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At least 577 records · Page 32

Spatio-spectral quantum state estimation of photon pairs from optical fiber using stimulated emission

Developing a quantum light source that carries more than one bit per photon is pivotal for expanding quantum information applications. Characterizing a high-dimensional multiple-degree-of-freedom source at the single-photon level is challenging due to the large parameter space as well as limited emission rates and detection efficiencies. Here, we characterize photon pairs generated in optical fiber in the transverse-mode and frequency degrees of freedom by applying stimulated emission in both degrees of freedom while detecting in one of them at a time. This method may be useful in the quantum state estimation and optimization of various photon-pair source platforms in which complicated correlations across multiple degrees of freedom may be present.

Kim, Dong Beom (ORCID:0000000346887375)↗

STILGAR: Subsurface Models for Graymont Pleasant Gap Mine

The detection, location, and monitoring of underground structures are of great importance to national and global security. Tunnels and voids generate seismic signatures detectable at the surface, but using non-invasive seismic data to image near-surface presents several challenges in real-world applications. In this report, we describe the use of a dense surface seismic deployment to generate subsurface models of the Graymont Pleasant Gap mine - a single-layer mine with a complex structure embedded in a high-velocity P-wave limestone bedrock. Our approach consists of three key methods. We use P-wave arrival times from local blast events to perform a tomography inversion with the tomoTD method, constructing a P-wave velocity model of the subsurface. We model the layer above the mine using Rayleigh wave ellipticity and inversion techniques. We leverage ongoing anthropogenic activities to identify and locate noise sources both on the surface and within the subsurface. With this integrated approach we aim to overcome the challenges and enhance our ability to non-invasively characterize underground structures, contributing to improved seismic monitoring techniques.

58 GEOSCIENCES↗

Topographic Characterization

The National Aeronautics and Space Administration (NASA), other government agencies, and private industry have requirements to map and analyze 3-dimensional surfaces of varying regularity and material composition. This requires a high fidelity, 3-dimensional description of the work space. In cases where complete and current information about the space is not available, topographic characterization allows on-line initialization and/or modification of the work space database. The mapping environment is often challenging with regard to lighting, radiation, temperature, atmosphere, and causticity. This paper describes a system that provides topographic characterization based on fusing intensity and depth information, and describes the application of this technique for inspection of Shuttle thermal tiles.

Goode, Plesent W.↗

Status of High-Strength Nanotube Composites at Johnson Space Center

Single-wall carbon nanotubes offer extraordinary mechanical properties that could start a revolution in materials science. The combination of very high strength and modulus with high strain to failure makes nanotubes an ideal fiber for strengthening in composites. Because of the scale of these fibers, new challenges exist for processing of composite materials and materials characterization. Our project includes aspects of nanotube materials from production and characterization to purification and incorporation into composites for mechanical testing. Early results show that some new techniques will be necessary for the strength of single wall nanotubes to be fully utilized. Current research at JSC focuses on structural polymeric materials to attempt to lower the weight of spacecraft necessary for interplanetary missions. Studies show good nanotube dispersion and wetting by the epoxy materials. Results of tensile strength tests will also be reported. This presentation will focus on current research into polymer nanotube composites and the next steps toward this revolution in aerospace materials.

Files, Bradley S.↗

A 2-D Array of Superconducting Magnesium Diboride (MgB2) Far-IR Thermal Detectors for Planetary Exploration

A 2-D array of superconducting Magnesium Diboride(MgB2) far IR thermal detectors has been fabricated. Such an array is intended to be at the focal plane of future generation thermal imaging far-IR instruments that will investigate the outer planets and their icy moons. Fabrication and processing of the pixels of the array as well as noise characterization of architectured MgB2 thin films will be presented. Challenges and solutions for improving the performance of the array will be discussed.

Lakew, Brook↗

Application of Ensemble Detection and Analysis to Modeling Uncertainty in Non Stationary Process

Characterization of non stationary and nonlinear processes is a challenge in many engineering and scientific disciplines. Climate change modeling and projection, retrieving information from Doppler measurements of hydrometeors, and modeling calibration architectures and algorithms in microwave radiometers are example applications that can benefit from improvements in the modeling and analysis of non stationary processes. Analyses of measured signals have traditionally been limited to a single measurement series. Ensemble Detection is a technique whereby mixing calibrated noise produces an ensemble measurement set. The collection of ensemble data sets enables new methods for analyzing random signals and offers powerful new approaches to studying and analyzing non stationary processes. Derived information contained in the dynamic stochastic moments of a process will enable many novel applications.

Racette, Paul↗

An Observation-Driven Framework for Modeling Post-Fire Hydrologic Response: Evaluation for Two Central California Case Studies

In a warming climate, wildfires are becoming increasingly common, especially in semi-arid environments. Wildfires can disrupt forest ecosystems and induce changes to the land surface. Collectively, these impacts can alter the hydrologic response of a catchment following a fire, resulting in increased potential for surface runoff, reduced evapotranspiration, and, ultimately, a higher risk for flash flooding and mass wasting. The timescale for post-fire recovery of hydrological processes to return to pre-fire conditions is not well established due to the lack of ground measurements. Accurate characterization of fire impacts on hydrologic response is also challenging to simulate, given the complex interplay of various processes. Here, we present a generalized framework to quantify wildfire impacts on runoff generation. We consider the vegetation and soil disturbances as the primary contributors to post-fire floods. Using an ensemble modeling structure to account for parameter uncertainty and consider model sensitivity, remotely sensed leaf area index (LAI) is assimilated into a land surface model (LSM) to simulate vegetation disturbance, and the maximum land surface saturation LSM parameter is decreased to parameterize the soil disturbance following observed fires. We evaluated the impacts of fire-induced changes to LAI and soil saturation on hydrologic states like runoff and evapotranspiration. Analysis of two events in central California shows that 1) the LAI assimilation has a greater impact on water balance; and 2) the soil scheme captures a range of outcomes, with substantial impacts on surface runoff for some ensemble members, which could affect flood potential.

Timothy M Lahmers↗

Decoherence Noise on the Superconducting Qubits Training Program

Quantum computing is a growing field with promising applications in a variety of fields such as healthcare, energy consumption, and cryptography. Quantum computing leverages the principles of quantum mechanics - superposition and entanglement. Yet, in the Noisy Intermediate Scale Quantum (NISQ) Era - quantum systems face the major challenge of decoherence due to noise. This era is characterized by low amounts of qubits and high gate error. Decoherence leads to the loss of the quantum information stored in the qubit. Noise occurs with any quantum system that is exposed to the environment. It should also be noted that quantum information can be stored in the cavity - Fermilab specializes in coupling transmons to ultrahigh-Q SRF cavities. The Superconducting Qubits Training Program (SQTP) provides a visualization for beginners in quantum computing. The open quantum system simulated is a superconducting qubit (two-level atom) coupled to a microwave cavity whose excitations are photons. The Rotating Wave Approximation of the Jaynes-Cumming Hamiltonian is used. SQTP utilizes open-source Python-based libraries scQubits, NumPy, and QuTiP alongside the Master Lindblad equation. In this project, we study the different decay behaviors of qubits and cavities with collapse operators.

Lopez, Sara↗

Perspectives and progress on wurtzite ferroelectrics: Synthesis, characterization, theory, and device applications

Wurtzite ferroelectrics are an emerging material class that expands the functionality and application space of wide bandgap semiconductors. Promising physical properties of binary wurtzite semiconductors include a large, reorientable spontaneous polarization, direct band gaps that span from the infrared to ultraviolet, large thermal conductivities and acoustic wave velocities, high mobility electron and hole channels, and low optical losses. The ability to reverse the polarization in ternary wurtzite semiconductors at room temperature enables memory and analog type functionality and quasi-phase matching in optical devices and boosts the ecosystem of wurtzite semiconductors, provided the appropriate combination of properties can be achieved for any given application. In this article, advances in the design, synthesis, and characterization of wurtzite ferroelectric materials and devices are discussed. Highlights include: the direct and quantitative observation of polarization reversal of ~135 μC/cm 2 charge in Al 1-x B x N via electron microscopy, Al 1-x B x N ferroelectric domain patterns poled down to 400 nm in width via scanning probe microscopy, and full polarization retention after over 1000 h of 200 °C baking and a 2× enhancement relative to ZnO in the nonlinear optical response of Zn 1-x Mg x O. In conclusion, the main tradeoffs, challenges, and opportunities in thin film deposition, heterostructure design and characterization, and device fabrication are overviewed.

30 DIRECT ENERGY CONVERSION↗

Experimental Investigation of Subsonic Turbulent Boundary Layer Flow Over a Wall-Mounted Axisymmetric Hill

An important goal for modern fluid mechanics experiments is to provide datasets which present a challenge for Computational Fluid Dynamics simulations to reproduce. Such "CFD validation experiments" should be well-characterized and well-documented, and should investigate flows which are difficult for CFD to calculate. It is also often convenient for the experiment to be challenging for CFD in some aspects while simple in others. This report is part of the continuing documentation of a series of experiments conducted to characterize the flow around an axisymmetric, modified-cosine-shaped, wall-mounted hill named "FAITH" (Fundamental Aero Investigates The Hill). Computation of this flow is easy in some ways - subsonic flow over a simple shape - while being complex in others - separated flow and boundary layer interactions. The primary set of experiments were performed on a 15.2 cm high, 45.7 cm base diameter machined aluminum model that was tested at mean speeds of 50 m/s (Reynolds Number based on height = 500,000). The ratio of model height to boundary later height was approximately 3. The flow was characterized using surface oil flow visualization, Cobra probe to determine point-wise steady and unsteady 3D velocities, Particle Image Velocimetry (PIV) to determine 3D velocities and turbulence statistics along specified planes, Pressure Sensitive Paint (PSP) to determine mean surface pressures, and Fringe Imaging Skin Friction (FISF) to determine surface skin friction magnitude and direction. A set of pathfinder experiments were also performed in a water channel on a smaller scale (5.1 cm high, 15.2 cm base diameter) sintered nylon model. The water channel test was conducted at a mean test section speed of 3 cm/s (Reynolds Number of 1500), but at the same ratio of model height to boundary layer thickness. Dye injection from both the model and an upstream rake was used to visualize the flow. This report summarizes the experimental set-up, techniques used, and data acquired. It also describes some details of the dataset that is being constructed for use by other researchers, especially the CFD community.

fluid machanics cfd validation wind tunnel↗

Supplying a Pharmacy for NASA Exploration Spaceflight: Challenges and Current Understanding

In order to maintain crew health and performance during long-duration spaceflight outside of low-Earth orbit, NASA and its international partners must be capable of providing a safe and effective pharmacy. Given few directed studies of pharmaceuticals in the space environment, it is difficult to characterize pharmaceutical effectiveness or stability during spaceflight; this in turn makes it challenging to select an appropriate formulary for exploration. Here we present the current state of literature regarding pharmaceutical stability, metabolism, and effectiveness during spaceflight. In particular, we have attempted to highlight the gaps in current knowledge and the difficulties in translating terrestrial-based drug studies to a meaningful interpretation of drug stability, safety, and effectiveness in space. We hope to identify high-yield opportunities for future research that might better define and mitigate pharmaceutical risk for exploration missions.

Rebecca S Blue↗

Exploration of LIBS as a novel and rapid elemental mapping technique of nuclear fuels in the form of surrogate TRISO particles

Laser-induced breakdown spectroscopy (LIBS) was employed to characterize coatings on surrogate fuel particles. Tri-structural isotropic (TRISO) particles are a proposed nuclear fuel alternative for high temperature reactors. These particles are constructed of a ZrO 2 kernel (as a surrogate to uranium), surrounded by an inner pyrolytic carbon layer and are surrounded by an outer carbide layer (ZrC, presented here) to act as a barrier to fission products generated during nuclear reactions. These particles are embedded within a graphite compact and housed within the reactor core. Simply put, due to their robust nature, performing elemental analysis of these particles poses a challenge. Presented here, LIBS is explored as a method for characterizing elemental constituents of these particles, with the focus being on rapid elemental mapping and depth profiling. Different from traditional elemental analysis techniques (e.g., inductively coupled plasma – based methods), LIBS is advantageous because it can directly analyze the sample surface and can detect light elements such as C and O, making it a viable technique for the analysis of small, multilayered particles as spatial elemental information is warranted in the production of these particles. In the work presented here, LIBS was successfully used for discerning small layers (30–50 μm), detecting the location of carbon and oxygen layers, providing fast 2-D mapping (<5 min per particle) and rapid depth profiling (10 s per particle).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Characterizing Surface Ice-Philicity Using Molecular Simulations and Enhanced Sampling

The formation of ice, which plays an important role in diverse contexts ranging from cryopreservation to atmospheric science, is often mediated by solid surfaces. Although surfaces that interact favorably with ice (relative to liquid water) can facilitate ice formation by lowering nucleation barriers, the molecular characteristics that confer ice-philicity to a surface are complex and incompletely understood. To address this challenge, here we introduce a robust and computationally efficient method for characterizing surface ice-philicity that combines molecular simulations and enhanced sampling techniques to quantify the free energetic cost of increasing surface–ice contact at the expense of surface–water contact. Using this method to characterize the ice-philicity of a family of model surfaces that are lattice matched with ice but vary in their polarity, we find that the nonpolar surfaces are moderately ice-phobic, whereas the polar surfaces are highly ice-philic. In contrast, for surfaces that display no complementarity to the ice lattice, we find that ice-philicity is independent of surface polarity and that both nonpolar and polar surfaces are moderately ice-phobic. Furthermore, our work thus provides a prescription for quantitatively characterizing surface ice-philicity and sheds light on how ice-philicity is influenced by lattice matching and polarity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Multiple origins, one evolutionary trajectory: gradual evolution characterizes distinct lineages of allotetraploid Brachypodium

The “genomic shock” hypothesis posits that unusual challenges to genome integrity such as whole genome duplication may induce chaotic genome restructuring. Decades of research on polyploid genomes have revealed that this is often, but not always the case. While some polyploids show major chromosomal rearrangements and derepression of transposable elements in the immediate aftermath of whole genome duplication, others do not. Nonetheless, all polyploids show gradual diploidization over evolutionary time. To evaluate these hypotheses, we produced a chromosome-scale reference genome for the natural allotetraploid grass Brachypodium hybridum, accession “Bhyb26.” We compared 2 independently derived accessions of B. hybridum and their deeply diverged diploid progenitor species Brachypodium stacei and Brachypodium distachyon. The 2 B. hybridum lineages provide a natural timecourse in genome evolution because one formed 1.4 million years ago, and the other formed 140 thousand years ago. The genome of the older lineage reveals signs of gradual post-whole genome duplication genome evolution including minor gene loss and genome rearrangement that are missing from the younger lineage. In neither B. hybridum lineage do we find signs of homeologous recombination or pronounced transposable element activation, though we find evidence supporting steady post-whole genome duplication transposable element activity in the older lineage. Gene loss in the older lineage was slightly biased toward 1 subgenome, but genome dominance was not observed at the transcriptomic level. We propose that relaxed selection, rather than an abrupt genomic shock, drives evolutionary novelty in B. hybridum, and that the progenitor species’ similarity in transposable element load may account for the subtlety of the observed genome dominance.

59 BASIC BIOLOGICAL SCIENCES↗

SR19016 - Characterization of AM Materials for SRTE Service

This project addresses several issues and challenges for the use of AM produced components in the tritium facility. It will evaluate the effect of low level hydrogen and tritium exposure on the mechanical and chemical characteristics of Arcam A2X Electron Beam Powder Bed Fusion Produced (EPBF) Ti-6AI-4V by printing tensile samples and testing them in the as printed, machined, and hydrogen exposed conditions. Hydrogen uptake will be measured using an Eltra Hydrogen-Oxygen- Nitrogen analyzer. Hydride response will be measured using a Seiffert's apparatus and determining the effects of various surface treatments on the hydriding susceptibility. Tools, fixtures, and other objects will be deigned and printed for use in the AM lab and tritum facility and for other groups that support the tiritum mission.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Challenges of short-haul air transportation

Short-haul transportation systems are characterized by low average utilization, high peak but low average passenger demand, severe competition from other transportation modes, high fixed costs and high operating costs. Studies were conducted to analyze the operational requirements and market size for medium-density air transportation. The determination of the aircraft that will most efficiently meet the requirements of this market requires the careful evaluation of variable parameters such as engine cycles, payload, field length range and type of high-lift system. Low noise, low cost and thrust reversing capability are the basic criteria for the propulsion system. It is concluded that aircraft of less than 50-seat capacity cannot generate satisfactory profits operating in the medium-density market.

Galloway, T. L.↗

Evolution and interplay of lithium metal interphase components revealed by experimental and theoretical studies

ABSTRACT: Lithium metal batteries (LMB) have high energy densities and are crucial for clean energy solutions. The characterization of lithium metal interphase is fundamentally and practically important but technically challenging. Taking advantage of synchrotron x-ray which has the unique capability of analyzing crystalline/amorphous phases quantitative-ly with statistical significance, we study the composition and dynamics of LMB interphase for a newly developed im-portant LMB electrolyte that is based on fluorinated ether. Pair distribution function analysis revealed the sequential role of anion and solvent in interphase formation during cycling. The relative ratio between Li2O and LiF first increases and then decreases during cycling, suggesting suppressed Li2O formation in both initial and long extended cycles. Theoretical studies revealed that in initial cycles, this is due to the energy barrier in many-electron transfer. In long extended cycles, the anion decomposition product Li2O encourages solvent decomposition by facilitating solvent adsorption on Li2O which is followed by concurrent depletion of both. This work highlights the important role of Li2O in transitioning from anion-derived interphase to a solvent-derived one.

Tan, Sha↗

Impact of Water Extraction on Malonamide Aggregation: A Molecular Dynamics and Graph Theoretic Approach

Solution structure in liquid-liquid extraction affects the efficacy of separation; however, even for simplified organic phases, structural characterization and attribution of aggregation to intermolecular interactions are fundamental challenges. We investigate water uptake into organic phases for two malonamides commonly applied to actinide and lanthanide separations. Extracted water induces reorganization of the amphiphilic extractant molecules, although we find this rearrangement is not strongly manifested in small-angle X-ray scattering making it challenging to probe without methods such as atomistic simulation. Using a graph theoretic approach to define hydrogen bonded water/malonamide aggregates from molecular dynamics simulations, we find evidence of a characteristic aggregate size by water number that results from geometric accommodation of the surrounding malonamide molecules. Furthermore, this implies a degree of size selectivity inherent to these water-in-oil aggregates. Conversely, we find no evidence of a characteristic size of the aggregates with respect to their malonamide number. By defining a separate graphical representation of self-association of the amphiphilic malonamides, we quantify how water affects the local and nonlocal topology of the malonamide network, providing a basis for characterization of the structure and impact of polar solutes in increasingly complex organic phases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗