Climate change and other disturbances significantly impact hydrogeochemical exports from mountainous headwater catchments such as the Upper Colorado River Basin. Developing a mechanistic understanding of how the physical and chemical processes interact in time and space in an integrated manner is key to quantifying the future impacts of such disturbances. The hydrogeochemical response of a mountainous catchment in the 2010–2019 period is evaluated quantitatively using a high‐resolution model that simulates integrated hydrology, and transport and reactions for selected solutes and minerals. The model assumes that pyrite is present only at depth while calcite is distributed uniformly, and captures the observed C‐Q reasonably well. Distinct C‐Q dynamics are observed in an average (WY16), a wet (WY17), and a dry (WY18) water year. The model also quantifies the water fraction from surface, shallow and deep groundwater compartments using tracers, and suggests greater groundwater contributions to peak stream discharge in the dry WY18. Results demonstrate that calcium concentrations do not change significantly from year to year, while sulfate shows significant temporal variability. Pyrite dissolution is affected by the changing hydrological drivers where it is enhanced in the dry WY18; calcite dissolution supplements calcium dilution under high flow conditions. The model simulates the reaction hotspots controlled by hydrological conditions, and the spatially‐resolved results show that higher soil saturation and less snowpack occur earlier on the south‐facing side than on the north‐facing side. This is a first‐of‐its‐kind demonstration of a model that integrates hydrologic processes, including evapotranspiration, and reactive transport to enable a predictive understanding of hydrogeochemical exports.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2003

Electrochemical approaches for chemical and biological analysis on Mars

Obtaining in situ chemical data from planetary bodies such as Mars or Europa can present significant challenges. The one analytical technique that has many of the requisite characteristics to meet such a challenge is electroanalysis. Described here are three electroanalytical devices designed for in situ geochemical and biological analysis on Mars. The Mars Environmental Compatibility Assessment (MECA) was built and flight qualified for the now cancelled NASA Mars 2001 Lander. Part of MECA consisted of four "cells" containing arrays of electrochemical based sensors for measuring the ionic species in soil samples. A next-generation MECA, the Robotic Chemical Analysis Laboratory (RCAL), uses a carousel-type system to allow for greater customization of analytical procedures. A second instrument, proposed as part of the 2007 CryoScout mission, consists of a flow-through inorganic chemical analyzer (MICA). CryoScout is a torpedo-like device designed for subsurface investigation of the stratigraphic climate record embedded in Mars' north polar cap. As the CryoScout melts its way through the ice cap, MICA will collect and analyze the meltwater for a variety of inorganics and chemical parameters. By analyzing the chemistry locked in the layers of dust, salt, and ice, geologists will be able to determine the recent history of climate, water, and atmosphere on Mars and link it to the past. Finally, electroanalysis shows its abilities in the detection of possible microorganism on Mars or elsewhere in the solar system. To identify an unknown microorganism, one that may not even use Earth-type biochemistry, requires a detection scheme which makes minimal assumptions and looks for the most general features. Recent work has demonstrated that the use of an array of electrochemical sensors which monitors the changes in a solution via electrical conductivity, pH, and ion selective electrodes, can be used to detect minute chemical perturbations caused by the growth of bacteria and with the correct methodology provide unamibiguous detection of such life forms.

Non-NASA Center↗
DOE OSTI2022

New Directions for Chemical Engineering

Over the past century, the work of chemical engineers has helped transform societies and the lives of individuals, from the synthetic fertilizers that helped feed the world to the development of novel materials used in fuels, electronics, medical devices, and other products. Chemical engineers' ability to apply systems-level thinking from molecular to manufacturing scales uniquely positions them to address today’s most pressing problems, including climate change and the overuse of resources by a growing population. New Directions for Chemical Engineering details a vision to guide chemical engineering research, innovation, and education over the next few decades. This report calls for new investments in U.S. chemical engineering and the interdisciplinary, cross-sector collaborations necessary to advance the societal goals of transitioning to a low-carbon energy system, ensuring our production and use of food and water is sustainable, developing medical advances and engineering solutions to health equity, and manufacturing with less waste and pollution. The report also calls for changes in chemical engineering education to ensure the next generation of chemical engineers is more diverse and equipped with the skills necessary to address the challenges ahead.

National Academies of Sciences, Engineering, and M↗
DOE OSTI2024

Structure–Composition Relationships for Mg–Ni and Mg–Fe Olivine

Olivine is a dynamic and important mineral in the crust and mantle with relevance to processes important to climate change technology, such as geologic carbon storage and critical mineral recovery. In this work, we critically evaluated and compiled a new database of olivine diffraction data, lattice parameters, and composition to enable rapid Ni-Mg-Fe olivine composition determination. A compilation of olivine X-ray diffraction data and chemical compositions from both the literature and the International Centre for Diffraction Data (ICDD) powder database was assembled to plot both the forsterite-fayalite and forsterite-liebenbergite solid solution lines. Here we present an expanded dataset to delineate equations and relationships used for quantifying the correlations between olivine lattice parameters and chemical compositions in Mg 2 SiO 4 -Fe 2 SiO 4 (forsterite-fayalite) and Mg 2 SiO 4 -Ni 2 SiO 4 (forsterite-liebenbergite) olivine solid solution series.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Inaugural Symposium of the Institute for Sustainable Energy and Environment, Virginia Commonwealth University

The Inaugural Symposium of the Institute for Sustainable Energy and Environment (ISEE) was held in Virginia Commonwealth University, Richmond, Virginia during April 26 – 28, 2023. The symposium addressed issues and challenges in energy and environment and highlighted the use of clean renewable energy to mitigate the adverse effects of fossil fuels and the greenhouse gases it produces. These issues are complex as the involve educating the public that the climate change is real, it is caused by the use of fossil fuels, it requires scientists and engineers to understand the fundamental science in the production and storage of renewable energy, it requires industries to manufacture and distribute the equipment necessary for commercial application of these technologies, it requires policy makers to put together policies and guidelines to make the transition from fossil fuels to renewable energies efficient, and it requires social scientists and educators to address environmental justice issues and create a workforce to sustain the transition. The symposium considered all the above issues with a diverse list of speakers from the federal and state government, industrial partners, and experts from science and technology to social sciences and public policy. Speakers from the White House Office of Science and Technology Policy, Department of Energy, universities, and non-governmental agencies discussed the challenges and solutions in Plenary as well as Panel sessions. The talks were recorded with permission from the speakers and the panelists and were put in the ISEE website. The participants included students, postdoctoral fellows, and professors from Virginia Commonwealth University and local area Historically Black College and Universities (HBCU) such as Virginia State University and Norfolk State University. The $5000 fund awarded by the Department of Energy were used to support the participation of students, postdoctoral fellows, and faculty from the HBCU institutions. The technical program the list of participants is provided later in the document.

08 HYDROGEN↗
NASA NTRS1980

Global geochemical problems

Application of remote sensing techniques to the solution of geochemical problems is considered with emphasis on the 'carbon-cycle'. The problem of carbon dioxide sinks and the areal extent of coral reefs are treated. In order to assess the problems cited it is suggested that remote sensing techniques be utilized to: (1)monitor globally the carbonate and bicarbonate concentrations in surface waters of the world ocean; (2)monitor the freshwater and oceanic biomass and associated dissolved organic carbon; (3) inventory the coral reef areas and types and the associated oceanographic climatic conditions; and (4)measure the heavy metal fluxes from forested and vegetated areas, from volcanos, from different types of crustal rocks, from soils, and from sea surfaces.

Harriss, R. C.↗