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At least 577 records · Page 32

Proof Testing of Small-Scale HE Press Shielding

High explosives pressing activities at Los Alamos National Laboratory have played a critical role in meeting the core missions of the lab since its early days. Small scale pressing (25 grams of energetic material or less) constitutes a significant portion of current production and much of this occurs as an attended operation. Workers that are present during HE pressing operations are to be protected from blast and fragment dangers associated with the potential violent reaction of the energetic material being pressed. Safety is paramount in all HE operations, and the ongoing evolution of analysis and mitigation of hazards contributes strongly to the development of adequate protections for personnel. Attended pressing operations satisfying Class 1 Level Protection criteria, until recently, have been allowed for small scale pressing activities on the basis of an undocumented design of shielding enclosures used at LANL. Recent review of the shield design has determined the necessity of proof testing an adequate enclosure and thoroughly documenting the test results and fabrication specifications. This will provide a basis for continuing attended operations and guidance for future design iterations. The results of the testing described in this report provide sufficient assurance that the new shield design is adequate to protect attendant workers against injury from direct blast and fragments resulting from full detonation of the maximum allowable mass of explosives (less than 25 grams) confined in a uniaxial pressing configuration typical for Los Alamos National Laboratory.

42 ENGINEERING↗

Understanding spectral dependance of laser-induced damage precursors in dielectric materials (Abbreviated report_23-ERD-006)

High peak and average power laser systems are typically limited by the handling fluence of the optical components. In particular, the multilayer dielectric coatings are known to be much lower operational fluence than the more ideal bulk materials. In this project we proposed and succeeded in probing different established classes of damage prone precursors at different wavelengths to understand their fundamental laser damage response as a function of wavelength. This study helped to shed light on the fundamental physics of the non-linear precursors that govern laser damage phenomena for ns-regime pulsed laser damage. In this study, we utilized the onsite coating capabilities (VPL, IBS coating lab) to purposefully generate laser damage-prone precursors in hafnia-based coatings (both single and multi-layer coatings). Specifically, we engineered coatings with craze lines initiated by nodules, generated coatings with our xenon-based coating process to suppress nanobubble formation and generated hafnia coatings under controlled oxygen flow conditions to study hafnia sub-oxides and oxygen flow dependance. In these studies we found that craze lines are rife with precursors that are sensitive to ultra-violet light but not to infrared light; we found that the removal of nanobubbles helps with all wavelengths tested, but is most impactful for ultra-violet light; we also found that ultra-violet laser damage performance of hafnia is closely matched to oxygen flow rate, while the infrared performance may be slightly better at lower flow rates. During this LDRD we also successfully stood up a new laser damage testing capability, namely a wavelength agile damage test station to study the spectral response of known laser-induced damage precursors. This is a unique and important capability for Lawrence Livermore National Lab, allowing us to understand the spectral response of materials under high intensity irradiation and damage. This is a vital tool to understand non-linear optical response at wavelengths that we have previously been unable to test at.

36 MATERIALS SCIENCE↗

Multi-Source Machine Learning and Thermoplastics Enhanced Aerostructure Manufacturing (mTEAM)

RTX Technology Research Center (RTRC), together with Collins Aerospace (Collins) and Oak Ridge National Laboratory (ORNL) has developed an Artificial Intelligence (AI) / Machine Learning (ML) guided solution to advance the manufacturing and assembly of high performance and lightweight thermoplastic composite (TPC) aerospace products. The solution aims to lower risk, cost and lead time for induction heating based welding and consolidation processes for TPC structure. The cost and lead time of part and material specific process development for induction welding (IW) and induction consolidation will be reduced by replacing traditional empirical methods with optimization methods that merge AI/ML and physics-based process simulations and process experiments with sensing and controls. TPC-IW process development is empirical in nature, and uncertainties in material & process behavior exist near & far from the induction coil. Physics-based simulations can be leveraged directly for process optimization but can be too computationally expensive to run in high fidelity and real time to do robust process optimization. The key impact of successful TPC induction consolidation and welding is cost & lead time reduction for part & material specific consolidation and welding recipes. This is an enabler for more rapid deployment of TPC structures via joining assembly, which can reduce energy & cost intensive usage of autoclaves & ovens. The solution aimed to advance the U.S. Department of Energy’s interests in using thermoplastics and automation in composite manufacturing for improvement of products for existing markets via increased production speeds, reduced costs, and lowered use of energy. Welded TPC structures can offer significant weight & energy savings for high-value commercial aerospace & industrial applications compared to metal & thermoset composite structures assembled by mechanical fastening and/or adhesive bonding. The project was organized into two Budget Periods. Budget Period 1 (BP1) was 15 months and its goal was to perform ML process optimization framework development & deployment on lab-coupon aerostructure components. A Go/No-Go Review was performed at the end of BP1 to verify fulfilment of key tasks & milestones to justify a Go Decision to move into the next Budget Period. Budget Period 2 (BP2) was 12 months and its goal was the deployment of the ML framework for ML process optimization of pilot industrial scale aerostructure components. The overall project aim was to develop & demonstrate ML-enhanced modeling framework that learns process-property mapping from multiple data sources at different fidelities. During BP1, the team accomplished key tasks & milestones to demonstrate the concept of multi-source ML for TPC aerostructure consolidation and assembly. First, the team completed documentation of induction based TPC heating requirements including baseline metrics to compare measured results against. Next the team completed demonstration of data generation from physics-based simulations for ML surrogate model generation and demonstrated the integration of physics-based simulation data into multi-source AI/ML algorithms. In parallel, the team established the lab-coupon scale induction welding system and completed a process to label and reduce generated data from physics-based simulation and experiments for ML surrogate models to enable multi-source ML model training & testing. To complete BP1, the team integrated physics-based simulation data and experimental data into multi-source ML algorithms. This was based on the team completing ML deployment of the induction welding on a lab system at RTRC and AI/ML deployment on existing induction welding line at Collins. ORNL visited both Collins and RTRC sites to witness the TPC induction welding process. Then, ORNL designed and constructed a new version of their vision-based sensing system better adapted to acquire process signals of the TPC induction welding process for process anomaly and defect detection. In BP2, the team accomplished key tasks & milestones to scale up multi-source ML for TPC aerostructure consolidation and assembly from the lab-coupon scale to the pilot-industrial scale. In BP2, the team demonstrated real time anomaly & defect detection via experiments performed by ORNL & RTRC. The team completed ML-optimization heating trials for TPC induction consolidation at Collins, and the team confirmed pilot industrial scale experimental data from Collins was compatible with the developed ML pipeline from RTRC. The team completed sub-element scale ML process optimization demonstration at RTRC, where the team leveraged RTRC’s robotic TPC welding setup to de-risk the ML process optimization by performing ML analysis of recorded temperatures to account for complex part features. Then, the team applied its ML-derived control strategies and ML process optimization framework at Collins to the pilot-industrial scale on a demo skin-stiffener part representative of a nacelle aerostructure fan cowl section. The key innovation is the AI/ML framework enabling effective process development of high performance, lightweight, energy efficient TPCs for composite aircraft structures.

36 MATERIALS SCIENCE↗

A New Family of Proton‐Conducting Electrolytes for Reversible Solid Oxide Cells: BaHf x Ce 0.8− x Y 0.1 Yb 0.1 O 3− δ

Abstract Reversible solid oxide cells based on ceramic proton conductors have potential to be the most efficient system for large‐scale energy storage. The performance and long‐term durability of these systems, however, are often limited by the ionic conductivity or stability of the proton‐conducting electrolyte. Here new family of solid oxide electrolytes, BaHf x Ce 0.8− x Y 0.1 Yb 0.1 O 3− δ (BHCYYb), which demonstrate a superior ionic conductivity to stability trade‐off than the state‐of‐the‐art proton conductors, BaZr x Ce 0.8− x Y 0.1 Yb 0.1 O 3− δ (BZCYYb), at similar Zr/Hf concentrations, as confirmed by thermogravimetric analysis, Raman, and X‐ray diffraction analysis of samples over 500 h of testing are reported. The increase in performance is revealed through thermodynamic arguments and first‐principle calculations. In addition, lab scale full cells are fabricated, demonstrating high peak power densities of 1.1, 1.4, and 1.6 W cm −2 at 600, 650, and 700 °C, respectively. Round‐trip efficiencies for steam electrolysis at 1 A cm −2 are 78%, 72%, and 62% at 700, 650, and 600 °C, respectively. Finally, CO 2 H 2 O electrolysis is carried out for over 700 h with no degradation.

Murphy, Ryan↗

Pressure drop and heat transfer characteristics of nitrate salt and supercritical CO 2 in a diffusion-bonded heat exchanger

A lab-scale 316/L stainless steel diffusion-bonded heat exchanger was examined within a coupled high-temperature test facility consisting of an atmospheric-pressure nitrate salt loop and a supercritical carbon dioxide (sCO 2 ) loop operating between 10 and 16 MPa. Pressure loss measurements collected for flow rates up to 0.55 kg/s of Solar Salt and up to 0.6 kg/s of carbon dioxide were used to generate friction factor correlations for the respective circular and semicircular zig-zag flow passages. Heat transfer measurements were also performed over a wide range of conditions to produce Nusselt correlations for the CO 2 and nitrate salt geometries. The Nusselt number is deduced from a heat transfer resistance network and overall conductance measurements collected across the operating envelope of the coupled sCO 2 – nitrate salt test facility. The CO 2 side correlation showed excellent agreement with existing correlations in the literature. Further, the salt side, having nearly circular channels with a different zig-zag angle and hydraulic diameter, yielded a new correlation applicable to the laminar flow regime. To examine the similitude of the friction correlations, pressure drop testing with water was performed on both sides of the component as well. Finally, results from non-destructive examination are discussed to provide insights regarding inspection methods and draining performance of high-temperature liquids in compact heat exchangers.

36 MATERIALS SCIENCE↗

Laser Diode Analysis and Verification (Professional Report)

The goal of this project at Lawrence Livermore National Laboratory (LLNL) was focused on analyzing and verifying laser diodes to ensure that the diodes meet requirements for LLNL mission applications. The different stages of this testing were documented in a process flow map which included location color coding so that each step was clearly defined in scope and location of appropriate testing facility. Data were collected and analyzed and compared to minimum acceptable values to see if requirements were met. The process map documents the initial receipt, inspection, and testing of the laser diodes. Initial inspections started with Keyence Microscope imaging and then moved on to High Potential, Ramp, and Burst Testing. Data from the diode testing were processed through MATLAB and Python codes to verify various metrics such as slope efficiency, threshold current, back irradiance, and beam divergence met requirements. These metrics were then recorded in Excel summary reports. Approximately 95% of the laser diodes passed all tests. Presentations were given to Lawrence Livermore’s internal leadership team, an external partner, and to a Lab-wide audience. The data released for this report was constrained by information protection considerations of LLNL’s national security missions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Review of Shock, Vibration, and Other Tests for Type IV Hydrogen Composite Pressure Vessels for Rail Use

Requirements specific to hydrogen rail transportation and its unique components are currently not well represented in safety codes and standards. Notably, one of the most important components of the system, the hydrogen storage vessel, may be subject to entirely different shock and vibration conditions compared to hydrogen tanks on road vehicles. This report focuses on how composite hydrogen tanks are tested for performance and how this may relate to these tanks being used on rail systems. The shock and vibration testing procedures that are relevant for hydrogen composite tanks used for rail applications have been identified, as well as some general testing requirements for hydrogen tanks and composite tanks.

42 ENGINEERING↗

SLAC joins the global fight against COVID-19

The lab is responding to the coronavirus crisis by imaging disease-related biomolecules, developing standards for reliable coronavirus testing and enabling other essential research.

Gnida, Manuel↗

A Strong-QCD Regime Measurement of the Proton’s Spin Structure

The theory of the strong force, Quantum Chromodynamics (QCD) remains one of the most important ways to understand the fundamental properties of ordinary matter. However, at low momentum transfer Q 2 , in the regime where the strong force becomes extremely strong, our understanding of QCD for ordinary nucleons becomes hazy. Several cutting edge theories such as Chiral Perturbation Theory (χPT) and Lattice QCD have provided valuable predictions in this regime, but Lattice QCD has not yet extended predictions of many important quantities to this kinematic region, and Chiral Perturbation Theory has faced several important disagreements with experimental data for the neutron over the last several decades. It is therefore of extreme importance to have a benchmark of experimental data in the low energy regime for the proton’s behavior, as a test of leading theories for the behavior of QCD in this regime. The E08-027 (g2p) experiment ran at Jefferson Lab in 2012 with the goal of collecting this valuable data, and though I was still completing my undergraduate studies at the time, I became involved in the analysis in 2015 and built on the previous work to complete it and analyze the exciting results. This experiment achieved a high precision measurement of the spin structure functions g1 and g2 for the proton, quantities which describe the internal spin structure of the proton. These measurements were taken in the valuable low Q 2 region described above, and used to extract several moments of these spin structure functions which can be directly compared to the cutting-edge predictions of Chiral Perturbation Theory. Though the experiment’s timeline was such that I didn’t have a chance to work directly on the experimental setup, I had the opportunity to acquire hands-on experience working on a polarized target at UNH which is very similar to the crucial polarized target used in the g2p experiment. Full details of the g2p experiment and my experimental work at the University of New Hampshire are presented in this thesis, as well as a detailed description of the analysis process and the exciting benchmark results, which serve as a direct test of all current and future theories of QCD in the low-Q 2 regime.

Ruth, David↗

Insights into catalyst degradation during alkaline water electrolysis under variable operation

Energy conversion technologies that are key to decarbonization efforts face significant durability challenges due to variable operation. Understanding the impact of variable operation on catalytic stability and identifying the key variables that dictate degradation is crucial for developing robust technologies. Here, we present a comprehensive investigation of the effects of variable operation on liquid alkaline water electrolysis. Our findings reveal that variable operation induces severe degradation of Ni, Fe, and Co catalytic films that is not observed during steady-state operation. By systematically interrogating the electrode discharge during simulated shutdown tests using Raman spectroscopy and mass spectrometry techniques, we uncover significant alterations caused by reverse currents in real time. These include changes in crystal structure, composition, film thickness, electronic conductivity, and dissolution rates. Lab-scale electrolyzer experiments further highlight the impact of variable operation on catalyst materials under relevant conditions. Finally, we provide guidelines for leveraging these insights to advance electrocatalysis research. This work underscores the importance of integrating realistic stressors into stability testing and offers practical guidelines for catalyst design, performance evaluation, and industrial implementation. Collectively, insights from this study will drive the development of more resilient energy conversion technologies.

Marquez, Raul A. [Univ. of Texas, Austin, TX (Unit↗

Modeling of Glycolate Destruction in the Recycle Collection Tank

The Savannah River Site’s DWPF is being upgraded with the introduction of the NG flowsheet. Glycolic acid has been shown to be a superior alternative to formic acid for sludge processing. The new flowsheet improves or maintains necessary parameters such as 1) reduction of mercury, 2) adjustment of feed rheology, 3) pH stability, and 4) adjustment of melter oxidation/reduction potential. Further, the use of glycolic acid virtually eliminates the potential for catalytic hydrogen generation in DWPF processing DWPF process condensates are collected and returned to the Savannah River Site (SRS) CSTF. The RCT collects off-gas condensate during chemical processing, vitrification, and other unit operations performed in DWPF and is the singular return vessel delivering recycle effluent back to CSTF. Each batch of recycle will have a small amount of glycolate from chemical processing and melter off-gas condensates. To avoid potential flammability issues due to thermolysis of glycolate in the CSTF, Savannah River National Laboratory (SRNL) provided to Savannah River Remediation (SRR) at their request a Task Technical and Quality Assurance Plan (TTQAP) to quantify and mitigate glycolate returns via DWPF’s recycle stream. The request included testing of a process to oxidize glycolate and other organic species that are responsible for hydrogen generation from thermolysis. Following that work SRR provided a Task Technical Request (TTR) that requested process modeling. In 2021 a TTQAP was issued to cover the modeling work. Modeling draws data from laboratory scale studies using chemical simulants and radioactive waste samples. Chemical kinetic modeling was performed to evaluate the feasibility of using sodium permanganate to destroy glycolate in the RCT. The results from the laboratory studies were summarized in a series of reports. Reference 9 is a report of lab scale processing of actual DWPF Slurry Mix Evaporate Condensate Tank (SMECT) and Offgas Condensate Tank (OGCT) samples in the SRNL Shielded Cells. Tests at caustic conditions demonstrated sodium permanganate was effective in converting glycolate to oxalate, and permanganate (Mn 7+ ) is reduced to manganate (Mn 6+ ) with no significant formation of carbon dioxide or carbonate. Equation (1) was found to best describe the observed reaction of glycolate with permanganate under nominal (60 to 145 mg/L in RCT) glycolate entrainment conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Evaluation of the interfacial bonding strength between hafnia and silica layers deposited by electron-beam evaporation

Factors contributing to the mechanical strength of multilayer optical coatings involving alternating layers of electron-beam evaporated hafnia and silica is investigated. It is observed that upon rupture resulting from nanosecond laser damage, fragments consisting of layer pairs are produced. These pairs are formed as a result of a strong asymmetry in adhesion strength between interfaces, leading to preferential delamination at interfaces where silica is deposited on hafnia, and not the reverse, despite the fact that both interface types consist of the same pair of materials. The observed disparity in adhesion strength was further studied using nanomechanical scratch tests, revealing loads at which fracture occurs, and fracture morphology, both of which are highly dependent on deposition order. Based on these measurements, along with the morphological analysis of the nanostructure of the coatings, we conclude that the surface microstructure in each coating layer affects its adhesion strength with the succeeding layer. The findings outlined here are particularly relevant to the production of large aperture, high-performance optics designed for use in next-generation lasers.

adhesion strength↗

Boosting the interfacial superionic conduction of halide solid electrolytes for all-solid-state batteries

Designing highly conductive and (electro)chemical stable inorganic solid electrolytes using cost-effective materials is crucial for developing all-solid-state batteries. Here, we report halide nanocomposite solid electrolytes (HNSEs) ZrO 2 (-ACl)-A 2 ZrCl 6 (A = Li or Na) that demonstrate improved ionic conductivities at 30 °C, from 0.40 to 1.3 mS cm -1 and from 0.011 to 0.11 mS cm -1 for Li + and Na + , respectively, compared to A 2 ZrCl 6 , and improved compatibility with sulfide solid electrolytes. The mechanochemical method employing Li 2 O for the HNSEs synthesis enables the formation of nanostructured networks that promote interfacial superionic conduction. Via density functional theory calculations combined with synchrotron X-ray and 6 Li nuclear magnetic resonance measurements and analyses, we demonstrate that interfacial oxygen-substituted compounds are responsible for the boosted interfacial conduction mechanism. Compared to state-of-the-art Li 2 ZrCl 6 , the fluorinated ZrO 2 -2Li 2 ZrCl 5 F HNSE shows improved high-voltage stability and interfacial compatibility with Li 6 PS 5 Cl and layered lithium transition metal oxide-based positive electrodes without detrimentally affecting Li + conductivity. We also report the assembly and testing of a Li-In||LiNi 0.88 Co 0.11 Mn 0.01 O 2 all-solid-state lab-scale cell operating at 30 °C and 70 MPa and capable of delivering a specific discharge of 115 mAh g -1 after almost 2000 cycles at 400 mA g -1 .

36 MATERIALS SCIENCE↗

Performance of photosensors in a high-rate environment for gas Cherenkov detectors

We report the solenoidal large intensity device (SoLID) at Jefferson Lab will push the boundaries of luminosity for a large-acceptance detector, which necessitates the use of a light-gas threshold Cherenkov counter for online event selection. Due to the high luminosity, the single-photon background rate in this counter can exceed 160 kHz/cm 2 at the photosensors. Therefore, it is essential to validate the high-rate limits of the planned photosensors and readout electronics in order to mitigate the risk of failure. We report on the design and an early set of studies carried out using a small Cherenkov counter in a high-rate environment up to 60 kHz/cm 2 , in Hall C at Jefferson Lab. Commercially available multi-anode photomultipliers (MaPMT) and low-cost large-area picosecond photodetectors (LAPPD) were tested using the JLab FADC250 modules for readout. The test beam results show that the MaPMT array and the internal stripline LAPPD can detect and identify single-electron and pair-production events in high-rate environments. Due to its higher quantum efficiency, the MaPMT array provided a better separation between the single-electron and the pair-production events compared to the internal stripline LAPPD. A GEANT4 simulation confirms the beam test performance of our counter device.

47 OTHER INSTRUMENTATION↗

ALDCP Student Team 7/25/19 Briefing [Slides]

This set of slides documents the activities of the Associate Laboratory Directorate for Capital Projects (ALDCP) student team during the week of July 25, 2019. It summarizes the involvement of the group in the Smart Lab project, and the individual progress of separate projects, including the Life-Cycle Cost Analysis (LCCA) Calculator and Tests, the HVAC Renovation, and the Renovation Feasibility Study, with accomplishments and barriers for each.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Aerial Crosspolarized NQR-NMR: Buried Explosive Detection From a Safe Distance

Nuclear quadrupole resonance is a non-destructive detection and inspection technique with potential as a non-destructive test (NDT) tool. Establishment of the capability opens the door to its use in furthering the mission of the labs. There are many possible uses of the capability: explosive detection and stress/strain detection in epoxies are two of the more obvious and are the main results of this work. Enhancement of the signal-to-noise ratio (SNR) and improvements in the acquisition time of the experiment were key focuses of this work. These were achieved by combing special spin-lock pulse sequences with cross-polarization (CP) schemes to improve the signals with shorter acquisition times. A novel rotating magnetic field device was created to facilitate CP in the field. Implementation of these schemes provided a significant reduction in SNR/time.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Exploring flexible communications for streamlining DNN ensemble training pipelines

Parallel training of a Deep Neural Network (DNN) ensemble on a cluster of nodes is a common practice to train multiple models in order to construct a model with a higher prediction accuracy, or to quickly tune the parameters of a training model. Existing ensemble training pipelines perform a great deal of redundant operations, resulting in unnecessary CPU usage, or even poor pipeline performance. In order to remove these redundancies, we need pipelines with more communication flexibility than existing DNN frameworks can provide. This project investigates a series of designs to improve pipeline flexibility and adaptivity, while also increasing performance. We implement our designs using Tensorflow with Horovod, and test it using several large DNNs in a large scale GPU cluster, the Titan supercomputer at Oak Ridge National Lab. Our results show that with the new flexible communication schemes, the CPU time spent during training is reduced by 2-11X. Furthermore, our implementation can achieve up to 10X speedups when CPU core limits are imposed. Our best pipeline also reduces the average power draw of the ensemble training process by 5--16% when compared to the baseline.

Pittman, Randall↗