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NASA NTRS1980

The washout of combustion-generated hydrogen chloride

The coefficient for the washout from a rocket exhaust cloud of HCl generated by the combustion of an ammonium perchlorate-based solid rocket propellant such as that to be used for the Space Shuttle Booster is determined. A mathematical model of HCl scavenging by rain is developed taking into account rain droplet size, fall velocity and concentration under various rain conditions, partitioning of exhaust HCl between liquid and gaseous phases, the tendency of HCl to promote water vapor condensation and the concentration and size of droplets within the exhaust cloud. The washout coefficient is calculated as a function of total cloud water content, total HCl content at 100% relative humidity, condensation nuclei concentration and rain intensity. The model predictions are compared with experimental results obtained in scavenging tests with solid rocket exhaust and raindrops of different sizes, and the large reduction in washout coefficient at high relative humidities predicted by the model is not observed. A washout coefficient equal to 0.0000512 times the -0.176 power of the mass concentration of HCl times the 0.773 power of the rainfall intensity is obtained from the experimental data.

Fenton, D. L.↗

NASA NTRS1981

Experimental determination of the effects of moisture on composite-to-composite adhesive joints

The primary mode of moisture ingress into bonded composite joints is determined using a nuclear probe for deuterium (NPD) to measure the localized D2O content along the length of the adhesive (FM-300 and EA-9601) and through the thickness of bonded composite speciments. Calculated diffusivities and NPD measured equilibrium moisture contents are used to predict the moisture profiles along the length of the adhesives as a function of exposure time, temperature, and relative humidity. These results are compared with the observed moisture profiles to evaluate the extent of enhanced edge diffusion. The FM-300 adhesive exhibits good agreement between measured and predicted profiles at 49 C, 70% and 90% RH, and 77 C, 70% RH. At 77 C, 90% RH, the measured moisture content near the adhesive edge is substantially larger than the predicted level. The EA-9601 adhesive also shows good agreement at 49 C, 70% and 90% RH, but at 77 C, the concentration of D20 near the edges is enhanced at each humidity level. The effect of moisture content on the bond shear strength at room temperature and at elevated temperature is evaluated.

Deiasi, R. J.↗

NASA NTRS1981

Do initial conditions matter? A comparison of model climatologies generated from different initial states

A coarse mesh (8 by 10) 7 layer global climate model was used to compute 15 months of meteorological history in two perpetual January experiments on a water planet (without continents) with a zonally symmetric climatological January sea surface temperature field. In the first of the two water planet experiments the initial atmospheric state was a set of zonal mean values of specific humidity, temperature, and wind at each latitude. In the second experiment the model was initialized with globally uniform mean values of specific humidity and temperature on each sigma level surface, constant surface pressure (1010 mb), and zero wind everywhere. A comparison was made of the mean January climatic states generated by the two water planet experiments. The first two months of each 15 January run were discarded, and 13 month averages were computed from months 3 through 15.

Spar, J.↗

NASA NTRS1981

Ambient ammonia measurements using laser photo-acoustic spectroscopy

Ammonia concentrations reached minimal levels (approximately 0.1 ppb) in early winter, followed by a sudden later winter increase. A direct relationship between ambient ammonia levels and air temperature was inferred from the data (linear correlation coefficient r=0.53). Ammonia concentrations were determined to be directly related to the absolute humidity of the air (r=0.72); a weaker relationship between ammonia concentrations and relative humidity was discovered (r=0.37). The data also indicated that ammonia levels were generally higher within continental air masses than those of maritime origin. Soil parameters such as pH and moisture content were found to have a major bearing on the release of gaseous ammonia from soils in the region.

Aldridge, M. D., III↗

NASA NTRS1980

Contact integrity testing of stress-tested silicon terrestrial solar cells

A test procedure was developed and applied to terrestrial silicon solar cells in order to determine the effect of accelerated environmental and time-temperature aging on metal contact integrity. Quantities of cells of four different manufacturers were given the contact integrity test after being subjected to accelerated stress tests that included forward bias-temperature, thermal cycle and thermal shock, power cycle, and bias-temperature humidity tests at two temperature-humidity levels. Significant effects due to certain stress tests were found for some cell types. It is concluded that cells fabricated using plated nickel/solder metallization showed significantly more serious contact integrity degradation than silver-metallized cells.

Prince, J. L.↗

NASA NTRS1981

Anomalous behavior of the atmospheric surface layer over a melting snowpack

During March, 1978 on a snow-covered field near Lee Vining, California, measurements were made that included: (1) variations above the snow surface of the net radiative flux and the profile of wind speed, air temperature and relative humidity; and (2) variations beneath the snow surface of the conductive heat flux and the temperature profile. The period was marked by clear skies, warm air and calm winds during the day, and cold air and moderate winds at night. During the day, a highly stable sublayer formed near the surface, with a persistent warm layer at approximately 0.5 m above the surface. At night, profiles agreed more with classical log-linear forms found in stable air. Numerical simulation of long and shortwave radiative fluxes near the surface, using observed humidity profiles, produced the daytime warm level in agreement with observations. It was concluded that in the absence of turbulent mixing, strong solar radiation and a supply of moisture from the snow will cause a raised maximum of temperature during the day.

Halberstam, I.↗

NASA NTRS1981

Effect of storing B-staged graphite/polyimide on fabrication of structural elements

Graphite/polyimide structural elements have been successfully fabricated by forming and curing B-staged Celion 6000/PMR-15 and Celion 6000/LaRC-160 laminates in heated matched metal tooling. The B-staged laminates were subjected to storage for various periods of time up to six months at ambient shop conditions and high humidity prior to fabrication into structural elements to determine the processability of the graphite/polyimide after exposure to these conditions. Changes in processability were monitored by measuring flexure and interlaminar shear strengths, glass transition temperature, moisture content, and formability of the B-staged laminates. No significant change in the processability of either Celion 6000/PMR or Celion 6000/LaRC-160 was recorded indicating that after B-staging the graphite/polyimide laminates can be stored for extended periods of time in normal shop and high humidity environments and then be fabricated into defect-free structural elements in heated platen presses.

Baucom, R. M.↗

NASA NTRS1981

Materials characterization study of conductive flexible second surface mirrors

The status of prequalification and qualification work on conductive flexible second surface mirrors is described. The basic material is FEP Teflon witn either aluminium or silver vacuum deposited reflectors. The top layer has been made conductive by deposition of layer of a indium oxide. The results of a prequalification program comprised of decontamination, humidity, thermal cycling, thermal shock and vibration tests are presented. Thermo-optical and electrical properties. The results of a prequalification program comprised of decontamination, humidity, thermal cycling, thermal shock and vibration tests are presented. Thermo-optical and electrical properties, the electrostatic behavior of the materials under simulated substorm environment and electrical conductivity at low temperatures are characterized. The effects of simulated ultra violet and particles irradiation on electrical and thermo-optical properties of the materials are also presented.

Levadou, F.↗

NASA NTRS1981

Cloud condensation nucleus counter by impactor sampling technique

Unlike typical CCN counters, this device counts the numbers of water droplets condensed on aerosol particles sampled on a microcover glass at various different relative humidities. The relative humidities ranged from 75 percent to a calculated value of 110 percent. A schematic of the apparatus is shown. The individual CCN can be identified in an optical micrograph and scanning electron micrograph and may be inspected for their chemical composition later.

Ohtake, T.↗

NASA NTRS1981

Multilevel measurements of surface temperature over undulating terrain planted to barley

A ground and aircraft program was conducted to extend ground based methods for measuring soil moisture and crop water stress to aircraft and satellite altitudes. A 260ha agricultural field in California was used over the 1977-78 growing season. For cloud free days ground based temperature measurements over bare soil were related to soil moisture content. Water stress resulted from too much water, not from lack of it, as was expected. A theoretical examination of the canopy air temperature difference as affected by vapor pressure deficit and net radiation was developed. This analysis shows why surface temperatures delineate crop water stress under conditions of low humidity, but not under high humidity conditions. Multilevel temperatures acquired from the ground, low and high altitude aircraft, and the Heat Capacity Mapping Mission (HCMM) spacecraft were compared for two day and one night overpasses. The U-2 and low altitude temperatures were within 0.5 C. The HCMM data were analyzed using both the pre- and post-launch calibrations, with the former being considerably closer in agreement with the aircraft data than the latter.

Reginato, R. J.↗

NASA NTRS1982

Preprototype independent air revitalization subsystem

The performance and maturity of a preprototype, three-person capacity, automatically controlled and monitored, self-contained independent air revitalization subsystem were evaluated. The subsystem maintains the cabin partial pressure of oxygen at 22 kPa (3.2 psia) and that of carbon dioxide at 400 Pa (3 mm Hg) over a wide range of cabin air relative humidity conditions. Consumption of water vapor by the water vapor electrolysis module also provides partial humidity control of the cabin environment. During operation, the average carbon dioxide removal efficiency at baseline conditions remained constant throughout the test at 84%. The average electrochemical depolarized concentrator cell voltage at the end of the parametric/endurance test was 0.41 V, representing a very slowly decreasing average cell voltage. The average water vapor electrolysis cell voltage increased only at a rate of 20 mu/h from the initial level of 1.67 V to the final level of 1.69 V at conclusion of the testing.

Schubert, F. H.↗

NASA NTRS1981

Moisture analysis from radiosonde and microwave spectrometer data

A method for analysis of the horizontal and vertical distributions of the moisture field utilizing satellite, upper air and surface data is proposed in this paper. A brief overview of the microwave sensors on board Nimbus 5 and 6 is also presented. A technique is provided utilizing the radiosonde data sets to calibrate the satellite field of total precipitable water. Next, the calibrated satellite-derived field is utilized along with ship and coastal reports of moisture, and a vertical structure function to generate vertical distribution of moisture and thus provide a mapping of specific humidity at several levels in the troposphere. Utilizing these procedures, analyses for several case studies were performed. The resultant maps show detailed distribution of specific humidity along with some interesting climatological features. A reasonable acceptance of the available aerological data sets by the analysis scheme is demonstrated.

Haydu, K. J.↗

NASA NTRS1981

Weather and climate needs for lidar observations from space and concepts for their realization

The spectrum of weather and climate needs for lidar observations from space is discussed. This paper focuses mainly on the requirements for winds, temperature, moisture, and pressure. Special emphasis is given to the need for wind observations, and it is shown that winds are required to depict realistically all atmospheric scales in the tropics and the smaller scales at higher latitudes, where both temperature and wind profiles are necessary. The need for means to estimate air-sea exchanges of sensible and latent heat also is noted. Lidar can aid here by measurement of the slope of the boundary layer. Recent theoretical feasibility studies concerning the profiling of temperature, pressure, and humidity by differential absorption lidar (DIAL) from space and expected accuracies are reviewed. Initial ground-based trials provide support for these approaches and also indicate their direct applicability to path-average temperature measurements near the surface. An alternative approach to Doppler lidar wind measurements also is presented. The concept involves the measurement of the displacement of the aerosol backscatter pattern, at constant height, between two successive scans of the same area, one ahead of the spacecraft and the other behind it, a few minutes later. Finally, an integrated space lidar system capable of measuring temperature, pressure, humidity, and winds which combines the DIAL methods with the aerosol pattern displacement concept is described briefly.

Atlas, D.↗

NASA NTRS1981

Delayed darkening of radiation-exposed radiochromic dye dosimeters

Experiments have verified the existence of considerable delayed darkening in FWT-60 dosimetry films that may, depending on relative humidity, last for several hours. The amount of delayed darkening depends very strongly on the relative humidity at which the films are equilibrated before irradiation. It is pointed out that the delayed darkening effect must be taken into account before any meaningful dosimetric measurements may be made using these nylon-based thin dosimetry films. The particular radiation-sensitive compound used in the FWT-60 films is the hexahydrosyethyl pararosanaline cyanide with the Dupont nylon resin, Elvamide 8061, which forms the host matrix of a solid-state solution.

Danchenko, V.↗

NASA NTRS1982

A method for estimation of atmospheric water vapor profiles by microwave radiometry

Simultaneous measurements of microwave emission from the earth, in the oxygen band near 60 GHz, and the water vapor line near 183 GHz are conducted to determine the atmospheric temperature as a function of the pressure and the water vapor burden, and a combination of these two profiles yields a profile of water vapor burden versus pressure. Numerical simulations are developed by using temperature and water vapor profiles from subtropical and midlatitude radiosonde stations, and by assuming surface reflectivities typical of either land or ocean. Over a land surface, the residual rms errors in the estimated water vapor burden profile between 300 and 1000 mb are determined to range from 23 to 43% of the a priori standard deviation of water vapor burden for the corresponding climate. The relative humidity profile is also estimated and found to contain rms errors ranging from 4 to 17% of saturation. Over a seawater surface, using three additional channels of 18.5, 22.2, and 31.7 GHz, the corresponding results are found to be 3-46% of the a priori standard deviation for water vapor burden and 4-15% rms error for relative humidity.

Rosenkranz, P. W.↗

NASA NTRS1982

Modelling of dimensional stability of fiber reinforced composite materials

Various methods of predicting the expansion and diffusion properties of composite laminates are reviewed. The prediction equations for continuous fiber composites can be applied to SMC composites as the effective fiber aspect ratio in the latter is large enough. The effect of hygrothermal expansion on the dimensional stability of composite laminates was demonstrated through the warping of unsymmetric graphite/epoxy laminates. The warping is very sensitive to the size of the panel, and to the moisture content which is in turn sensitive to the relative humidity in the environment. Thus, any long term creep test must be carried out in a humidity-controlled environment. Environmental effects in SMC composites and bulk polyester were studied under seven different environments. The SMC composites chosen are SMC-R25, SMC-R40, and SMC-R65.

Hahn, H. T.↗

NASA NTRS1982

Stable polyurethane coatings for electronic circuits. NASA tech briefs, fall 1982, volume 7, no. 1

One of the most severe deficiencies of polyurethanes as engineering materials for electrical applications has been their sensitivity to combined humidity and temperature environments. Gross failure by reversion of urethane connector potting materials has occurred under these conditions. This has resulted in both scrapping of expensive hardware and reduction in reliability in other instances. A basic objective of this study has been to gain a more complete understanding of the mechanisms and interactions of moisture in urethane systems to guide the development of reversion resistant materials for connector potting and conformal coating applications in high humidity environments. Basic polymer studies of molecular weight and distribution, polymer structure, and functionality were carried out to define those areas responsible for hydrolytic instability and to define polymer structural feature conducive to optimum hydrolytic stability.

Source record↗

NASA NTRS1982

An atmospheric exposure chamber for small animals

The purpose of this project was to design a long-term environmental exposure chamber for small animals. This chamber is capable of producing hypoxic, normoxic and hyperoxic atmospheres which are closely regulated. The chamber, which is of the recycling type, is fashioned after clear plastic germ-free isolators. Oxygen concentration is set and controlled by a paramagnetic O2 analyzer and a 3-way solenoid valve. In this way either O2 or N2 may be provided to the system by way of negative O2 feedback. Relative humidity is maintained at 40-50 percent by a refrigeration type dryer. Carbon dioxide is absorbed by indicating soda lime. A diaphragm pump continuously circulates chamber gas at a high enough flow rate to prevent buildup of CO2 and humidity. This chamber has been used for numerous studies which involve prolonged exposure of small animals to various O2 concentrations.

Glaser, R. M.↗