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At least 577 records · Page 32

Botswana water and surface energy balance research program. Part 1: Integrated approach and field campaign results

The Botswana water and surface energy balance research program was developed to study and evaluate the integrated use of multispectral satellite remote sensing for monitoring the hydrological status of the Earth's surface. Results of the first part of the program (Botswana 1) which ran from 1 Jan. 1988 - 31 Dec. 1990 are summarized. Botswana 1 consisted of two major, mutually related components: a surface energy balance modeling component, built around an extensive field campaign; and a passive microwave research component which consisted of a retrospective study of large scale moisture conditions and Nimbus scanning multichannel microwave radiometer microwave signatures. The integrated approach of both components in general are described and activities performed during the surface energy modeling component including the extensive field campaign are summarized. The results of the passive microwave component are summarized. The key of the field campaign was a multilevel approach, whereby measurements by various similar sensors were made at several altitudes and resolution. Data collection was performed at two adjacent sites of contrasting surface character. The following measurements were made: micrometeorological measurements, surface temperatures, soil temperatures, soil moisture, vegetation (leaf area index and biomass), satellite data, aircraft data, atmospheric soundings, stomatal resistance, and surface emissivity.

Vandegriend, A. A.↗

Single Primary Heat Extraction and Removal Emulator (SPHERE) Long Duration Testing

For the development of heat-pipe cooled microreactors, it is crucial to thoroughly understand the characteristics and functioning of heat pipes across a wide spectrum of operating conditions. Passive heat removal and its long-term performance stability are critical factors in this context. Enhanced experimental data is vital for evaluating the operational lifespan of alkali metal heat pipes. Idaho National Laboratory (INL) has successfully conducted an extended duration test on a high-performance sodium-filled heat pipe, closely monitoring the axial temperature profile, power supplied by the heaters, and heat removed by a gas-gap calorimeter. The results from this testing provide valuable data that are instrumental in supporting heat pipe validation efforts. Specifically, this data aids in the development and validation of Sockeye, the Multiphysics Object-Oriented Simulation Environment (MOOSE) tool under the US-DOE NEAMS program designed for heat pipe modeling. By comparing experimental results with Sockeye’s predictions, the tool's accuracy and reliability can be assessed and improved, thereby enhancing its capability to simulate heat pipe operations under various conditions.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Effect of fluctuating redox conditions on trace metal release from wetland soils from South Carolina and stream sediments from Tennessee

Natural aquatic systems undergo fluctuating redox conditions due to microbial activity, varying water saturation levels, and nutrients dynamics. With fluctuating oxic and anoxic conditions, trace metals can be mobilized or sequestered in response to changes in iron and sulfur speciation and the concentrations and lability of organic carbon. We conducted a systematic laboratory-based microcosm study to examine the effect of redox fluctuations on trace metal mobility in samples collected from two different natural aquatic systems: riparian wetlands and a stream. We incubated water-saturated soils under three cycles of anoxic-oxic conditions (τanoxic:τoxic = 3) spanning 24 days and monitored the change in dissolved and bioavailable metal (copper (Cu), nickel (Ni), zinc (Zn), cobalt (Co), iron (Fe), and manganese (Mn)) concentrations. The dataset includes the results of the variation in metal concentrations due to redox fluctuations in wetland soils and stream sediments. Additionally, the variation in the bioavailable concentration of metals obtained using passive samplers based on diffuse gradient in thin-films technique is included in the dataset. We have also reported the change in the pH values and dissolved oxygen concentrations in the microcosms during the entire study of 24 days. The dataset also contains the dissolved organic carbon and sulfate concentrations, and the data on fractions of metals bound to reducible and oxidizable phases. For materials from both the wetlands and the stream, anoxic conditions favored Co and Zn release, which corresponded with the reductive dissolution of iron oxides. In contrast, dissolved Cu concentrations increased under oxic conditions for both sites and correlated positively with the release of sulfate. In wetland soils, dissolution of Fe (hydr)oxides increased Ni solubility; however, in stream sediments, Ni release occurred when sulfides or organic matter were oxidized. For stream sediments, each subsequent redox cycle increased the bioavailability of trace metals. Upon redox fluctuations in wetland soils, the bioavailability of Zn and Cu increased, whereas bioavailable Ni and Co decreased. This study illustrates that different trace metals display distinct bioavailability patterns during oxic-anoxic fluctuations in natural environments. The biogeochemical cycling of carbon and nitrogen in systems with redox fluctuations may be influenced by these patterns in trace metal availability in addition to the availability of electron donors and acceptors.

54 ENVIRONMENTAL SCIENCES↗

Precision slew/settle technologies for flexible spacecraft

Many spacecraft missions in the next decade will require both a high degree of agility and precision pointing. Agility includes both rotational maneuvering for retargeting and translational motion for orbit adjustment and threat avoidance. The major challenge associated with such missions is the need for control over a wide range of amplitudes and frequencies, ranging from tens of degrees at less than 1 Hz to a few micron radians at hundreds of Hz. TRW's internally funded Precision Control of Agile Spacecraft (PCAS) project is concerned with developing and validating in hardware the tools necessary to successfully complete the combined agile maneuvering/precision pointing missions. Development has been undertaken on a number of fronts for quietly slewing flexible structures. Various methods for designing slew torque profiles have been investigated. Prime candidates for slew/settle scenarios include Inverse Dynamics and Parameterized Function Space. Joint work with Processor Bayo at the University of California, Santa Barbara and Professor Flashner at the University of Southern California has led to promising torque profile design methods. Active and passive vibration suppression techniques also play a key role for rapid slew/settle mission scenarios. Active members with local control loops and passive members with high loss factor viscoelastic material have been selected for hardware verification. Progress in each of these areas produces large gains in the quiet slewing of flexible spacecraft. The main thrust of the effort to date has been the development of a modular testbed for hardware validation of the precision control concepts. The testbed is a slewing eighteen foot long flexible truss. Active and passive members can be interchanged with the baseline aluminum members to augment the inherent damping in the system. For precision control the active members utilize control laws running on a high speed digital structural control processor. Tip and midspan motions of the truss are determined using optical sensors while accelerometers can be used to monitor the motions of other points of interest. Preliminary results indicate that a mix of technologies produces the greatest benefit. For example, shaping the torque profile produces large improvements in slew/settle performance, but without added damping settling times may still be excessive. With the introduction of moderate amounts of damping, slew/settle performance is vastly improved. On the other hand, introducing damping without shaping the torque profile may not yield the desired level of performance.

Manning, R. A.↗

Coupled Bunch Instabilities Growth in the Fermilab Booster during Acceleration Cycle

Currently, Fermilab Booster accelerates ~4.5E12 protons per pulse (ppp) in 81 bunches from 400 MeV to 8 GeV at 15 Hz to provide beam to multiple HEP experiments and is being upgraded to handle higher beam intensity >6.7E12 ppp at a repetition rate of 20 Hz. In the current mode of operation, we control longitudinal coupled bunch instabilities (LCBI) using combination of passive and active dampers. The issues with LCBI are expected to worsen at higher beam intensities. Here, we would like to investigate at what time in the beam cycle a particular mode is going to originate and how much it contributes at a different time of the acceleration cycle using the collected wall current monitor data from injection to extraction. Also, measure growth rates as a function of beam intensity for some dominant modes. Finally, this paper presents results from the observed LCBI analysis for the highest available beam intensities, unexpected findings, and future plans to mitigate the LCBI at higher beam intensities

43 PARTICLE ACCELERATORS↗

Neutron Measurements for Radiation Protection in Low Earth Orbit - History and Future

The neutron environment inside spacecraft has been of interest from a scientific and radiation protection perspective since early in the history of manned spaceflight. With 1:.1e exception of a few missions which carried plutonium-fueled radioisotope thermoelectric generators, all of the neutrons inside the spacecraft are secondary radiations resulting from interactions of high-energy charged particles with nuclei in the Earth's atmosphere, spacecraft structural materials, and the astronaut's own bodies. Although of great interest, definitive measurements of the spacecraft neutron field have been difficult due to the wide particle energy range and the limited available volume and power for traditional techniques involving Bonner spheres. A multitude of measurements, however, have been made of the neutron environment inside spacecraft. The majority of measurements were made using passive techniques including metal activation fo ils, fission foils, nuclear photoemulsions, plastic track detectors, and thermoluminescent detectors. Active measurements have utilized proton recoil spectrometers (stilbene), Bonner Spheres eRe proportional counter based), and LiI(Eu)phoswich scintillation detectors. For the International Space Station (ISS), only the plastic track! thermoluminescent detectors are used with any regularity. A monitoring program utilizing a set of active Bonner spheres was carried out in the ISS Lab module from March - December 200l. These measurements provide a very limited look at the crew neutron exposure, both in time coverage and neutron energy coverage. A review of the currently published data from past flights will be made and compared with the more recent results from the ISS. Future measurement efforts using currently available techniques and those in development will be also discussed.

Golightly, M. J.↗

Thermal Development of a Commercial off the Shelf (COTS) Camera for Exploration Upper Stage (EUS)

NASA’s Flight Imagery Launch Monitoring Real-time System (FILMRS) cameras were originally developed for the Space Launch System (SLS) Core Stage. These Commercial Off the Shelf (COTS) cameras have been redesigned and reduced by an order of magnitude in size for the Exploration Upper Stage (EUS). The change in thermal environment has led to the application of various passive thermal control methods and the addition of a heater option. This paper will give a summary of the design and development test effort associated with adapting the COTS camera for the demands of the space environment and associated thermal mitigations applied as the project prepares to complete the design. The application of this camera for other space systems is discussed.

Hernandez, Deborah↗

Towards Commercialization of Hydrophone Flow Shields to Improve Passive Acoustic Data Quality (CRADA 678) (Final Report)

This project performed testing, market research, and manufacturing refinement to ready patent-pending hydrophone flow shields developed at PNNL for commercialization. The flow shields reduce the impact of flow noise on underwater sound recordings in areas of strong flow, like tidal channels or rivers. Flow noise is a challenge in many applications where it is necessary to measure underwater sound, including measuring the sound produced by marine energy converters and monitoring marine mammals. This project addressed several key questions about flow shield performance that are high-priority for potential customers and refined existing manufacturing processes to be scalable for market-level production. Specifically, this project conducted both laboratory and field evaluations of the flow shields to comprehensively evaluate their performance. Overall, the results indicate that the flow shields reduce flow noise by over 20 dB at frequencies below 50 Hz at flow speeds greater than 0.5 m/s and are proven to survive deployments more than 6 months long.

42 ENGINEERING↗

Monitoring Aerosols from Space: What We can Say, and What We Can't

Aerosols are understood to play a significant role is the global energy balance, and especially on atmospheric as well as surface energy balances regionally. A combination of direct radiative cooling of the surface, atmospheric warming through diabatic heating, and indirect effects of aerosol on clouds are all thought to contribute to the net aerosol effect, though the magnitudes of each are both highly variable in space and time, and highly uncertain. Passive space-based remote sensing is a key tool for constraining these effects, due to the frequent, global coverage satellites can provide. However, information from such observations about total-column aerosol amount (i.e., aerosol optical depth or AOD), and especially about aerosol type, is limited. The current generation of passive aerosol remote-sensing instruments, including the Multi-angle Imaging SpectroRadiometer (MISR) and the MODerate resolution Imaging Spectroradiometer (MODIS) offer vast improvements over previous instruments, including AOD over water and much of the land surface, fine vs. coarse particle type over ocean from MODIS, and discrimination of about a dozen aerosol types from MISR under good retrieval conditions, based on particle size, shape, and single-scattering albedo (SSA) constraints. This presentation will summarize the capabilities and expected improvements in the currently available aerosol products, in light of required energy budget constraints. Ways of addressing the need for detailed information about particle microphysical properties, especially SSA, unobtainable from MISR or MODIS, will be discussed.

Kahn, Ralph A.↗

Passive Wireless Vibration Sensing for Measuring Aerospace Structural Flutter

To reduce energy consumption, emissions, and noise, NASA is exploring the use of high aspect ratio wings on subsonic aircraft. Because high aspect ratio wings are susceptible to flutter events, NASA is also investigating methods of flutter detection and suppression. In support of that work a new remote, non-contact method for measuring flutter-induced vibrations has been developed. The new sensing scheme utilizes a microwave reflectometer to monitor the reflected response from an aeroelastic structure to ultimately characterize structural vibrations. To demonstrate the ability of microwaves to detect flutter vibrations, a carbon fiber-reinforced polymer (CFRP) composite panel was vibrated at various frequencies from 1Hz to 130Hz. The reflectometer response was found to closely resemble the sinusoidal response as measured with an accelerometer up to 100 Hz. The data presented demonstrate that microwaves can be used to measure flutter-induced aircraft vibrations.

Wilson, William C.↗

Microwave Satellite Data for Hydrologic Modeling in Ungauged Basins

An innovative flood-prediction framework is developed using Tropical Rainfall Measuring Mission precipitation forcing and a proxy for river discharge from the Advanced Microwave Scanning Radiometer for Earth Observing System (AMSR-E) onboard the National Aeronautics and Space Administration's Aqua satellite. The AMSR-E-detected water surface signal was correlated with in situ measurements of streamflow in the Okavango Basin in Southern Africa as indicated by a Pearson correlation coefficient of 0.90. A distributed hydrologic model, with structural data sets derived from remote-sensing data, was calibrated to yield simulations matching the flood frequencies from the AMSR-E-detected water surface signal. Model performance during a validation period yielded a Nash-Sutcliffe efficiency of 0.84. We concluded that remote-sensing data from microwave sensors could be used to supplement stream gauges in large sparsely gauged or ungauged basins to calibrate hydrologic models. Given the global availability of all required data sets, this approach can be potentially expanded to improve flood monitoring and prediction in sparsely gauged basins throughout the world

Distributed hydrologic modeling↗

Surface melting over the Greenland ice sheet from enhanced resolution passive microwave brightness temperatures (1979–2019)

Surface melting is a major component of the Greenland ice sheet (GrIS) surface mass balance, affecting sea level rise through direct runoff and the modulation on ice dynamics and hydrological processes, supraglacially, englacially and subglacially. Passive microwave (PMW) brightness temperature observations are of paramount importance in studying the spatial and temporal evolution of surface melting in view of their long temporal coverage (1979–to date) and high temporal resolution (daily). However, a major limitation of PMW datasets has been the relatively coarse spatial resolution, being historically of the order of tens of kilometres. Here, we use a newly released passive microwave dataset (37 GHz, horizontal polarization) made available through the NASA MeASUREs program to study the spatiotemporal evolution of surface melting over the GrIS at an enhanced spatial resolution of 3.125 Km. We assess the outputs of different detection algorithms through data collected by Automatic Weather Stations (AWS) and the outputs of the MAR regional climate model. We found that surface melting is well captured using a dynamic algorithm based on the outputs of MEMLS model, capable to detect sporadic and persistent melting. Our results indicate that, during the reference period 1979–2019 (1988–2019), surface melting over the GrIS increased in terms of both duration, up to ~4.5 (2.9) days per decade, and extension, up to 6.9 % (3.6 %) of the GrIS surface extent per decade, according to the MEMLS algorithm. Furthermore, the melting season has started up to ~4 (2.5) days earlier and ended ~7 (3.9) days later per decade. We also explored the information content of the enhanced resolution dataset with respect to the one at 25 km and MAR outputs through a semi-variogram approach. We found that the enhanced product is more sensitive to local scale processes, hence confirming the potential interest of this new enhanced product for studying surface melting over Greenland at a higher spatial resolution than the historical products and monitor its impact on sea level rise. This offers the opportunity to improve our understanding of the processes driving melting, to validate modelled melt extent at high resolution and potentially to assimilate this data in climate models.

Surface melting↗

Initial development of a method for correlating indentation test results to damage accumulation in high temperature structural materials

This report describes an experimental approach based on microindentation creep or relaxation tests for assessing the remaining creep life of a sample material. The objective for this experimental program is to complement the development of passively loaded in situ surveillance specimens. These surveillance specimens could be placed in future advanced reactors to assess the degradation of structural properties, primary creep and creep-fatigue life, when the material is exposed to actual reactor operating conditions. The specimens and the corresponding indentation test protocol could form the basis of a structural health monitoring program designed to ensure the safe continued operation of the component given the relatively unknown effect of the reactor coolant chemistry, radiation exposure, and other environmental effects on the material properties of the constituent structural materials.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Advanced Laboratory and Field Arrays: Evaluating Sampling Techniques for MHK Biological Monitoring (Task 6)

The overall goal of the task was to identify cost effective biological sampling techniques for MHK environmental monitoring. Protected, demersal, and pelagic fish and selected nektonic invertebrates were surveyed using capture and remote sensing techniques at the PacWave sites. The performance of capture and remote sensing monitoring techniques were evaluated and generic nekton monitoring indices were developed for MHK technologies and sites. In parallel to data collections at the PacWave site, the ability of regression models to characterize, detect, and predict change in acoustic data was evaluated using acoustic data collected in Admiralty Inlet, WA, during a biological monitoring study of the proposed SnoPud tidal turbine project site. Expected outcomes of these efforts included an evaluation of instrumentation and techniques used to monitor biological variability; identification of data streams that can be used to detect and quantify change; and sampling requirements to ensure detection of change in monitored variables.

13 HYDRO ENERGY↗

Online Monitoring of Medium Voltage Cable Systems with Spread Spectrum Time Domain and Frequency Domain Reflectometry

In-service failures of wave energy convertor (WEC) cable systems can have a significant cost and power availability impact. Close parallel research 2019 data showed > 1B£ and 9 Terra-Watt-Hours associated with global off-shore wind (OSW) cable failures (Strang-Moran 2020). OSW is a closely related technology but currently is significantly cheaper than WEC technology. For wave energy to compete, the problem of reliable cable transmission must be mitigated. This project develops isolation technology to allow online high frequency reflectometry testing of medium voltage cables (1 to 10 kV and higher) without arcing or damage to the test instrument. Online spread spectrum time domain reflectometry (SSTDR) testing has been established for low voltage cable systems in the aircraft and rail industry and the ability to detect and locate cable flaws of interest is well understood. Extending reflectometry testing to medium voltage systems could enable detection of cable damage before failures occur thereby allowing repair and replacement of damaged cable segments to be scheduled and managed. The seedling project succeeded to pass and receive high frequency SSTDR signals onto a cable up to 1 kV using a parallel trace isolation circuit board that can be connected onto the test cable. The approach used a novel circuit design for which an invention disclosure has been filed. A proposed sapling project would extend the technology toward the higher operating voltages used by WEC systems, thereby enabling online SSTDR cable monitoring. The goal of the seedling project was to extend the capability of the ARENA cable/motor test bed to address medium voltages and to develop a high pass filter isolation architecture to protect the reflectometry instrument from the low frequency (DC – 60 Hz) line voltage while allowing the high frequency diagnostic signal to pass to and from the test instrument to the live line. Initial efforts focused on passive LCR filter circuits to reduce 60 Hz levels below 10 volts from a 10 kV line while allowing the MHz high frequency chirps to pass onto the cables and for mV signals to be detected. We discovered that the parasitic loss behavior of real high voltage components precluded this approach from working. An alternate approach was adapted for the electric field to couple between two parallel traces on a printed circuit board much like a radio-frequency coupler. The challenge here was and is to have the parallel traces close enough to each other to effectively pass the high frequency chirp onto the live line and receive any reflected signal from any encountered impedance change along the cable. This reflected signal will be in the mV range. The traces however must be far enough apart to not allow arcing on the board. A design with 3 mm spacing was determined to allow the high frequency signal to pass onto the live line and receive the mV signal back into the instrument while reducing the 60 Hz voltage amplitude by >80 dB (more than a factor of 10,000) without allowing arcing from across the parallel traces. This was confirmed by simulation and test.

16 TIDAL AND WAVE POWER↗

Irreversible Catalyst Deactivation Mechanisms of PdO/γ-Al 2 O 3 Catalysts for Lean Methane Oxidation

PdO/γ-Al 2 O 3 catalysts suffer from gradual and irreversible catalyst deactivation under lean CH 4 oxidation conditions, especially in a wet feed. Here, time-resolved CO chemisorption DRIFTS measurements are conducted systematically on a series of PdO/γ-Al 2 O 3 catalysts to probe the surface reactivity of PdO nanoparticles after various in situ pretreatments. At 80 °C, CO barely adsorbs on fully oxidized PdO surfaces but interacts with coordinatively unsaturated Pd sites, causing gradual reduction of the PdO surfaces. This results in the formation of characteristic IR bands on various metallic Pd 0 sites. By monitoring and comparing the formation kinetics of these IR bands on samples before and after CH 4 oxidation, we theorize that the irreversible catalyst deactivation during CH 4 oxidation is caused by PdO surface reconstruction, in which coordinatively unsaturated Pd sites gradually become fully coordinated by oxygen. Effectively, the surface reconstruction leads to the formation of a passivation layer on the PdO nanoparticles, which hinders their ability in activating CH 4 , and hence the subsequent oxidation reaction. Temperature-programmed reduction with CO as the reductant (CO-TPR) reveals that the passivation layer formed during CH 4 oxidation is significant enough to increase the reduction temperature of PdO nanoparticles of the 3.0% PdO/γ-Al 2 O 3 samples, although such an effect is less obvious for the 0.4% PdO/γ-Al 2 O 3 samples. On the other hand, it is also discovered that the passivation layer is not completely inert. Under certain reaction conditions, with some being relatively mild, such as low-temperature CO oxidation in a net lean atmosphere and in the presence of H 2 O, the passivation layer can undergo structure change which results in regeneration or even activation of CH 4 oxidation activity of an already deactivated catalyst. Additionally, it is discovered that the fully coordinated Pd–O surface is a metastable phase under CH 4 oxidation conditions. In the presence of H 2 O and at ambient temperatures, surfaces with coordinatively unsaturated Pd sites are thermodynamically more favorable.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Satellite sensor estimates of Northern Hemisphere snow volume

In the Northern Hemisphere the mean monthly snow-covered area ranges from about 7 percent of the land area in summer to over 40 percent in winter, thus making snow one of the most rapidly varying natural surface features. The mean monthly snow volume ranges from about 1.5 x 10 to the 16th g in summer to about 3.0 x 10 to the 18th g in winter. Currently several algorithms utilizing passive microwave brightness temperatures are available to estimate snow cover and depth. The algorithm presented here uses the difference between the 37-GHz channel and the 18-GHz channel of the SMMR on the Nimbus-7 satellite to derive estimates of snow volume. Even though satellite sensor snow records are currently too short to reveal trends, continued monitoring over about the next 10 years should make it possible to establish whether incipient or current trends are significant in the context of global climate change.

Chang, A. T. C.↗

Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS): Final Report of the ASCENDS Ad Hoc Science Definition Team

Improved remote sensing observations of atmospheric carbon dioxide (CO2) are critically needed to quantify, monitor, and understand the Earth's carbon cycle and its evolution in a changing climate. The processes governing ocean and terrestrial carbon uptake remain poorly understood,especially in dynamic regions with large carbon stocks and strong vulnerability to climate change,for example, the tropical land biosphere, the northern hemisphere high latitudes, and the Southern Ocean. Because the passive spectrometers used by GOSAT (Greenhouse gases Observing SATellite) and OCO-2 (Orbiting Carbon Observatory-2) require sunlit and cloud-free conditions,current observations over these regions remain infrequent and are subject to biases. These short comings limit our ability to understand and predict the processes controlling the carbon cycle on regional to global scales.In contrast, active CO2 remote-sensing techniques allow accurate measurements to be taken day and night, over ocean and land surfaces, in the presence of thin or scattered clouds, and at all times of year. Because of these benefits, the National Research Council recommended the National Aeronautics and Space Administration (NASA) Active Sensing of CO2 Emissions over Nights,Days, and Seasons (ASCENDS) mission in the 2007 report Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond. The ability of ASCENDS to collect low-bias observations in these key regions is expected to address important gaps in our knowledge of the contemporary carbon cycle.The ASCENDS ad hoc Science Definition Team (SDT), comprised of carbon cycle modeling and active remote sensing instrument teams throughout the United States (US), worked to develop the mission's requirements and advance its readiness from 2008 through 2018. Numerous scientific investigations were carried out to identify the benefit and feasibility of active CO2 remote sensing measurements for improving our understanding of CO2 sources and sinks. This report summarizes their findings and recommendations based on mission modeling studies, analysis of ancillary meteorological data products, development and demonstration of candidate technologies, anddesign studies of the ASCENDS mission concept.

Kawa, S. Randolph↗