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At least 577 records · Page 32

Adventures in Actinide Chemistry: A Year of Exploring Uranium and Thorium in Los Alamos

The first part of this collection of slides is concerned with considerations when working with actinides. The topics discussed in the document as a whole are the following: Actinide chemistry vs. transition metal chemistry--tools we can use; New synthetic methods to obtain actinide hydrides; Actinide metallacycles: synthesis, structure, and properties; and Reactivity of actinide metallacycles.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Dose Assessment of Los Alamos National Laboratory-Derived Residual Radionuclides in Soils within C Tracts (C-2, C-3, and C-4) for Land Transfer Decisions

Three separate Sampling and Analysis Plans (SAPs) were prepared for tracts C-2, C-3, and C-4. The objective of sampling was to confirm, within the stated statistical confidence limits, that the mean levels of potential radioactive residual contamination in soils in the C Tracts are documented, in appropriate units, and are below the 15 mrem/y (150 μSv/y) Screening Action Levels (SALs). Results show that radionuclide concentration upper-bound 95% confidence levels were close to background levels, with the exception of Pu-239 and Cs-137 being slightly elevated above background, and all measurements were below the ALs and meet the real property release criteria for future construction or recreational use. A follow-up ALARA analysis showed that the costs of cleanup of the soil in areas of elevated concentration and confirmatory sampling would far exceed any benefit from dose reduction.

54 ENVIRONMENTAL SCIENCES↗

Meteorology Assessment of Historic Rainfall for Los Alamos During September 2013

DOE Order 420.1, Facility Safety, requires that site natural phenomena hazards be evaluated every 10 years to support the design of nuclear facilities. The evaluation requires calculating return period rainfall to determine roof loading requirements and flooding potential based on our on-site rainfall measurements. The return period rainfall calculations are done based on statistical techniques and not site-specific meteorology. This and future studies analyze the meteorological factors that produce the significant rainfall events. These studies provide the meteorology context of the return period rainfall events.

54 ENVIRONMENTAL SCIENCES↗

Los Alamos National Security, LLC Request for Information on how industry may partner with the Laboratory on KIVA software.

KIVA is a family of Fortran-based computational fluid dynamics software developed by LANL. The software predicts complex fuel and air flows as well as ignition, combustion, and pollutant-formation processes in engines. The KIVA models have been used to understand combustion chemistry processes, such as auto-ignition of fuels, and to optimize diesel engines for high efficiency and low emissions. Fuel economy is heavily dependent upon engine efficiency, which in turn depends to a large degree on how fuel is burned within the cylinders of the engine. Higher in-cylinder pressures and temperatures lead to increased fuel economy, but they also create more difficulty in controlling the combustion process. Poorly controlled and incomplete combustion can cause higher levels of emissions and lower engine efficiencies.

33 ADVANCED PROPULSION SYSTEMS↗

Los Alamos National Laboratory Support for Commercial U.S. Production of 99 Mo without the Use of Highly Enriched Uranium

There is currently a serious shortage of 99 Mo, from which to generate the medically significant isotope 99m Tc. Most of the world's supply comes from the fission of highly enriched uranium targets--this is a proliferation concern. This document focuses on the technology involved in two alternative methods: electron accelerator production of 99 Mo from the 100 Mo(γ,n) 99 Mo reaction and production of 99 Mo as a fission product in a subcritical, DT accelerator-driven low enriched uranium salt solution.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Evaluation of Tower Shadowing on Anemometer Measurements at Los Alamos National Laboratory

The objective of this study is to evaluate the effect of tower shadowing from the meteorology towers at LANL during 2014. This study is in response to the Department of Energy Meteorological Coordinating Council visit in 2015 that recommended an evaluation of any biases in the wind data introduced by the tower and boom alignment at all meteorology towers.

47 OTHER INSTRUMENTATION↗

Experimental Studies of Engineered Barrier Systems Conducted at Los Alamos National Laboratory (FY16)

Over the past five years the Used Fuel Campaign has investigated Engineered Barrier Systems (EBS) at higher heat loads (up to 300°C) and pressure (150 bar). This past year experimental work was hindered due to a revamping of the hydrothermal lab. Regardless, two experiments were run this past year, EBS-18 and EBS-19. EBS-18 was run using Low Carbon Steel (LCS) and opalinus clay in addition to the bentonite and opalinus brine. Many of the past results were confirmed in EBS-18, such as the restriction of illite formation due to the bulk chemistry, pyrite degradation, and zeolite formation dependent on the bentonite and opalinus clay. The LCS show vast amounts of pit corrosion (over 100μm of corrosion in six weeks), leading a corrosion rate of 1083 μm/year. In addition, a mineral goethite, an iron-bearing hydroxide, formed in the pits of the LCS. Preliminary results from EBS-19 water chemistry are included but SEM imaging, micro probe and XRD are still needed for further results. Copper corrosion was investigated further and over 850 measurements were taken. It was concluded that pitting and pyrite degradation drastically increase the corrosion rate from 0.12 to 0.39 μm/day. However, the growth of a layer of the mineral chalcocite is thought to subdue the corrosion rate to 0.024 μm/day as observed in the EBS-13, a sixth month experiment. This document presents the findings of this past year.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

2016 Final Reports from the Los Alamos National Laboratory Computational Physics Student Summer Workshop

The two primary purposes of LANL’s Computational Physics Student Summer Workshop are (1) To educate graduate and exceptional undergraduate students in the challenges and applications of computational physics of interest to LANL, and (2) Entice their interest toward those challenges. Computational physics is emerging as a discipline in its own right, combining expertise in mathematics, physics, and computer science. The mathematical aspects focus on numerical methods for solving equations on the computer as well as developing test problems with analytical solutions. The physics aspects are very broad, ranging from low-temperature material modeling to extremely high temperature plasma physics, radiation transport and neutron transport. The computer science issues are concerned with matching numerical algorithms to emerging architectures and maintaining the quality of extremely large codes built to perform multi-physics calculations. Although graduate programs associated with computational physics are emerging, it is apparent that the pool of U.S. citizens in this multi-disciplinary field is relatively small and is typically not focused on the aspects that are of primary interest to LANL. Furthermore, more structured foundations for LANL interaction with universities in computational physics is needed; historically interactions rely heavily on individuals’ personalities and personal contacts. Thus a tertiary purpose of the Summer Workshop is to build an educational network of LANL researchers, university professors, and emerging students to advance the field and LANL’s involvement in it.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Nuclear Forensics at Los Alamos National Laboratory

Nuclear forensics assists in responding to any event where nuclear material is found outside of regulatory control; a response plan is presented and a nuclear forensics program is undergoing further development so that smugglers are sufficiently deterred.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Los Alamos National Laboratory Request for Proposals: Trident Laser System (TLS) Redeployment and Life Extension, October 5, 2016

In May 2016, LANS announced that the Trident Laser Facility would cease operating effective September 15, 2016. That date was subsequently extended. The current plan is to operate for an additional, limited period in early CY 2017, and to leverage that activity to provide a training opportunity to the party that will redeploy the TLS. The TLS will then be disassembled and packaged for shipping to the new site, where it may be reconstituted and continue to be used by the physics research community. It is LANS’ intent that Trident will be sited with an organization that will supply its own funding for TLS installation, calibration, and lifecycle operation. Ideally, the receiving party will plan to upgrade TLS with new capability. The equipment to be transferred includes the laser, its power supply, target station and chamber, and a suite of diagnostic instrumentation. Under a Joint Use Agreement it is anticipated that all equipment will remain property of the Laboratory and subject to on-site configuration verification.

99 GENERAL AND MISCELLANEOUS↗