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DOE OSTI2024

Quantum teleportation coexisting with classical communications in optical fiber

The ability for quantum and conventional networks to operate in the same optical fibers would aid the deployment of quantum network technology on a large scale. Quantum teleportation is a fundamental operation in quantum networking, but has yet to be demonstrated in fibers populated with high-power conventional optical signals. Here we report, to the best of our knowledge, the first demonstration of quantum teleportation over fibers carrying conventional telecommunications traffic. Quantum state transfer is achieved over a 30.2-km fiber carrying 400-Gbps C-band classical traffic with a Bell state measurement performed at the fiber’s midpoint. To protect quantum fidelity from spontaneous Raman scattering noise, we use optimal O-band quantum channels, narrow spectro-temporal filtering, and multi-photon coincidence detection. Fidelity is shown to be well maintained with an elevated C-band launch power of 18.7 dBm for the single-channel 400-Gbps signal, which we project could support multiple classical channels totaling many terabits/s aggregate data rates. These results show the feasibility of advanced quantum and classical network applications operating within a unified fiber infrastructure.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2019

Biogeochemical Equation of State for the Sea-Air Interface

We have recently argued that marine interfacial surface tension must have a distinctive biogeography because it is mediated by fresh surfactant macromolecules released locally through the food web. Here we begin the process of quantification for associated climate flux implications. A low dimensionality (planar) equation of state is invoked at the global scale as our main analysis tool. For the reader’s convenience, fundamental surfactant physical chemistry principles are reviewed first, as they pertain to tangential forces that may alter oceanic eddy, ripple, and bubble fields. A model Prandtl (neutral) wind stress regime is defined for demonstration purposes. It is given the usual dependence on roughness, but then in turn on the tension reduction quantity known as surface pressure. This captures the main net influences of biology and detrital organics on global microlayer physics. Based on well-established surrogate species, tangent pressures are related to distributed ecodynamics as reflected by the current marine systems science knowledge base. Reductions to momentum and related heat-vapor exchange plus gas and salt transfer are estimated and placed on a coarse biogeographic grid. High primary production situations appear to strongly control all types of transfer, whether seasonally or regionally. Classic chemical oceanographic data on boundary state composition and behaviors are well reproduced, and there is a high degree of consistency with conventional micrometeorological wisdom. But although our initial best guesses are quite revealing, coordinated laboratory and field experiments will be required to confirm the broad hypotheses even partially. We note that if the concepts have large scale validity, they are super-Gaian. Biological control over key planetary climate-transfer modes may be accomplished through just a single rapidly renewed organic monolayer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1974

Maximizing profits in international technology transfer

Maximum profit can be introduced into international technology transfer by observing the following: (1) ethical and open dealing between the parties; (2) maximum knowledge of all facts concerning the technology, the use of the technology, the market, competition, prices, and alternatives; (3) ability to coordinate exports, service, support activities, licensing and cross licensing; and (4) knowledgeable people which put these factors together.

Straube, W.↗

NASA NTRS1974

Radiative relaxation rates and intensities during outer planet entries

Gas properties which can affect outer planetary entry probe radiative heat transfer are reviewed in order to predict the effect of processes such as radiative relaxation, radiative cooling, and equilibrium radiation intensities on entry. These processes are quantified in order to avoid overestimating the radiative transfer by an over simplified approach to the problem. By reducing the uncertainties in the knowledge of these processes, the heatshield weight is minimized by reducing safety factors and performance limits.

Leibowitz, L.↗

NASA NTRS1991

Direct simulation of turbulent combustion

Understanding and modeling of turbulent combustion are key problems in the computation of numerous practical systems. Because of the lack of analytical theories in this field and of the difficulty of performing precise experiments, direct simulation appears to be one of the most attractive tools to use in addressing this problem. From Sep. 1989 - Sep. 1990, the following problems were studied using direct simulation but also experiments and theoretical models: (1) the influence of curvature on premixed flame fronts; (2) the construction of a model for the flame stretch based on direct simulation and multifractal analysis; and (3) the simulation of the interaction between random flow field and a flame front. The general objective was to improve knowledge of turbulent combustion but also to use this information for turbulent combustion models. The transfer of direct simulation results towards models is also in progress. A submodel to evaluate the flame stretch was derived from the present study and incorporated in the Coherent Flame model used in France for piston and aircraft engines.

Poinsot, Thierry J.↗

DOE OSTI2016

Hierarchical Inorganic Assemblies for Artificial Photosynthesis

Artificial photosynthesis is an attractive approach for renewable fuel generation because it offers the prospect of a technology suitable for deployment on highly abundant, non-arable land. Recent leaps forward in the development of efficient and durable light absorbers and catalysts for oxygen evolution and the growing attention to catalysts for carbon dioxide activation brings into focus the tasks of hierarchically integrating the components into assemblies for closing of the photosynthetic cycle. A particular challenge is the efficient coupling of the multi-electron processes of CO 2 reduction and H 2 O oxidation. Among the most important requirements for a complete integrated system are catalytic rates that match the solar flux, efficient charge transport between the various components, and scalability of the photosynthetic assembly on the unprecedented scale of terawatts in order to have impact on fuel consumption. To address these challenges, we have developed in this paper a heterogeneous inorganic materials approach with molecularly precise control of light absorption and charge transport pathways. Oxo-bridged heterobinuclear units with metal-to-metal charge-transfer transitions absorbing deep in the visible act as single photon, single charge transfer pumps for driving multi-electron catalysts. A photodeposition method has been introduced for the spatially directed assembly of nanoparticle catalysts for selective coupling to the donor or acceptor metal of the light absorber. For CO 2 reduction, a Cu oxide cluster is coupled to the Zr center of a ZrOCo light absorber, while coupling of an Ir nanoparticle catalyst for water oxidation to the Co donor affords closing of the photosynthetic cycle of CO 2 conversion by H 2 O to CO and O 2 . Optical, vibrational, and X-ray spectroscopy provide detailed structural knowledge of the polynuclear assemblies. Time resolved visible and rapid-scan FT-IR studies reveal charge transfer mechanisms and transient surface intermediates under photocatalytic conditions for guiding performance improvements. Separation of the water oxidation and carbon dioxide reduction half reactions by a membrane is essential for efficient photoreduction of CO 2 by H 2 O to liquid fuel products. A concept of a macroscale artificial photosystem consisting of arrays of Co oxide–silica core–shell nanotubes is introduced in which each tube operates as a complete, independent photosynthetic unit with built-in membrane separation. The ultrathin amorphous silica shell with embedded molecular wires functions as a proton conducting, molecule impermeable membrane. Photoelectrochemical and transient optical measurements confirm tight control of charge transport through the membrane by the orbital energetics of the wire molecules. Finally, hierarchical arrangement of the components is accomplished by a combination of photodeposition, controlled anchoring, and atomic layer deposition methods.

36 MATERIALS SCIENCE↗

NASA NTRS2005

Measurement of the Shear Lift Force on a Bubble in a Channel Flow

Two-phase flow systems play vital roles in the design of some current and anticipated space applications of two-phase systems which include: thermal management systems, transfer line flow in cryogenic storage, space nuclear power facilities, design and operation of thermal bus, life support systems, propulsion systems, In Situ Resource Utilization (ISRU), and space processes for pharmaceutical applications. The design of two-phase flow systems for space applications requires a clear knowledge of the behaviors of the dispersed phase (bubble), its interaction with the continuous phase (liquid) and its effect on heat and mass transfer processes, The need to understand the bubble generation process arises from the fact that for all space applications, the size and distribution of bubbles are extremely crucial for heat and mass transfer control. One important force in two-phase flow systems is the lift force on a bubble or particle in a liquid shear flow. The shear lift is usually overwhelmed by buoyancy in normal gravity, but it becomes an important force in reduced gravity. Since the liquid flow is usually sheared because of the confining wall, the trajectories of bubbles and particles injected into the liquid flow are affected by the shear lift in reduced gravity. A series of experiments are performed to investigate the lift force on a bubble in a liquid shear flow and its effect on the detachment of a bubble from a wall under low gravity conditions. Experiments are executed in a Poiseuille flow in a channel. An air-water system is used in these experiments that are performed in the 2.2 second drop tower. A bubble is injected into the shear flow from a small injector and the shear lift is measured while the bubble is held stationary relative to the fluid. The trajectory of the bubble prior, during and after its detachment from the injector is investigated. The measured shear lift force is calculated from the trajectory of the bubble at the detachment point. These values for the shear lift are then compared with the theoretical predictions from various published works on shear lift in the open literature, which include asymptotic solutions at low bubble Reynolds number, potential flow predictions and numerical studies that deal with intermediate bubble Reynolds numbers.

Nahra, Henry K.↗

DOE OSTI2018

A visual wikipedia for satellite imagery

GeoVisipedia (Geospatial Visual Wikipedia) is a new and novel approach to sharing knowledge about complex geospatial entities such as facilities. Facilities are composed of interconnected objects such as buildings, chemical processing units, electrical generation equipment and similar structures. Satellite imagery of a facility reveals a great deal about the organization and visual appearance of objects in a facility, but very little about the identity or function of the object. For example, given a satellite imagery of an oil refinery, an expert in refining readily identifies distillation units and can explain how they work. A non-expert would have a very difficult time identifying these objects let alone explaining how they function. To make highly complex information accessible to non-experts, GeoVisipedia associates a wiki page with objects in satellite imagery. A user selects an object in the image and a wiki page appears that provides the user with detailed information about the object. Experts can author information into the wiki and this information is shared with other users. Additionally, GeoVisipedia automatically transfers all wiki pages from one image of a facility to other imagery of the facility. Consequentially, knowledge about objects in the facility integrates over time as new imagery becomes available and as new wiki pages are created and additional information is added to existing wiki pages. In this respect, satellite imagery becomes a portal to expert knowledge and insight about objects in a facility.

Roberts, Randy↗

NASA NTRS2000

Modeling Heat-Transfer in Animal Habitats in the Shuttle Orbiter Middeck

A mathematical model has been developed to evaluate the heat transfer characteristics of an Animal Enclosure Module (AEM) in the microgravity environment. The AEM is a spaceflight habitat that provides life support for up to six rodents in the Space Shuttle Middeck. Currently, temperatures within the AEM are recorded in real time using a solid state data recorder; however, the data are only available for analysis post-flight. This temperature information is useful for characterizing the thermal environment of the AEM for researchers, but is unavailable during flight operations. Because animal health in microgravity is directly linked to the thermal environment, the ability to predict internal AEM temperatures is extremely useful to life science researchers. NASA flight crews typically carry hand-held temperature measurement devices which allow them to provide ground researchers with near real time readings of AEM inlet temperature; however, higher priority operations limit the frequency at which these measurements can be made and subsequently downlinked. The mathematical model developed allows users to predict internal cage volume temperatures based on knowledge of the ambient air temperature entering the AEM air intake ports. Additionally, an average convective heat transfer coefficient for the AEM has been determined to provide engineers with the requisite information to facilitate future design improvements and product upgrades. The model has been validated using empirical data from a series of three Space Shuttle missions.

Eodice, Michael T.↗

NASA NTRS2019

Micrometeoroid Events in LISA Pathfinder

The zodiacal dust complex, a population of dust and small particles that pervades the solar system, provides important insight into the formation and dynamics of planets, comets, asteroids, and other bodies. We present a new set of data obtained from direct measurements of momentum transfer to a spacecraft from individual particle impacts. This technique is made possible by the extreme precision of the instruments flown on the LISA Pathfinder spacecraft, a technology demonstrator for a future space-based gravitational wave observatory. Pathfinder employed a technique known as drag-free control that achieved rejection of external disturbances, including particle impacts, using a micropropulsion system. Using a simple model of the impacts and knowledge of the control system, we show that it is possible to detect impacts and measure properties such as the transferred momentum, direction of travel, and location of impact on the spacecraft. In this paper, we present the results of a systematic search for impacts during 4348 hr of Pathfinder data. We report a total of 54 candidates with transferred momenta ranging from 0.2 to 230 μNs. We furthermore make a comparison of these candidates with models of micrometeoroid populations in the inner solar system, including those resulting from Jupiter-family comets (JFCs), Oort Cloud comets, Halley-type comets, and asteroids. We find that our measured population is consistent with a population dominated by JFCs, with some evidence for a smaller contribution from Halley-type comets, in agreement with consensus models of the zodiacal dust complex in the momentum range sampled by LISA Pathfinder.

Thorpe, J. I.↗

NASA NTRS2011

Docking Offset Between the Space Shuttle and the International Space Station and Resulting Impacts to the Transfer of Attitude Reference and Control

The Space Shuttle does not dock at an exact 90 degrees to the International Space Station (ISS) x-body axis. This offset from 90 degrees, along with error sources within their respective attitude knowledge, causes the two vehicles to never completely agree on their attitude, even though they operate as a single, mated stack while docked. The docking offset can be measured in flight when both vehicles have good attitude reference and is a critical component in calculations to transfer attitude reference from one vehicle to another. This paper will describe how the docking offset and attitude reference errors between both vehicles are measured and how this information would be used to recover Shuttle attitude reference from ISS in the event of multiple failures. During STS-117, ISS on-board Guidance, Navigation and Control (GNC) computers began having problems and after several continuous restarts, the systems failed. The failure took the ability for ISS to maintain attitude knowledge. This paper will also demonstrate how with knowledge of the docking offset, the contingency procedure to recover Shuttle attitude reference from ISS was reversed in order to provide ISS an attitude reference from Shuttle. Finally, this paper will show how knowledge of the docking offset can be used to speed up attitude control handovers from Shuttle to ISS momentum management. By taking into account the docking offset, Shuttle can be commanded to hold a more precise attitude which better agrees with the ISS commanded attitude such that start up transients with the ISS momentum management controllers are reduced. By reducing start-up transients, attitude control can be transferred from Shuttle to ISS without the use of ISS thrusters saving precious on-board propellant, crew time and minimizing loads placed upon the mated stack.

Helms, W. Jason↗

NASA NTRS2004

Developing Advanced Support Technologies for Planetary Exploration Missions

The United States Vision for Space Exploration calls for sending robots and humans to explore the Earth s moon, the planet Mars, and beyond. The National Aeronautics and Space Administration (NASA) is developing a set of design reference missions that will provide further detail to these plans. Lunar missions are expected to provide a stepping stone, through operational research and evaluation, in developing the knowledge base necessary to send crews on long duration missions to Mars and other distant destinations. The NASA Exploration Systems Directorate (ExSD), in its program of bioastronautics research, manages the development of technologies that maintain human life, health, and performance in space. Using a systems engineering process and risk management methods, ExSD s Human Support Systems (HSS) Program selects and performs research and technology development in several critical areas and transfers the results of its efforts to NASA exploration mission/systems development programs in the form of developed technologies and new knowledge about the capabilities and constraints of systems required to support human existence beyond Low Earth Orbit. HSS efforts include the areas of advanced environmental monitoring and control, extravehicular activity, food technologies, life support systems, space human factors engineering, and systems integration of all these elements. The HSS Program provides a structured set of deliverable products to meet the needs of exploration programs. these products reduce the gaps that exist in our knowledge of and capabilities for human support for long duration, remote space missions. They also reduce the performance gap between the efficiency of current space systems and the greater efficiency that must be achieved to make human planetary exploration missions economically and logistically feasible. In conducting this research and technology development program, it is necessary for HSS technologists and program managers to develop a common currency for decision making and the allocation of funding. A high level assessment is made of both the knowledge gaps and the system performance gaps across the program s technical project portfolio. This allows decision making that assures proper emphasis areas and provides a key measure of annual technological progress, as exploration mission plans continue to mature.

Berdich, Debra P.↗

NASA NTRS2004

Developing Advanced Human Support Technologies for Planetary Exploration Missions

The United States Vision for Space Exploration calls for sending robots and humans to explore the Earth's moon, the planet Mars, and beyond. The National Aeronautics and Space Administration (NASA) is developing a set of design reference missions that will provide further detail to these plans. Lunar missions are expected to provide a stepping stone, through operational research and evaluation, in developing the knowledge base necessary to send crews on long duration missions to Mars and other distant destinations. The NASA Exploration Systems Directorate (ExSD), in its program of bioastronautics research, manages the development of technologies that maintain human life, health, and performance in space. Using a system engineering process and risk management methods, ExSD's Human Support Systems (HSS) Program selects and performs research and technology development in several critical areas and transfers the results of its efforts to NASA exploration mission/systems development programs in the form of developed technologies and new knowledge about the capabilities and constraints of systems required to support human existence beyond Low Earth Orbit. HSS efforts include the areas of advanced environmental monitoring and control, extravehicular activity, food technologies, life support systems, space human factors engineering, and systems integration of all these elements. The HSS Program provides a structured set of deliverable products to meet the needs of exploration programs. These products reduce the gaps that exist in our knowledge of and capabilities for human support for long duration, remote space missions. They also reduce the performance gap between the efficiency of current space systems and the greater efficiency that must be achieved to make human planetary exploration missions economically and logistically feasible. In conducting this research and technology development program, it is necessary for HSS technologists and program managers to develop a common currency for decision making and the allocation of funding. A high level assessment is made of both the knowledge gaps and the system performance gaps across the program s technical project portfolio. This allows decision making that assures proper emphasis areas and provides a key measure of annual technological progress, as exploration mission plans continue to mature.

Berdich, Debra P.↗

DOE OSTI2017

Identification and Characterization of Thermal Fluid Phenomena Associated with Selected Operating/Accident Scenarios in Modular High Temperature Gas-cooled Reactors

Dominant phenomena are identified and characterized for the loss-of-forced-convection (LOFC) scenario, the depressurized loss-of-forced-convection (DLOFC) scenario, and the moisture ingress scenario with relief valves available scenario. These scenarios are considered for the modular high temperature gas-cooled reactor (MHTGR) baseline design—with both a prismatic core and a pebble-bed core. The objectives of this effort, described in the above paragraph, were achieved by following a methodology identified by the U.S. Nuclear Regulatory Commission (NRC) and recommended in their Regulatory Guide 1.203. The methodology employed is described. For the above scenarios, baseline phenomena identification and ranking tables (PIRTs) generated by a NRC-sponsored effort in 2008 for the LOFC and DLOFC scenarios and a baseline PIRT generated by a Department of Energy-sponsored effort in 2011 by their Next Generation Nuclear Plant (NGNP) Moisture Ingress Assessment Committee were used to identify the dominant phenomena and existing levels-of-knowledge. Ten dominant phenomena (with only medium or low levels-of-knowledge) were identified for the LOFC and DLOFC scenarios including: (1) Inlet plenum stratification and plumes, (2) core coolant flow distribution, (3) radiant heat transfer from the top of the core to the upper vessel head, (4) reactor cavity air circulation and heat transfer, (5) reactor cavity cooling system behavior, (6) decay heat distributions, (7) core effective thermal conductivity, (8) molecular diffusion in air ingress DLOFC, (9) duct exchange flow, (10) phenomena that affect cavity gas composition for air-ingress. Five dominant phenomena, with high levels of knowledge, were identified for the moisture-ingress scenario with relief valves available including: (1) flow through break, (2) moisture level in the primary, (3) transport to moisture monitor, (4) moisture monitor instrument response, and (5) heat removal by shutdown cooling system. These phenomena are discussed and characterized. A listing of experiments—both completed and ongoing—is given with a view toward including data useful for further more detailed examination of the dominant phenomena listed in the previous paragraph. Note that only data for the LOFC and DLOFC scenarios are listed—since the moisture ingress scenario with relief valves available –have been identified as having adequate levels-of-knowledge by the PIRT committee. Finally, a preliminary computational fluid dynamics (CFD) calculation of inlet plenum stratification and plumes is described. Techniques employed for this calculation are typical for preliminary scoping calculations performed to validate numeric tools.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2018

Experimental and Computational Investigations of Plenum-to-Plenum Heat Transfer and Gas Dynamics under Natural Circulation in a Prismatic Very High Temperature Reactor

All the goals and the objectives set for the project were successfully executed and achieved and all the milestones have been successfully completed. The results that have been obtained for the first time advance the scientific and engineering knowledge and understanding of the plenum-to plenum natural convection of prismatic block nuclear reactors that is encountered during accident or abnormal operation. These have been accomplished by developing and implementing for the first time unique and flexible scaled-down separate and integrated effects experimental plenumto- plenum facility (P2PF) with dual channels at this time that has been equipped with sophisticated measurement techniques integrated in a novel way on the heated and cooled channels. The unique facility is an asset now that can be extended to research multiple channels and to study the effects of hot plumes in the plena for future projects if funding will be available. It can also be modified to research natural convection of pebble bed reactors. Hence, it complement the HTTF at Oregon State University. However, in this study, heat transfer coefficients from the inner wall surface to the flowing gas (both helium and air were used) and the radial temperature and gas velocity profiles have been measured and investigated along the height of the heated and cooled channels using in house developed wall flush mounted heat transfer probes, thermocouple with in house developed adjuster for radial movement with 1 mm increment inside the channel and hot wire anemometry with also in house developed adjuster for 1 mm radial movement inside the channel, respectively. Also advanced tracer technique has been developed to quantify also for the first time the dispersion of the gas dynamics of the hot and cold channels. The research has provided new knowledge and new benchmarking data that can be used to validate computational fluid dynamics (CFD) codes with conjugate heat transfer. The work and its results that have been performed within the budget have demonstrated their superior technical effectiveness and high economic feasibility to perform needed studies for safety analysis and assessment at least cost for these types of gas cooled very high temperature 4th generation nuclear reactors. Accordingly, the results obtained in this project and the unique facility and techniques that have been developed will benefit greatly the public by advancing the technology of the prismatic block nuclear reactors toward commercialization and to ensure they will be designed and operated safely by utilizing the obtained knowledge and having well validated CFD simulations integrated with heat transfer computations

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2017

Polarization transfer observables in elastic electron-proton scattering at Q 2 = 2.5 , 5.2, 6.8, and 8.5 GeV 2

In this paper, interest in the behavior of nucleon electromagnetic form factors at large momentum transfers has steadily increased since the discovery, using polarization observables, of the rapid decrease of the ratio G p E /G p M of the proton's electric and magnetic form factors for momentum transfers Q 2 ≳ 1 GeV 2 , in strong disagreement with previous extractions of this ratio using the traditional Rosenbluth separation technique. The GEp-III and GEp-2$\gamma$ experiments were carried out in Jefferson Lab's (JLab's) Hall C from 2007-2008, to extend the knowledge of $G_E^p/G_M^p$ to the highest practically achievable $Q^2$ and to search for effects beyond the Born approximation in polarization transfer observables of elastic $\vec{e}p$ scattering. This article reports an expanded description of the common experimental apparatus and data analysis procedure, and the results of a final reanalysis of the data from both experiments, including the previously unpublished results of the full-acceptance data of the GEp-2$\gamma$ experiment. The Hall C High Momentum Spectrometer detected and measured the polarization of protons recoiling elastically from collisions of JLab's polarized electron beam with a liquid hydrogen target. A large-acceptance electromagnetic calorimeter detected the elastically scattered electrons in coincidence to suppress inelastic backgrounds. The final GEp-III data are largely unchanged relative to the originally published results. The statistical uncertainties of the final GEp-2$\gamma$ data are significantly reduced at $\epsilon = 0.632$ and $0.783$ relative to the original publication. The decrease with $Q^2$ of $G_E^p/G_M^p$ continues to $Q^2 = 8.5$ GeV$^2$, but at a slowing rate relative to the approximately linear decrease observed in earlier Hall A measurements. At $Q^2 = 2.5$ GeV$^2$, the proton form factor ratio $G_E^p/G_M^p$ shows no statistically significant $\epsilon$-dependence, as expected in the Born approximation. The ratio $P_\ell/P_\ell^{Born}$ of the longitudinal polarization transfer component to its Born value shows an enhancement of roughly 1.7\% at $\epsilon = 0.783$ relative to $\epsilon = 0.149$, with $\approx 2.2\sigma$ significance based on the total uncertainty, implying a similar effect in the transverse component $P_t$ that cancels in the ratio $R$.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

NASA NTRS2021

LET and Range Characteristics of Proton Recoil Ions in Gallium Nitride (GaN)

A better understanding of the linear energy transfer and the range of proton recoil ions in gallium nitride is necessary to properly evaluate GaN device radiation tolerance. By analyzing the linear energy transfer (LET) and range of recoil heavy ions in GaN we can begin to reproduce the body of knowledge that exists for Si-based devices for this upcoming technology. Although the previous data on older technology has impressive depth and breadth we must be diligent and cautious in the application of these institutional intuitions when applied to emerging technologies such as GaN. As ever increasing materials science advances emerge, a sound methodology for evaluating new technologies must be established in order to apply what we know towards the effort of ensuring radiation tolerance.

gallium nitride (GaN)↗

NASA NTRS1985

Energy transfer mechanisms between molecules

Reliable rate coefficients for energy transfer and relaxation phenomena are needed in order to do the theoretical modeling which is necessary for accomplishing the following objectives: understanding and justifying proposed laser systems, determining limitations, identifying control parameters, and scaling to space-power requirements. Modeling also establishes the criteria to be followed for lasant selection. Lack of knowledge of rate coefficients is invariably the biggest obstacle to successful modeling. Existing theoretical methods are discussed, sources of error are identified, and transfer laser criteria suggested by the theory are listed. The emphasis is on vibrational-vibrational (V-V) energy transfer caused by both short range and long range interactions between molecules. Special attention is given to the importance of near-resonant collisional and dipole-dipole transfer. A technique is proposed for significantly improving the theoretical predictions of rate coefficients.

Meador, W. E.↗