Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “TROPOSPHERE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Ozone in the upper troposphere from Gasp measurements

Several aspects of tropospheric ozone variations are examined by using ozone measurements made from commercial airliners (Gasp data). Through visual inspection of the autocorrelation function it is shown that the east-west variations of ozone have a predominant wavelength near 2400 km, while temperature and wind have predominant wavelengths near 3300 km. Distance-lagged correlation functions of ozone with temperature and wind show a definite periodicity with wavelengths near 2400 km. Attention is given to the tropical tropospheric ozone values above 100 parts per billion by volume, which appear to be associated with meridional transport from middle latitudes, and in some cases, relatively large tropical ozone values are coincident with clouds.

Nastrom, G. D.↗
NASA NTRS1979

Tropospheric and lower stratospheric vertical profiles of ethane and acetylene

The first known vertical distributions of ethane and acetylene which extend into the lower stratosphere are reported. The average upper tropospheric concentrations, between 20,000 ft and 35,000 ft, near 37 deg N-123 deg W were 1.2 micrograms/cu m (1.0 ppb) for ethane and 0.24 micrograms /cu m (0.23 ppb) for acetylene while the values near 9 N-80 W were 0.95 micrograms/cu m (0.77 ppb) and 0.09 micrograms/cu m (0.09 ppb), respectively. Detectable quantities of both ethane and acetylene are present in the lower stratosphere. There is a sharp decrease in the levels of these two compounds as one crosses the tropopause and ascends into the lower stratosphere. The observed levels of ethane and acetylene may allow some impact on the background chemistry of the troposphere and stratosphere.

Cronn, D.↗
NASA NTRS1979

Remote measurement of tropospheric ozone

It is shown that a differential absorption lidar employing a pulsed CO2 laser and a direct detection receiver is capable of significantly improving the existing data base on the tropospheric ozone burden. As a ground-based system, the lidar could obtain urban to regional scale O3 measurements with a vertical or horizontal resolution of at least 1 km in the troposphere. As a space-based system, it could obtain global scale coverage of the O3 burden below the stratospheric maximum of O3.

Bufton, J. L.↗
NASA NTRS1979

Tropospheric UV flux calculations and photolysis rates for use with zonally and diurnally averaged models

A computationally fast and efficient method for calculating solar UV fluxes in the troposphere is developed. Calculated fluxes compare favorably with more rigorous multiple scattering results, and qualitatively correct behavior of the direct and diffuse flux components is maintained. In view of the relatively large uncertainties in other aspects of tropospheric photochemical models, the use of approximate UV flux calculations appears warranted. The technique is applied to the calculation of photolysis rates for twelve significant photolytic reactions of nine species.

Matloff, G. L.↗
NASA NTRS1980

Major and minor stratospheric warmings and their interactions on the troposphere

The evolution of the kinetic and thermal energy associated with the major and minor stratospheric warmings in the winters of 1975-76 and 1976-77 is investigated on the basis of NMC gridded analysis of meteorological data and then related to changes in the stratosphere and troposphere. It is found that the predominant ultra-long waves in the stratosphere oscillated at periods of 10-20 days, while in the troposphere the predominant long waves oscillated at periods of 8 to 12 days and were almost out-of-phase for the major warming. The kinetic energy of the zonal mean flow in the stratosphere for the minor warming is shown to be much greater than that for the major warming, indicating the dependence of the major warming occurrence on the kinetic energy magnitude of the zonal mean flow relative to that of the meridional convergence of the poleward flux of sensible heat.

Koermer, J. P.↗
NASA NTRS1980

The vertical distribution of tropospheric ammonia

A one-dimensional tropospheric photochemical model is used to simulate measured profiles of NH3 obtained with the Infrared Heterodyne Radiometer. The relative roles of homogeneous loss, heterogeneous loss, and vertical eddy transport are discussed in terms of selecting parameters which best fit the measurements. The best fit was obtained for a vertical eddy diffusion coefficient of 200,000/sq cm per sec or greater (corresponding to a characteristic vertical transport time in excess of about 35 days), and a characteristic heterogeneous loss time in excess of 10 days. The characteristic homogeneous chemical loss time was found to be about 40 days at the surface and decreased to about 180 days at 10 km, and not very sensitive to model chemical perturbations. Increased ground-level concentrations of NH3 to about 10 ppb, compared to background surface concentrations of about 1 ppb, were measured several weeks after application of ammonium nitrate fertilizer. This suggests that the volatilization of ammonium nitrate fertilizer is rapid, and an important source of NH3. Because of the characteristic times for the loss mechanisms, synoptic time-scale phenomena may play an important role in determining the tropospheric distribution of NH3 concentrations.

Levine, J. S.↗
NASA NTRS1979

Satellite measurements of tropospheric aerosols

Landsat data were originally used to demonstrate that a linear relationship exists between the upwelling visible radiance and the aerosol optical thickness (essentially all of this thickness is in the troposphere) over oceans. Since that time similar relationships have been shown to exist for sensors on the GOES and NOAA-5 satellites. A global scale ground truth experiment using Tiros-N data is planned and will investigate the variability of the linear relationship at different sites around the globe. A comparison of the results for the different satellites is presented, together with a discussion of the requirements for routine satellite monitoring of tropospheric aerosols on a global scale.

Griggs, M.↗
NASA NTRS1981

Preliminary feasibility analysis of a pressure modulator radiometer for remote sensing of tropospheric constituents

A pressure modulator radiometer operated in a nadir viewing mode from the top of a midlatitude summer model of the atmosphere was theoretically studied for monitoring the mean volumetric mixing ratio of carbon monoxide in the troposphere. The mechanical characteristics of the instrument on the Nimbus 7 stratospheric and mesospheric sounder experiment are assumed and CO is assumed to be the only infrared active constituent. A line by line radiative transfer computer program is used to simulate the upwelling radiation reaching the top of the atmosphere. The performance of the instrument is examined as a function of the mean pressure in and the length of the instrument gas correlation cell. Instrument sensitivity is described in terms of signal to noise ratio for a 10 percent change in CO mixing ratio. Sensitivity to mixing ratio changes is also studied. It is concluded that tropospheric monitoring requires a pressure modulator drive having a larger swept volume and producing higher compression ratios at higher mean cell pressures than the Nimbus 7 design.

Orr, H. D., III↗
NASA NTRS1980

The chemistry and transport of methane and carbon monoxide in the troposphere

The present understanding of the physical and chemical behavior of methane, carbon monoxide and the chemical species involved in the conversion of CH4 to CO in the troposphere is reviewed. Following a brief summary of CO and CH4 emission and reactions in urban areas, attention is given to measurements of the spatial and temporal distributions of CO and CH4 in the rural atmosphere, the contribution of the oceans to atmospheric CO and CH4 concentrations, and interactions of CH4 and CO with soils and vegetation. Estimates of the transport of CH4 and CO from the troposphere to the stratosphere are discussed, and photochemical reactions of the constituents are examined. Two- and three-dimensional models for CH4 and CO transport are presented, and possible future variations in atmospheric abundances of the molecules are considered. Finally, present estimates of the global methane and carbon dioxide budgets are summarized, and it is pointed out that, despite the large contribution of anthropogenic sources, the budgets appear to be in balance.

Peters, L. K.↗
NASA NTRS1981

Dependence of tropospheric temperature on the parameterization of cumulus convection in the GLAS model of the general circulation

Analysis of the simulation of seasonal change by the GLAS model of the general circulation reveals deficiencies in the simulation of tropospheric temperature and of convective cloud cover. These interrelated deficiencies are due to a spurious doubling from January to July in the convective cloud cover of the Northern Hemisphere. The spurious doubling, in turn, is due to the oversensitivity of cumulus convection, in the GLAS model, to the specific humidity of the lower atmosphere. The oversensitivity is enhanced by a feedback mechanism which perpetuates the existence of deep, penetrative convective clouds at certain preferred locations. The cumulus parameterization scheme has been modified to more realistically relate the onset of cumulus convection to the relative humidity of the lower atmosphere. The modified parameterization has improved the simulation of tropospheric temperature, planetary albedo and convective cloud cover as well as their seasonal variations. Comparison of this experiment with its control has shown a high degree of interrelation among these fields in the GLAS model and has demonstrated the sensitivity of the atmospheric heat budget to the design of the cumulus parameterization scheme. Also, the modification to the cumulus scheme has demonstrated a plausible mechanism to explain the correlation between convective cloud cover and relative humidity in the real atmosphere.

Helfand, H. M.↗
NASA NTRS1981

Implications of natural sources for the latitudinal gradients of NO/y/ in the unpolluted troposphere

The latitudinal distributions of tropospheric odd nitrogen (NO/y/) due to lightning discharges and stratospheric injection are studied by estimating latitude dependences of the sources and the rainout sink from data obtained in August-September, 1977, and May-June, 1978, during project GAMETAG. A one-dimensional (latitude dependent) model is developed for the annually, zonally, and vertically averaged concentration of trace species, NO(y) being treated as a single species, which decouples the NO(y) calculation from the rest of the model since NO(y) has no chemical sources or sinks in the troposphere. The equation governing the NO(y) distribution is solved using finite differences with 33 uniformly spaced grid points in the micron range of -1 to 1. The distribution due to the stratospheric source has a minimum in the tropics, and there are broad maxima centered in the 25-30 degree region in both hemispheres. The calculated NO(y) due to lightning has a maximum near 15 degrees S, and it decreases to nearly a fourth of the maximum value near the poles. The drop off from the maximum is sharper in the Southern Hemisphere in comparison with the Northern Hemisphere.

Hameed, S.↗
NASA NTRS1981

The two-dimensional diagnostic model for tropospheric OH - An uncertainty analysis

Tropospheric OH is believed to play a major role in atmospheric photochemistry, and, via its chemical interactions OH ultimately may affect the climate, stratospheric ozone levels, and the pH of rain. A valuable tool for predicting the global OH abundance as a function of latitude and altitude is the two-dimensional diagnostic model for tropospheric OH. This model can also be applied to budget studies of species which interact with OH, such as CH4, CO, and O3. In addition to laboratory-obtained kinetic data, important variables include the rate constants for several reactions, the rate of heterogeneous removal of soluble species, and the global abundance and spatial variability in H2O, O3, CO, and NOx. The uncertainties in these parameters imply over a factor of 3 variability in the calculated global OH concentration as well as significant uncertainties in the latitudinal and vertical OH distribution.

Chameides, W. L.↗
NASA NTRS1982

The tropospheric gas composition of Jupiter's north equatorial belt (NH3, PH3, CH3D, GeH4, H2O) and the Jovian D/H isotropic ratio

The gas composition of the troposphere of Jupiter in the clearest regions of the North Equatorial Belt (NEB) was derived from the Voyager 1 IRIS data. The infrared spectrum for this homogeneous cloud free region was modeled to infer altitude profiles for NH3, PH3, GeH4 and H2O. The Profiles for NH3 and PH3 were found to be depleted in the upper troposphere but otherwise in agreement with their solar values at the 1 bar level. The mole fraction for CH3D was determined to be 3.5(+1.0 or -1.3) x 10 to the minus 7th power. The GeH4 mole fraction of 7+ or -2 x 10 to the minus 10th power at the 2 to 3 bar level is a factor of 10 lower than the solar value. The H2O mole fraction is approximately 1 x 0.00001 at the 2.5 bar level and is increasing to approximately 3 x 0.00001 at 4 bars where it is a factor of 30 lower than solar. Using IRIS infrared values for the mole fractions of CH3D and CH4 a value of D/H = 3.6(+1.0 or -1.4)x 0.00001 is derived. Assuming this Jovian D/H ratio is representative of the protosolar nebula, and correcting for chemical galactic evolution, yields a value of 5.5 - 9.0 x 0.00001 for the primordial D/H ratio and an upper limit of 1.8 to 2.4 x 10 to the minus 31st power cu cm for the present day baryon density.

Kunde, V.↗
NASA NTRS1982

Results from the July 1981 Workshop on Passive Remote Sensing of the Troposphere

Potential roles of passive remote sensors in the study of the chemistry and related dynamics of the lower atmosphere were defined by a Tropospheric Passive Remote Sensing Workshop, and technology advances required to implement these roles were identified. A promising role is in making global-scale, multilayer measurements of the more abundant trace tropospheric gaseous species (e.g., O3, CO, CH4, HNO3) and of aerosol thickness and size distribution. It includes both nadirand limb-viewing measurements. Technology advances focus on both scanning- and fixed-spectra, nadir-viewing techniques with resolutions of 0.1 kaysers or better. Balloon- and Shuttle-borne experiments should be performed to study the effects of instrument noise and background fluctuations on data inversion and to determine the utility of simultaneously obtained nadir- and limb-viewing data.

Keafer, L. S., Jr.↗
NASA NTRS1982

The importance of ozone in the oxidation of sulfur dioxide in nonurban tropospheric clouds

In studies of the various possible mechanisms which contribute to the conversion of atmospheric sulfur dioxide to sulfate aerosol in the atmosphere, oxidation within the aqueous, droplet phase of tropospheric clouds has been identified as a major contributor. It has appeared that possibly much of this oxidation is by hydrogen peroxide, with the contribution from ozone being only minimal. The present investigation is concerned with the relative importance of O3 and H2O2 oxidation as a function of pH. The results of a new experimental study of the O3-S(IV) reaction in aqueous solution are presented, and potential S(IV) oxidation rates by O3 in cloud water are compared with those predicted for H2O2. The investigation indicates the potential importance of O3 as a contributor to the overall oxidative conversion of SO2 within typical nonpolluted tropospheric clouds.

Maahs, H. G.↗
NASA NTRS1982

Exchange of sulfur between the free troposphere, marine boundary layer, and the sea surface

A steady state analysis has been made of the sources and sinks of sulfur in the remote marine atmosphere and of the steady state exhanges of SO2 and sulfate between the sea, boundary layer, and free troposphere. Two situations were examined: an area of high biological productivity (Gulf of Guinea) and an area of low productivity (tropical Atlantic). The results of the analysis suggest that about one-third of the background concentrations of SO2 and excess sulfate observed in the remote marine atmosphere mixes in from the free troposphere, with the balance, about 100 micrograms S/sq m per day, attributed to the local oxidation of reduced sulfur-bearing precursors in the boundary layer.

Kritz, M. A.↗