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At least 577 records · Page 32

Numerical investigation and experimental validation of water condensation in the gas diffusion layer with different properties

Liquid water in porous media hinders the transport of reactant to catalyst layer, where the electrochemical reactions occur, which in turn, reduces performance and lifetime of a proton exchange membrane fuel cell (PEMFC). In this study, two types of gas diffusion layer (GDL) materials are used to study the two-phase saturation distribution in a PEMFC. The correlations between the effective and anisotropic transport properties and porosity of the two GDLs are solved by the pore scale model. In addition, the anisotropic liquid water permeability and the relationship between saturation pressure and capillary pressure is determined by using the Lattice-Boltzmann method. Fuel cell performance as well as liquid water distribution in the GDL using neutron radiography are obtained for validation. Under wet conditions, the cell with Freudenberg GDL performs better than that using Toray GDL, especially at high current densities. The results of the two-phase model simulation show that the peak water saturation for Toray GDL occurs in the catalyst layer and can reach 40%, while the peak water saturation for Freudenberg GDL occurs inside the GDL directly under the ribs and only reaches 25% saturation. The combined results provide key insights to enable high power density operation of a PEMFC through GDL material optimization.

42 ENGINEERING↗

Analysis of IUE observations of hydrogen in comets

The large body of hydrogen Lyman-alpha observations of cometary comae obtained with the International Ultraviolet Explorer satellite has gone generally unanalyzed because of two main modeling complications. First, the inner comae of many bright (gas productive) comets are often optically thick to solar Lyman-alpha radiation. Second, even in the case of a small comet (low gas production) the large IUE aperture is quite small as compared with the immense size of the hydrogen coma, so an accurate model which properly accounts for the spatial distribution of the coma is required to invert the inferred brightnesses to column densities and finally to H atom production rates. Our Monte Carlo particle trajectory model (MPTM), which for the first time provides the realistic full phase space distribution of H atoms throughout the coma was used as the basis for the analysis of IUE observations of the inner coma. The MCPTM includes the effects of the vectorial ejection of the H atoms upon dissociation of their parent species (H2O and OH) and of their partial collisional thermalization. Both of these effects are crucial to characterize the velocity distribution of the H atoms. A new spherical radiative transfer calculation based on our MCPTM was developed to analyze IUE observations of optically thick H comae. The models were applied to observations of comets P/Giacobini-Zinner and P/Halley.

Combi, Michael R.↗

Analysis of IUE Observations of Hydrogen in Comets

The 15-years worth of hydrogen Lyman-alpha observations of cometary comae obtained with the International Ultraviolet Explorer (IUE) satellite had gone generally unanalyzed because of two main modeling complications. First, the inner comae of many bright (gas productive) comets are often optically thick to solar Lyman-alpha radiation. Second, even in the case of a small comet (low gas production) the large IUE aperture is quite small as compared with the immense size of the hydrogen coma, so an accurate model which properly accounts for the spatial distribution of the coma is required to invert the infrared brightnesses to column densities and finally to H atom production rates. Our Monte Carlo particle trajectory model (MCPTM), which for the first time provides the realistic full phase space distribution of H atoms throughout the coma has been used as the basis for the analysis of IUE observations of the inner coma. The MCPTM includes the effects of the vectorial ejection of the H atoms upon dissociation of their parent species (H2O and OH) and of their partial collisional thermalization. Both of these effects are crucial to characterize the velocity distribution of the H atoms. This combination of the MCPTM and spherical radiative transfer code had already been shown to be successful in understanding the moderately optically thick coma of comet P/Giacobini-Zinner and the coma of comet Halley that varied from being slightly to very optically thick. Both of these comets were observed during solar minimum conditions. Solar activity affects both the photochemistry of water and the solar Lyman-alpha radiation flux. The overall plan of this program here was to concentrate on comets observed by IUE at other time during the solar cycle, most importantly during the two solar maxima of 1980 and 1990. Described herein are the work performed and the results obtained.

Combi, Michael R.↗

Influence of transient baroclinic eddies on planetary-scale waves

Low-order models with a mean zonal flow forced by zonally symmetric heating and one planetary-scale wave forced by topography have multiple flow equilibria. Two stable equilibria are characterized by strong zonal flow with low wave amplitude (high index circulation) and weak zonal flow with a high wave amplitude (low index circulation) fixed in phase with the topography. These two states presumably represent normal zonal circulation and a blocking configuration, respectively. When a shorter, baroclinically unstable wave is dded to this low-order model, the planetary-scale wave no longer stays in stable equilibrium states. Instead, the long wave remains in weather regimes or preferred regions in phase space. These regimes are, in general, different from the equilibria of the model with the planetary-scale wave only. Thus, the short unstable wave adds some randomness to planetary-scale circulation and changes its position with respect to the planetary-scale topography. The Reinhold and Pierrehumbert model is further explored here by adding a long-wave in the thermal forcing and exploring wider parameter space. When the symmetric thermal forcing is weak so that the short wave is stable, the planetary scale wave is fixed in amplitude and phase by the asymmetric forcing. However, when the symmetric forcing is increased to an unstable level, the planetary-scale wave becomes less organized. With asymmetric thermal forcing only (i.e., no topography) the long-wave is randomly distributed through phase space. Thermal forcing seems to be less effective in organizing weather regimes than topographic forcing.

Branscome, L. E.↗

Formation of the low-resistivity compound Cu{sub 3}Ge by low-temperature treatment in an atomic hydrogen flux

The systematic features of the formation of the low-resistivity compound Cu{sub 3}Ge by low-temperature treatment of a Cu/Ge two-layer system in an atomic hydrogen flux are studied. The Cu/Ge two-layer system is deposited onto an i-GaAs substrate. Treatment of the Cu/Ge/i-GaAs system, in which the layer thicknesses are, correspondingly, 122 and 78 nm, in atomic hydrogen with a flux density of 10{sup 15} at cm{sup 2} s{sup –1} for 2.5–10 min at room temperature induces the interdiffusion of Cu and Ge, with the formation of a polycrystalline film containing the stoichiometric Cu{sub 3}Ge phase. The film consists of vertically oriented grains 100–150 nm in size and exhibits a minimum resistivity of 4.5 µΩ cm. Variations in the time of treatment of the Cu/Ge/i-GaAs samples in atomic hydrogen affect the Cu and Ge depth distribution, the phase composition of the films, and their resistivity. Experimental observation of the synthesis of the Cu{sub 3}Ge compound at room temperature suggests that treatment in atomic hydrogen has a stimulating effect on both the diffusion of Cu and Ge and the chemical reaction of Cu{sub 3}Ge-compound formation. These processes can be activated by the energy released upon the recombination of hydrogen atoms adsorbed at the surface of the Cu/Ge/i-GaAs sample.

36 MATERIALS SCIENCE↗

Phase speed spectra of transient eddy fluxes and critical layer absorption

Tropospheric zonal mean eddy fluxes of heat and momentum, and the divergence of the Eliassen-Palm flux, are decomposed into contributions from different zonal phase speeds. Data analyzed are the European Center for Medium Range Weather Forecasts operational global analyses covering 1980-1987. Eastward moving medium-scale waves (zonal waves 4-7) dominate the spectra of lower tropospheric heat fluxes in both hemispheres and all seasons. Upper tropospheric wave flux spectra are similar to the low level spectra in midlatitudes, but shift to slower zonal phase speeds as low latitudes are approached. The cause of this shift is the selective absorption of faster moving components in midlatitudes as the waves propagate meridionally. Latitude-phase speed distributions of eddy fluxes are constructed and compared to the zonal mean wind structure. These results demonstrate that upper tropospheric eddies break and decelerate the zonal mean flow approximately 10-20 deg in latitude away from their critical line (where phase speed equals zonal wind speed). Comparisons are also made with results from the middle stratosphere.

Randel, William J.↗

Gas distribution equipment in hydrogen service - Phase II

The hydrogen permeability of three different types of commercially available natural gas polyethylene pipes was determined. Ring tensile tests were conducted on permeability-exposed and as-received samples. Hydrogen-methane leakage experiments were also performed. The results show no selective leakage of hydrogen via Poiseuille, turbulent, or orifice flow (through leaks) on the distribution of blends of hydrogen and methane. The data collected show that the polyethylene pipe is 4 to 6 times more permeable to hydrogen than to methane.

Jasionowski, W. J.↗

New methodology for measuring electron density perturbations caused by plasma coherent modes using profile reflectometry: Magnitudes and radial profiles in DIII-D

New capabilities of fast-sweep frequency-modulated profile reflectometry are explored to measure electron density ne perturbation magnitudes and radial profiles due to plasma coherent modes in DIII-D. The first approach is based on the frequency analysis of phase perturbations associated with high frequency (~MHz) Alfvén eigenmodes (AEs). The measurement of ~5.5 MHz fast-ion-driven global Alfvén eigenmodes (GAEs) is demonstrated in a neutral beam-heated DIII-D plasma. The GAE induced a broad radial distribution of phase perturbations in the profile reflectometer data. Analysis of these data determined the effective cutoff location displacement and the estimated ne fluctuation profile. In the second approach, high resolution ne profiles are used directly to determine the radial structure of ne perturbations due to a neo-classical tearing mode. These new measurements broaden the application of profile reflectometry and advance the development of AE spectroscopy as a tool for non-invasive diagnosis of fast-ion-driven modes in DIII-D and burning plasmas such as ITER.

47 OTHER INSTRUMENTATION↗

Hybrid-gyrokinetic simulations of low- n toroidal Alfvén eigenmodes using gKPSP

Here, we report a benchmark study of toroidal Alfvén eigenmode (TAE) simulation using the hybrid-gyrokinetic code GyroKinetic Plasma Simulation Program (gKPSP). A simulation capability for energetic particles based on the gyrokinetic δf method has been newly implemented in the gKPSP code. Benchmark simulations have been performed in both circular and realistic tokamak geometries. Good agreement has been found with previously reported results, demonstrating the new capability of the gKPSP code. We have investigated the effects of the distribution function on TAE stability by examining both isotropic and anisotropic slowing-down distributions of energetic particles. The slowing-down distribution produces a higher linear growth rate than a Maxwellian distribution, while a growth rate scan with the anisotropy shows an opposite trend. This can be attributed to competition between Landau damping and the linear drive, which are correlated with the fraction of resonant passing particles and their distribution in phase space.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The cleanroom case study in the Software Engineering Laboratory: Project description and early analysis

This case study analyzes the application of the cleanroom software development methodology to the development of production software at the NASA/Goddard Space Flight Center. The cleanroom methodology emphasizes human discipline in program verification to produce reliable software products that are right the first time. Preliminary analysis of the cleanroom case study shows that the method can be applied successfully in the FDD environment and may increase staff productivity and product quality. Compared to typical Software Engineering Laboratory (SEL) activities, there is evidence of lower failure rates, a more complete and consistent set of inline code documentation, a different distribution of phase effort activity, and a different growth profile in terms of lines of code developed. The major goals of the study were to: (1) assess the process used in the SEL cleanroom model with respect to team structure, team activities, and effort distribution; (2) analyze the products of the SEL cleanroom model and determine the impact on measures of interest, including reliability, productivity, overall life-cycle cost, and software quality; and (3) analyze the residual products in the application of the SEL cleanroom model, such as fault distribution, error characteristics, system growth, and computer usage.

Green, Scott↗

Recovering Gardner restacking with purely diffusive operations

The maximum particle kinetic energy that can be extracted from an initial six-dimensional phase space distribution motivates the concept of free or available energy. The free energy depends on the allowed operations that can be performed. A key concept underlying the theoretical treatment of plasmas is the Gardner free energy, where the exchange of the contents of equal phase volumes is allowed. Further, a second free energy concept is the diffusive free energy, in which the contents of volumes are instead averaged. For any finite discretization of phase space, the diffusive free energy is known to be less than the Gardner free energy. However, despite the apparent fundamental differences between these free energies, it is demonstrated here that the Gardner free energy may be recovered from the continuous limit of the diffusive free energy, leading to the surprise that macroscopic phase-space conservation can be achieved by ostensibly entropy-producing microscopic operations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Observations of aerosol optical depth during the First ISLSCP Field Experiment (FIFE)

Solar radiation measurements were made with a multiwavelength airborne tracking sunphotometer during the First International Satellite Land Surface Climatology Project Field Experiment (FIFE). Data from June 6, and October 11, 1987 are analyzed. Atmospheric optical properties were derived from the data, including total optical depth, aerosol optical depth, aerosol size distribution, aerosol phase function, and aerosol single scattering albedo. The aerosol optical depths for June 6 exhibited a spectral dependence that peaked at short wavelengths, whereas those for October 11 decreased monotonically with wavelength and closely followed an Angstrom wavelength dependence. Also, a unimodal aerosol size distribution was found for the June 6 data, while the October 11 data exhibited a power law size distribution. It is suggested that these differences indicate the need for simultaneous sunphotometer measurements and remotely sensed data.

Spanner, Michael A.↗

Time-drift Aware RF Optimization with Machine Learning Techniques

The Fermilab Linac delivers 400 MeV H- beam to the rest of the accelerator chain. Providing stable intensity, energy, and emittance is key since it directly affects downstream machines. To operate high current beam, accelerators must minimize uncontrolled particle loss; this can be accomplished by minimizing beam longitudinal emittance via RF parameter optimization. However, RF tuning is required daily since the resonance frequency of the accelerating cavities is affected by ambient temperature and humidity variations and thus drifts with time. In addition, the energy and phase space distribution of particles emerging from the ion source are subject to fluctuations. Such drift is not unique to Fermilab, but rather affects most laboratories. We are exploring machine learning (ML) algorithms for automated RF tuning for 2 objectives: optimization of Linac output energy and phase oscillation correction, with an emphasis on time-drift aware modeling that can account for conditions changing over time.

43 PARTICLE ACCELERATORS↗

Latent diffusion can map beam loss to two-dimensional phase-space projections

Beam loss monitors (BLMs) and beam current monitors (BCMs) are ubiquitous at particle accelerators around the world. These simple devices provide noninvasive high-level beam measurements but give no insight into the detailed 6D (𝑥,𝑦,𝑧,𝑝 𝑥 ,𝑝 𝑦 ,𝑝 𝑧 ) beam phase-space distributions or dynamics. We show that generative conditional latent diffusion models can learn intricate patterns to solve the extreme inverse problem of mapping waveforms of tens of BLMs or BCMs along an accelerator to detailed 2D projections of a charged particle beam’s 6D phase-space density. This transformational method can be used at any particle accelerator to transform simple noninvasive devices into detailed beam phase-space diagnostics. We demonstrate this concept via multiparticle simulations of the high-intensity beam in the kilometer-long Los Alamos Neutron Science Center linear proton accelerator.

43 PARTICLE ACCELERATORS↗

The QCD phase diagram and statistics friendly distributions

The preliminary STAR data for proton cumulants for central collisions at \sqrt{s}=7.7 GeV are consistent with a two-component proton multiplicity distribution. We show that this two-component distribution is statistics friendly in that factorial cumulants of surprisingly high orders may be extracted with a relatively small number of events. As a consequence the two-component model can be tested and verified right now with the presently available STAR data from the first phase of the RHIC beam energy scan.

Koch, Volker↗