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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Infrared Photon Pair-Production in Ligand-Sensitized Lanthanide Nanocrystals

This report details spectroscopic characterizations of rare-earth, core-shell nanoparticles decorated with the f -element chelator 3,4,3-LI(1,2-HOPO). Evidence of photon downconversion is corroborated through detailed power dependence measurements, which suggest two-photon decay paths are active in these materials, albeit only representing a minority contribution of the sum luminescence, with emission being dominated by normal, Stokes' shifted fluorescence. Specifically, ultraviolet ligand photosensitization of Nd 3+ ions in a NaGdF 4 host shell results in energy transfer to a Nd 3+ /Yb 3+ -doped NaGdF 4 nanoparticle core. The population and subsequent decay of core, Yb 3+ 2 F 5/2 states result in a spectral shift of 620 nm, manifested in a NIR emission displaying luminescence profiles diagnostic of Yb 3+ and Nd 3+ excited state decays. Emphasis is placed on the generality of this material architecture for realizing ligand-pumped, multi-photon downconversion, with the Nd 3+ /Yb 3+ system presented here functioning as a working prototype for a design principle that may be readily extended to other lanthanide pairs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Numerical and Experimental Investigation of Nanostructure-Based Asymmetric Light Transmission Interfaces for Solar Concentrator Applications

Research in asymmetric light transmission interfaces has been recently gaining traction. While traditionally considered for optical circuitry applications, there is a new interest to use these interfaces in luminescent solar concentrators. Previous studies have shown that applying them to the top surface of a concentrator could mitigate surface losses. This paper presents experimental results for proof-of-concept asymmetric light transmission interfaces that may have potential applications in luminescent solar concentrators. The interfaces and the underneath substrate were created in a single step from polydimethylsiloxane using silicon molds fabricated on <100> wafers via anisotropic wet etching. The resulting structures were pyramidal in shape. Large surface areas of nanostructures repeating at 800 nm, 900 nm, and 1000 nm were tested for backward and forward transmission using a spectrometer. Results showed a 21%, 10%, and 0% average transmissivity difference between the forward and backward directions for each periodicity, respectively. The trends seen experimentally were confirmed numerically via COMSOL simulations.

Oliveto, Vincent↗
DOE OSTI2022

Near Infrared Emitting Semiconductor Polymer Dots for Bioimaging and Sensing

Semiconducting polymer dots (Pdots) are rapidly becoming one of the most studied nanoparticles in fluorescence bioimaging and sensing. Their small size, high brightness, and resistance to photobleaching make them one of the most attractive fluorophores for fluorescence imaging and sensing applications. This paper highlights our recent advances in fluorescence bioimaging and sensing with nanoscale luminescent Pdots, specifically the use of organic dyes as dopant molecules to modify the optical properties of Pdots to enable deep red and near infrared fluorescence bioimaging applications and to impart sensitivity of dye doped Pdots towards selected analytes. Building on our earlier work, we report the formation of secondary antibody-conjugated Pdots and provide Cryo-TEM evidence for their formation. We demonstrate the selective targeting of the antibody-conjugated Pdots to FLAG-tagged FLS2 membrane receptors in genetically engineered plant leaf cells. We also report the formation of a new class of luminescent Pdots with emission wavelengths of around 1000 nm. Finally, we demonstrate the formation and utility of oxygen sensing Pdots in aqueous media.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Intrinsic and Extrinsic Exciton Recombination Pathways in AgInS 2 Colloidal Nanocrystals

Ternary I-III-VI 2 nanocrystals (NCs), such as AgInS 2 and CuInS 2 , are garnering interest as heavy-metal-free materials for photovoltaics, luminescent solar concentrators, LEDs, and bioimaging. The origin of the emission and absorption properties in this class of NCs is still a subject of debate. Recent theoretical and experimental studies revealed that the characteristic Stokes-shifted and long-lived luminescence of stoichiometric CuInS 2 NCs arises from the detailed structure of the valence band featuring two sublevels with different parity. The same valence band substructure is predicted to occur in AgInS 2 NCs, yet no experimental confirmation is available to date. Here, we use complementary spectroscopic, spectro-electrochemical, and magneto-optical investigations as a function of temperature to investigate the band structure and the excitonic recombination mechanisms in stoichiometric AgInS 2 NCs. Transient transmission measurements reveal the signatures of two subbands with opposite parity, and photoluminescence studies at cryogenic temperatures evidence a dark state emission due to enhanced exchange interaction, consistent with the behavior of stoichiometric CuInS 2 NCs. Lowering the temperature as well as applying reducing electrochemical potentials further suppress electron trapping, which represents the main nonradiative channel for exciton decay, leading to nearly 100% emission efficiency.

36 MATERIALS SCIENCE↗
NASA NTRS1969

The Fraunhofer line discriminator: An airborne fluorometer

An experimental Fraunhofer Line Discriminator (FLD) can differentiate and measure solar-stimulated luminescence when viewed against a background of reflected light. Key elements are two extremely sensitive photomultipliers, two glass-spaced Fabry-Perot filters having a bandwidth less than 1 A, and an analog computer. As in conventional fluorometers, concentration of a fluorescent substance is measured by comparison with standards. Quantitative use is probably accurate only at low altitudes but detection of luminescent substances should be possible from any altitude. Applications of the present FLD include remote sensing of fluorescent dyes used in studies of current dynamics. The basic technique is applicable to detection of oil spills, monitoring of pollutants, and sensing over land areas.

Stoertz, G. E.↗
NASA NTRS1969

Fraunhofer line-dept sensing applied to water

An experimental Fraunhofer line discriminator is basically an airborne fluorometer, capable of quantitatively measuring the concentration of fluorescent substances dissolved in water. It must be calibrated against standards and supplemented by ground-truth data on turbidity and on approximate vertical distribution of the fluorescent substance. Quantitative use requires that it be known in advance what substance is the source of the luminescence emission; qualitative sensing, or detection of luminescence is also possible. The two approaches are fundamentally different, having different purposes, different applications, and different instruments. When used for sensing of Rhodamine WT dye in coastal waters and estuaries, the FLD is sensing in the spectral region permitting nearly maximum depth of light penetration.

Stoertz, G. E.↗
NASA NTRS1971

A study of irradiation-induced defects in silicon using low temperature photoluminescence

Irradiation-induced defects in silicon, using low temperature photoluminescence as a probe of defect properties were investigated. The goal of this research was to gain new understanding of defects which degrade solar cell characteristics in a radiation environment. In this regard, an important aspect of this program was a study of radiation damage and annealing in lithium doped silicon, which is useful in reducing solar cell degradation. Luminescence was used to study defects because this property reveals electron transitions through a number of defect energy levels at any given annealing stage; the luminescence spectra give excellent resolution of many defect energy levels, and these measurements can be used to give defect symmetry in the lattice, impurity dependence, and annealing properties.

Streetman, B. G.↗
NASA NTRS1973

GaN for LED applications

In order to improve the synthesis of GaN the effect of various growth and doping parameters has been studied. Although Be, Li, Mg, and Dy can be used to overcompensate native donors, the most interesting acceptor element is Zn. The emission spectrum and the luminescence efficiency depend on the growth temperature (below 800 C), on the partial pressure of the doping impurity, and on the duration of growth. Blue-green electroluminescence with a power efficiency of 0.1 percent and a brightness of 850 fL (at 0.6 mA and 22.5 V) was obtained. Some diodes allow the color of the emitted light to change by reversing the polarity of the bias. Continuous operation of a diode over a period of 5 months showed no evidence of degradation. The luminescence properties of ion-implanted GaN were studied. Delay effects were found in the electroluminescence of diodes, although, with a dc bias, a 70-MHz modulation was possible.

Pankove, J. I.↗
NASA NTRS1977

Application of luciferase assay for ATP to antimicrobial drug susceptibility

The susceptibility of bacteria, particularly those derived from body fluids, to antimicrobial agents is determined in terms of an ATP index measured by culturing a bacterium in a growth medium. The amount of ATP is assayed in a sample of the cultured bacterium by measuring the amount of luminescent light emitted when the bacterial ATP is reacted with a luciferase-luciferin mixture. The sample of the cultured bacterium is subjected to an antibiotic agent. The amount of bacterial adenosine triphosphate is assayed after treatment with the antibiotic by measuring the luminescent light resulting from the reaction. The ATP index is determined from the values obtained from the assay procedures.

Chappelle, E. W.↗
NASA NTRS1977

Lunar transient phenomena /LTP/ - Manifestations, site distribution, correlations and possible causes

More than 1400 observations of lunar transient phenomena (LTP), encompassing brightenings, darkenings, and gaseous, reddish, and bluish events, are analyzed in an attempt to determine the possible causes of LTP. Hypotheses considered include effects of earth tides on the moon, low-angle illumination, thermal luminescence, UV heating, solar-particle acceleration by the magnetopause of earth's magnetotail, terrestrial magnetotail bow-shock-front turbulence, cathode luminescence due to magnetotail effects, and solar-flare particle bombardment. Analysis are performed in terms of histograms of the number of observations vs. phase of anomalistic period and of number vs. moon's age, percentage of numbers of observed phenomena and percentage of expected numbers as well as their ratios, and albedo behavior over a lunation period of chosen permanent points in ten specific features. The results indicate that different phenomena may have different causes, strong tidal effects are dubious, correlations with sunrise are most frequent, and the distribution of all LTP sites is distinct from that of deep- and shallow-focus moonquake epicenters.

Cameron, W. S.↗
NASA NTRS1981

Mechanical aggregation of enstatite chondrites from an inhomogeneous debris cloud

Enstatite chondrites have oxygen isotope ratios closer to those of the earth and moon than other meteorites. Their minerals are chemically reduced; metal contains Si, and some Ca, Ti, Mg and Mn are incorporated in sulphides rather than silicates. Clinoenstatite and olivine are virtually Fe-free. Two types of clinoenstatite in the Indarch enstatite chondrite have been reported, one luminescing blue and one red. Similar clinoenstatites in the Kota-Kota enstatite chondrite are associated with two distinct types of forsteritic olivine, one luminescing orange and the other blue. The textural relations and differences in chemical composition cannot be explained by progressive condensation from the solar nebula and require the mechanical mixing of material from at least two sources. It is suggested here that enstatite chondrites result from mechanical and chemical processes during aerodynamic sorting and gravitational settling of debris from a hot cloud of dust, liquid and gas produced during collision of planetesimals.

Leitch, C. A.↗
NASA NTRS1983

Theory of interstellar medium diagnostics

The theoretical interpretation of observed interplanetary resonance luminescence patterns is used as one of the must promising methods to determine the state of the local interstellar medium (LISM). However, these methods lead to discrepant results that would be hard to understand in the framework of any physical LISM scenario. Assuming that the observational data are reliable, two possibilities which could help to resolve these discrepancies are discussed: (1) the current modeling of resonance luminescence patterns is unsatisfactory and has to be improved, and (2) the extrapolated interstellar parameters are not indicative of the unperturbed LISM state, but rather designate an intermediate state attained in the outer regions of the solar system. It is shown that a quantitative treatment of the neutral gas-plasma interaction effects in the interface between the heliospheric and the interstellar plasmas is of major importance for the correct understanding of the whole complex.

Fahr, H. J.↗
NASA NTRS1984

Changes of LISM Characteristics in the Heliospheric Interface

The LISM properties can be deduced from observations of interstellar neutral gases in the inner solar system. Parameters accessible by this method are the interstellar wind vector and the densities and temperatures of hydrogen and helium, implying also the deduction of the relative abundance ratios and the degree of ionization in the LISM. Direct inference from observations, for example resonance luminescence measurements of Ly-alpha and He-58.4 nm radiation, yields values appropriate only for the inner solar system, i.e. for the regions within the heliopause dominated by the solar wind plasma. Particularly the subsonic LISM plasma interface ahead of the heliopause causes profound changes in the properties of the neutral LISM gas traversing this region. Mainly p-H charge exchange processes ive rise to the destruction of primary hydrogen and the production of secondary hydrogen atoms, the net effect being a depletion of the neutral hydrogen component of the LISM by about 50%. Details on the depletion mechanisms, the hydrogen and oxygen extinctions, and the consequences for the Ly-alpha resonance luminescence intensity interpretations are presented.

Ripken, H. W.↗
NASA NTRS1986

Pregraphitic molecules and the red-rectangle emission

In light of the recent identification of an infrared emission band at 3.3, 6.2, 7.7, 8.6, and 11 microns as emissions from pregraphitic molecules, the possibility that a large broad emission bump in the red part of the spectrum of the Red-Rectangle (AFGL 918) nebula is luminescence from the same molecules was investigated. The abundance, luminescence yield of the carrier, and the phosphorescence is discussed.

Dhendecourt, L.↗
NASA NTRS1987

Method and apparatus for measuring minority carrier lifetime in a direct band-gap semiconductor

A direct band-gap semiconductor is exposed to intensity-modulated photon radiation having a characteristic energy at least as great as the energy gap of the semiconductor. This produces a time dependent concentration of excess charge carriers through the material, producing a luminescence signal modulated at the same frequency as the incident radiation but shifted in phase by an amount related to the lifetime of minority carriers. In a preferred embodiment, the phase shift of the luminescence signal is determined by transforming it to a modulated electrical signal and mixing the electrical signal with a reference signal modulated at the same frequency and having a phase which is known relative to the incident radiation. Minority carrier lifetime is calculated by integrating a direct current component of the mixed signal (F sub dc) over a 2 pi range in phase of the reference signal.

Vonroos, Oldwig↗
NASA NTRS1989

Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices

During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.

Wdowiak, Thomas J.↗
NASA NTRS1992

Phosphor Scanner For Imaging X-Ray Diffraction

Improved optoelectronic scanning apparatus generates digitized image of x-ray image recorded in phosphor. Scanning fiber-optic probe supplies laser light stimulating luminescence in areas of phosphor exposed to x rays. Luminescence passes through probe and fiber to integrating sphere and photomultiplier. Sensitivity and resolution exceed previously available scanners. Intended for use in x-ray crystallography, medical radiography, and molecular biology.

Carter, Daniel C.↗
NASA NTRS1992

Near-infrared cathodoluminescence imaging of defect distributions in In(0.2)Ga(0.8)As/GaAs multiple quantum wells grown on prepatterned GaAs

The defect distribution in a highly strained In(0.2)Ga(0.8)As/GaAs multiple-quantum-well (MQW) structure grown on a patterned GaAs substrate is examined with cathodoluminescence imaging and spectroscopy in the near IR. By spatially correlating the luminescence arising from the MQW exciton recombination (950 nm) with the longer wavelength (1000-1200 nm) luminescence arising from the defect-induced recombination, it is demonstrated that it is possible to determine the regions of highest film quality in both the mesa and valley regions. The present approach enables a judicious determination of the optimal regions to be used for active pixels in InGaAs/GaAs spatial light modulators.

Rich, D. H.↗