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At least 577 records · Page 32

Influence of Added Salt on Chain Conformations in Poly(ethylene oxide) Melts: SANS Analysis with Complications

Poly(ethylene oxide) (PEO)-based electrolytes have gained increasing attention in both the rechargeable battery industry and fundamental research, but any influence of the ions on the polymer conformation is not fully understood. Small-angle neutron scattering (SANS) is a powerful means to determine single-polymer chain conformations. We conducted SANS experiments on 50:50 blends of perdeuterated PEO (dPEO) and hydrogenous PEO (hPEO) of two different molecular weights (20 and 40 kDa) doped with two different salts (LiTFSI and LiClO 4 ) at various concentrations. An additional measurement with LiI is also reported. The scattering profiles of salt-doped dPEO/hPEO blends were measured, and the incoherent scattering from dPEO and hPEO doped with salt was measured separately. A strong low q upturn was observed in some of the blends and in the pure dPEO homopolymers. The statistical segment lengths of PEO–salt mixtures were derived using a Kratky analysis. The segment length decreases modestly with increasing amounts of LiTFSI but apparently first increases then decreases with added LiClO 4 . At the highest salt concentration examined (r = [Li+]/[EO] = 0.125), a roughly 10% decrease in the statistical segment length was observed in both LiTFSI and LiClO 4 -doped PEOs, for both molecular weights. This work confirms that added salt causes a contraction of the PEO chain dimensions, but the effect appears slightly weaker than reported recently. Certain difficulties in data analysis are also discussed, including the unexplained low q scattering even in pure deuterated polymers, uncertainties in background subtraction, and inappropriate application of the Debye function.

36 MATERIALS SCIENCE↗

Advances in understanding the gravity wave spectrum during MAP

Prior to MAP, virtually nothing was known about gravity wave spectra in the atmosphere. The development of observational techniques has played a major role in these studies. Radar and lidar have been particularly important since they can measure atmospheric parameters continuously over large height ranges. Some advances made are: (1) The observed fluctuations and power spectra in the free atmosphere are mostly if not entirely due to a superposition of gravity waves, which can be modeled by the Garrett Munk (GM) model; (2) There is no evidence that 2-D turbulence makes a significant contribution to the observed fluctuations. In any case, the agreement between observations and the GM model shows that the 2DT contribution must be relatively small; (3) Spectra versus vertical wave number are saturated at large wave number, with theory and observations indicating that t approximately equals 3; and (4) Vertical velocity fluctuations and spectra measured near rough terrain are strongly contaminated by mountain waves. But over very flat terrain the spectra are dominated by gravity waves at periods shorter than about 6 hours and apparently by synoptic scale velocities at periods longer than 6 hours. Thus it may be possible to study synoptic scale vertical velocities using radars located in very flat terrain.

Vanzandt, T. E.↗

Chandra X-Ray Observatory Observations of the Globular Cluster M28 and its Millisecond Pulsar PSR B1821-24

We report here the results of the first Chandra X-Ray Observatory observations of the globular cluster M28 (NGC 6626). We detect 46 X-ray sources of which 12 lie within one core radius of the center. We show that the apparently extended X-ray core emission seen with the ROSAT HRI is due to the superposition of multiple discrete sources for which we determine the X-ray luminosity function down to a limit of about 6 x 10(exp 30) erg/s. We measure the radial distribution of the X-ray sources and fit it to a King profile finding a core radius of r(sub c,x) approx. 11 sec. We obtain the best-fit mass of the X-ray sources to be M(sub x) approx. 1.9 solar masses. We measure for the first time the unconfused phase-averaged X-ray spectrum of the 3.05-ms pulsar B1821-24 and find it best described by a power law with photon-index Gamma approx. equal to 1.2. We find marginal evidence of an emission line centered at 3.3 kev in the pulsar spectrum, which could be interpreted as cyclotron emission from a corona above the pulsar's polar cap if the the magnetic field is strongly different from a centered dipole. The unabsorbed pulsar flux in the 0.5-8.0 keV band is approx. 3.5 x 10(exp -13) ergs/s/sq cm. We present spectral analyses of the 5 brightest unidentified sources. Based on the spectral parameters of the brightest of these sources, we suggest that it is a transiently accreting neutron star in a low-mass X-ray binary, in quiescence. Fitting its spectrum with a hydrogen neutron star atmosphere model yields the effective temperature T(sup infinity)(sub eff) = 90(sup +30)(sub -10) eV and the radius R(sup infinity)(sub NS) = 14.5(sup +6.9)(sub -3.8) km. In addition to the resolved sources, we detect fainter, unresolved X-ray emission from the central core. Using the Chandra-derived positions, we also present a preliminary report on the result of searching archival Hubble Space Telescope data for possible optical counterparts.

Becker, Werner↗

Dynamic evolution of the source volumes of gradual and impulsive solar flare emissions

This study compares flare source volumes inferred from impulsive hard X-rays and microwaves with those derived from density sensitive soft X-ray line ratios in the O VII spectrum. The data for this study were obtained with the SMM Hard X-Ray Burst Spectrometer, Earth-based radio observatories, and the SOLEX-B spectrometer on the P78-1 satellite. Data were available for the flares of 1980 April 8, 1980 May 9, and 1981 February 26. The hard X-ray/microwave source volume is determined under the assumption that the same electron temperature or power law index characterizes both the source of hard X-rays and the source of microwaves. The O VII line ratios yield the density and volume of the 2 X 10 to the 6th K plasma. For all three flares, the O VII source volume is found to be smallest at the beginning of the flare, near the time when the impulsive hard X-ray/microwave volume reaches its first maximum. At this time, the O VII volume is three to four orders of magnitude smaller than that inferred from the hard X-ray/microwave analysis. Subsequently, the O VII source volume increases by one or two orders of magnitude then remains almost constant until the end of the flare when it apparently increases again.

Bruner, M. E.↗

Dynamic evolution of the source volumes of gradual and impulsive solar flare emissions

This study compares flare source volumes inferred from impulsive hard X-rays and microwaves with those derived from density sensitive soft X-ray line ratios in the O VII spectrum. The data for this study were obtained with the SMM Hard X-ray Burst Spectrometer, Earth-based radio observatories, and the SOLEX-B spectrometer on the P78-1 satellite. Data were available for the flares of 1980 April 8, 1980 May 9, and 1981 February 26. The hard X-ray/microwave source volume is determined under the assumption that the same electron temperature or power law index characterizes both the source of hard X-rays and the source of microwaves. The O VII line ratios yield the density and volume of the 2 x 10 to the 6th K plasma. For all three flares, the O VII source volume is found to be smallest at the beginning of the flare, near the time when the impulsive hard X-ray/microwave volume reaches its first maximum. At this time, the O VII volume is three to four orders of magnitude smaller than that inferred from the hard X-ray/microwave analysis. Subsequently, the O VII source volume increases by one or two orders of magnitude then remains almost constant until the end of the flare when it apparently increases again.

Bruner, M. E.↗

Copper emissions from a high volume air sampler

High volume air samplers (hi vols) are described which utilize a brush-type electric motor to power the fans used for pulling air through the filter. Anomalously high copper values were attributed to removal of copper from the commutator into the air stream due to arcing of the brushes and recirculation through the filter. Duplicate hi vols were set up under three operating conditions: (1) unmodified; (2) gasketed to prevent internal recirculation; and (3) gasketed and provided with a pipe to transport the motor exhaust some 20 feet away. The results of 5 days' operation demonstrate that hi vols can suddenly start emitting increased amounts of copper with no discernible operational indication, and that recirculation and capture on the filter can take place. Copper levels found with hi vols whose exhaust was discharged at a distance downwind were among the lowest found, and apparently provides a satisfactory solution to copper contamination.

King, R. B.↗

Solar Wind Ablation of Terrestrial Planet Atmospheres

Internal plasma sources usually arise in planetary magnetospheres as a product of stellar ablation processes. With the ignition of a new star and the onset of its ultraviolet and stellar wind emissions, much of the volatiles in the stellar system undergo a phase transition from gas to plasma. Condensation and accretion into a disk is replaced by radiation and stellar wind ablation of volatile materials from the system- Planets or smaller bodies that harbor intrinsic magnetic fields develop an apparent shield against direct stellar wind impact, but UV radiation still ionizes their gas phases, and the resulting internal plasmas serve to conduct currents to and from the central body along reconnected magnetic field linkages. Photoionization and thermalization of electrons warms the ionospheric topside, enhancing Jeans' escape of super-thermal particles, with ambipolar diffusion and acceleration. Moreover, observations and simulations of auroral processes at Earth indicate that solar wind energy dissipation is concentrated by the geomagnetic field by a factor of 10-100, enhancing heavy species plasma and gas escape from gravity, and providing more current carrying capacity. Thus internal plasmas enable coupling with the plasma, neutral gas and by extension, the entire body. The stellar wind is locally loaded and slowed to develop the required power. The internal source plasma is accelerated and heated, inflating the magnetosphere as it seeks escape, and is ultimately blown away in the stellar wind. Bodies with little sensible atmosphere may still produce an exosphere of sputtered matter when exposed to direct solar wind impact. Bodies with a magnetosphere and internal sources of plasma interact more strongly with the stellar wind owing to the magnetic linkage between the two created by reconnection.

Moore, Thomas Earle↗

Temperature anisotropy of the Jovian sulfur nebula

The apparent paradox between the reported observation of a 3-eV gyration energy of Jupiter's ionized sulfur nebula and its observed thickness is discussed. An observation of the thickness of the cloud taken nearly edge-on is presented and shown to imply a large bounce-averaged anisotropy of the sulfur in temperature. These observations are used to construct a self-consistent model of the sulfur nebula in which the sulfur ions are injected by Io as ions and remain sufficiently collisionless in the magnetosphere to maintain the anisotropy for a time longer than a characteristic diffusion time. It is also shown that the proton-electron plasma is collisionally thermalized and provides an adequate means of tapping the rotational energy of the planet to provide the power radiated in the sulfur lines.

Eviatar, A.↗

Striving to translate shale physics across ten orders of magnitude: What have we learned?

Shales will play an important role in the successful transition of energy from fossil-based resources to renewables in the coming decades. Aside from being a significant source of low-carbon intensity fuels, like natural gas, they also serve as geologic seals of subsurface formations that may be used to isolate nuclear waste, sequester CO 2 , or store intermittent energy (e.g., solar hydrogen). Despite their importance, shales pose significant engineering and environmental challenges due to their nanoporous structure and extreme heterogeneity that spans at least ~10 orders of magnitude in spatial scale. Two challenges inhibit a system-level understanding: (1) the physics of fluid flow and phase behavior in shales are poorly understood due to the dominant molecular interactions between minerals and fluids under confinement, and (2) the apparent lack of scale separation that prevents a reliable (closed) description of the physics at any single scale of observation. In this review, we focus on the latter issue and discuss scale translation, which in its broadest sense is transforming data or simulations from one spatiotemporal scale to another. While effective scale translation is not exclusive to shales, but all geologic porous media, the need for it is especially acute in shales given their high degree of heterogeneity. Classical theories like homogenization, while indispensable, fail when scales are not separated. Other methods, like numerical upscaling, scale-translate in only one direction: small to large, but not the reverse, called downscaling. However, the confluence of advances in three areas are bringing challenging problems such as shales within reach: increased computational power and scalable algorithms; high-resolution imaging and multi-modal data acquisition; and machine learning to process massive amounts of data. While these advances equip geoscientists with a wide array of experimental and computational tools, no individual tool can probe the entire gamut of heterogeneity in shales. Their effective use, therefore, requires an ability to bridge between various data types obtained at different scales. The aim of this review is to present a coherent account of computational and experimental methods that may be used to achieve just that, i.e., to perform scale translation. We provide a broader definition of scale translation, one that transcends classical homogenization and upscaling methods, but is consistent with them and accommodates notions like downscaling and data translation. After a brief introduction to homogenization, we review hybrid methods, numerical upscaling and its recent extensions, multiscale computing, high-resolution imaging, and machine learning. We place particular emphasis on multiscale computing and propose an algorithmic framework to bridge between the pore (micro) and Darcy (macro) scales. Throughout the paper, we draw comparisons between the various methods and highlight their (often hidden) similarities, differences, benefits, and pitfalls. We finally conclude with two case studies on shales that exemplify some of the methods presented.

58 GEOSCIENCES↗

Comparison of the Arrhenius parameters between conventional hydrothermal and microwave-assisted synthesis methods for tin oxide nanoparticles

Microwave (MW) irradiation has emerged as a powerful tool for accelerating materials synthesis, yet the origins of its specific influence on reaction kinetics remain elusive. While multiple studies have attributed the observed enhancements in reaction rates under MW heating to reduced activation energies, other accounts have suggested modifications to the Arrhenius pre-exponential factor as the predominant cause. Distinguishing between these parameters in modern applications of MW processing in nanomaterials requires experimental approaches capable of resolving the dynamic and nuanced structural kinetics that govern MW-assisted chemistry. Here, we combine in-situ synchrotron X-ray total scattering with pair distribution function (PDF) analysis to track the structural evolution of SnO 2 nanoparticles synthesized via MW-assisted and conventional hydrothermal conditions. Avrami modeling and Arrhenius analysis suggest that although MW irradiation yields a higher apparent activation energy, the enhanced crystallization is better explained by a pre-exponential factor several orders of magnitude larger than that of conventional heating. These findings suggest that the MW field induces a higher frequency of successful molecular rearrangements rather than lowering the intrinsic activation barrier. The results contribute further insights clarifying the role of the applied MW field for materials design where MW-specific effects can be deliberately harnessed. Furthermore, this work presents a framework promoting the utility of in-situ PDF characterization coupled with kinetic analysis for developing more sophisticated descriptions of nanoscale transformations for MW-driven reaction kinetics.

36 MATERIALS SCIENCE↗

Reduction and analysis of VLA maps for 281 radio-loud quasars using the UNLV Cray Y-MP supercomputer

The identification of distorted radio-loud quasars provides a potentially very powerful tool for basic cosmological studies. If large morphological distortions are correlated with membership of the quasars in rich clusters of galaxies, optical observations can be used to identify rich clusters of galaxies at large redshifts. Hintzen, Ulvestad, and Owen (1983, HUO) undertook a VLA A array snapshot survey at 20 cm of 123 radio-loud quasars, and they found that among triple sources in their sample, 17 percent had radio axes which were bent more than 20 deg and 5 percent were bent more than 40 deg. Their subsequent optical observations showed that excess galaxy densities within 30 arcsec of 6 low-redshift distorted quasars were on average 3 times as great as those around undistorted quasars (Hintzen 1984). At least one of the distorted quasars observed, 3C275.1, apparently lies in the first-ranked galaxy at the center of a rich cluster of galaxies (Hintzen and Romanishin, 1986). Although their sample was small, these results indicated that observations of distorted quasars could be used to identify clusters of galaxies at large redshifts. The purpose of this project is to increase the available sample of distorted quasars to allow optical detection of a significant sample of quasar-associated clusters of galaxies at large redshifts.

Ding, Ailian↗

Radiation Quality Effects on Transcriptome Profiles in 3-d Cultures After Particle Irradiation

In this work, we evaluate the differential effects of low- and high-LET radiation on 3-D organotypic cultures in order to investigate radiation quality impacts on gene expression and cellular responses. Reducing uncertainties in current risk models requires new knowledge on the fundamental differences in biological responses (the so-called radiation quality effects) triggered by heavy ion particle radiation versus low-LET radiation associated with Earth-based exposures. We are utilizing novel 3-D organotypic human tissue models that provide a format for study of human cells within a realistic tissue framework, thereby bridging the gap between 2-D monolayer culture and animal models for risk extrapolation to humans. To identify biological pathway signatures unique to heavy ion particle exposure, functional gene set enrichment analysis (GSEA) was used with whole transcriptome profiling. GSEA has been used extensively as a method to garner biological information in a variety of model systems but has not been commonly used to analyze radiation effects. It is a powerful approach for assessing the functional significance of radiation quality-dependent changes from datasets where the changes are subtle but broad, and where single gene based analysis using rankings of fold-change may not reveal important biological information. We identified 45 statistically significant gene sets at 0.05 q-value cutoff, including 14 gene sets common to gamma and titanium irradiation, 19 gene sets specific to gamma irradiation, and 12 titanium-specific gene sets. Common gene sets largely align with DNA damage, cell cycle, early immune response, and inflammatory cytokine pathway activation. The top gene set enriched for the gamma- and titanium-irradiated samples involved KRAS pathway activation and genes activated in TNF-treated cells, respectively. Another difference noted for the high-LET samples was an apparent enrichment in gene sets involved in cycle cycle/mitotic control. It is plausible that the enrichment in these particular pathways results from the complex DNA damage resulting from high-LET exposure where repair processes are not completed during the same time scale as the less complex damage resulting from low-LET radiation.

Patel, Z. S.↗

Bubbles and braided jets in galaxies with compact radio nuclei

Narrow-band H-alpha CCD images showing ionized gas in organized kiloparsec-scale structures in three galaxies with low-level active nuclei are presented. The edge-on spiral NGC 3079 contains an apparent loop structure which corresponds to previously reported nonthermal radio emission along the minor axis. The optical emission probably results from interaction between the ejected plasma and the ISM in the disk and halo. The S0 galaxy NGC 3998 exhibits an S-shaped structure centered on the nucleus, with no other evidence for spiral structure. In the spiral galaxy NGC 4258, the presence of continuum-free emission-line arms which coincide with the nonthermal radio arms is confirmed. The morphology of the arms suggests the presence of two double-sided jets which braid or wrap around one another and which bifurcate on both sides. It is concluded that the optical and radio emission in NGC 3079 and in NGC 4258 are related, and it is suggested that both are powered by a plasma which flows from the active nucleus and dissipates kinetic energy in the surrounding ISM.

Ford, Holland C.↗

Hybrid gausslet/Gaussian basis sets

We introduce hybrid gausslet/Gaussian basis sets, where a standard Gaussian basis is added to a gausslet basis in order to increase accuracy near the nuclei while keeping the spacing of the grid of gausslets relatively large. The Gaussians are orthogonalized to the gausslets, which are already orthonormal, and approximations are introduced to maintain the diagonal property of the two electron part of the Hamiltonian so that it continues to scale as the second power of the number of basis functions rather than the fourth. We introduce several corrections to the Hamiltonian designed to enforce certain exact properties, such as the values of certain two-electron integrals. We also introduce a simple universal energy correction that compensates for the incompleteness of the basis stemming from the electron–electron cusps based on the measured double occupancy of each basis function. We perform a number of Hartree Fock and full configuration interaction (full-CI) test calculations on two electron systems and Hartree Fock on a ten-atom hydrogen chain to benchmark these techniques. The inclusion of the cusp correction allows us to obtain complete basis set full-CI results for the two electron cases at the level of several micro-Hartrees, and we see similar apparent accuracy for Hartree Fock on the ten-atom hydrogen chain.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Aerodynamic and Landing Measurements Obtained During the First Powered Flight of the North American X-15 Research Airplane

During the first powered flight of the North American X-15 research airplane on September 17, 1959, a Mach number of 2.1 and an altitude of 52,000 feet were attained. Static and dynamic maneuvers were performed to evaluate the characteristics of the airplane at subsonic and supersonic speeds. Data from these maneuvers as well as from the launch and landing phases are presented, discussed, and compared with predicted values. The rate of separation of the X-15 from the B-52 carrier airplane at launch was less than that predicted by wind-tunnel studies and was less rapid than in the lightweight condition of the initial glide flight. In addition, the angular motions and bank angle attained following the launch were of lesser magnitude than in the glide flight. Stable longitudinal-stability trends were apparent during the acceleration to maximum speed, and the pilot reported experiencing little or no transonic trim excursions. An inexplicable high-frequency vibration, which occurred at Mach numbers above 1.4, is being investigated further. Essentially linear lift and stability characteristics were indicated within the limited ranges of angle of attack and angle of sideslip investigated. The dynamic longitudinal and lateral-directional stability and control-effectiveness characteristics appeared satisfactory to the pilot. Although the longitudinal- and lateral-directional-damping ratios showed no significant change from subsonic to supersonic speeds, on the basis of time to damp, the damping characteristics at supersonic speeds appeared to the pilot to be somewhat improved over those at subsonic speeds.

Source record↗

Multiwavelength Observations of 2HWC J1928+177: Dark Accelerator or New TeV Gamma-Ray Binary?

2HWC J1928+177 is a Galactic TeV gamma-ray source detected by the High Altitude Water Cherenkov (HAWC) Observatory up to ~56 TeV. The HAWC source, later confirmed by the High Energy Stereoscopic System, still remains unidentified as a dark accelerator since there is no apparent supernova remnant or pulsar wind nebula detected in the lower-energy bands. The radio pulsar PSR J1928+1746, coinciding with the HAWC source position, has no X-ray counterpart. In this work, our SED modeling shows that inverse Compton scattering in the putative pulsar wind nebula can account for the TeV emission only if the unseen nebula is extended beyond $r\sim 4^{\prime} $. Alternatively, TeV gamma-rays may be produced by hadronic interactions between relativistic protons from an undetected supernova remnant associated with the radio pulsar and a nearby molecular cloud G52.9+0.1. NuSTAR and Chandra observations detected a variable X-ray point source within the HAWC error circle, potentially associated with a bright infrared (IR) source. The X-ray spectra can be fitted with an absorbed power-law model with N H = (9 ± 3) × 10 22 cm –2 and Γ X = 1.6 ± 0.3 and exhibit long-term X-ray flux variability over the last decade. If the X-ray source, possibly associated with the IR source (likely an O star), is the counterpart of the HAWC source, it may be a new TeV gamma-ray binary powered by collisions between the pulsar wind and stellar wind. Follow-up X-ray observations are warranted to search for diffuse X-ray emission and determine the nature of the HAWC source.

79 ASTRONOMY AND ASTROPHYSICS↗

A load factor formula

The ultimate test of a load factor formula is experience. The chief advantages of a semi rational formula over arbitrary factors are that it fairs in between points of experience and it differentiates according to variables within a type. Structural failure of an airplane apparently safe according to the formula would call for a specific change in the formula. The best class of airplanes with which to check a load factor formula seems to be those which have experienced structural failure. Table I comprises a list of the airplanes which have experienced failure in flight traceable to the wing structure. The load factor by formula is observed to be greater than the designed strength in each case, without a single exception. Table II comprises the load factor by formula with the designed strength of a number of well-known service types. The formula indicates that by far the majority of these have ample structural strength. One case considered here in deriving a suitable formula is that of a heavy load carrier of large size and practically no reserve power.

Miller, Roy G↗

Face Gear Technology for Aerospace Power Transmission Progresses

The use of face gears in an advanced rotorcraft transmission design was first proposed by the McDonnell Douglas Helicopter Company during their contracted effort with the U.S. Army under the Advanced Rotorcraft Transmission (ART) program. Face gears would be used to turn the corner between the horizontal gas turbine engine and the vertical output rotor shaft--a function currently done by spiral bevel gears. This novel gearing arrangement would substantially lower the drive system weight partly because a face gear mesh would be used to split the input power between two output gears. However, the use of face gears and their ability to operate successfully at the speeds and loads required for an aerospace environment was unknown. Therefore a proof-of-concept phase with an existing test stand at the NASA Lewis Research Center was pursued. Hardware was designed that could be tested in Lewis' Spiral Bevel Gear Test Rig. The initial testing indicated that the face gear mesh was a feasible design that could be used at high speeds and load. Surface pitting fatigue was the typical failure mode, and that could lead to tooth fracture. An interim project was conducted to see if slight modifications to the gear tooth geometry or an alternative heat treating process could overcome the surface fatigue problems. From the initial and interim tests, it was apparent that for the surface fatigue problems to be overcome the manufacturing process used for this component would have to be developed to the level used for spiral bevel gears. The current state of the art for face gear manufacturing required using less than optimal gear materials and manufacturing techniques because the surface of the tooth form does not receive final finishing after heat treatment as it does for spiral bevel gears. This resulted in less than desirable surface hardness and manufacturing tolerances. An Advanced Research and Projects Agency (ARPA) Technology Reinvestment Project has been funded to investigate the effects of manufacturing process improvements on the operating characteristics of face gears. The program is being conducted with McDonnell Douglas Helicopter Co., Lucas Western Inc., the University of Illinois at Chicago, and a NASA/U.S. Army team. The goal of the project is develop the grinding process, experimentally verify the improvement in face gear fatigue life, and conduct a full-scale helicopter transmission test. The theory and methodology to grind face gears has been completed, and manufacture of the test hardware is ongoing. Experimental verification on test hardware is scheduled to begin in fiscal 1996.

Source record↗