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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Embodied energy and carbon from the manufacture of cadmium telluride and silicon photovoltaics

Here, looking beyond the traditional cost and efficiency metrics of photovoltaics (PV), this work evaluates the impact of embodied energy, embodied carbon, and energy payback time of two dominant technologies (CdTe and Si) on global decarbonization goals. The relative effects of PV technology type, technological advances, energy grid mix, and recycling are evaluated in terms of fostering decarbonization goals. If the highest carbon-intensity scenarios are realized, 2%-14% of the remaining estimated global carbon budget might be consumed to manufacture modules without including their balance of systems. Applying a carbon cost indicates that CdTe might have an additional value of $\$$0.02-$\$$0.04/W relative to Si PV manufactured with the same energy mix. Due to the scale of the challenge, any actions leading to an increased deployment of thin-film PV and/or a significant decrease in the deployed PV's embodied carbon through changing the manufacturing grid mix have demonstrable value in helping the world stay within its remaining estimated carbon budget.

14 SOLAR ENERGY↗
DOE OSTI2022

Multilevel peel-off patterning of a prototype semitransparent organic photovoltaic module

Semitransparent organic photovoltaics (ST-OPVs) with applications to power generating windows have shown substantial increases in power conversion efficiency (PCE) and average photopic transmission (APT) at the laboratory scale. Here, the demonstration of similarly efficient, large-scale ST-OPV modules with geometric fill factors (GFF) approaching 100%, however, remains a challenge. Here, we employ a multilevel peel-off patterning method that can achieve micron-scale resolution without exposing chemically sensitive organic materials to solvents. Eight, 4 cm × 0.4 cm cells are connected in series to realize a prototype ST-OPV module with GFF = 95.8%, with PCE = 7.3 ± 0.2% under simulated AM 1.5G illumination at 1 sun intensity, APT = 41.8 ± 1.4%, and a light utilization efficiency of LUE = 3.1 ± 0.1%. A neutral color STOPV module is also demonstrated with 1.7 ± 0.1% and International Commission on Illumination (CIE) LAB coordinates of (L*, a*, b*) = (53.7, -1.9, -3.9).

14 SOLAR ENERGY↗
DOE OSTI2025

Roadmap to 100 GWDC: Scientific and supply chain challenges for CdTe photovoltaics

This roadmap highlights pathways to expand the CdTe module manufacturing capacity per year to 100 GW DC by 2030 by improving Te extraction from existing supply chains, minimizing Te usage in modules by leveraging thinner absorbers, and focusing research efforts in key areas to improve module efficiencies. Both scientific and supply chain innovations will be necessary to maintain the high compound annual growth rate of the CdTe photovoltaic (PV) industry and cement its role as a key technology for multi-TW-scale PV deployment.

14 SOLAR ENERGY↗
DOE OSTI2022

Optimizing spectral and morphological match of nonfullerene acceptors toward efficient indoor organic photovoltaics with enhanced light source adaptability

High-performance indoor organic photovoltaics (IOPV) require large-bandgap material systems to absorb visible light efficiently and reduce energy loss. However, state-of-the-art non-fullerene acceptors (NFAs) have absorptions in the near-infrared region and are thus not suitable for IOPV applications. Herein, we report a series of large-bandgap (>1.70 eV) NFAs named FCC-Cl-C8, FCC-Cl-4Ph and FCC-Cl-6Ph by modifying the alkyl side chains with alkylphenyl chains partially or completely. Results show that the bulky alkylphenyl side chains can finely tune the absorption properties of the NFAs and also affect their morphological properties. Interestingly, the best-performing NFA is the one (named FCC-Cl-4Ph) with partial alkyl and alkylphenyl substitutions, which blue-shift the absorption of the NFAs while minimizing the negative morphological effect of the bulky alkylphenyl chains. As a result, FCC-Cl-4Ph can achieve excellent indoor efficiencies over 29% under a 3000 K LED lamp at 1000 lux and show better solution processability over FCC-Cl-C8. More importantly, FCC-Cl-4Ph can maintain high indoor performance (29.7–26.8% at 1000 lux) under a wide range of indoor lighting spectra (2600, 3000, 4000, and 6500 K LED lamps), which should be due to the blue-shifted spectra of FCC-Cl-4Ph and better matching with various indoor conditions. Finally, this work reveals an interesting structure-property relationship and offers useful strategies for the further design of NFAs toward efficient IOPV devices.

14 SOLAR ENERGY↗
DOE OSTI2022

Incorporating energy justice into utility-scale photovoltaic deployment: A policy framework

Utility-scale photovoltaic (PV) installations made up 77 GW (6%) of installed capacity in the United States, as of the end of 2021. This will grow to more than 500 GW by 2050 under a mid-case projection or more than 800 GW if solar costs decline more rapidly. While utility-scale PV is projected to grow rapidly, to date, unlike energy efficiency or distributed PV, utility-scale PV has not been used to provide substantial financial benefits to underserved communities, either through ownership, financing of assets, or direct electricity bill reduction. We assess two mechanisms through which utility-scale PV could benefit underserved communities. We find that while a framework for direct electricity bill reduction can be meaningful to customers, this mechanism falls short of providing restorative justice via wealth creation for minority-owned businesses. In contrast, we find that a framework for procurement of utility-scale PV by public and private entities from PV projects that are financed, owned, and/or developed by minority-owned businesses can provide this restorative justice benefit, and thereby facilitate an equitable energy transition. We conclude with concrete recommendations for new policies and programs to ensure that the benefits of utility-scale PV systems are distributed to underserved communities.

14 SOLAR ENERGY↗
DOE OSTI2020

Photovoltaic Cleaning Frequency Optimization Under Different Degradation Rate Patterns

Dust accumulation significantly affects the performance of photovoltaic modules and its impact can be mitigated by various cleaning methods. Optimizing the cleaning frequency is essential to minimize the soiling losses and, at the same time, the costs. However, the effectiveness of cleaning lowers with time because of the reduced energy yield due to degradation. Additionally, economic factors such as the escalation in electricity price and inflation can compound or counterbalance the effect of degradation on the soiling mitigation profits. The present study analyzes the impact of degradation, escalation in electricity price and inflation on the revenues and costs of cleanings and proposes a methodology to maximize the profits of soiling mitigation of any system. Here, the energy performance and soiling losses of a 1 MW system installed in southern Spain were analyzed and integrated with theoretical linear and nonlinear degradation rate patterns. The Levelized Cost of Energy and Net Present Value were used as criteria to identify the optimum cleaning strategies. The results showed that the two metrics convey distinct cleaning recommendations, as they are influenced by different factors. For the given site, despite the degradation effects, the optimum cleaning frequency is found to increase with time of operation.

14 SOLAR ENERGY↗
DOE OSTI2021

Impact of duration and missing data on the long-term photovoltaic degradation rate estimation

Accurate quantification of photovoltaic (PV) system degradation rate (R D ) is essential for lifetime yield predictions. Although R D is a critical parameter, its estimation lacks a standardized methodology that can be applied on outdoor field data. The purpose of this paper is to investigate the impact of time period duration and missing data on R D by analyzing the performance of different techniques applied to synthetic PV system data at different linear R D patterns and known noise conditions. The analysis includes the application of different techniques to a 10-year synthetic dataset of a crystalline Silicon PV system, with emulated degradation levels and imputed missing data. Here, the analysis demonstrated that the accuracy of ordinary least squares (OLS), year-on-year (YOY), autoregressive integrated moving average (ARIMA) and robust principal component analysis (RPCA) techniques is affected by the evaluation duration with all techniques converging to lower R D deviations over the 10-year evaluation, apart from RPCA at high degradation levels. Moreover, the estimated R D is strongly affected by the amount of missing data. Filtering out the corrupted data yielded more accurate R D results for all techniques. It is proven that the application of a change-point detection stage is necessary and guidelines for accurate R D estimation are provided.

14 SOLAR ENERGY↗
DOE OSTI2022

The economic value of photovoltaic performance loss mitigation in electricity spot markets

Photovoltaic (PV) performance is affected by reversible and irreversible losses. These can typically be mitigated through responsive and proactive operations and maintenance (O&M) activities. However, to generate profit, the cost of O&M must be lower than the value of the recovered electricity. This value depends both on the amount of recovered energy and on the electricity prices, which can vary significantly over time in spot markets. The present work investigates the impact of the electricity price variability on the PV profitability and on the related O&M activities in Italy, Portugal, and Spain. Here, it is found that the PV revenues varied by 1.6 × to 1.8 × within the investigated countries in the last 5 years. Moreover, forecasts predict higher average prices in the current decade compared to the previous one. These will increase the future PV revenues by up to 60% by 2030 compared to their 2015–2020 mean values. These higher revenues will make more funds available for better maintenance and for higher quality components, potentially leading to even higher energy yield and profits. Linearly growing or constant price assumptions cannot fully reproduce these expected price trends. Furthermore, significant price fluctuations can lead to unexpected scenarios and alter the predictions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

The electric vehicles-solar photovoltaics Nexus: Driving cross-sectoral adoption of sustainable technologies

Residential and transportation energy consumption account for more than one-half of the overall energy consumption in the United States. Adoption of electric vehicles (EVs) can play a key role in decarbonizing the transportation sector, while the adoption of renewable energy sources (e.g., solar photovoltaics [PVs]) could bring similar benefits to the residential energy sector and in turn support transport electrification. Although the market shares for both EVs and PVs continue to grow, both of these emerging technologies are deployed rather disjointly, without considering the existence of potential similarities among users who own (or aspire to own) these technologies. This might be due to lack of understanding of the behavioral interdependence in consumer preferences toward these technologies. To fill this gap in knowledge, this study utilizes data from the 2018 WholeTraveler Transportation Behavior Study to develop an integrated model system that explores interactive EV and PV adoption behaviors. A structural equation model is employed that incorporates direct effects as well as error correlations among the adoption behaviors for EVs and PVs. Model results indicate that the adoption behavior for both these technologies is indeed interconnected and significantly influenced by attitudes, values, and personality traits. Findings from this research suggest that incentives (e.g., subsidies) that drive bundled adoption of EV-PV systems could accelerate the adoption of both of these sustainable technologies. In conclusion, this study highlights the need to consider transport and building energy-efficient technology adoption behavior in a single integrated structure.

14 SOLAR ENERGY↗
DOE OSTI2024

Impacts of photovoltaic solar energy on soil carbon: A global systematic review and framework

Globally, solar energy is anticipated to be the primary source of electricity as early as 2050, and the greatest additions in capacity are currently in the form of large, ground-mounted photovoltaic solar energy facilities (GPVs). Growing interest lies in understanding and anticipating opportunities to increase soil carbon sequestration across the footprint and perimeter of both conventional and multi-use GPVs (e.g., ecovoltaics, agrivoltaics, and rangevolatics), especially as operators increasingly deputize as land managers. To date, studies on the relationship between soils and PV solar energy are limited to unique, localized sites. This study employed a systematic review to (i) identify a global corpus of 18 studies on interactions between GPVs and soils, (ii) collect and characterize 113 soil and soil-related experimental variables interacting with GPVs from this corpus, and (iii) synthesize trends among these experimental variables. Next, this study combined data from the systematic review with an iterative, knowledge co-production approach to produce a conceptual model for the study of soil and GPV interactions that applies to multiple installation types, scales, and contexts where GPVs are deployed, and identified research opportunities, threats, and priorities. This study's baseline understanding, conceptual model, and co-produced knowledge confer unique insight into the feasibility of combining soil carbon sequestration with the climate change mitigation potential of PV solar energy.

agrivoltaics↗
DOE OSTI2020

Development of high concentration photovoltaics (HCPV) power plants in the US Southwest: Economic assessment and sensitivity analysis

High concentration photovoltaic (HCPV) technologies offer several advantages over typical PV systems. In this study, a detailed economic assessment and sensitivity analysis of deploying HCPV plants in the US southwest is performed. To do this, a 20 MWdc HCPV power plant is designed using the System Advisor Model (SAM) and is evaluated from both technical and financial aspects. The sensitivity analysis shows that reducing the installed cost per capacity of the HCPV system can significantly improve the economics and reduce the levelized cost of electricity (LCOE) and levelized power purchase agreement (LPPA). Also, providing proper incentives including both investment tax credits (ITC) and production tax credit (PTC), loan debt ratio, and interest rate are among the most influential parameters. The analysis shows that with the 30% ITC, the LCOE, and LPPA of the designed HCPV projects are between $65.4/MWh and $69.3/MWh and between $71.0/MWh and $75.2/MWh, respectively. The estimated LCOE and LPPA values are almost 50% higher than the utility-scale PV projects. If proper funding is provided to continue the support of the HCPV system, they would become more economical and competitive with PV plants. Federal and state government policies must also be established to advocate HCPV systems.

14 SOLAR ENERGY↗
DOE OSTI2021

State-by-State comparison of combined heat and power to photovoltaic installations at manufacturing facilities with heat and power loads

Manufacturing facilities with large electricity and steam loads commonly meet those loads with a grid and boiler (GB) system configuration. In this study, two alternatives, a natural gas turbine cycle driven combined heat and power (CHP) system configuration and a grid boiler system augmented with photovoltaics (GB-PV), are investigated sustainable manufacturing in reference to the GB system configuration. For this purpose, their discounted payback period (DPP), carbon dioxide (CO 2 ) and nitrogen oxides (NO x ) emission reductions, and primary fossil energy impacts are calculated. The major contribution of this study is that it directly compares the application of both CHP and PV technologies at an assumed manufacturing facility in all 50 states of the United States. This highlights the location-specific impacts of the facility. The examined manufacturing facility utility requirements are 5 MW of power and over 12,000 kg/h of 250 kPa and 400 K saturated steam. A DPP of less than 25 years, the technology lifetime, is found in 44 states for the CHP system configuration and 6 states for the GB-PV system configuration. GB-PV and CHP cost-effectively reduce CO 2 in 44 and 38 states, respectively. CHP is better for NO x reduction, whereas GB-PV is better for primary fossil energy reduction.

14 SOLAR ENERGY↗
DOE OSTI2020

A review of Sb 2 Se 3 photovoltaic absorber materials and thin-film solar cells

Energy generated from environmentally friendly, cost-effective solar cells is a key aspect for developing a clean renewable-energy economy. Non-toxic and Earth-abundant materials with high absorption coefficient (>10 5 cm -1 ) and optimal bandgap (1-1.5 eV) have received great attention as photovoltaic (PV) absorber layers during the last few decades. Among them, antimony selenide (Sb 2 Se 3 ) has been a promising PV absorber, with steadily increasing power-conversion efficiency (PCE) compared to other emerging compounds. Very recent studies showed that high-quality ZnO:Al/ZnO/CdS/TiO 2 /Sb 2 Se 3 /MoSe 2 /Mo devices with PCE of 9.2% can be fabricated using cost-effective novel compounds. Considering these recent advances, this article provides an overview of the material properties of Sb2Se3 thin films and the recent progress made with Sb 2 Se 3 -based solar cells. Furthermore, analysis of Sb 2 Se 3 -based thin-film solar cells has also shown that the devices have relatively good light management due to their suitable bandgap and high absorption coefficient, whereas carrier management, i.e. collection efficiency of photo-generated carriers, needs significant improvement. Overall, this study provides background knowledge on material properties and device performance and suggests main research directions to overcome the limiting factors of solar cell performance.

14 SOLAR ENERGY↗
DOE OSTI2020

Comparative study on the overall energy performance between photovoltaic and Low-E insulated glass units

In this report a novel semi-transparent building integrated photovoltaic (BIPV) laminate was developed and introduced in this paper. It was produced by cutting standard mono-crystalline silicon solar cells into small strips and then making electrical connections between each strip before laminating the cells between two layers of glass. The overall energy performance and energy saving potential of the BIPV insulated glass unit (IGU) under real world conditions were identified through a side by side comparative study. Compared to the reference IGU, the BIPV IGU had lower solar heat gain coefficient (SHGC) but much higher U-factor. The average HVAC electricity saving of the BIPV IGU was about 10% relative to the reference IGU. Daylighting measurement and analysis were carried out to evaluate the trade-offs associated with the BIPV IGU between daylight, glare, and lighting energy use. The results indicated that the BIPV IGU is better than the reference IGU in reducing discomfort glare. However, if the most conservative viewpoint near the window is used for the assessment, a lower transmittance BIPV IGU is required to bring the overall discomfort levels below the perceptible level. Lastly, the net energy saving potential associated with the novel BIPV IGU was identified based on the power, thermal and daylighting performance. On average, the BIPV IGU saved 16.8% of the total electricity use of the room. Further studies and improvement on the energy conversion efficiency of solar cells, the optimal transmittance as well as the thermal properties would make this technology more energy-efficient and affordable.

14 SOLAR ENERGY↗
DOE OSTI2021

Cohesive and adhesive degradation in PET-based photovoltaic backsheets subjected to ultraviolet accelerated weathering

Delamination between layers in photovoltaic (PV) backsheets is often reported in the literature, causing voids that can collect moisture, diminish module backside heat dissipation, and reduce the backsheet’s effectiveness as a physical barrier. While backsheets with weathering-resistant fluoropolymer outer layers have traditionally been used in modules, more recent backsheets using non-fluoropolymer outer layers, such as polyethylene terephthalate (PET), have been developed. These backsheets have shown signs of premature degradation, and their adhesion degradation, in particular, has not been widely studied. In the present work, the single cantilever beam (SCB) adhesion test was used to quantify the adhesion energy in two commercially available PET-based backsheets. To study the effect of minor changes in formulation, the backsheets were obtained from same manufacturer and product line but during different years. To study the effect of environmental variables on adhesion degradation, the backsheets were subjected to artificial weathering at controlled temperature, humidity, and ultraviolet (UV) radiation in an indoor weathering chamber, and the adhesion energy was quantified at several intervals of exposure time. Layering structure, composition, and adhesion failure mode were compared between the backsheets, using Raman and infrared spectroscopy and thermogravimetric analysis. The results show a large difference in initial (unexposed) adhesion energy between the backsheets, despite very similar structures and compositions. Following exposure, adhesion energy dropped significantly, primarily due to thermo-hydrolytic degradation of the polyurethane (PU)-based adhesive layers. Significant UV-induced adhesion degradation of the PET outer layer surface was also observed. The study represents an important step in understanding adhesion degradation in PET-based backsheets, suggesting ways in which adhesion integrity – and, correspondingly, module service life – can be improved.

14 SOLAR ENERGY↗
DOE OSTI2021

Evaluation of clear-sky and satellite-derived irradiance data for determining the degradation of photovoltaic system performance

Knowing the degradation in performance of a photovoltaic (PV) system over time is important for estimating the lifetime energy produced and the financial return. A key parameter for normalizing performance and determining degradation is the plane-of-array (POA) irradiance. Because accurate long-term POA measurements are not always readily available, three methods of providing irradiance data for determining the degradation rate of PV systems were evaluated—a method using irradiance data modeled with the Ineichen clear-sky model and monthly Linke turbidity coefficients, a method using the supplemental clear-sky irradiance data from the National Solar Radiation Data Base (NSRDB), and a method using the NSRDB solar irradiance data for both cloudy and clear-sky conditions (all-sky). The irradiance data from the three methods were evaluated using measured irradiance data from 1998 through 2018 for the seven-station SURFRAD network and for 3-, 5-, and 10-year periods that might be used for evaluating PV system performance. Only the two clear-sky methods for the 10-year periods had less uncertainty with respect to determining PV system degradation than the expected median degradation rate for PV systems of -0.5%/year to -0.6%/year. Shorter periods and the all-sky method had larger uncertainties, making their use questionable for determining the degradation rates of PV systems.

14 SOLAR ENERGY↗
DOE OSTI2022

Optimizing the Orientation of Solar Photovoltaic Systems Considering the Effects of Irradiation and Cell Temperature Models with Dust Accumulation

To cope with the growing installation capacities of solar photovoltaic (PV) systems in desert areas, it is necessary to revisit the energy production models and the optimal angles of PV panels given the significant impacts of ambient temperature, wind speed, dust accumulation, and cleaning frequency. In this study, these four factors are examined for four PV technologies (polycrystalline, microcrystalline, monocrystalline, and thin-film) at three cities in Jordan, Egypt, and Tunisia using precise ground-level meteo-solar measurements. Different models are compared to estimate the diffuse irradiance, as well as account for the effects of operating temperature, wind speed, and dust accumulation on energy production and optimal tilt and azimuth angles of the panels. The results reveal 1.5 % higher energy production estimates using the isotropic model, compared to the anisotropic model in the summer months. Considering the cooling effect of wind speed decreases the operating cell temperature drops by up to 7.05 % for thin film panels. The annually produced energy decreases by 24 % when the panels are cleaned bi-monthly. When the dust accumulation rate doubles, the energy production decreases by ~10 % for all studied cases. Also, the variations in optimal tilt and azimuth angles with dust accumulation rate are within ~3.0 degrees .

14 SOLAR ENERGY↗
DOE OSTI2023

Field retrieved photovoltaic backsheet survey from diverse climate zones: Analysis of degradation patterns and phenomena

Understanding the impact of climate stressors on photovoltaic (PV) backsheet degradation in real-use conditions is critical to improve the accelerated testing exposures, extend the backsheet lifetime, and increase the confidence in PV reliability. Here, in this work, a total of 33 PV module backsheets were retrieved from six climatic zones worldwide with 2 - 28 years of exposure. These modules included five types of backsheet air-side materials (or outer layer): poly(vinylidene fluoride) (PVDF), poly(tetrafluoroethylene-co-hexafluoropropylene-co-vinylidene fluoride) (THV), poly(vinyl fluoride) (PVF), poly(ethylene terephthalate) (PET), and polyamide (PA). Attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR) was used to identify air-side materials. The degradation induced color change, gloss loss, and chemical material changes analyzed using optical microscopy, differential scanning calorimetry (DSC), scanning electron microscopy (SEM), colorimetry (yellowness index (YI)), and gloss measurements. PVDF, THV, and PVF air-side layer backsheets, in particular PVF, had minimal degradation in the air-side layer appearance and chemical structures after exposure in different climatic zones. The PET air-side backsheets exhibited obvious color increase (22.55 YI units after about 9 years exposure) and the PA/PA/PA backsheets showed large gloss loss (up to 76.4 %) relative to the unexposed backsheets. Severe cracks between cells that penetrated through the entire thickness of backsheets are observed on PA/PA/PA backsheets after 4-6 years of exposure in 6 climatic zones. The current indoor exposure standards were not sufficient to identify this degradation type. However, fluoropolymer based PV backsheets showed lower levels of degradation predictors and increased climatic resistance. Specific samples (PVF) showed little change from baseline after 28 years of outdoor exposure.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗