The thermodynamics of nitrogen austenite
Nitrogen austenite solute-solute binding energy derivation from experimental data for comparison with carbon austenite
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Nitrogen austenite solute-solute binding energy derivation from experimental data for comparison with carbon austenite
Charged scalar static model, using dispersion theory to include two-meson effects in two nucleons binding energy at zero separation
Canine ventricular myocardium as cardiac beta- adrenergic receptor, describing binding of norepinephrine to microsomal particles
For the first time the Brueckner-Hartree-Fock (BHF) method was applied to nuclei whose intrinsic structure is nonspherical. One aim was to investigate whether the energy dependent reaction matrix calculated from a realistic nucleon-nucleon interaction leads to deformations similar to, or different from, those obtained from energy independent interactions in Hartree-Fock (HF) calculations. Reaction matrix elements were calculated as a function of starting energy for the Hamada-Johnston interaction, using a Pauli operator appropriate to O-16 and a shifted oscillator spectrum for virtual excited states. Binding energies, single-particle energies, radii, and shape deformations of the intrinsic state in unrenormalized as well as renormalized BHF are discussed and compared with previous HF studies. Results are presented for C-12, O-16, and Ne-20.
Following the big-bang baryon symmetric cosmology of Omnes, the redshift was calculated to be on the order of 500-600. It is show that, at these redshifts, annihilation pressure at the boundaries between regions of matter and antimatter drives large scale supersonic turbulence which can trigger galaxy formation. This picture is consistent with the gamma-ray background observations discussed previously. Gravitational binding of galaxies then occurs at a redshift of about 70, at which time vortical turbulent velocities of about 3 x 10 to the 7th power cm/s lead to angular momenta for galaxies comparable with measured values.
The mechanical problems associated with testing the two high-heat load pipes are discussed. One of these pipes was tested three times before being accepted. The first test resulted in the discovery of non-condensable hydrogen gas, which prevented the pipe from functioning properly. The second test was a repeat of the first, to see if all the gas had been removed. The third test was to see if any changes had occurred to the pipe as a result of saddle modifications. Saddle modifications were necessary because the epoxy binding agent between the saddles and the pipe had decomposed during the testing. The test problems discussed deal with the specially designed heat-removal devices, the mobile tilt table, the table position indicator, and the heat input mechanisms, all of which were necessary to conduct a high-heat load, thermal-vacuum test. The final results showed that the techniques used were adequate for thermal-vacuum testing of heat pipes.
The physical adsorption of nitrogen on the chemically cleaned surfaces of Pyrex, 347 stainless steel and polycrystalline nickel was investigated over the pressure range 1 x 10 to the minus 12th power to 3 x 10 to the minus 7th power torr and for temperatures 77.4 and 87.4 K. The adsorption data were linearized by the Dubinin-Radushkevich equation. The metal surfaces were cleaned by electron impact desorption (EID) and the desorbed gases analyzed by mass spectrometry. Work function measurements were also used to indicate changes in the surface condition following an EID dose. At least a monolayer of gas was observed to desorb from the metal surfaces. The isotherms revealed that the metal surfaces were very heterogeneous and that the Pyrex surface had been leached. The calculated isosteric heats of adsorption indicated that the relative order of the physical binding of nitrogen to the solids was 347 stainless steel Pyrex nickel. A relationship was observed to exist in the dynamic technique between the equilibration time and the pressure above the absorbed layer. The slope of the log-log plot of these parameters was found to be sensitive to the surface heterogeneity and may be related to the activation energy for surface diffusion of physically absorbed molecules.
The renormalized Brueckner-Hartree-Fock (RBHF) theory for many-body nuclear systems is generalized to permit calculations for intrinsic states having permanent deformation. Both Hartree-Fock and Brueckner self-consistencies are satisfied, and details of the numerical techniques are discussed. The Hamada-Johnston interaction is used in a study of deformations, binding, size, and separation energies for several nuclei. Electromagnetic transition rates, moments, and electron scattering form factors are calculated using nuclear wave functions obtained by angular momentum projection. Comparison is made to experiment as well as to predictions of ordinary and density-dependent Hartree-Fock Theory.
A model of the galaxy is constructed and evolved in which the integrated influence of stellar and supernova nucleosynthesis on the composition of the interstellar gas is traced numerically. Our detailed assumptions concerning the character of the matter released from evolving stars and supernovae are guided by the results of recent stellar evolutionary calculations and hydrodynamic studies of supernova events. It is difficult to visualize an epoch of massive star formation in the collapsing gas cloud which formed our galaxy which would enrich the gas rapidly enough to account for the level of heavy element abundances in halo population stars; we have therefore proposed a stage of star formation which is entirely pregalactic in character. We suggest that the Jeans' length-sized initial condensations in the expanding universe discussed by Peebles and Dicke may provide the appropriate setting for this first generation of stars. Guided by these considerations, and by the need for a substantial quantity of 'unseen' mass to bind our local group of galaxies, we have constructed a model of the galaxy in which this violent early phase of massive star formation produces both (1) approximately 25% of the level of heavy elements observed in the solar system and (2) an enormous unseen mass in the form of black holes.
The redshifted L alpha flux from the Coma cluster of galaxies is determined to be less than 6000 photons per cm sq per sec, leading to severe (and perhaps fatal) new restrictions on hot ionized gas models for the gravitational binding of the cluster.
Discussion of the results of adhesion experiments conducted with various metals contacting a clean iron surface. The metals included gold, silver, nickel, platinum, lead, tantalum, aluminum, and cobalt. Some of the metals were examined with oxygen present on their surface as well as in the clean state. The results indicate that, with the various metals contacting iron, the cohesively weaker will adhere and transfer to the cohesively stronger. The chemical activity of the metal also influenced the adhesive forces measured. With oxygen present on the metal surface, the adhesive forces measured could be correlated with the binding energy of the metal to oxygen.
High gravity, cold and starvation elicited similar responses in male Simonson rats. These responses included a decreased rate in body weight gain, increased metabolism of aniline and p-nitroanisole, and no consistent pattern of change in the metabolism of ethylmorphine. Cold and starvation increased the amount of hepatic cytochrome P-450, while hypobaric-hyperoxia caused no change in any of the parameters measured. When 1% acetone was given to the rats in their drinking water, the effects on drug metabolism were similar to those produced by food restriction in that the metabolism of aniline and p-nitroanisole was increased, and the metabolism of ethylmorphine unchanged. The type I binding spectrum of acetone suggests that it is either a substrate, inhibitor, or both for hepatitic oxidative enzymes.
Total energy distributions of field emitted electrons from the tungsten (110) and (100) planes as a function of coverage by hydrogen and deuterium have been recorded utilizing a spherical deflection energy analyzer. The elastic tunneling resonance spectrum gives a plot of the 'local density of states' in the adsorbate. The inelastic tunneling spectrum reveals those discrete excitation energies available in the adsorbate-substrate complex. These spectroscopic data have been used to infer the chemical nature of the binding states which have been observed in the flash desorption spectrum of hydrogen from tungsten.
The technique of electron spectroscopy for chemical analysis (ESCA) is used to obtain rapid, nondestructive elemental analyses of selected lunar samples, and the chemical shift of the Fe(2p) line in lunar materials is found characteristic of iron in the Fe(2+) state. A difference in binding energy of approximately 0.5 eV is observed between the 0(1s) levels of the terrestrial minerals fayalite and quartz, and effects due to surface oxidation and absorption are also observed in terrestrial materials. The new ESCA technique is based on energy analysis at high resolution of electrons emitted from the surface of a sample on irradiation with X rays and is valuable for the study of the electronic structure of atoms and molecules.
Semi-empirical potentials are constructed that have eigenvalues close in magnitude to the binding energies of the valence electron in lithium. The potentials include the long range polarization force between the electron and the core. The corresponding eigenfunctions are used to calculate dynamic polarizabilities, discrete oscillator strengths, photoionization cross sections and radiative recombination coefficients. A consistent application of the theory imposes a modification on the transition operator, but its effects are small for lithium. The method presented can be regarded as a numerical generalization of the widely used Coulomb approximation.
The rates of chemical reactions which deteriorate foods prepared to an intermediate moisture content and water activity (A sub w 0.6 to 0.9) were studied. The phenomenon of sorption hysteresis was used to prepare model systems and foods to similar A sub w's but different moisture levels so that the separate effects of water binding and water content could be elucidated. It was found that water content is the controlling factor for lipid oxidation in model systems comprised of a solid support and an oxidizable liquid. It was proposed that metal chelating agents like EDTA should give good protection to oxidation. EDTA exhibited the highest efficacy, about 10-15 times better than BHA which is a radical scavenger when studied in the model systems.
A possible alternative to the ordinary gas-like computation for nuclear matter is investigated under the assumption that the nucleons are arranged in a lattice. BCC, FCC and HCP structures are investigated. Only HCP shows a minimum in the energy vs. density curve with a modest binding energy of -1.5 MeV. The very low density limit is investigated and sensible results are obtained only if the tensor force decreases with the density. A study of the elastic properties indicates that the previous structures are mechanically unstable against shearing stresses.
The renormalized Brueckner-Hartree-Fock (RBHF) theory for many-body nuclear systems has been generalized to permit calculations for intrinsic states having permanent deformation. Both Hartree-Fock and Brueckner self-consistencies are satisfied, and details of the numerical techniques are discussed. The Hamada-Johnston interaction is used in a study of deformations, binding, size, and separation energies for several nuclei. Electromagnetic transition rates, moments, and electron scattering form factors are calculated using nuclear wave functions obtained by angular momentum projection. Comparison is made to experiment as well as to predictions of ordinary and density-dependent Hartree-Fock theory.