IC w22_phadiagractox Highlight: Systematics of the ambient melting points of stoichiometric uranium oxides and mixed-oxide (MOX) fuel [Slide]
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Ethylene is recognized as one of the most significant chemicals globally. The projected ethylene production for 2023 stands at 227.6 million tonnes, with expectations of continued demand growth. The primary use of ethylene, accounting for over 76%, lies in the production of plastics such as polyethylene, polyvinyl chloride, and polystyrene. Despite the enduring carbon retention potential of plastics themselves, traditional ethylene feedstock production from fossil resources contributes substantially to greenhouse gas emissions, ranging from 0.29 to 2.29 kg CO2 /kg Ethylene depending on various factors like feedstock and process design. Various decarbonization strategies, including the utilization of hydrogen as a primary heat source, have been proposed to reduce the carbon footprint of ethylene production, but their efficacy remains limited, offering at best a 0–30% reduction in on-site CO 2 emissions.
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The spontaneous alpha promoted PuO 2 -H 2 O reaction proceeds with establishment of a steady state that is unattainable via an equilibrium-controlled reaction or a sequence of equilibrium reactions.
The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.
The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.
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Separator materials for secondary silver zinc electrochemical cells for use in space missions
Surface interactions of ZnO and ZnS with NO determined with EPR spectrum
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The processing of yttria, zirconia, and alumina under weightless conditions is discussed. The process consists of levitation or position control, heating and melting, superheating, and supercooling. The use of arc imaging furnaces, lasers, induction heating, microwave, and electron beam methods are analyzed to show the advantages and disadvantages of each.
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Seasonal and diurnal emissions of NO and N2O from agricultural sites in Jamestown, Virginia and Boulder, Colorado are estimated in terms of soil temperature; percent moisture; and exchangeable nitrate, nitrite, and ammonium concentrations. The techniques and procedures used to analyze the soil parameters are described. The spatial and temporal variability of the NO and N2O emissions is studied. A correlation between NO fluxes in the Virginia sample and nitrate concentration, temperature, and percent moisture is detected, and NO fluxes for the Colorado site correspond with temperature and moisture. It is observed that the N2O emissions are only present when percent moisture approaches or exceeds the field capacity of the soil. The data suggest that NO is produced primarily by nitrification in aerobic soils, and N2O is formed by denitrification in anaerobic soils.
Grain growth of ZnO in the presence of a liquid phase of the ZnO-BaO system has been studied for temperatures from 1300 to 1400 C. The specimens were treated in boiling water and the grains were separated by dissolving the matrix phase in an ultrasonic bath. As a consequence 3D grain size measurements were possible. Microstructural examination shows some grain coalescence with a wide range of neck size ratios and corresponding dihedral angles, however, most grains are isolated. Lognormal grain size distributions show similar shapes, indicating that the growth mechanism is invariant over this time and temperature. All regressions between G exp n and time for n = 2 and 3 proved statistically significant. The rate constants calculated with the growth exponent set to n = 3 are on the same order of magnitude as in metallic systems. The apparent activation energy for growth is estimated between 355 and 458 kJ/mol.
A study is presented which is aimed at distinguishing among autotrophic nitrification, denitrification, and abiological processes as sources of NO and N2O production following wetting of dry soil. To distinguish among these processes, combinations of treatments in laboratory incubations of soil were used which included varying soil water content, autoclaving, C2H2 inhibition, and NO2(-) addition. Biological sources of NO and N2O commenced within minutes of wetting dry soil. Acetylene inhibition revealed that emissions of NO were dependent on nitrification, although a combination of NO2(-) production by nitrifiers and abiological reduction of NO2(-) to NO is also possible. NO emissions exceeded N2O emissions, and nitrification was the dominant source of both gases when soil water was below field capacity. It is concluded that NO emissions appear to be more important when good soil aeration favors nitrification, whereas N2O emissions appear more important when elevated soil water favors denitrification.
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