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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32

Black Molecular Adsorber Coatings for Spaceflight Applications

The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

adsorption↗

Black Molecular Adsorber Coatings for Spaceflight Applications

The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

adsorption↗

Modeling of Bulk Evaporation and Condensation

This report describes the modeling and mathematical formulation of the bulk evaporation and condensation involved in liquid-vapor phase change processes. An internal energy formulation, for these phase change processes that occur under the constraint of constant volume, was studied. Compared to the enthalpy formulation, the internal energy formulation has a more concise and compact form. The velocity and time scales of the interface movement were obtained through scaling analysis and verified by performing detailed numerical experiments. The convection effect induced by the density change was analyzed and found to be negligible compared to the conduction effect. Two iterative methods for updating the value of the vapor phase fraction, the energy based (E-based) and temperature based (T-based) methods, were investigated. Numerical experiments revealed that for the evaporation and condensation problems the E-based method is superior to the T-based method in terms of computational efficiency. The internal energy formulation and the E-based method were used to compute the bulk evaporation and condensation processes under different conditions. The evolution of the phase change processes was investigated. This work provided a basis for the modeling of thermal performance of multi-phase nuclear fuel elements under variable gravity conditions, in which the buoyancy convection due to gravity effects and internal heating are involved.

Anghaie, S.↗

X-57 Traction Power and Command Systems Development

This paper describes the final, as-built design of the X‑57 Maxwell aircraft power and command system architecture that implements the electrified propulsion capability. The development of the traction power, command, and avionics power subsystems proceeded as planned at the initial project critical design review, but improvements to the design were identified following the development of detailed operations concepts and integrated subsystem and system testing. The redundant architecture with A‑side and B‑side buses provided a robust framework for a developmental system that would turn out to have a lower technology readiness than had been assumed upon project formulation. As the project team identified reliability or performance gaps in the electrified propulsion powertrain components and their interactions with the other vehicle systems, the traction power, command, and avionics architectures were modified to accommodate the modified systems. Following the publication of the planned design approach at the critical design review milestone [1], the project team developed the flight hardware and software, integrated the systems, and adjusted the design and qualification activities to address gaps in the components, system architecture, and requirements as the gaps were realized. In addition to inherent challenges in development of these subsystems, the integration of this new technology with adjacent critical systems in an aircraft configuration posed additional challenges that drove design considerations across the subsystem development and the other vehicle systems. Integration complications included electromagnetic compatibility, thermal performance, and tolerance of single-point failures internal and external to the powerplant. Development of a qualification program was required for the new motors, inverters, and batteries, and hardware performance during component qualification fed back into the development process and led lessons learned and redesign of key elements.

distributed propulsion↗

Evacuated load-bearing high performance insulation study

A light weight, vacuum jacketed, load bearing cryogenic insulation system was developed and tested on a 1.17-m (46-in.) spherical test tank. The vacuum jacket consists of 0.08 mm (0.003 in.) thick 321 stainless steel formed into a wedge design that allows elastic jacket movements as the tank shrinks (cools) or expands (warms up or is pressurized). Hollow glass spheres, approximately 80 micrometers in diameter with a bulk density of 0.069 g/cc (4.3 lb cubic foot), provide the insulating qualities and one atmosphere load bearing capability required. The design, fabrication, and test effort developed the manufacturing methods and engineering data needed to scale the system to other tank sizes, shapes, and applications. The program demonstrated that thin wall jackets can be formed and welded to maintain the required vacuum level of .013 Pa yet flex elastically for multiple reuses. No significant shifting or breakage of the microspheres occurred after 13 simulated Space Tug flight cycles on the test tank and a hundred 1 atmosphere load cycles in a flat plate calorimeter. The test data were then scaled to the Space Tug LO2 and LH2 tanks, and weight, thermal performance, payload performance, and costs were compared with a helium purged multilayer insulation system.

Parmley, R. T.↗

Hollow Fiber Space Water Membrane Evaporator Flight Prototype Design and Testing

The spacesuit water membrane evaporator (SWME) is being developed to perform thermal control for advanced spacesuits and to take advantage of recent advances in micropore membrane technology. This results in a robust heat-rejection device that is potentially less sensitive to contamination than is the sublimator. The current design was based on a previous design that grouped the fiber layers into stacks, which were separated by small spaces and packaged into a cylindrical shape. This was developed into a full-scale prototype consisting of 14,300 tube bundled into 30 stacks, each of which is formed into a chevron shape and separated by spacers and organized into three sectors of 10 nested stacks. The new design replaced metal components with plastic ones, eliminated the spacers, and has a custom built flight like backpressure valve mounted on the side of the SWME housing to reduce backpressure when fully open. A number of tests were performed in order to improve the strength of the polyurethane header that holds the fibers in place while the system is pressurized. Vacuum chamber testing showed similar heat rejection as a function of inlet water temperature and water vapor backpressure was similar to the previous design. Other tests pushed the limits of tolerance to freezing and showed suitability to reject heat in a Mars pressure environment with and without a sweep gas. Tolerance to contamination by constituents expected to be found in potable water produced by distillation processes was tested in a conventional way by allowing constituents to accumulate in the coolant as evaporation occurs. For this purpose, the SWME cartridge has endured an equivalent of 30 EVAs exposure and demonstrated acceptable performance decline.

Bue, Grant C.↗

Integrated Refrigeration and Storage of LNG for Compositional Stability

Growing interest in liquefied natural gas (LNG) as a rocket fuel necessitates a greater technical understanding of the compositional changes due to preferential boil-off (or weathering) that occurs during long duration storage. The purity of methane in LNG can range from 90 to 98%, and is subject to preferential boil-off due to its low boiling point compared to other constituents despite the use of high-performance thermal insulation systems. Active heat extraction (i.e. refrigeration) is required to completely eliminate weathering. For future operational safety and reliability, and to better understand the quality and efficiency of the LNG as a cryofuel, a 400-liter Cryostat vessel was designed and constructed to measure the composition and temperatures of the LNG at a number of different liquid levels over long durations. The vessel is the centerpiece of a custom-designed lab-scale integrated refrigeration and storage (IRaS) system employing a pulse tube cryocooler capable of roughly 50 W of lift at 100 K. Instrumentation includes ten temperature sensors mounted on a vertical rake and five liquid sample tubes corresponding to five liquid levels. Two modes of operation are studied. The first is without refrigeration in order to determine a baseline in the change in composition, and to study stratification of the LNG. The second is performed with the cryocooler active to determine the operational parameters of the IRaS system for eliminating the weathering as well as stratification effects in the bulk liquid. The apparatus design and test method, as well as preliminary test results are presented in this paper. As a bonus in cost-saving and operational efficiency, the capability of the IRaS system to provide zero-loss capabilities such as zero boil-off (ZBO) keeping of the LNG and zero-loss filling/transfer operations are also discussed.

Rose, Laura P.↗

Integrated Refrigeration and Storage of LNG for Compositional Stability

Growing interest in liquefied natural gas (LNG) as a rocket fuel necessitates a greater technical understanding of the compositional changes due to preferential boil-off (or weathering) that occurs during long duration storage. The purity of methane in LNG can range from 90 to 98%, and is subject to preferential boil-off due to its low boiling point compared to other constituents despite the use of high-performance thermal insulation systems. Active heat extraction (i.e. refrigeration) is required to completely eliminate weathering. For future operational safety and reliability, and to better understand the quality and efficiency of the LNG as a cryofuel, a 400-liter Cryostat vessel was designed and constructed to measure the composition and temperatures of the LNG at a number of different liquid levels over long durations. The vessel is the centerpiece of a custom-designed lab-scale integrated refrigeration and storage (IRaS) system employing a pulse tube cryocooler capable of roughly 50 W of lift at 100 K. Instrumentation includes ten temperature sensors mounted on a vertical rake and five liquid sample tubes corresponding to five liquid levels. Two modes of operation are studied. The first is without refrigeration in order to determine a baseline in the change in composition, and to study stratification of the LNG. The second is performed with the cryocooler active to determine the operational parameters of the IRaS system for eliminating the weathering as well as stratification effects in the bulk liquid. The apparatus design and test method, as well as preliminary test results are presented in this paper. As a bonus in cost-saving and operational efficiency, the capability of the IRaS system to provide zero-loss capabilities such as zero boil-off (ZBO) keeping of the LNG and zero-loss filling/transfer operations are also discussed.

Rose, L.↗

Measurement of Insulation Compaction in the Cryogenic Fuel Tanks at Kennedy Space Center by Fast/Thermal Neutron Techniques

The liquid hydrogen and oxygen cryogenic storage tanks at John F. Kennedy Space Center (KSC) use expanded perlite as thermal insulation. Th ere is evidence that some of the perlite has compacted over time, com promising the thermal performance and possibly also structural integr ity of the tanks. Therefore an Non-destructive Testing (NDT) method for measuring the perlite density or void fraction is urgently needed. Methods based on neutrons are good candidates because they can readil y penetrate through the 1.75 cm outer steel shell and through the ent ire 120 cm thickness of the perlite zone. Neutrons interact with the nuclei of materials to produce characteristic gamma rays which are the n detected. The gamma ray signal strength is proportional to the atom ic number density. Consequently, if the perlite is compacted then the count rates in the individual peaks in the gamma ray spectrum will i ncrease. Perlite is a feldspathic volcanic rock made up of the major elements Si, AI, Na, K and 0 along with some water. With commercially available portable neutron generators it is possible to produce simul taneously fluxes of neutrons in two energy ranges: fast (14 MeV) and thermal (25 meV). Fast neutrons produce gamma rays by inelastic scatt ering which is sensitive to Fe and O. Thermal neutrons produce gamma rays by radiative capture in prompt gamma neutron activation (PGNA) and this is sensitive to Si, AI, Na, Kand H. Thus the two energy ranges produce complementary information. The R&D program has three phases: numerical simulations of neutron and gamma ray transport with MCNP s oftware, evaluation of the system in the laboratory on test articles and finally mapping of the perlite density in the cryogenic tanks at KSC. The preliminary MCNP calculations have shown that the fast/therma l neutron NDT method is capable of distinguishing between expanded an d compacted perlite with excellent statistics.

Livingston, R. A.↗

Aerothermodynamic environments of aerobraking vehicles for manned Mars missions

The aerothermodynamic environments of manned spacraft aerobraking in the Martian and earth atmospheres are evaluated. Thermal performance of aerobrake concepts are examined for current cryogenic-aerobrake and advanced propulsion missions entailing three different modes of aerobraking: (1) aerocapture into an orbit about Mars, (2) descent and landing at Mars, and (3) Mars return direct entry at earth. Analyses for these vehicles and modes included both radiative and convective heating, where radiative heating is shown to be a significant portion of the total stagnation point heating induced on the vehicle. A comprehensive parametric study of the effects of ballistic coefficient, nose radius, entry velocity, and L/D on stagnation point heating is described. Optimal nose radii for ranges of ballistic coefficient and entry velocity are determined. The peak heating rates are shown to be 83 W/sq cm and 90 W/sq cm for a low and high L/D Mars transfer vehicle configuration, respectively. Heating profiles for these vehicles using boundary layer techniques show that a high L/D shape will result in a smaller high-temperature region provided the flow is laminar. An examination of a crew return vehicle for a Mars return direct entry trajectory shows that the thermal protection for this aerobrake will require an ablative material for heat rejection due to the large heating rates (about 1 kW/sq cm).

Ledoux, Stephen T.↗

Energy Efficient Large-Scale Storage of Liquid Hydrogen

The world’s largest liquid hydrogen storage tanks were constructed in the mid-1960sat the NASA Kennedy Space Center. These two vacuum-jacketed, perlite powder insulated tanks, still in service today, have 3,200 m3 of useable capacity. In 2018, construction began on an additional storage tank at Launch Complex 39B. This new tank will give an additional storage capacity of 4,700 m3 for a total on-site storage capacity of roughly 8,000 m3. NASA’s new Space Launch System (SLS) heavy lift rocket for the Artemis program includes an LH2tank that makes up the bulk of the vehicle, holding 2,033 m3 of LH2 in its 8.4-m diameter by40-m height. The new storage tank includes two new energy-efficient technologies: a glass bubbles insulation system in lieu of perlite, and an Integrated Refrigeration and Storage (IRAS)heat exchanger for controlled storage capability. The evacuated glass bubbles insulation system is based on the prior two decades of research to prove the thermal performance benefits as well as the mechanical and vacuum integrity; and has been shown to reduce LH2 boiloff by 46%versus perlite in field demonstrations. The IRAS capability is centered on a heat exchanger system that is built within the inner vessel to reject heat from the bulk liquid through the future implementation of an external helium refrigerator. Controlled storage via IRAS, when fully implemented, will provide full control of the ullage pressure, zero boiloff, and even production of densified LH2 pending its adoption on future launch vehicles. The design basics are described along with main construction and testing processes involved. The key features of the new technology items and implications on simplified operations and long-term energy savings are addressed

cryogenics↗

Thermal Materials and Coatings for Near Rectilinear Halo Orbit (NRHO)

Passive thermal control of a spacecraft is reliant on external surface optical properties (solar absorptivity and IR emissivity), which degrade over time depending on length of mission, material or coating, and natural and induced environments. Understanding the degradation and resulting End of Life (EOL) optical properties enables optimization of the thermal performance and reduces risk. The environmental factors that affect degradation of materials and coatings include UV, solar wind, vacuum, contamination, lunar dust, atomic oxygen, and more. Future spacecraft such as Gateway will be flying in the Near Rectilinear Halo Orbit (NRHO), an environment that has not been flown before and environmental factors are different from Low Earth Orbit. There is no on orbit data for materials in this environment, and optical property data from on-orbit and ground experiments for other environments is of limited use. This 1.5 hour short course will explore optical properties and degradation by introducing the expected environment of NRHO, types of materials and coatings that could be used, how to estimate their EOL properties, and future work. This course will focus on the NRHO environment, but it will be beneficial for anyone interested in optical property degradation in the space environment.

Optics↗

Solar Absorptivity Degradation of Spacecraft Materials Due to UV and Charged Particles in the Gateway Environment

Gateway will be an outpost in cislunar space designed to survive a 15-year mission to support human Moon landings and future deep space exploration. The Gateway Passive Thermal Control System (PTCS) Group has identified charged particle and UV degradation of potential Gateway materials as a knowledge gap for the Near Rectilinear Halo Orbit (NRHO) and transit environment, especially the slow spiral transit planned for the first two modules. Solar absorptivity degradation is important to quantify because the end-of-life absorptivity impacts thermal performance of the system. To address this, ground testing has been completed at NASA Goddard Space Flight Center in which potential Gateway materials, including radiators, multi-layer insulation (MLI), and structural materials are subjected to the expected transit plus 15-year on-orbit charged particle fluence (9.86x1015 protons/cm2 at 2.5 keV and 3.1x1016 electrons/cm2 at 10 keV) and 5093 Equivalent Solar Hours (ESH). Reflectivity of a single sample of each material was measured in atmosphere and in vacuum inside the chamber after exposure to incremental levels of ESH and charged particle fluence. Increase in absorptivity of most samples were seen throughout the test including large differences in absorptivity of materials of the same category. Future planned testing will validate these results and include additional materials of interest.

Optical Property↗

Hollow Fiber Flight Prototype Spacesuit Water Membrane Evaporator Design and Testing

The spacesuit water membrane evaporator (SWME) is being developed to perform thermal control for advanced spacesuits and to take advantage of recent advances in micropore membrane technology. This results in a robust heat-rejection device that is potentially less sensitive to contamination than is the sublimator. The Membrana Celgard X50-215 microporous hollow-fiber (HoFi) membrane was selected after recent extensive testing as the most suitable candidate among commercial alternatives for continued SWME prototype development. The current design was based on a previous design that grouped the fiber layers into stacks, which were separated by small spaces and packaged into a cylindrical shape. This was developed into a full-scale prototype consisting of 14,300 tube bundled into 30 stacks, each of which is formed into a chevron shape and separated by spacers and organized into three sectors of 10 nested stacks. The new design replaced metal components with plastic ones, and has a custom built flight like backpressure valve mounted on the side of the SWME housing to reduce backpressure when fully open. The spacers that provided separation of the chevron fiber stacks were eliminated. Vacuum chamber testing showed improved heat rejection as a function of inlet water temperature and water vapor backpressure compared with the previous design. Other tests pushed the limits of tolerance to freezing and showed suitability to reject heat in a Mars pressure environment with and without a sweep gas. Tolerance to contamination by constituents expected to be found in potable water produced by distillation processes was tested in a conventional way by allowing constituents to accumulate in the coolant as evaporation occurs. For this purpose, the SWME cartridge has endured an equivalent of 30 EVAs exposure and demonstrated minimal performance decline.

Bue, Grant↗

Estimation of End-of-Life Solar Absorptivity for Complex, Multi-Phased Space Missions

Solar absorptivity degradation over time is an important contributor to the thermal performance of a spacecraft at the end of its life. When environments are complex and include many different factors known to impact solar absorptivity degradation, such as UV, charged particles, contamination, or lunar dust coverage, combining data from several different studies can be done to estimate total degradation. While the most conservative way is to stack delta absorptivity from each factor to come up with a total delta, this may be overly conservative for long or complex missions with multiple mission phases. As absorptivity increases the rate of degradation decreases, and synergistic effects need to be taken into account. In this report an alternate method is proposed using Gateway materials as an example. This method determines which environmental factor will be dominant at what time (such as contamination or charged particles) and uses that degradation rate for that mission phase. For the next mission phase, the new absorptivity can be used instead of the original BOL absorptivity to determine degradation rate. This approach prevents overestimating optical degradation when considering degradation from interconnected sources.

thermo-optical properties↗

Multidimensional reaction kinetic ablation program /REKAP/

Multidimensional reaction kinetics ablation program provides an improved capability for analyzing thermal performance of partially penetrated charring ablator heat shields. The capability was provided for determining transient temperature histories in an ablating three-dimensional shape consisting of up to five layers of material.

Aston, B.↗