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Hydrogen Research at Florida Universities

This final report describes the R&D activities and projects conducted for NASA under the 6-year NASA Hydrogen Research at Florida Universities grant program. Contained within this report are summaries of the overall activities, one-page description of all the reports funded under this program and all of the individual reports from each of the 29 projects supported by the effort. The R&D activities cover hydrogen technologies related to production, cryogenics, sensors, storage, separation processes, fuel cells, resource assessments and education. In the span of 6 years, the NASA Hydrogen Research at Florida Universities program funded a total of 44 individual university projects, and employed more than 100 faculty and over 100 graduate research students in the six participating universities. Researchers involved in this program have filed more than 20 patents in all hydrogen technology areas and put out over 220 technical publications in the last 2 years alone. This 6 year hydrogen research program was conducted by a consortium of six Florida universities: Florida International University (FIU) in Miami, Florida State University (FSU) and Florida A&M University (FAMU) in Tallahassee, University of Central Florida (UCF) in Orlando, University of South Florida (USF) in Tampa, and University of Florida (UF) in Gainesville. The Florida Solar Energy Center (FSEC) of the University of Central Florida managed the research activities of all consortium member universities except those at the University of Florida. This report does not include any of the programs or activities conducted at the University of Florida, but can be found in NASA/CR-2008-215440-PART 1-3.

Block, David L.↗

Monitoring Global Freshwater Resources with GRACE

Freshwater resources include surface waters, groundwater, and seasonal snowpack. Given adequate ground based measurements, all of these can be monitored effectively, however, outside of the developed world such measurements often are not systematic and the data not centralized, and as a result reports of freshwater availability may be largely anecdotal. Even in the developed world it can be difficult to quantify changes in groundwater storage over large scales. Owing to its global coverage, satellite remote sensing has become a valuable tool for freshwater resources assessment. In particular, the Gravity Recovery and Climate Experiment (GRACE) has demonstrated an unequaled ability to monitor total terrestrial water storage including groundwater at regional to continental scales. In this presentation we will identify apparent trends in terrestrial water storage observed by GRACE over the past nine years and attempt to explain their origins and predict whether they are likely to continue. Trends in certain regions where groundwater extraction has significantly depleted aquifers, including northern India and California, will be discussed in detail.

Rodell, Matt↗

Evaluation ofthe Middle East and North Africa Land Data Assimilation System

The Middle East and North Africa (MENA) region is dominated by dry, warm deserts, areas of dense population, and inefficient use of fresh water resources. Due to the scarcity, high intensity, and short duration of rainfall in the MENA, the region is prone to hydro climatic extremes that are realized by devastating floods and times of drought. However, given its widespread water stress and the considerable demand for water, the MENA remains relatively poorly monitored. This is due in part to the shortage of meteorological observations and the lack of data sharing between nations. As a result, the accurate monitoring of the dynamics of the water cycle in the MENA is difficult. The Land Data Assimilation System for the MENA region (MENA LDAS) has been developed to provide regional, gridded fields of hydrological states and fluxes relevant for water resources assessments. As an extension of the Global Land Data Assimilation System (GLDAS), the MENA LDAS was designed to aid in the identification and evaluation of regional hydrological anomalies by synergistically combining the physically-based Catchment Land Surface Model (CLSM) with observations from several independent data products including soil-water storage variations from the Gravity Recovery and Climate Experiment (GRACE) and irrigation intensity derived from the Moderate Resolution Imaging Spectroradiometer (MODIS). In this fashion, we estimate the mean and seasonal cycle of the water budget components across the MENA.

Bolten, John D.↗

Characterizing the Effects of Irrigation in the Middle East and North Africa Using Remotely Sensed Vegetation and Water Cycle Observations

A majority of the countries in the Middle East and North Africa (MENA) region suffer from water scarcity due in part to widespread rainfall deficits, unprecedented levels of water demand, and the inefficient use of renewable freshwater resources. Since a majority of the water withdrawal in the MENA is used for irrigation, there is a desperate need for improved understanding of irrigation practices and agricultural water use in the region. Here, satellite-derived irrigation maps and crop-type agricultural data are applied to the Land Data Assimilation System for the MENA region (MENA LDAS), designed to provide regional, gridded fields of hydrological states and fluxes relevant for water resources assessments. Within MENA-LDAS, the Catchment Land Surface Model (CLSM) simulates the location, timing, and amount of water applied through agricultural irrigation practices over the region from 2002-2012. In addition to simulating the irrigation impact on evapotranspiration, soil moisture, and runoff, we also investigate regional changes in terrestrial water storage (TWS) observed from the Gravity Recovery and Climate Experiment (GRACE) and simulated by CLSM.

Bolten, John↗

GeoDash: Assisting Visual Image Interpretation in Collect Earth Online by Leveraging Big Data on Google Earth Engine

Collect Earth Online (CEO) is a free and open online implementation of the FAO Collect Earth system for collaboratively collecting environmental data through the visual interpretation of Earth observation imagery. The primary collection mechanism in CEO is human interpretation of land surface characteristics in imagery served via Web Map Services (WMS). However, interpreters may not have enough contextual information to classify samples by only viewing the imagery served via WMS, be they high resolution or otherwise. To assist in the interpretation and collection processes in CEO, SERVIR, a joint NASA-USAID initiative that brings Earth observations to improve environmental decision making in developing countries, developed the GeoDash system, an embedded and critical component of CEO. GeoDash leverages Google Earth Engine (GEE) by allowing users to set up custom browser-based widgets that pull from GEE's massive public data catalog. These widgets can be quick looks of other satellite imagery, time series graphs of environmental variables, and statistics panels of the same. Users can customize widgets with any of GEE's image collections, such as the historical Landsat collection with data available since the 1970s, select date ranges, image stretch parameters, graph characteristics, and create custom layouts, all on-the-fly to support plot interpretation in CEO. This presentation focuses on the implementation and potential applications, including the back-end links to GEE and the user interface with custom widget building. GeoDash takes large data volumes and condenses them into meaningful, relevant information for interpreters. While designed initially with national and global forest resource assessments in mind, the system will complement disaster assessments, agriculture management, project monitoring and evaluation, and more.

SERVI↗

Celestial Mapping System

Celestial Mapping System (CMS) is a desktop application that provides a toolkit of features for visualization and analysis of celestial bodies, beginning with a 3D lunar globe. Although there are lunar mapping products publicly available, they use old data from lunar missions, have no native desktop version, and they are mostly 2D. CMS addresses this by providing high-resolution datasets from recent lunar missions, accurate elevation data to display and read 3D terrain, and is built on top of World Wind Java library which provides a rich set of functionality and the ability to easily expand to other celestial bodies. CMS is also looking at implementing features to support situational awareness, path optimization and resource assessment, which will be of use in upcoming missions to the lunar surface. CMS utilizes geospatial tools such as QGIS and GDAL to test and modify planetary data. Other features include the ability to enable specific place names, a measurement toolbox, terrain profiler, the ability to view the moon in stereo, navigation capabilities, and an interactive visit to the Apollo landing sites which showcase 3D objects of the astronauts and lunar landers. In the world of planetary mapping, CMS aims to significantly improve upon existing functionalities, and bring new tools, that will be useful to the planetary science community and mission planners.

Kaitlyn Dickinson↗

A High-Resolution Land Data Assimilation System Optimized for the Western United States

The Western Land Data Assimilation System (WLDAS) is a custom instance of the NASA Land Information System that combines land surface parameters, meteorological forcing data, and satellite products within a land surface model to produce daily estimates of the water and energy budget variables for the western United States. WLDAS was configured through discussions with partners, with the goal of groundwater sustainability planning for the state of California in mind. The publicly available output dataset has a 1-km grid resolution and spans 1979–present, which makes it suitable for water resources assessments. The data are also able to contextualize the recent drought events in California. Assimilation of Leaf Area Index, which is demonstrated herein to improve simulation over agricultural areas in California, specifically in terms of evapotranspiration in irrigation regions, will be included along with other data assimilation in subsequent releases of WLDAS.

land surface modeling↗

Surface Biology and Geology (SBG) Thermal Infrared (TIR) Free -Flyer Concept

Scientists and engineers from the United States and Italy are developing a thermal infrared (TIR) free-flyer concept that forms an essential element of the NASA Surface Biology & Geology (SBG) designated observable and the greater NASA Earth System Observatory (ESO), which also includes observations of aerosols, clouds, convection, and precipitation; mass change; and surface deformation & change.In response to the recommendations from the 2017 National Academies decadal survey for Earth science, NASA initiated the SBG designated observable with five key research and applications focus areas: ecosystems and natural resources, hydrology, weather, climate, and solid Earth. SBG includes spaceborne measurements of hyperspectral imagery in the visible to shortwave infrared (0.4-2.5 um) and multispectral imagery in the mid and thermal infrared (3-12 um) that provide the remote sensing data needed to inform each research and applications area. High-level TIR data products include Earth surface temperature & emissivity, evapotranspiration, substrate composition, volcanic plumes, and high-temperature features. While the science, applications, and technology build on prior mission studies conducted for more than a decade, it has only been recently that a joint team of scientists and engineers from the NASA Jet Propulsion Laboratory (JPL), Agenzia Spaziale Italiana (ASI), Istituto Nazionale Geofisica e Volcanologia (INGV), and the Istituto Nazionale Astrofisica (INAF) have developed a compelling concept for a TIR free-flyer. In this concept, the TIR instrument is an eight-band radiometer. Seven of the bands are between 3 and 12 um with an additional band at 1.65 um. The instrument’s 68.8 deg total viewing angle and the free-flyer’s 665 km operational altitude results in a ground sampling distance (GSD) of <60 m at nadir, produces a swath width of 935 km, and allows for a 2-3-day revisit time. A two-band visible and near infrared (VNIR) camera, with <30 m GSD at nadir and 935 km swath width, will complement the TIR instrument. VNIR high-level data products include top & bottom of atmosphere reflectance and normalized difference vegetation indices (NDVI). The TIR instrument and VNIR camera will be mounted on a PLATiNO+ spacecraft, a multi-application, reconfigurable, and scalable platform. The launcher selected for the TIR free-flyer is the VEGA-C. To maximize the science and applications benefits the SBG-TIR free-flyer team are collaborating with personnel from the ESA Land Surface Temperature Monitoring mission (LSTM) as well individuals from the Thermal Infrared Imaging Satellite for High-resolution Natural resource Assessment (TRISHNA), a joint mission by CNES and ISRO. Pre-Phase A concept studies for the SBG-TIR free-flyer commenced in the spring 2021. This allows for the concept to be refined; for technical risks to be identified and mitigated, as necessary; and strategies for reducing the development schedule to be defined and assessed before conducting a NASA-ASI Mission Concept Review (MCR) in the spring of 2022 and a NASA Key Decision Point-A (KDP-A) as early as the summer of 2022. These are key milestones in being able to launch and begin operating the SBG-TIR free-flyer in the second half of the decade, so that many of the questions posed by the National Academies in the 2017 decadal survey can be answered.

Fabrizia-Buongiorno, Maria↗

Mass Spectrometer Observing Lunar Operations (MSoLo)

Introduction: In 2019, the National Aeronautics and Space Administration (NASA) announced that it would seek to have humans return to the moon by 2024 in the hopes of establishing a more sustainable lunar presence by 2028. This goal comes with many challenges, one of upmost importance will be to utilize resources that can be found on the moon. Water, which has been identified in the lunar Polar Regions, will be a key resource for in-situ resource utilization (ISRU), as it is capable of being processed for vehicular fuel, as well as life support systems materials such as oxygen. Upcoming Commercial Lunar Payload Services (CLPS) missions will be critical for these resource assessments. Methods: A modified commercial off-the-shelf (COTS) mass spectrometer developed at Kennedy Space Center known as MSolo, consisting of a quadrupole mass filter and space rated electronics undergoes testing and modifications in order to study operational parameters to unconventional approaches needed in flight situations. In general, MSolo operates in the 0-100 m/z range with the ability to detect with a faraday cup (FC) or an electron multiplier (EM) for enhanced detection. A crossbeam (XB) ionization source is used. Preliminary Data: Prior to construction, little information was available on how the MSolo system would perform at lunar like environments, factors such as temperatures (possible fluctuations from 70 to -45 °C), vibrations from launch and their side effects, the general ability to operate while the entire system (hardware and electronic components) were in a vacuum environment, were factors that while know to flight instruments, were something new to a modified COTS system. As components start to warm up, temperature becomes a key factor (ie. heat can no longer escape the electronics as no atmosphere is present), therefore it becomes crucial to find new ways to maintain stable signals and keep the instrument tuned. Calibration itself becomes an important parameter that needs to be performed while maintaining all flight like characteristics. Even the structure itself of MSolo’s sensor needed to be changed to survive the verification parameters needed to be approved for flight. Most important, all the modifications made to the COTS system have to keep the instrument working at the same specifications of the standard commercial systems. Novel Aspect: Results gathered provide key parameters that will assist to the unconventional mass spectrometry approaches of the upcoming CLPS missions to which MSolo has been selected to.

MSolo↗

A Multi-Pixel Split-Window Approach to Sea Surface Temperature Retrieval from Thermal Imagers with Relatively High Radiometric Noise: Preliminary Studies

In the following decade(s), a set of satellite missions carrying thermal infrared (TIR) imagers with a relatively high noise equivalent differential temperature (NEdT) are expected, e.g., the high resolution TIR imagers flying on the future Thermal infraRed Imaging Satellite for High-resolution Natural resource Assessment (TRISHNA), Land Surface Temperature Monitoring (LSTM) and NASA-JPL/ASI Surface Biology and Geology Thermal (SBG) missions or the secondary payload on board the ESA Earth Explorer 10 Harmony. The instruments on board these missions are expected to be characterized by an NEdT of ⪆0.1 K. In order to reduce the impact of radiometric noise on the retrieved sea surface temperature (SST), this study investigates the possibility of applying a multi-pixel atmospheric correction based on the hypotheses that (i) the spatial variability scales of radiatively active atmospheric variables are, on average, larger than those of the SST and (ii) the effect of atmosphere is accounted for via the split window (SW) difference. Based on 32 Sentinel 3 SLSTR case studies selected in oceanic regions where SST features are mainly driven by meso to sub-mesoscale turbulence (e.g., corresponding to major western boundary currents), this study documents that the local spatial variability of the SW difference term on the scale of ≃3 × 3 km2 is comparable with the noise associated with the SW difference. Similarly, the power spectra of the SW term are shown to have, for small scales, the behavior of white noise spectra. On this basis, we suggest to average the SW term and to use it for the atmospheric correction procedure to reduce the impact of radiometric noise. In principle, this methodology can be applied on proper scales that can be dynamically defined for each pixel. The applicability of our findings to high-resolution TIR missions is discussed and an example of an application to ECOSTRESS data is reported.

sea surface temperature↗

Evaluation of Photodiode and Thermopile Pyranometers for Photovoltaic Applications: Preprint

Accurately determining PV module performance in the field requires measurement of solar irradiance reaching the PV panel at a high level of accuracy and known uncertainty. Silicon detectors used in various solar energy measuring instruments including reference cells are potentially an attractive choice for multiple reasons that include faster responsivity than thermopile detectors, cheaper cost and lower maintenance. The main drawback though is the fact that the silicon detectors are only spectrally responsive in a narrow part of the solar spectrum. Therefore, to determine broadband solar irradiance a calibration factor that converts the narrowband response to broadband is required. Normally this calibration factor is a single number determined under standard conditions but then used for various scenarios including varying air-mass, panel orientation and atmospheric conditions. This would not have been an issue if all wavelengths that form the broadband spectrum responded uniformly to atmospheric constituents. Unfortunately the scattering and absorption signature varies widely across wavelengths and the calibration factor computed under certain test conditions is not appropriate for other conditions. This paper lays out the issues that will arise from the use of silicon detectors for PV performance measurement in the field. We also present a comparison of simultaneous spectral and broadband measurements from silicon and thermopile detectors and estimated measurement errors when using silicon devices for both array performance and resource assessment.

14 SOLAR ENERGY↗

Three-Dimensional Geothermal Fairway Mapping: Examples From the Western Great Basin, USA

Elevated permeability along fault systems provides pathways for circulation of geothermal fluids. Accurate location of such fluid flow pathways in the subsurface is crucial to future geothermal development in order to both accurately assess resource potential and mitigate drilling costs by increasing drilling success rates. Employing a variety of surface and subsurface data sets, we present detailed 3D geologic analyses of two Great Basin geothermal systems, the actively producing Brady’s geothermal system and a ‘greenfield’ geothermal prospect at Astor Pass, Nevada. 3D modeling provides the framework for quantitative structural analyses. We combine 3D slip and dilation tendency analysis along fault zones and calculations of fault intersection density in the two geothermal systems with the locations of lithologies capable of supporting dense, interconnected fracture networks. The collocation of these permeability promoting characteristics with elevated heat represent geothermal ‘fairways’, areas with ideal conditions for geothermal fluid flow. Location of geothermal fairways at high resolution in 3D space can help to mitigate the costs of geothermal exploration by providing discrete drilling targets and data-based evaluations of reservoir potential.

15 GEOTHERMAL ENERGY↗

Fast All-Sky Radiation Model for Solar Applications (FARMS): A Brief Overview of Mechanisms, Performance, and Applications: Preprint

Solar radiation can be computed using radiative transfer models, such as the Rapid Radiation Transfer Model (RRTM) and its general circulation model applications, and used for various energy applications. Due to the complexity of computing radiation fields in aerosol and cloudy atmospheres, simulating solar radiation can be extremely time-consuming, but many approximations--e.g., the two-stream approach and the delta-M truncation scheme--can be utilized. To provide a new fast option for computing solar radiation, we developed the Fast All-sky Radiation Model for Solar applications (FARMS) by parameterizing the simulated diffuse horizontal irradiance and direct normal irradiance for cloudy conditions from the RRTM runs using a 16-stream discrete ordinates radiative transfer method. The solar irradiance at the surface was simulated by combining the cloud irradiance parameterizations with a fast clear-sky model, REST2. To understand the accuracy and efficiency of the newly developed fast model, we analyzed FARMS runs using cloud optical and microphysical properties retrieved using GOES data from 2009-2012. The global horizontal irradiance for cloudy conditions was simulated using FARMS and RRTM for global circulation modeling with a two-stream approximation and compared to measurements taken from the U.S. Department of Energy's Atmospheric Radiation Measurement Climate Research Facility Southern Great Plains site. Our results indicate that the accuracy of FARMS is comparable to or better than the two-stream approach; however, FARMS is approximately 400 times more efficient because it does not explicitly solve the radiative transfer equation for each individual cloud condition. Radiative transfer model runs are computationally expensive, but this model is promising for broad applications in solar resource assessment and forecasting. It is currently being used in the National Solar Radiation Database, which is publicly available from the National Renewable Energy Laboratory at http://nsrdb.nrel.gov.

14 SOLAR ENERGY↗

Hydrothermal Liquefaction of Wastewater Treatment Plant Solids

Feedstock cost is the greatest barrier to the commercial production of biofuels. The merits of any thermochemical or biological conversion process are constrained by their applicability to the lowest cost feedstocks. At PNNL, a recent resource assessment of wet waste feedstocks led to the identification of waste water treatment plant (WWTP) solids as a cost-negative source of biomass. WWTP solids disposal is a growing environmental concern [1, 2] and can account for up to half of WWTP operating costs. The high moisture content is well-suited for hydrothermal liquefaction (HTL), avoiding the costs and parasitic energy losses associated with drying the feedstock for incineration. The yield and quality of biocrude and upgraded biocrude from WWTP solids is comparable to that obtained from algae feedstocks but the feedstock cost is $500-1200 less per dry ton. A collaborative project was initiated and directed by the Water Environment & Reuse Foundation (WERF) and included feedstock identification, dewatering, shipping to PNNL, conversion to biocrude by HTL, and catalytic hydrothermal gasification of the aqueous byproduct. Additional testing at PNNL included biocrude upgrading by catalytic hydrotreatment, characterization of the hydrotreated product, and a preliminary techno-economic analysis (TEA) based on empirical results. This short article will cover HTL conversion and biocrude upgrading. The WERF project report with complete HTL results is now available through the WERF website [3]. The preliminary TEA is available as a PNNL report [4].

biocrude upgrading↗

Development of a Dynamic Lidar Uncertainty Framework

As wind turbine sizes increase and wind energy expands to more complex and remote sites, remote-sensing devices such as lidars are expected to play a key role in wind resource assessment and power performance testing. The switch to remote-sensing devices represents a paradigm shift in the way the wind industry typically obtains and interprets measurement data for wind energy. For example, the measurement techniques and sources of uncertainty for a remote-sensing device are vastly different from those associated with a cup anemometer on a meteorological tower. Current IEC standards for quantifying remote sensing device uncertainty for power performance testing consider uncertainty due to mounting, calibration, and classification of the remote sensing device, among other parameters. Values of the uncertainty are typically given as a function of the mean wind speed measured by a reference device and are generally fixed, leading to climatic uncertainty values that apply to the entire measurement campaign. However, real-world experience and a consideration of the fundamentals of the measurement process have shown that lidar performance is highly dependent on atmospheric conditions, such as wind shear, turbulence, and aerosol content. At present, these conditions are not directly incorporated into the estimated uncertainty of a lidar device. In this presentation, we describe the development of a new dynamic lidar uncertainty framework that adapts to current flow conditions and more accurately represents the actual uncertainty inherent in lidar measurements under different conditions. In this new framework, sources of uncertainty are identified for estimation of the line-of-sight wind speed and reconstruction of the three-dimensional wind field. These sources are then related to physical processes caused by the atmosphere and lidar operating conditions. The framework is applied to lidar data from a field measurement site to assess the ability of the framework to predict errors in lidar-measured wind speed. The results show how uncertainty varies over time and can be used to help select data with different levels of uncertainty for different applications, for example, low uncertainty data for power performance testing versus all data for plant performance monitoring.

17 WIND ENERGY↗

Microalgae Feedstocks for Aviation Fuels

There is significant global interest in developing, testing, and using alternative jet fuels for both commercial and military use in an effort to create a sustainable and stable fuel supply while reducing greenhouse gas emissions. Currently, the aviation industry is entirely dependent on a finite-supply of petroleum based fuel sourced in part by politically and economically unstable regions of the world. Commercial jet fuel use within the contiguous United States (CONUS) was 17.8 billion gallons per year (BGY) in 2009, while jet fuel use in 2010 by the U.S. Air Force (USAF), Navy, and Army was 1.5 BGY, 0.6 BGY, and 0.8 BGY, respectively (Carter et al., 2011). U.S. commercial and military aviation sectors have set ambitious near-term alternative fuel and environmental performance targets. This includes a tentative Federal Aviation Administration (FAA) goal of 1 BGY alternative fuel use by commercial aircraft by 2018. The USAF has set a target of 50% for USAF domestic aviation via alternative fuels by 2016 (0.73 BGY), and 50% of the Navy’s total energy consumption afloat (0.3 BGY) will come from alternative fuels by 2020 (Carter et al., 2011). If these targets become policy, at least 2 BGY of domestically-produced alternative jet fuel will be required by 2020. The Energy Independence and Security Act (EISA) of 2007 established production requirements for domestic alternative fuels under the Renewable Fuel Standard (RFS). For example, 36 billion gallons of renewable fuel must be produced by 2022, of which 21 billion gallons shall be advanced biofuels. EISA defines advanced biofuels as non-corn starch derived biofuels having lifecycle greenhouse gas emissions 50% lower than gasoline. There a number of potential fuel pathways for meeting the RFS. One of these is biomass-based diesel, including jet fuel (Schnepf and Yacobucci, 2013). The U.S. Department of Energy (DOE) Bioenergy Technologies Office (BETO) has a stated goal in its 2013 Multi-Year Program Plan (USDOE, 2013) to support the RFS through development of “…commercially viable biomass utilization technologies to encourage the creation of a new domestic bioenergy industry…”. BETO has also recognized the potential for aviation biofuels to support the bioenergy industry, seeing drop-in bio-based jet fuels one of the viable alternatives for the aviation industry and the military to meet their ambitious near-term GHG reduction targets (USDOE, 2014). One of the important Multi-year Program Plan Targets (USDOE, 2013) is to establish feedstock resource assessment models to evaluate the geographic, economic, quality and environmental criteria for which 20 million metric tons of ash free dry weight (AFDW) algal biomass can be produced by 2022. Toward meeting the EISA requirements, algal biofuels may offer a number of advantages. They can produce a range of biofuel feedstocks suitable for diesel and aviation fuels. Microalgae, on a strain-specific basis, can be cultivated using impaired water including saline, and/or brackish pumped groundwater or seawater, treated industrial wastewater, municipal sewage effluent, and produced water generated from oil and gas drilling operations. Additionally, microalgae require nitrogen and phosphates as essential nutrients and could provide water treatment co-benefits to municipalities, industry, and the environment.

algae↗