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At least 577 records · Page 32

On the combustion of n-butyl acetate droplets

This paper presents an experimental and numerical study of the combustion of isolated n‑butyl acetate droplets in the standard atmosphere. Numerical simulations are reported using a model that incorporates unsteady gas and liquid transport, variable properties, and radiation. Three skeletal mechanisms of n‑butyl acetate, derived from a large detailed mechanism comprised of 819 species and 52,698 reactions, were used in the numerical simulations to evaluate the influence of the kinetic mechanism on burning. The reduced mechanisms comprised 212 species and 5413 reactions, 157 species and 3089 reactions, and 105 species and 1035 reactions. The numerical model did not include soot formation, though qualitatively mild sooting was noted only for droplets larger than 0.7 mm. The numerical predictions were in good agreement with experimental measurements of droplet and flame diameters. Flame extinction was numerically predicted which was attributed to a decrease of the characteristic diffusion time relative to the chemical time as droplet burned. Effects of initial droplet diameter on the evolution of maximum gas temperature (Tmax) and peak mole fractions of CO2 and CO are also examined numerically.

09 BIOMASS FUELS↗

Isotopic composition of nitrogen - Implications for the past history of Mars' atmosphere

Models are presented for the past history of nitrogen on Mars, based on Viking measurements showing that the atmosphere is enriched in N-15. The enrichment is attributed to selective escape, with fast atoms formed in the exosphere by electron impact dissociation of N2 and by dissociative recombination of N2(+). The initial partial pressure of N2 should have been at least as large as several millibars and could have been as large as 30 millibars if surface processes were to represent an important sink for atmospheric HNO2 and HNO3.

Mcelroy, M. B.↗

Formulation of electrically conductive, thermal-control coatings

Formulation of electrically conductive, thermal-control coatings was undertaken for use on the International Sun Earth Explorer (ISEE) spacecraft. Unsuccessful formulation efforts as well as the successful use of oxide pigments fired at 1175 C are described. Problems attributed to reactivity of specific coating vehicles exposed to high humidity are discussed. Measurement and testing methods, including resulting data are mentioned, but the emphasis, in this report, is placed on coating formulation and application techniques. Methods of varying, as desired, optical properties are also described as well as formulations of white, low-absorptance coatings.

Shai, M. C.↗

Turbomachinery noise studies of the AiResearch QCGAT engine with inflow control

The AiResearch Quiet Clean General Aviation Turbofan engine was tested on an outdoor test stand to compare the acoustic performance of two inflow control devices (ICD's) of similar design, and three inlet lips of different external shape. Only small performance differences were found. Far-field directivity patterns calculated by applicable existing analyses were compared with the measured tone and broadband patterns. For some of these comparisons, tests were made with an ICD to reduce rotor/inflow disturbance interaction noise, or with the acoustic suppression panels in the inlet or bypass duct covered with aluminum tape to determine hard wall acoustic performance. The comparisons showed that the analytical expressions used predict many directivity pattern features and trends, but can deviate in shape from the measured patterns under certain engine operating conditions. Some patterns showed lobes from modes attributable to rotor/engine strut interaction sources.

Mcardle, J. G.↗

Lunar luminescence and the filling-in of Fraunhofer lines in moonlight

The filling-in of Fraunhofer lines in moonlight has been attributed to lunar luminescence. In order to test mechanisms proposed for this effect, measurements were made of the filling-in of the H-alpha line, the Na D doublet, and a number of lines near the doublet. The degree of filling-in was not correlated with wavelength in a way expected from a broadband luminescence, such as thermoluminescence. However, it was correlated with equivalent width of the Fraunhofer line, such that it increased as equivalent width decreased. This suggests that the Fraunhofer line filling at the moon's surface is caused by inelastic scattering of sunlight with a small wavelength shift, as for example, photon-phonon scattering.

Potter, A. E.↗

Effects of aerosols and surface shadowing on bidirectional reflectance measurements of deserts

Desert surfaces are probably one of the most stable of the Earth's natural targets for remote sensing. The bidirectional reflectance properties of the Saudi Arabian desert was investigated during the Summer Monsoon Experiment (Summer Monex). A comparison of high-altitude with near-surface measurements of the White Sands desert showed significant differences. These discrepancies have been attributed to forward scattering of the dust-laden atmosphere prevalent during Summer Monex. This paper is concerned in general with modeling the effects of atmospheric aerosols and surface shadowing on the remote sensing of bidirectional reflectance factors of desert targets, and in particular with comparing the results of these models with flight results. Although it is possible to approximate the latter, it is felt that a surface reflectance model with a smaller specular component would have permitted using a more realistic set of atmospheric conditions in the simulations.

Bowker, David E.↗

Projection-operator calculations of the lowest e(-)-He resonance

The 1s (2s)2:2S Schulz resonance of He(-) is investigated theoretically, applying the full projection-operator formalism developed by Temkin and Bhatia (1985) in a Rayleigh-Ritz variational calculation. The technique is described in detail, and results for five different approximations of the He target state are presented in a table. Good convergence is obtained, but it is found that even the best calculated value of the resonance is about 130 meV higher than the experimentally measured value of 19.367 + or - 0.007 eV (Brunt et al., 1977), a discrepancy attributed to the contribution of the shift in the Feshbach formalism.

Berk, A.↗

Temperature-dependent absorption cross sections for hydrogen peroxide vapor

Relative absorption cross sections for hydrogen peroxide vapor were measured over the temperature ranges 285-381 K for lambda = 230 nm-295 nm and 300-381 K for lambda = 193 nm-350 nm. The well established 298 K cross sections at 202.6 and 228.8 nm were used as an absolute calibration. A significant temperature dependence was observed at the important tropospheric photolysis wavelengths lambda over 300 nm. Measured cross sections were extrapolated to lower temperatures, using a simple model which attributes the observed temperature dependence to enhanced absorption by molecules possessing one quantum of O-O stretch vibrational excitation. Upper tropospheric photodissociation rates calculated using the extrapolated cross sections are about 25 percent lower than those calculated using currently recommended 298 K cross sections.

Nicovich, J. M.↗

Spacelab 1 experiments on interactions of an energetic electron beam with neutral gas

An unusual signature of return current and spacecraft charging potential was observed during the Spacelab 1 mission launched on November 28, 1983. The phenomenon occurred during neutral gas releases from the SEPAC (Space Experiments with Particle Accelerators) magnetoplasma-dynamic arcjet (MPD) concurrent with firings of the PICPAB (Phenomena Induced by Charged Particle Beams) electron gun and was recorded by the instruments of the SEPAC diagnostic package (DGP). Data from the langmuir probe, floating probes, neutral gas pressure gauge, and the plasma wave probes are reported. As the dense neutral gas was released, the return current measured by the langmuir probe changed from positive to negative and a positive potential relative to the spacecraft was measured by the floating probe. The anomalous return current is believed to be attributable to secondary electron fluxes escaping from the spacecraft, and the unusual charging situation is attributed to the formation of a double-layer structure between a hot plasma cloud localized to the MPD and the spacecraft. The charging scenario is supported by a computer simulation.

Marshall, J. A.↗

The mesospheric responses to short-term solar ultraviolet variability

The response of mesospheric ozone and temperature to short term solar ultraviolet variations related the the 27 day rotation of the Sun has been recently detected from analysis of satellite measurements. A systematic depletion of ozone was detected near 70 km, which is attributed to solar Lyman alpha photodissociation of water vapor with subsequent catalytic destruction of O(x) by HO(x) and temperature feedback effects resulting from the unexpectedly strong temperature/UV response near 70 km. The nature of latitudinal and semiannual variations in the ozone/UV and temperature/UV response were isolated. Observed variations are compared to theoretical models.

Keating, Gerald M.↗

LDEF polymeric materials: 10 months versus 5.8 years of exposure

The chemical characterization of several polymeric materials which received both 10 months and 5.8 years of exposure on a Row 9 experiment (A0134) is reported. Specimens include polysulfone film, polysulfone matrix/graphite-fiber reinforced composites, and coated and uncoated epoxy matrix/graphite fiber reinforced composites. The effect of 10 months of exposure on an experimental silicon-containing polyimide copolymer film is also reported. The results of infrared, thermal, x-ray photoelectron, and scanning electron microscope analyses will be compared for the two exposures. Solution property measurements on the thermoplastic polysulfone resin will also be presented. Molecular level effects attributable to exposure and present in 10-month specimens are not present in 5.8-year specimens. This suggests that increased atomic oxygen fluence toward the end of the mission may have eroded selected environmentally-induced changes in surface chemistry for 5.8-year specimens.

Young, Philip R.↗

Coupled Gravity and Elevation Measurement of Ice Sheet Mass Change

During June 2003, we measured surface gravity at six locations about a glaciological measurement site located on the South-central Greenland Ice. We operated a GPS unit for 90 minutes at each site -the unit was operated simultaneously with a base station unit in Sondrestrom Fjord so as to enable differential, post-processing of the data. We installed an aluminum, accumulation-rate-pole at each site. The base section of the pole also served as the mount for the GPS antenna. Two gravimeters were used simultaneously at each site. Measurements were repeated at each site with at time lapse of at least 50 minutes. We measured snow physical properties in two shallow pits The same measurement sites were occupied in 1981 and all were part of a hexagonal network of geodetic and glaciological measurements established by The Ohio State University in 1980. Additional gravity observations were acquired at three of the sites in 1993 and 1995. Gravity data were collected in conjunction with Doppler satellite measurements of position and elevation in 1981 and global positioning system measurements subsequently. The use of satellite navigation techniques permitted reoccupation of the same sites in each year to within a few 10 s of meters or better. After detrending the gravity data, making adjustments for tides and removing the residual effects of local spatial gradients in gravity, we observe an average secular decrease in gravity of about 0.01 milligal/year, but with tenths of milligal variations about the mean trend. The trend is consistent with a nearly linear increase in surface elevation of between 7 to 10 c d y r (depending on location) as measured by repeated airborne laser altimeter, surface Doppler satellite and GPS elevation measurements. Differences between the residual gravity anomalies after free air correction may be attributable to local mass changes. This project is a collaboration between the Byrd Polar Research Center of the Ohio State University and the Arctic Technology Center of the Danish Technical University.

Jezek, K. C.↗

Test and Analysis of Sub-Components of Aluminum-Lithium Alloy Cylinders

Integrally machined blade-stiffened panels subjected to an axial compressive load were tested and analyzed to observe the buckling, crippling, and postcrippling response of the panels. The panels were fabricated from aluminum-lithium alloys 2195 and 2050, and both alloys have reduced material properties in the short transverse material direction. The tests were designed to capture a failure mode characterized by the stiffener separating from the panel in the postbuckling range. This failure mode is attributed to the reduced properties in the short transverse direction. Full-field measurements of displacements and strains using three-dimensional digital image correlation systems and local measurements using strain gages were used to capture the deformation of the panel leading up to the failure of the panel for specimens fabricated from 2195. High-speed cameras were used to capture the initiation of the failure. Finite element models were developed using an isotropic strain-hardening material model. Good agreement was observed between the measured and predicted responses for both alloys.

Haynie, Waddy T.↗

Recalibration of the NASA Exterior Effects Room

The Exterior Effects Room (EER) is a psychoacoustic testing facility at NASA Langley Research Center which primarily focuses on testing human response to aircraft noise. The 39-seat auditorium houses a real-time spatial audio system and flyover simulation environment. The audio server utilizes an implementation of three-dimensional vector base amplitude panning (VBAP), a perceptual spatial audio technique exploiting loudspeaker triplets to place a virtual sound source at an arbitrary spatial position. Due to the irregular room geometry and non-uniform loudspeaker setup, the audio server applies equalization filtering to compensate for spectral coloration attributed to loudspeaker installation, crossover filtering, and delay/gain offsets. These filters can incorporate measurements taken at multiple listening points, allowing a more extensive listening area than filters derived from measurements taken at a single listening point. This work endeavors to update the existing equalization filter generation process by producing a new set of filters for various human subject testing scenarios.

calibration↗

Recalibration of the NASA Exterior Effects Room

The Exterior Effects Room (EER) is a psychoacoustic testing facility at NASA Langley Research Center which primarily focuses on testing human response to aircraft noise. The 39-seat auditorium houses a real-time spatial audio system and flyover simulation environment. The audio server utilizes an implementation of three-dimensional vector base amplitude panning (VBAP), a perceptual spatial audio technique exploiting loudspeaker triplets to place a virtual sound source at an arbitrary spatial position. Due to the irregular room geometry and nonuniform loudspeaker setup, the audio server applies equalization filtering to compensate for spectral coloration attributed to loudspeaker installation, crossover filtering, and delay/gain offsets. These filters can incorporate measurements taken at multiple listening points, allowing a more extensive listening area than filters derived from measurements taken at a single listening point. This work endeavors to update the existing equalization filter generation process by producing a new set of filters for various human subject testing scenarios.

Signal Processing↗

Role of Anions in Stabilizing the [Zn–Al] Layered Double Hydroxides: A Thermodynamic Study

Here, room-temperature acid solution calorimetry, high-temperature oxide melt solution calorimetry, and low-temperature heat capacity measurements were employed to calculate the thermodynamic stabilities of the [Zn–Al–X] layered double hydroxides (LDH) containing different anions (X = Cl – , CO 3 2– , and SO 4 2– ). Cryogenic heat capacity measurements demonstrated a Schottky-type anomaly in the heat capacity of all three LDHs below 11 K. This anomaly is attributed to the tunneling of protons between adjacent oxygen atoms in the LDH interlayer as this creates an energy system similar to a two-level system modeled with a Schottky term. These heat capacity measurements were also used to determine vibrational entropies which, when combined with configurational entropies, provide standard entropies of these LDHs. Enthalpies of formation of LDHs from binary components were determined and combined with the entropies of formation to calculate Gibbs free energies. Based on these values, the order of stability is [Zn–Al–SO 4 ] > [Zn–Al–CO 3 ] > [Zn–Al–Cl]. This trend results from a combination of the interlayer spacing, amount of water in the interlayer, interactions among the interlayer species, and interactions between the metal hydroxide layer and the interlayer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis of measurements from an array of radioxenon samplers near to Hartlepool Nuclear Power Station

As part of a scientific research and development project, the radionuclide fingerprint of an operating advanced gas-cooled reactor 25 (AGR) has been studied across several facets (Goodwin et al., 2024). One part of this project was to deploy an array of 26 radioxenon samplers to the region for a period of around 1 year, to measure any radioxenon emissions from the reactors of the 27 Hartlepool nuclear power station at a range of tens of kilometres away. The array of 3 sensors was operational for around 12 28 months from March 2022 and detected many occurrences of isotopes of radioxenon. Here we provide a detailed analysis and 29 interpretation of the data and where possible, attribution of detections to a source or region. Whilst a key part of this work is to 30 measure any emissions of radioxenon from Hartlepool, this work presents one of the most comprehensive efforts to determine the 31 source of a great number of (mostly) 133Xe detections. A combination of different types of atmospheric dispersion modelling 32 techniques, including the use of stack monitoring data from nearby civil radioxenon-emitting nuclear facilities has enabled the 33 majority of detections to be attributed to one or more possible sources. Whilst emissions from Hartlepool have been detected on 34 the systems, the majority of detections are associated with a medical isotope production facility in Fleurus, Belgium (IRE).

Advanced gas-cooled reactor↗

1.2-kV Vertical GaN PIN Rectifier With Ion-Implanted Floating Guard Rings

Here, this work reports on the fabrication and properties of a homojunction gallium nitride (GaN) p-i-n (PIN) rectifier fabricated on a free-standing GaN substrate. Uniform device performance is achieved with breakdown voltage (BV) >1.2 kV and low ON-resistance × area ( R ON A ). The statistics of the BV measurements show 58.5% of devices achieve BV >1.3 kV, and 71.1% of devices achieve BV >1.2 kV, as attributed to high quality and control in both epitaxial growth and device process. At room temperature, R ON A is 0.23 mΩ∙ cm 2 at a current density ( J ) of 6.9 kA/cm2. The corresponding Baliga’s figure of merit is >5.97 GW/cm 2 . Temperature-dependent reverse I – V measurements were performed and show a positive temperature coefficient of 0.42 V/K, indicating the avalanche capability of reverse breakdown. Further analysis with the Poole-Frenkel model on the temperature-dependent measurement suggested that a trap-assisted tunneling process contributed to the reverse leakage current. Floating guard rings (FGRs) formed by nitrogen implantation serve as an effective edge termination technique in these GaN PIN rectifiers, resulting in uniform performance in both forward and reverse bias.

42 ENGINEERING↗