Crystal structure and cryogenic properties.
Mechanical properties of metals at low temperatures as function of crystal structure
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The control of stoichiometry in Epitaxial semiconductor structures. Interfacial Chemistry: Property relations. A workshop review
A workshop on the control of stoichiometry in epitaxial semiconductor structures was held on August 21-26, 1995 in the hotel Stutenhaus at Vesser in Germany. The secluded location of the workshop in the forest of Thuringia and its informal style stimulated extensive private discussions among the participants and promoted new contacts between young scientists from Eastern and Western Europe and the USA. Topics addressed by the presentations were interactions of precursors to heteroepitaxy and doping with the substrate surface, the control of interfacial properties under the conditions of heteroepitaxy for selected materials systems, methods of characterization of interfaces and native point defects in semiconductor heterostructures and an in depth evaluation of the present status of the control and characterization of the point defect chemistry for one specific semiconductor (ZnGeP2), including studies of both heterostructures and bulk single crystals. The selected examples of presentations and comments given here represent individual choices - made by the author to highlight major points of the discussions.
Bachmann, Klaus J.↗
Mass properties of a rigid structure
Program MASPROP rapidly calculates mass properties of complex, rigid structural systems. Its basic premise is that complex systems can be adequately described by combination of basic elementary structural shapes.
Gilbert, J. L.↗
Structure, composition, and properties of lunar crust.
Lunar seismic data from three Apollo seismometers are interpreted to determine the structure of the moon's interior to a depth of about 100 km. The travel times and amplitudes of P and S arrivals from Saturn IV-B and LM impacts are interpreted in terms of a velocity profile. The most outstanding feature of the model is that, in the Fra Mauro region of Oceanus Procellarum, the moon has a 65 km-thick layered crust. Other features of the model are: (1) rapid increase of velocity near the surface due to pressure effects on dry rocks, (2) a discontinuity at a depth of about 25 km, (3) near-constant velocities between 25 and 65 km deep, (4) a major discontinuity at 65 km marking the base of the lunar crust, and (5) very high apparent velocities (about 9 km/sec for P waves) in the lunar mantle below the crust.
Toksoz, M. N.↗
On linear structure and phase rotation invariant properties of block M-PSK modulation codes
Two important structural properties of block M(=2')-ary PSK modulation codes, linear structure and phase symmetry, are investigated. An M-ary modulation code is first represented as a code with symbols from the integer group S(MPSK) = (0,1,2,...M-1) under modulo-M addition. Then the linear structure of block MPSK modulation codes over S(M-PSK) with respect to modulo-M vector addition is defined, and conditions are derived under which a block MPSK modulation code is linear. Once the linear structure is developed, the phase symmetry of block M-PSK modulation codes is studied. In particular, a necessary and sufficient condition for a block MPSK modulation code that is linear as a binary code to be invariant under 2 h 180 deg/M phase rotation (for h = 1 to l) is derived. Finally, a list of short 8PSK and 16PSK modulation codes is given, together with their linear structure and the smallest phase rotation for which a code is invariant.
Kasami, Tadao↗
The structure of variable property, compressible mixing layers in binary gas mixtures
We present the results of a study of the structure of a parallel compressible mixing layer in a binary mixture of gases. The gases included in this study are hydrogen (H2), helium (He), nitrogen (N2), oxygen (02), neon (Ne) and argon (Ar). Profiles of the variation of the Lewis and Prandtl numbers across the mixing layer for all thirty combinations of gases are given. It is shown that the Lewis number can vary by as much as a factor of eight and the Prandtl number by a factor of two across the mixing layer. Thus assuming constant values for the Lewis and Prandtl numbers of a binary gas mixture in the shear layer, as is done in many theoretical studies, is a poor approximation. We also present profiles of the velocity, mass fraction, temperature and density for representative binary gas mixtures at zero and supersonic Mach numbers. We show that the shape of these profiles is strongly dependent on which gases are in the mixture as well as on whether the denser gas is in the fast stream or the slow stream.
Kozusko, F.↗
Structure and Early Soot Oxidation Properties of Laminar Diffusion Flames
Soot is an important unsolved problem of combustion science because it is present in most hydrocarbon-fueled flames and current understanding of the reactive and physical properties of soot in flame environments is limited. This lack of understanding affects progress toward developing reliable predictions of flame radiation properties, reliable predictions of flame pollutant emission properties and reliable methods of computational combustion, among others. Motivated by these observations, the present investigation extended past studies of soot formation in this laboratory, to consider soot oxidation in laminar diffusion flames using similar methods. Early work showed that O2 was responsible for soot oxidation in high temperature O2-rich environments. Subsequent work in high temperature flame environments having small O2 concentrations, however, showed that soot oxidation rates substantially exceeded estimates based on the classical O2 oxidation rates of Nagle and Strickland-Constable and suggests that radicals such as O and OH might be strong contributors to soot oxidation for such conditions. Neoh et al. subsequently made observations in premixed flames, supported by later work, that showed that OH was responsible for soot oxidation at these conditions with a very reasonable collision efficiency of 0.13. Subsequent studies in diffusion flames, however, were not in agreement with the premixed flame studies: they agreed that OH played a dominant role in soot oxidation in flames, but found collision efficiencies that varied with flame conditions and were not in good agreement with each other or with Neoh et al. One explanation for these discrepancies is that optical scattering and extinction properties were used to infer soot structure properties for the studies that have not been very successful for representing the optical properties of soot. Whatever the source of the problem, however, these differences among observations of soot oxidation in premixed and diffusion flames clearly must be resolved. Motivated by these findings, the present study undertook measurements of soot and flame properties within the soot oxidation region of some typical laminar diffusion flames and exploited the new measurements to identify soot oxidation mechanisms for these conditions. Present considerations were limited to the early stages of soot oxidation (carbon consumption less than 70%) where reactions at the surface of primary soot particles dominate the process, rather than the later stages when particle porosity and internal particle oxidation become important as discussed by Neoh et al.
El-Leathy, A. M.↗
Application of dust for space structures
Physical properties and applications of dust structures in space technology
Cutler, S. N.↗
Structural Fluctuations and Thermophysical Properties of Molten II-VI Compounds
The objectives of the project are to conduct ground-based experimental and theoretical research on the structural fluctuations and thermophysical properties of molten II-VI compounds to enhance the basic understanding of the existing flight experiments in microgravity materials science programs as well as to study the fundamental heterophase fluctuation phenomena in these melts by: 1) conducting neutron scattering analysis and measuring quantitatively the relevant thermophysical properties of the II-VI melts (such as viscosity, electrical conductivity, thermal diffusivity and density) as well as the relaxation characteristics of these properties to advance the understanding of the structural properties and the relaxation phenomena in these melts and 2) performing theoretical analyses on the melt systems to interpret the experimental results. All the facilities required for the experimental measurements have been procured, installed and tested. It has long been recognized that liquid Te presents a unique case having properties between those of metals and semiconductors. The electrical conductivity for Te melt increases rapidly at melting point, indicating a semiconductor-metal transition. Te melts comprise two features, which are usually considered to be incompatible with each other: covalently bound atoms and metallic-like behavior. Why do Te liquids show metallic behavior? is one of the long-standing issues in liquid metal physics. Since thermophysical properties are very sensitive to the structural variations of a melt, we have conducted extensive thermophysical measurements on Te melt.
Su, Ching-Hua↗
Harmonic and Anharmonic Properties of Diamond Structure Crystals with Application to the Calculation of the Thermal Expansion of Silicon
Silicon has interesting harmonic and anharmonic properties such as the low lying transverse acoustic modes at the X and L points of the Brillouin zone, negative Gruneisen parameters, negative thermal expansion and anomalous acoustic attenuation. In an attempt to understand these properties, a lattice dynamical model employing long range, nonlocal, dipole-dipole interactions was developed. Analytic expression for the Gruneisen parameters of several modes are presented. These expressions explain how the negative Gruneisen parameters arise. This model is applied to the calculation of the thermal expansion of silicon from 5K to 1700K. The thermoelastic contribution to the acoustic attenuation of silicon is computed from 1 to 300 K. Strong attenuation anomalies associated with negative thermal expansion are found in the vicinity of 17K and 125K.
Wanser, K. H.↗
Liquid Structures and Physical Properties -- Ground Based Studies for ISS Experiments
Studies of electrostatically-levitated supercooled liquids have demonstrated strong short- and medium-range ordering in transition metal and alloy liquids, which can influence phase transitions like crystal nucleation and the glass transition. The structure is also related to the liquid properties. Planned ISS experiments will allow a deeper investigation of these results as well as the first investigations of a new type of coupling in crystal nucleation in primary crystallizing liquids, resulting from a linking of the stochastic processes of diffusion with interfacial-attachment. A brief description of the techniques used for ground-based studies and some results relevant to planned ISS investigations are discussed.
Kelton, K. F.↗
Residual structure and mechanical properties of alpha brass and stainless steel following deformation by cold rolling and explosive shock loading
Mechanical responses and residual defect structures in brass and stainless steel following explosive shock loading and cold reduction by rolling
Grace, F. I.↗
On linear structure and phase rotation invariant properties of block 2(sup l)-PSK modulation codes
Two important structural properties of block 2(l)-ary PSK (phase shift keying) modulation codes, linear structure and phase symmetry, are investigated. For an additive white Gaussian noise (AWGN) channel, the error performance of a modulation code depends on its squared Euclidean distance distribution. Linear structure of a code makes the error performance analysis much easier. Phase symmetry of a code is important in resolving carrier phase ambiguity and ensuring rapid carrier phase resynchronization after temporary loss of synchronization. It is desirable for a code to have as many phase symmetries as possible. A 2(l)-ary modulation code is represented here as a code with symbols from the integer group. S sub 2(l) PSK = (0,1,2,...,2(l)-1), under the modulo-2(l) addition. The linear structure of block 2(l)-ary PSK modulation codes over S sub 2(l)-ary PSK with respect to the modulo-2(l) vector addition is defined, and conditions under which a block 2(l)-ary PSK modulation code is linear are derived. Once the linear structure is developed, phase symmetry of a block 2(l)-ary PSK modulation code is studied. It is a necessary and sufficient condition for a block 2(l)-PSK modulation code, which is linear as a binary code, to be invariant under 180 deg/2(l-h) phase rotation, for 1 is less than or equal to h is less than or equal to l. A list of short 8-PSK and 16-PSK modulation codes is given, together with their linear structure and the smallest phase rotation for which a code is invariant.
Lin, Shu↗
Statistical analysis of the modal properties of large structural systems.
A theory is developed to predict eigenvalue and eigenvector uncertainty in large dynamic models. The uncertainty is based on physical property uncertainty and should not be confused with numerical roundoff, although the method can be extended to include the latter. The theory, when implemented on a computer, is used to analyze the uncertainties in frequencies and mode shapes based on uncertainties in mass, stiffness, modulus of elasticity, etc. The method incorporates a linear statistical model which is quite adequate for handling property uncertainties of 10% or more. The model is not limited to small systems but uses certain statistical assumptions as well as selective matrix manipulations to keep the size of all matrix operations to within the number of degrees of freedom of the system. Examples are given for two longitudinal vibration problems, and the results are supported by a Monte Carlo analysis.
Collins, J. D.↗
Structural Fluctuations and Thermophysical Properties of Molten II-VI Compounds
The objectives of the project are to conduct ground-based experimental and theoretical research on the structural fluctuations and thermophysical properties of molten II-VI compounds to enhance the basic understanding of the existing flight experiments in microgravity materials science programs as well as to study the fundamental heterophase fluctuation phenomena in these melts by: 1) conducting neutron scattering analysis and measuring quantitatively the relevant thermophysical properties of the II-VI melts (such as viscosity, electrical conductivity, thermal diffusivity and density) as well as the relaxation characteristics of these properties to advance the understanding of the structural properties and the relaxation phenomena in these melts and 2) performing theoretical analyses on the melt systems to interpret the experimental results. All the facilities required for the experimental measurements have been procured, installed and tested. Thermal diffusivity of molten tellurium has been measured by a laser flash method in the temperature range of 500 C to 900 C. The measured diffusivity as a function of temperature agrees fairly well with published data. However, a relaxation phenomenon, which shows a slow drift of the measured thermal conductivity toward the equilibrium value after cooling of the melt, was observed for the first time. An apparatus based on the transient torque induced by a rotating magnetic field has been developed to determine the viscosity and electrical conductivity of semiconducting liquids. Viscosity measurements on molten tellurium showed a similar relaxation behavior to the measured diffusivity. The density and volume expansion coefficients for pure Te and HgTe melts were measured as a function of temperature using a pycnometric method. A density maximum was found for both melts but no relaxation behavior was observed. Neutron scattering experiments were performed on the HgTe and HgZnTe melts and the results on pair distribution showed better resolution than previously reported. A simple kinetic theory, which contains the formation reactions of Te polymerization that increases the molecular weight, was proposed to interpret the relaxation behavior of HgZnTe viscosity data.
Su, Ching-Hua↗
Structural Fluctuation and Thermophysical Properties of Molten II-VI Compounds
The objectives of the project is to conduct ground-based experimental and theoretical research on the structural fluctuations and thermophysical properties of molten II-VI compounds to enhance the basic understanding of the existing flight experiments in microgravity materials science programs and to study the fundamental heterophase fluctuations phenomena in these melts by: 1) Conducting neutron scattering analysis and measuring quantitatively the relevant thermophysical properties of the II-VI melts such as viscosity, electrical conductivity, thermal diffusivity and density as well as the relaxation characteristics of these properties to advance the understanding of the structural properties and the relaxation phenomena in these melts and 2) Performing theoretical analyses on the melt systems to interpret the experimental results. All the facilities required for the experimental measurements have been procured, installed and tested. A relaxation phenomenon, which shows a slow drift of the measured thermal conductivity toward the equilibrium value after cooling of the sample, was observed for the first time. An apparatus based on the transient torque induced by a rotating magnetic field has been developed to determine the viscosity and electrical conductivity of semiconducting liquids. Viscosity measurements on molten tellurium showed similar relaxation behavior as the measured diffusivity. Neutron scattering experiments were performed on the HgTe and HgZnTe melts and the results on pair distribution showed better resolution than previous reported.
Source record↗
The effects of molecular structure on the thermochemical properties of phenolics and related polymers
Molecular structure effects on thermochemical properties of phenolic resins and related polymers
Miles, B. H.↗
Correlation of mechanical properties with metallurgical structure for 18Ni 200 grade maraging steel at room and cryogenic temperatures
An extensive metallurgical study is presented which is intended to explain variations in the mechanical properties of Ni18 200 grade maraging steel in various product forms and orientations. Fracture toughness and Charpy impact values are found to decrease with decreasing temperature and be dependent on product form, specimen orientation, and metallurgical condition. Fatigue crack growth rates are dependent on temperature only. Fractographic analysis reveals that the decrease in toughness at -170 C is not associated with cleavage-type fracture morphology. Those specimens exhibiting low fracture toughness at room temperature or -170 C are found to have a significantly larger number of titanium-rich particles associated with dimple formation on the fracture surface.
Wagner, J. A.↗