Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “SHIPPING”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 577 records · Page 32

Apollo 16 Press Kit

The Apollo 16 spacecraft is scheduled for launch on Apr. 16, 1972 from Complex 39A at the Kennedy Space Center, Florida by the Saturn V launch vehicle. Crewmen are mission commander John W. Young, command module pilot Thomas K. Mattingly II and lunar module pilot Charles M. Duke Jr. Objectives of the mission, to last up to 12 days, as outlined by NASA: to perform selenological inspection, survey and sampling of materials in a preselected region of Descartes using a lunar roving' vehicle; deploy and activate Apollo surface experiments; develop man's capability to work in the lunar environment; obtain photographs of candidate exploration sites; and toconduct inflight experiments and photographic tasks in lunar orbit. Following launch, the spacecraft will reach Earth Parking Orbit and remain in orbit for about two and one-half revolutions prior to Translunar Injection. Next, the Command and Service Module docks with the Lunar Module and the spacecraft "coasts" to the moon. In orbit around the moon, the Command and Service Module/Lunar Module combination will descend to within 50,000 feet of the lunar surface before undocking. The Lunar Module will continue to descend while the Command and Service Module returns to an orbit approximately 60 miles high. Stay time on the lunar surface is scheduled for approximately 73 hours. The ascent stage of the Lunar Module then lifts the astronauts back into lunar orbit where they will dock with the Command/Service Module. The Lunar Module is jettisoned and Transearth Injection follows. Just prior to reentry into the earth's atmosphere, the Service Module is jettisoned, and the astronauts in the Command Module splashdown in the Pacific Ocean. The target point for end-of-mission splashdown is at 05 degrees 0 minutes north latitude and 158 degrees 40 minutes west longitude or approximately 985 nautical miles south of Honolulu, Hawaii. Splashdown is scheduled for Apr. 28, 1972 at 10:30 a.m. Hawaiian Standard Time (2:30 p.m. CST). Recovery forces for Apollo 16, stationed in both the Atlantic and Pacific Oceans, will consist of three ships, nine aircraft and nearly 1,700 personnel. CTF-130 (Manned Spacecraft Recovery Force, Pacific) forces will be stationed south of Hawaii. Three ships, eight helicopters and three Air Force HC-130H aircraft, and nearly 1,100 personnel, will take part. Task Force 140 (Manned Spacecraft Recovery Force, Atlantic), comprising one ship, six HC-130H aircraft, three helicopters and approximately 300 personnel, will be positioned for possible launch abort operations. Two ships in the Atlantic will also be used for acoustical testing. Other forces, primarily aircraft and personnel of the Air Force Aerospace Rescue and Recovery Service will be on alert around the world for contingency recovery support.

Source record↗

TPSAS-NF1676L-34796-DND

The recently completed 2015-2017 EVS-2 mission NAAMES (The North Atlantic Aerosols and Marine Ecosystems Study) provides a unique set of airborne remote sensing and ship-based in situ measurements in a remote and under-sampled region of the Earth?s ocean. The NASA SABOR (Ship-Aircraft Bio-Optical Research) campaign was conducted during the summer of 2014, also in the Atlantic Ocean, out of the Chesapeake Bay and in the eastern coastal region of the United States. For both campaigns, the NASA GISS Research Scanning Polarimeter, a multi-angle, multi-spectral polarimeter measured the upwelling polarized radiances from aircraft. And for both campaigns, ship-based in situ measurements of the ocean were collected jointly with the aircraft measurements. We present results from the new RSP-MAPP (1) that is based on optimal estimation and that can retrieve simultaneous aerosol microphysical properties (including effective radius, single-scattering albedo, and real refractive index) and ocean color products using accurate radiative transfer, Mie calculations, and the DP (Detritus Plankton) series of accurate, numerically efficient ocean bio-optical models. The RSP-MAPP algorithm was applied to data collected during SABOR and NAAMES to retrieve aerosol microphysics and ocean products for all Aerosols-Above-Ocean (AAO) scenes. The RSP-MAPP products are compared against i) collocated aerosol extinction and backscatter profiles collected by the NASA LaRC airborne High Spectral Resolution Lidar (HSRL-1), including lidar depth profiles of the ocean diffuse attenuation coefficient and the hemispherical backscatter coefficient, and ii) collocated ship-based in situ measurements of the ocean.

Snorre Stamnes↗

An Operational Overview of the EXport Processes in the Ocean from RemoTe Sensing (EXPORTS) Northeast Pacific Field Deployment

The goal of the EXport Processes in the Ocean from RemoTe Sensing (EXPORTS) field campaign is to develop a predictive understanding of the export, fate, and carbon cycle impacts of global ocean net primary production. To accomplish this goal, observations of export flux pathways, plankton community composition, food web processes, and optical, physical, and biogeochemical (BGC) properties are needed over a range of ecosystem states. Here we introduce the first EXPORTS field deployment to Ocean Station Papa in the Northeast Pacific Ocean during summer of 2018, providing context for other papers in this special collection. The experiment was conducted with two ships: a Process Ship, focused on ecological rates, BGC fluxes, temporal changes in food web, and BGC and optical properties, that followed an instrumented Lagrangian float; and a Survey Ship that sampled BGC and optical properties in spatial patterns around the Process Ship. An array of autonomous underwater assets provided measurements over a range of spatial and temporal scales, and partnering programs and remote sensing observations provided additional observational context. The oceanographic setting was typical of late-summer conditions at Ocean Station Papa: a shallow mixed layer, strong vertical and weak horizontal gradients in hydrographic properties, sluggish sub-inertial currents, elevated macronutrient concentrations and low phytoplankton abundances. Although nutrient concentrations were consistent with previous observations, mixed layer chlorophyll was lower than typically observed, resulting in a deeper euphotic zone. Analyses of surface layer temperature and salinity found three distinct surface water types, allowing for diagnosis of whether observed changes were spatial or temporal.The 2018 EXPORTS field deployment is among the most comprehensive biological pump studies ever conducted. A second deployment to the North Atlantic Ocean occurred in spring 2021, which will be followed by focused work on data synthesis and modeling using the entire EXPORTS data set.

Biological pump↗

SCOAPE-II: A 2024 Multiplatform Measurement Campaign off the US Gulf Coast to Assess Oil and Gas Emissions on the Outer Continental Shelf

Nine years ago, the Department of Interior’s Bureau of Ocean Energy Management (BOEM), the Agency with Air Quality (AQ) jurisdiction over the Outer Continental Shelf (OCS) of the US Gulf Coast west of 87.5° W longitude, asked NASA to determine the feasibility of using satellite data to measure offshore emissions in a region of concentrated oil and natural gas (ONG) operations. To study this issue NASA and BOEM conducted the May 2019 Satellite Coastal and Oceanic Atmospheric Pollution Experiment (SCOAPE) cruise in the Gulf. SCOAPE addressed both technological and scientific issues related to measuring nitrogen dioxide (NO 2 , a common air pollutant), including contrasting near-shore and deepwater regimes. Given the April 2023 launch of the geostationary Tropospheric Emissions: Monitoring of Pollution (TEMPO) AQ satellite, a 2024 SCOAPE-II was conducted in the Gulf with both ship and aircraft measurements. We present an overview of the SCOAPE-II campaign, analysis and validation of satellite-observed NO 2 , and evaluate measurements of methane from ship, aircraft, and satellite near ONG platforms. Our SCOAPE-II results are as follows: 1) Satellite NO 2 measurements (∼13:30 local time) from the TROPOspheric Monitoring Instrument (TROPOMI) are more accurate than TEMPO’s hourly scans (8.6% vs. 23.6% mean absolute bias); a new version of TEMPO data is currently being processed; 2) ship and aircraft measurements captured dozens of NO 2 and methane plumes from ONG operations, showing that they are persistent emitters; 3) satellite measurements of methane failed to replicate ship and aircraft measurements, presenting ongoing challenges for operational emissions monitoring over the Gulf.

satellite validation↗

Planning for Receipt of Mk-18A Recovered Nuclear Material at Oak Ridge National Laboratory

Oak Ridge National Laboratory (ORNL) ships and receives a wide variety of radioisotopes. These shipments will include the Mark-18A high-burnup targets, which are being processed at Savannah River National Laboratory to recover valuable isotopes that will then be shipped to ORNL for programmatic use. The Mark-18A targets will be processed to recover two products: a plutonium oxide stream and an oxide material that will contain the americium, curium, and lanthanides. A Type A shipping package has been designed, fabricated, and certified to transport the americium/curium/lanthanide oxide product in special form capsules. The package was designed with both gamma and neutron shielding for contents reading up to 5,000 R/hour. The plutonium stream will be shipped to ORNL in a Model 9975 Type B transport cask. A new content envelope for the Type B cask is being developed. This paper discusses the preparation underway at ORNL to receive the packages and transfer the material into hot cell processing and storage facilities for subsequent use in research and development applications and as feedstock for heavy actinide production.

Patton, Bradley↗

Improvements for LCLS-II Cryomodule Transportation

The Linear Coherent Light Source (LCLS-II) is currently being constructed at the SLAC National Laboratory. A total of 35 cryomodules will be fabricated at Jefferson Lab (JLab) in Virginia and Fermi National Laboratory (FNAL) in Illinois and transported via road to SLAC. A shipping frame with an inner bed isolated by springs was designed to protect the CMs from shocks and vibrations during shipments. Successful road testing of the JLab prototype paved the way for production CM shipments. The initial production shipments lead to several catastrophic failures in beamline vacuum in the cryomodules. The failures were determined to be due to fatigue in Fundamental Power Coupler (FPC) bellows due to excessive motion during shipment. A series of instrumented CM shipping tests and component tests were undertaken to develop a solution. A modified spring layout was tested and implemented, which reduced shocks on the CMs. FPC coupler bellows restraints were tested on a shaker table and on a CM during shipping; they were able to reduce bellows motion by a factor of three. The updated shipping system is currently in use and has successfully delivered six cryomodules to SLAC from JLab and FNAL.

Huque, N. A.↗

Mitigating Extremist Maritime Threats to Radiological Material Transport Vessels

The 21st century has experienced a rise in the threat of global radicalism and extremist organizations, and there has been oft-reported interest from these groups in obtaining or exploiting radiological materials. The threat of extremists acquiring radiological materials while in transit or sabotaging a transport vessel carrying materials at sea is one that requires increased attention. Transport is already one of the most vulnerable times for any cargo but including the difficulties in securing a large ship on the open ocean makes oceanic transport of radiological materials a space of elevated vulnerability for sabotage, theft, or other attacks. The risks of violent extremist attacks on trade ships and trading routes are serious, as shipping routes sustain the global economy, but an attack on a radiological transport vessel could be a magnitude worse, impacting national and international security. While radicalists have largely remained on land in the past due to minimal maritime expertise or inability to project power out of their immediate vicinity, the world has witnessed past attacks on ships such as the USS Cole and the MV Limburg and it is likely only a matter of time before groups extend further into the sea and engage in more maritime campaigns against material transport vessels. This paper suggests methods for increasing safety and security on oceanic transport voyages through behavioral science principles and insider threat recognition training, as well as a better understanding of adversarial and extremist psychology. By providing transport personnel with the knowledge and support to identify and respond to unique maritime threats by extremists, these principles and training suggestions should advance and increase security on the high seas.

Kinney, Justin↗

WIPP Status and Plans - 2013 - 13379

An up-to-date look at the many aspects of America's only deep geologic long-lived radioactive waste repository is presented in this paper. WIPP's mission includes coordination of all Department of Energy (DOE) sites to prepare, package and characterize defense transuranic waste for final shipment and emplacement in WIPP. The Waste Isolation Pilot Plant (WIPP) is completing its 14. year of operations. Five of the ten planned disposal panels have been filled and sealed from ventilation, with about half of the legislated volume capacity consumed. About 11,000 shipments have been made successfully, traveling more than 40 million kilometers across the nation's highways. A fleet of new Type B shipping packages, the TRUPACT-III, has been added to the transportation capability, with an ongoing campaign to de-inventory large waste items from the Savannah River Site, while minimizing size reduction and repackaging. A new shipping and emplacement method for remote handled waste in shielded containers has been approved for disposal, and will significantly improve operational efficiency. Remote handled waste packaged in these shielded containers will be shipped, handled and emplaced as contact handled waste. Also described is a new criticality control over-pack container, which will improve efficiency when shipping high fissile-content waste streams consisting of Special Nuclear Material declared as waste from nuclear weapons sites. The paper describes the importance of the infrastructure at WIPP to ensure disposal site availability for defense transuranic waste sites across the weapons complex. With the facility reaching its original design lifetime, there are many infrastructure maintenance and improvements being planned and performed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Savannah River Site Eastern Transportation Hub: A Concept For a DOE Eastern Packaging, Staging and Maintenance Center - 13143

The Department of Energy (DOE) is working to de-inventory sites and consolidate hazardous materials for processing and disposal. The DOE administers a wide range of certified shipping packages for the transport of hazardous materials to include Special Nuclear Material (SNM), radioactive materials, sealed sources and radioactive wastes. A critical element to successful and safe transportation of these materials is the availability of certified shipping packages. There are over seven thousand certified packagings (i.e., Type B/Type AF) utilized within the DOE for current missions. The synergistic effects of consolidated maintenance, refurbishment, testing, certification, and costing of these services would allow for efficient management of the packagings inventory and to support anticipated future in-commerce shipping needs. The Savannah River Site (SRS) receives and ships radioactive materials (including SNM) and waste on a regular basis for critical missions such as consolidated storage, stabilization, purification, or disposition using H-Canyon and HB-Line. The Savannah River National Laboratory (SRNL) has the technical capability and equipment for all aspects of packaging management. SRS has the only active material processing facility in the DOE complex and is one of the sites of choice for nuclear material consolidation. SRS is a logical location to perform maintenance and periodic testing of the DOE fleet of certified packagings. This initiative envisions a DOE Eastern Packaging Staging and Maintenance Center (PSMC) at the SRS and a western hub at the Nevada National Security Site (NNSS), an active DOE Regional Disposal Site. The PSMC's would be the first place DOE would go to meet their radioactive packaging needs and the primary locations projects would go to disposition excess packaging for beneficial reuse. These two hubs would provide the centralized management of a packaging fleet rather than the current approach to design, procure, maintain and dispose of packagings on a project-by-project basis. This initiative provides significant savings in packaging costs and acceleration of project schedules. In addition to certified packaging, the PSMC would be well suited for select designs of 7A Type A packaging and Industrial Packaging. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Decommissioning and Dismantling of the Floating Maintenance Base 'Lepse' - 13316

The Lepse was built in Russia in 1934 and commissioned as a dry cargo ship. In 1961 she was re-equipped for use as a nuclear service ship (NSS), specifically a floating maintenance base (FMB), to support the operation of the civilian nuclear fleet (ice-breakers) of the USSR. In 1988 Lepse was taken out of service and in 1990 she was re-classified as a 'berth connected ship', located at a berth near the port of Murmansk under the ownership of Federal State Unitary Enterprise (FSUE) Atomflot. Lepse has special storage facilities for spent nuclear fuel assemblies (SFA) that have been used to store several hundred SFAs for nearly 40 years. High and intermediate-level liquid radioactive waste (LRW) is also present in the spent nuclear fuel assembly storage channels, in special tanks and also in the SFA cooling circuit. Many of the SFAs stored in Lepse are classified as damaged and cannot be removed using standard procedures. The removal of the SFA and LRW from the Lepse storage facilities is a hazardous task and requires specially designed tools, equipment and an infrastructure in which these can be deployed safely. Lepse is a significant environmental hazard in the North West of Russia. Storing spent nuclear fuel and high-level liquid radioactive waste on board Lepse in the current conditions is not acceptable with respect to Russian Federation health, safety and environmental standards and with international best practice. The approved concept design for the removal of the SFA and LRW and dismantling of Lepse requires that the ship be transported to Nerpa shipyard where specialist infrastructure will be constructed and equipment installed. One of the main complexities of the Project lies within the number of interested stakeholders involved in the Project. The Lepse project has been high focus on the international stage for many years with previous international efforts failing to make significant progress towards the objective of decommissioning Lepse. The Northern Dimension Environmental Partnership (NDEP) approved an internationally funded project to identify and prioritise nuclear and environmental hazards in NW Russia. Within this project the Lepse was recognised as being one of the highest nuclear hazards in NW Russia. Removal of SNF, SRW and LRW from Lepse requires innovative design and development of bespoke equipment. The main drivers of the NDEP Donors are first to safely transport Lepse in 2012 from her current berth close to the local population in Murmansk to the nominated dismantling shipyard, and secondly to raise Lepse from the water in 2013 onto the slip-way at the dismantling shipyard. A description is provided of the approach and progress towards preparing the Lepse for the removal of SFAs and other radioactive waste, to decontaminate and then dismantle the vessel under international donor funding. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Multi-Year Work Plan to De-Inventory TRU Waste Stored at LANL - 12121

The Los Alamos National Laboratory (LANL) continues to accelerate disposition of transuranic (TRU) waste stored at its Technical Area 54 (TA-54) Area G waste management facility. The current focus is on complete removal of all non-cemented above-grade Legacy and newly-generated TRU waste that was in storage on October 1, 2011, by no later than June 30, 2014. This inventory of above-grade TRU is defined as 3,706 m{sup 3} of material. Legacy TRU waste containers were placed into storage up to 40 years ago, and most of the older containers must be remediated to address compliance issues before the waste can be characterized, certified as meeting the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC), and shipped for disposition. More than half of the remaining TRU waste volume stored above grade is contained within oversize boxes that contain waste items that must be repackaged or size reduced. Facilities and major types of equipment needed to remediate and characterize the TRU waste inventory are largely in place, but two additional oversize box processing lines are being implemented in 2012. Multiple work shifts are planned for most remediation lines in 2013. An integrated risk-based project management schedule for all disposition activities has been developed that is based on a 'Solution Package' approach. Inventories of containers that have issues in common were compiled into about 15 waste categories and about 70 'Solution Packages' that identify all of the activities needed to disposition the inventory of TRU waste in storage. Scheduled activities include all precursor activities to begin remediation, remediation processing, characterization and certification to the WIPP WAC, and shipping of containers to WIPP. Processing of the 3,706 m{sup 3} is projected to result in about 4,500 55-gallon (208 L) drums and 1,000 standard waste boxes that will be shipped to WIPP. About 385 shipments from LANL to WIPP are projected before June 30, 2014, to ship these containers, at a rate of 5 to 6 shipments a week. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

GNF fuel technology update

In 2015, Global Nuclear Fuel (GNF) launched the GNF3 fuel design by inserting lead-use assemblies into two boiling water reactors (BWRs) in the U.S. A lead use assembly is a nuclear fuel assembly which is inserted in a reactor core to confirm its performance. A third set of GNF3 lead-use assemblies are scheduled to be inserted into another reactor in the spring of 2017. GNF3 is a robust next-generation 10*10 fuel design that will improve both fuel cycle and fuel reliability. In addition, GNF3 will be delivered in a fully assembled condition - forgoing the need to insert fuel channels over the bundles at the site. The process of shipping BWR fuel in a channeled configuration is complex and requires an understanding of the potential high-cycle and low-cycle fatigue conditions that can occur during shipping, as characterized by accelerometer data from ship tests. The key component in evaluating channeled fuel shipping is the spacer, and the GNF3 spacer fatigue performance was found to be approximately twice that of GNF2. While fuel reliability has traditionally been related to the avoidance of fuel leakers, for the past 15 years channel - control blade interference has been a close second for concern. To eliminate this problem, GNF3 will come standard with NSF (a zirconium alloy) channels that are effectively resistant to fluence gradient-induced bow and shadow corrosion-induced bow. In addition to the development of GNF3, GNF is evaluating the use of advancing 3D metal printing or additive manufacturing for manufacturing fuel bundle components. Additive manufacture offers the hope of more flexibility in design and shorter manufacturing development cycles. However, since there is little experience with this technology in the nuclear industry, GNF has been evaluating the use of additive manufacture to fabricate small scale components that are easily retrieved from the reactor for testing. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Development of Type A Transport Packagings - 17073a

ORNL ships a wide variety of radioisotopes. Many of these are associated with the DOE Isotope Program and Office of Nuclear Materials Integration (ONMI) and can be shipped as DOT Type A quantities of material. The DOT Specification 6M Type B packaging previously used for many shipments at ORNL is no longer authorized. Most materials could be shipped in Type B packagings, but many of them can meet the requirements for shipping as Type A. As a result, ORNL is working with a packaging manufacturer to develop, test, and certify several Type A packagings. These include a 38 L (10 gal) Type A packaging primarily to be used for transport of Cf-252 sources, a 208 L (55 gal) Type A packaging primarily to be used for transport of americium/curium/lanthanide oxide materials recovered from high-burnup targets, and a Type A packaging for transport of irradiated actinium targets. These are being developed with consideration for both gamma and neutron shielding for contents reading up to 5000 R/h. (authors)

07 ISOTOPE AND RADIATION SOURCES↗

What's in WIPP? Packaging TRU Waste to Enhance WIPP's Capacity - 16515

Beginning in 1999, and continuing for 15 years, the US DOE Waste Isolation Pilot Plant (WIPP) repository successfully disposed of defense Transuranic (TRU) waste. Six of the originally planned ten disposal panels were filled before two unrelated accidents temporarily halted disposal operations in February 2014. Based on counting the gross volume of all containers emplaced in WIPP to date, a little more than half of the legislated volume capacity has been subscribed (91,000 cubic meters). This paper describes the many different packaging configurations that have been used to ship TRU waste to WIPP, and makes observations that may enhance the repository capacity when shipments resume. The contents of shipments to WIPP are limited by many requirements of the repository waste acceptance criteria. These criteria derive from three primary sources; 1) the Certificate of Compliance (CoC), issued by the NRC for Type B shipping packaging used by WIPP; 2) The Hazardous Waste Facility Permit, issued by the New Mexico Environment Department; and 3) the WIPP facility's own Documented Safety Analysis (DSA), developed under DOE's regulation 10CFR830. To meet these criteria, various TRU waste forms have been packaged in different ways, with varying packaging efficiency. Of course, there is an overall upper limit on WIPP's volume capacity that was legislated as part of the WIPP Land Withdrawal Act. The volume counted against this limit has been calculated by simply summing the volumes of individual payload containers shipped to and emplaced at WIPP. This method counts significant non-waste volumes inside the containers due to over-packing inner containers and partially filled containers. Without some change to how disposal volumes are calculated, or how waste is packaged, the amount of TRU waste yet to be shipped to WIPP could exceed the legislated capacity. Concepts to enhance the packaging efficiency of future waste shipments to WIPP are presented. Approximate estimates of the waste versus non-waste volumes that have been emplaced to date are discussed. This paper only considers contact handled TRU waste (i.e., contact dose rates < 2 mSv/hr). (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Idaho-Developed Technologies, Processes Offer Unique Solutions to Waste Management Challenges - 19281

INL Site cleanup contractor Fluor Idaho, LLC (Fluor Idaho) and its predecessors have developed a host of state-of-the-art technologies and specialized processes for nuclear waste handling, treatment, storage, and shipping. The cleanup program has also repurposed and upgraded previously idled Cold War-era buildings to treat and repackage both on- and off-site generated radioactive and hazardous wastes. And lastly, Fluor Idaho is using one-of-a-kind equipment to protect waste management personnel as they undertake their work to meet cleanup commitments that the Department of Energy (DOE) made to the state of Idaho. Such applications, although developed for Idaho's wastes, have the potential to benefit other facilities within the DOE Complex. Engineers and fabricators have teamed up to develop truly unique devices made of specialized metals, like stainless steel alloys, and more readily available materials such as Lexan. All waste types that Fluor Idaho manages daily - spent nuclear fuel, both high- and low-level wastes, and both remote-handled (RH) and CH-TRU - benefit from these innovations. Without question, the greatest number of specialized equipment, processes, and worker-protection technologies developed are for the retrieving, characterizing, repackaging, and shipping of TRU wastes, which makes sense considering the INL Site stores the most TRU waste in the DOE Complex. On the CH-TRU retrieval front, crews are using specially modified Gradall excavators to protect workers while they exhume Rocky Flats Plant wastes that were sent to Idaho in the 1950's and 1960's and buried in a shallow landfill. The excavators are supplied with extra Lexan windows to protect operators from the potential for flying debris during exhumation. On-board supplied air, pumped into the cab, and individual air supplies protect workers from inhalation hazards. Also on-board infrared cameras allow operators to detect heat generating from reactive metals at the dig face. At the Advanced Mixed Waste Treatment Facility (AMWTP), Brokk robotic arm operators use a 'super clam' claw, designed and built at the INL Site, on the remotely operated heavy equipment to size-reduce waste boxes, drums, concrete, and metal containing TRU constituents. The super clam is so powerful and dexterous that operators can crush a 55-gallon drum into the size of a basketball, but also delicately turn the pages of a magazine. Boxes too large to be sized at the AMWTP's box-lines are sent to the Accelerated Retrieval Project VII facility to be sized by Waste Management personnel. Such waste boxes, which sometimes contain 'flighty' plutonium-238 material, have forced the project to employ a heavily ventilated and filtered interior tent. Not all technologies developed for the Waste Management program are high-technology; in fact, one piece of equipment is so simple it's literally ingenious. Operators who inspect and repackage RH-TRU inside a hot cell at the Idaho Nuclear Technology and Engineering Center (INTEC) needed a backup plan in case the hot cell port couldn't be closed in the event of a power outage. Engineers and fabricators collaborated to develop a port cover actuator mechanism, which allows operators to open and close the cell's hatch cover with nothing more than a cordless drill. Also at INTEC, Maintenance Shop fabricators developed a Lexan container or 'pig' suitable for shielding neutron-emitting TRU waste sources. Lexan was chosen as the preferred shielded container material for this special type of waste because neutrons are best shielded with materials containing lots of hydrogen, such as plastics, which are composed of carbon and hydrogen molecules. Once approved for shipment, the high-activity waste will be loaded into specialty casks and shipped to WIPP for permanent disposal. Although all these technologies and processes were initially developed for resolving challenges at the INL Site, their applications could be far-reaching. Like the INL Site, many other facilities in the DOE Complex manage, treat, store, and ship TRU, low-and high-level wastes, and spent nuclear fuel. The technologies and processes developed in Idaho protect Waste Management personnel as they undertake their work, but these benefits could be utilized by other facilities and personnel doing similar work. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Environmentally improved CdTe photovoltaic recycling through novel technologies and facility location strategies

Abstract Photovoltaic waste is projected to reach up to 78 million tons across globally dispersed locations through 2050. Current recycling infrastructure is inadequate to process these waste volumes responsibly. This necessitates commercializing novel, environmentally advantageous photovoltaic recycling technologies that improve upon incumbent industrial operations. CdTe photovoltaic recycling is a promising candidate for improvements as 25,000 tons of spent modules are recycled worldwide annually. This paper evaluates the operational performance and compares six novel technologies, the incumbent technology used in industry and one technology which extends the incumbent process across ten environmental impact categories. The tradeoff between incurring a transportation burden (ship or road) to recycle in a large‐scale centralized facility with a higher operational efficiency and avoiding transportation by recycling in a small‐scale decentralized facility with a lower operational efficiency is evaluated. Thermal delamination to eliminate the ethylene vinyl acetate and separate the photovoltaic glass panels is preferable to the incumbent mechanical process across nine environmental impact categories and decreases the climate‐change impact of CdTe photovoltaic recycling by 23%. Bath and probe sonication are ineffective for delamination, and the use of organic solvents is more environmentally burdensome than the incumbent mechanical process. Centralized recycling with shipping is environmentally preferable than with road‐based transportation. For every 100‐km increase in road transportation from the decentralized to the centralized facility, the inventory requirement in the centralized facility should be 6% lower than the decentralized facility for centralized recycling to have a lower climate‐change impact than decentralized recycling. The corresponding value for shipping is 0.4%.

Ravikumar, Dwarakanath↗

Top-down estimate of anthropogenic emission inventories and their interannual variability in Houston using a mesoscale inverse modeling technique

The 2000 and 2006 Texas Air Quality Study (TexAQS 2000 and 2006) field campaigns took place in eastern Texas in August-October of 2000 and 2006. Several flights of the National Oceanic and Atmospheric Administration (NOAA) and National Center for Atmospheric Research (NCAR) research aircraft were dedicated to characterizing anthropogenic emissions over Houston. Houston is known for having serious problems with non-attainment of air quality standards. We present a method that uses three models and aircraft observations to assess and improve existing emission inventories using an inverse modeling technique. We used 3-dimensional and 4-dimensional variational (3D-VAR and 4D-VAR) inverse modeling techniques based on a least-squares method to improve the spatial and temporal distribution of CO, NOy (sum of all reactive nitrogen compounds), and SO2 emissions predicted by the 4-km-resolution U.S. Environmental Protection Agency (EPA) National Emission Inventory (NEI) for 2005. Differences between the prior and posterior inventories are discussed in detail. We found that in 2006 the prior daytime emissions in the urban area of Houston have to be reduced by 40% {+-} 12% for CO and 7% {+-} 13% for NOy. Over the Houston Ship Channel, where industrial emissions are predominant, the prior emissions have to be reduced by 41% {+-} 15% for CO and 51% {+-} 9% for NOy. Major ports around Houston have their NOy emissions reduced as well, probably due to uncertainties in near-shore ship emissions in the EPA NEI inventory. Using the measurements from the two field campaigns, we assessed the interannual emission variability between 2000 and 2006. Daytime CO emissions from the Houston urban area have been reduced by 8% {+-} 20%, while the NOy emissions have increased by 20% {+-} 12% from 2000 to 2006. In the Houston Ship Channel, the daytime NOy emissions have increased by 13% {+-} 17%. Our results show qualitative consistencies with known changes in Houston emissions sources.

54 ENVIRONMENTAL SCIENCES↗

Improved Reanalysis and Prediction of Atmospheric Fields Over the Southern Ocean Using Campaign‐Based Radiosonde Observations

Abstract This study investigated the impact of radiosonde observations from the Southern Ocean obtained by the Australian R/V Aurora Australis on the ALERA2 experimental ensemble reanalysis data set and ensemble forecast experiment. An observing system experiment (OSE) that included additional ship‐launched radiosonde data captured the atmospheric structure over the Southern Ocean. ALERA2 without additional radiosondes had positive temperature biases exceeding 7 °C in the upper troposphere when low‐pressure cyclonic systems passed over the ship. The spread in the upper level was reduced by 15% in the OSE, which propagated downstream from the ship's position because of the sparse observing network over southern high latitudes. Comparison of two 63‐member ensemble forecast experiments initialized by ALERA2 and the OSE revealed that prediction of midlatitude cyclone tracks was improved by the realistic representation of upper‐level troughs in the OSE forecast. This confirms that additional radiosondes over the Southern Ocean reduce uncertainty and error in midlatitude cyclone forecasts.

54 ENVIRONMENTAL SCIENCES↗