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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Stratigraphy of Oceanus Procellarum basalts - Sources and styles of emplacement

The basaltic fill of Oceanus Procellarum has been formally subdivided into four lithostratigraphic formations: The Repsold Formation, the Telemann Formation, the Hermann Formation, and the Sharp Formation. The Repsold Formation is composed of high-Ti basalts and pyroclastic deposits with an estimated age of 3.75 + or - 0.05 b.y. and an estimated volume of about 2.1 x 10 to the 5th cu km. This is overlain by the Telemann Formation composed of very low-Ti basalts and pyroclastic deposits with an estimated age of 3.6 + or - 0.2 b.y. and a volume of 4.2 x 10 to the 5th cu km. The Hermann Formation, composed of intermediate basalts with an estimated age of 3.3 + or - 0.3 b.y., represents the next youngest unit with an estimated volume of 2.2 x 10 to the 5th cu km. The youngest materials in Procellarum are the medium-to-high-Ti basalts comprising the Sharp Formation with an estimated age of 2.7 + or - 0.7 b.y. and a volume of 1.8 x 10 to the 4th cu km.

Whitford-Stark, J. L.↗
NASA NTRS1981

The application of surface analysis to polymer/metal adhesion

The use of scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) in the analysis of Ti 6-4 adherend surfaces is described. Differences in Ti 6-4 surface composition as determined by XPS after different chemical pretreatments are detailed. Analysis of fractured surfaces by SEM/XPS is used to establish the failure mode. The surface acidity of Ti 6-4 coupons can be established by reflectance visible spectroscopy using indicator dyes.

Wightman, J. P.↗
NASA NTRS1983

The TEKLIB graphic library

TEKLIB is a library of procedures written in TI PASCAL to perform basic graphic tasks. TEKLIB was written to provide an interface between a graphics terminal and the TI 990. The TI 990 is used as a controller for the Finite Element Machine which is an array of microprocessors designed to solve problems by finite element methods in parallel. The use of TEKLIB provides a means of inputting data graphically and displaying output.

Bostic, S. W.↗
NASA NTRS1983

Nitriding of titanium and titanium: 8 percent aluminum, 1 percent molybdenum, 1 percent vanadium alloy with an ion-beam source

Titanium and Ti-8Al-1Mo-1V alloy were nitrided with an ion-beam source of nitrogen or argon and nitrogen at a total pressure of 2 x 10 to the minus 4th power to 10 x 10 to the minus 4th power torr. The treated surface was characterized by surface profilometry, X-ray diffractometry, Auger electron spectroscopy and microhardness measurements. The tetragonal Ti2N phase formed in pure titanium and Ti-8Al-1Mo-1V alloy with traces of AlN in the alloy. Two opposite processes competed during the ion-beam-nitriding process: (1) formation of nitrides in the surface layer and (2) sputtering of the nitrided layers by the ion beam. The highest surface hardnesses, about 500 kg/sq mm in titanium and 800 kg/sq mm in Ti-8Al-1Mo-1V, were obtained by ion nitriding with an ion beam of pure nitrogen at 4.2 x 10 to the minus 4th power torr at a beam voltage of 1000 V.

Gill, A.↗
NASA NTRS1982

Iron metal production in silicate melts through the direct reduction of Fe/II/ by Ti/III/, Cr/II/, and Eu/II/

The production of metallic iron in silicate melts by chemical reactions of Ti(3+), Cr(2+), and Eu(2+) with Fe(2+) is demonstrated under experimental conditions in a simplified basaltic liquid. These reactions form a basis for interpreting the role of isochemical valency exchange models in explanations for the reduced nature of lunar basalts. The redox couples are individually investigated in the silicate melt to ascertain reference redox ratios that are independent of mutual interactions. These studies also provide calibrations of spectral absorptions of the Fe(2+) and Ti(2+) species in these glasses. Subsequent spectrophotometric analyses of Fe(2+) and Ti(2+) in glasses doped with both iron and titanium and of Fe(2+) in glasses doped with either iron and chromium or iron and europium ascertain the degree of mutual interactions in these dual-doped glasses.

Schreiber, H. D.↗
NASA NTRS1983

A critical study of the role of the surface oxide layer in titanium bonding

Scanning electron microscope/X-ray photoelectron spectroscopy (SEM/XPS) analysis of fractured adhesively bonded Ti 6-4 samples is discussed. The text adhesives incuded NR 056X polyimide, polypheylquinoxaline (PPQ), and LARC-13 polyimide. Differentiation between cohesive and interfacial failure was based on the absence of presence of a Ti 2p XPS photopeak. In addition, the surface oxide layer on Ti-(6A1-4V) adherends is characterized and bond strength and durability are addressed. Bond durability in various environmental conditions is discussed.

Dias, S.↗
NASA NTRS1984

Effects of alloy composition on cyclic flame hot-corrosion attack of cast nickel-base superalloys at 900 deg C

The effects of Cr, Al, Ti, Mo, Ta, Nb, and W content on the hot corrosion of nickel base alloys were investigated. The alloys were tested in a Mach 0.3 flame with 0.5 ppmw sodium at a temperature of 900 C. One nondestructive and three destructive tests were conducted. The best corrosion resistance was achieved when the Cr content was 12 wt %. However, some lower-Cr-content alloys ( 10 wt%) exhibited reasonable resistance provided that the Al content alloys ( 10 wt %) exhibited reasonable resistance provided that the Al content was 2.5 wt % and the Ti content was Aa wt %. The effect of W, Ta, Mo, and Nb contents on the hot-corrosion resistance varied depending on the Al and Ti contents. Several commercial alloy compositions were also tested and the corrosion attack was measured. Predicted attack was calculated for these alloys from derived regression equations and was in reasonable agreement with that experimentally measured. The regression equations were derived from measurements made on alloys in a one-quarter replicate of a 2(7) statistical design alloy composition experiment. These regression equations represent a simple linear model and are only a very preliminary analysis of the data needed to provide insights into the experimental method.

Deadmore, D. L.↗
NASA NTRS1984

Effect of alloy chemistry and exposure conditions on the oxidation of titanium

Multiwall is a new thermal protection system concept for advanced space transportation vehicles. The system consists of discrete panels made up of multiple layers of foil gage metal. Titanium is the proposed candidate metal for multiwall panels in the reentry temperature range up to 675 C. Oxidation and embrittlement are the principal concerns related to the use of Ti in heat shield applications. The results of a broad study on the oxidation kinetics of several titanium alloys subjected to different exposure conditions are described. The alloys include commercially pure titanium, Ti-6Al-4V, and Ti-6Al-2Sn-4Zr-2Mo. Oxidation studies were performed on these alloys exposed at 704 C in 5-760 torr air pressure and 0 to 50% relative humidity. The resulting weight gains were correlated with oxide thickness and substrate contamination. The contamination depth and weight gains due to solid solutioning were obtained from microhardness depth profiles and hardness versus weight percent oxygen calibration data.

Unnam, J.↗
NASA NTRS1984

Fast collisionless tearing in an anisotropic neutral sheet

The collisionless tearing mode in a neutral sheet is studied in the presence of ion temperature (Ti) anisotropy, using Vlasov description for both ions and electrons. It is found that the growth rate of the instability is significantly enhanced if the ratio of Ti perpendicular to the equilibrium magnetic field to Ti parallel to the field is greater than one. For typical magnetotail parameters with modest temperature anisotropy, it is shown that the linear e-folding time is reduced to a small fraction of the time delays believed to precede the onset of reconnection. This enhancement of the growth rate is due to the Lorentz force acting on the ions that cross the neutral plane, traversing beyond the conventional electron-tearing layer.

Chen, J.↗
NASA NTRS1984

Lu-Hf constraints on the evolution of lunar basalts

It is shown that a cumulate-remelting model best explains the recently acquired data on the Lu-Hf systematics of lunar mare basalts. The model is constructed using Lu and Hf concentration data and is strengthened by Hf isotopic evidence of Unruh et al. (1984). It is shown that the similarity in MgO/FeO ratios and Cr2O3 content in high-Ti and low-Ti basalts are not important constraints on lunar basalt petrogenesis. The model demonstrates that even the very low Ti or green glass samples are remelting products of a cumulate formed after at least 80-90 percent of the lunar magma ocean had solidified. In the model, all the mare basalts and green glasses were derived from 100-150 km depth in the lunar mantle. The Lu-Hf systematics of KREEP basalts clearly indicate that they would be the final residual liquid of the lunar magma ocean.

Fujimaki, H.↗
NASA NTRS1985

Crystal Chemistry of Meteoritic Hibonites

The characteristics of cation vacancies and site occupancies of natural hibonites in meteors are discussed. Note is taken of the effect of the specific locations of the hibonites in the matrices on the crystal chemistry, electronic stabilities, and spectral features of the metal ions which replace the Al(3+). Hibonites form beta-alumina hexagonal cells with 26 cation sites. Fe cations are found in octahedral, tetrahedral, and five-fold coordinates. Fe(2+) is found in face-shared Al(3) octahedra, a siting explained in terms of ionic radius and crystal field stabilization energy criteria. Spectral colors are attributed to V(3+) and Ti(3+) field transitions at 400 and 700 nm, respectively, although the 700 nm line may arise from transitions of Ti(3+) to Ti(4+) or Fe(2+) to Fe(3+) during heating. Excesses of Mg-26 can be traced to decay of nebular Al-26.

Burns, R. G.↗
NASA NTRS1984

Crystal chemistry of meteoritic hibonites

The characteristics of cation vacancies and site occupancies of natural hibonites in meteors are discussed. Note is taken of the effect of the specific locations of the hibonites in the matrices on the crystal chemistry, electronic stabilities, and spectral features of the metal ions which replace the Al(3+). Hibonites form beta-alumina hexagonal cells with 26 cation sites. Fe cations are found in octahedral, tetrahedral, and five-fold coordinations. Fe(2+) is found in face-shared Al(3) octahedra, a siting explained in terms of ionic radius and crystal field stabilization energy criteria. Spectral colors are attributed to V(3+) and Ti(3+) field transitions at 400 and 700 nm, respectively, although the 700 nm line may arise from transitions of Ti(3+) to Ti(4+) or Fe(2+) to Fe(3+) during heating. Excesses of Mg-26 can be traced to decay of nebular Al-26.

Burns, R. G.↗
NASA NTRS1984

Ca isotope variations in Allende

Ca-isotope measurements of Allende Ca-Al-rich inclusions (CAIs), together with those on an apatite-enriched fraction from Orgueil, indicate the existence of widespread excesses on the neutron-rich isotope Ca-48. Isotopic anomalies are noted in 7 out of 11 CAIs analyzed. This abundance of isotopic excesses places Ca alongside Ti and O, although no clear correlation has yet been found between Ca-48 and Ti-50, which are thought to be coproduced by neutron-rich nucleosynthetic processes within stars. It is suggested that the higher volatility of Ca, by comparison with Ti compounds, led to a variable dilution with isotopically normal Ca in vaporization and recondensation processes in stellar envelopes, the interstellar medium, and/or the solar nebula.

Jungck, M. H. A.↗
NASA NTRS1985

Titanium isotopic anomalies in hibonites from the Murchison carbonaceous chondrite

The isotopic compositions of titanium in eight grains of hibonite (CaAl12O19) from the carbonaceous chondrite Murchison have been determined by high precision secondary ion mass spectrometry using an ion microprobe. The titanium in the hibonites varies greatly in Ti-50 from about -42 to +8 permil (relative to terrestrial) with smaller (up to 4 permil), but clearly resolvable, effects in Ti-46 and Ti-48. These results confirm the presence of widespread negative anomalies suggested by the results of Hutcheon et al. (1983) on hibonites from Murchison. The magnitude of these variations seems explicable only in terms of nucleogenic processes which produced extremely variable titanium isotopic abundances in the hibonite source materials. The hibonites evidently did not participate to the same extent as most material in the mixing and homogenisation processes that accompanied the formation and later evolution of the solar system.

Ireland, T.↗
NASA NTRS1984

Optimal redesign study of the harm wing

The purpose of this project was to investigate the use of optimization techniques to improve the flutter margins of the HARM AGM-88A wing. The missile has four cruciform wings, located near mid-fuselage, that are actuated in pairs symmetrically and antisymmetrically to provide pitch, yaw, and roll control. The wings have a solid stainless steel forward section and a stainless steel crushed-honeycomb aft section. The wing restraint stiffness is dependent upon wing pitch amplitude and varies from a low value near neutral pitch attitude to a much higher value at off-neutral pitch attitudes, where aerodynamic loads lock out any free play in the control system. The most critical condition for flutter is the low-stiffness condition in which the wings are moved symmetrically. Although a tendency toward limit-cycle flutter is controlled in the current design by controller logic, wing redesign to improve this situation is attractive because it can be accomplished as a retrofit. In view of the exploratory nature of the study, it was decided to apply the optimization to a wing-only model, validated by comparison with results obtained by Texas Instruments (TI). Any wing designs that looked promising were to be evaluated at TI with more complicated models, including body modes. The optimization work was performed by McIntosh Structural Dynamics, Inc. (MSD) under a contract from TI.

Mcintosh, S. C., Jr.↗
NASA NTRS1986

Oxidation of commercial purity titanium

The oxidation kinetics of commercial purity Ti-A55 exposed to laboratory air in the 593-760 C temperature range were continuously monitored by thermogravimetric analysis. The oxide thickness was measured by microscopy, and the substrate contamination was estimated from microhardness measurements. The microhardness depth profiles were converted to oxygen composition profiles using calibration depth. The oxygen diffusion coefficient in alpha-Ti appears to be approximately concentration-independent in the 1-10 at. pct oxygen range. Diffusion coefficient for oxygen in TiO2 has been estimated as a function of temperature and is found to be about 50 times the value in alpha-Ti. The metallographically prepared cross sections of the oxidized specimens revealed a 'moving boundary' in the substrate, parallel to the oxide-metal interface. This boundary was associated with a specific oxygen level of 5.0 + or - 0.5 at. pct. It occurred at a distance from the oxide-metal interface which was correlatable with temperature and time of exposure. The diffusion coefficient corresponding to the composition of this moving boundary is in excellent agreement with the effective diffusion coefficient for the substrate contamination.

Unnam, J.↗
NASA NTRS1986

Pulsed injection control of a titanium-doped sapphire laser

Injection control of a tunable Ti:sapphire laser using a narrow-bandwidth pulsed dye laser operating at a wavelength removed from the peak of the Ti:sapphire-laser gain curve is reported. The free-running Ti:sapphire laser had broadband laser emission from 750 to 790 nm. Injection at 727 nm resulted in essentially complete energy extraction at that wavelength in a 2.5-pm bandwidth matching the injection source.

Brockman, Philip↗
NASA NTRS1987

Plagioclase-rich inclusions in carbonaceous chondrite meteorites - Liquid condensates?

The characteristics and formation of coarse-grained, plagioclase-rich inclusions are investigated. The textures, mineralogical compositions, and initial Al-26/Al-27 ratios for the plagioclase-rich inclusions are described. It is observed that plagioclase-rich inclusions in carbonaceous chondrites are either Ca-Al-rich inclusions (CAIs) composed of 30-60 vol pct anorthite, and less than 35 vol pct Ti-Al-pyroxene and melilite, or CA chondrites composed of plagioclase, pyroxene, olivine, spinel, and melilite. It is observed that CA chondrules are chemically and mineralogically the most similar components shared by carbonaceous and ordinary chondrites. The textural changes observed in the inclusions are examined. The data reveal that the CAIs have three textural groups: coarse anorthite laths, equigranular anorthite and Ti-Al-pyroxene, and lacy Ti-Al-pyroxene and fine-grained anorthite.

Wark, D. A.↗