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At least 577 records · Page 32

Transmission electron microscopic examination of phosphoric acid fuel cell components

Transmission electron microscopy (TEM) was used to physically characterize tested and untested phosphoric acid fuel cell (PAFC) components. Those examined included carbon-supported platinum catalysts, carbon backing paper, and Teflon-bonded catalyst layers at various stages of fabrication and after testing in pressurized PAFC's. Applicability of electron diffraction and electron energy loss spectroscopy for identifying the various phases was explored. The discussion focuses on the morphology and size distribution of platinum, the morphology and structural aspects of Teflon in catalyst layers, and the structural evidence of carbon corrosion. Reference is made to other physical characterization techniques where appropriate. A qualitative model of the catalyst layer that emerged from the TEM studies is presented.

Pebler, A.↗

Subscale Testing of Nozzle Ablative Materials in a Supersonic Particle Impingement Environment

Recent efforts to evaluate materials to replace the current NARC rayon used in the nozzle ablative of the NASA's Reusable Solid Rocket Motor (SRM), several tests were developed to look at the performance of supersonic particle impact region of the aft exit cone. It was seen in early testing that some potential candidates did not perform as well as the current NARC based material and so the 24 inch Solid Rocket Motor (SRTM) exit cone design was extended and contoured to induce particle impingement in the aft end. The SRTM testing provided a larger testbed to evaluate the results seen in the Solid Fuel Supersonic Blast Tube. Testing was performed in each test bed on two variants of the final two candidate materials. The materials were a standard prewoven Lyocell, a postwoven Lyocell, an Enka rayon, and Enka rayon processed at a higher carbonization temperature. This paper presents the results of the four materials in the SSBT and the SRTM tests as compared against the NARC baseline. Erosion, char, and plylift results are discussed in detail.

Howse, S.↗

Effects of Non-Uniform Fuel Distribution on Detonation Tube Performance

A pulse detonation engine uses a series of high frequency intermittent detonation tubes to generate thrust. The process of filling the detonation tube with fuel and air for each cycle may yield non-uniform mixtures. Uniform mixing is commonly assumed when calculating detonation tube thrust performance. In this study, detonation cycles featuring idealized non-uniform H2/air mixtures were analyzed using a two-dimensional Navier-Stokes computational fluid dynamics code with detailed chemistry. Mixture non-uniformities examined included axial equivalence ratio gradients, transverse equivalence ratio gradients, and partially fueled tubes. Three different average test section equivalence ratios were studied; one stoichiometric, one fuel lean, and one fuel rich. All mixtures were detonable throughout the detonation tube. Various mixtures representing the same average test section equivalence ratio were shown to have specific impulses within 1% of each other, indicating that good fuel/air mixing is not a prerequisite for optimal detonation tube performance under the conditions investigated.

Perkins, H. Douglas↗

Effects of Fuel Distribution on Detonation Tube Performance

A pulse detonation engine uses a series of high frequency intermittent detonation tubes to generate thrust. The process of filling the detonation tube with fuel and air for each cycle may yield non-uniform mixtures. Uniform mixing is commonly assumed when calculating detonation tube thrust performance. In this study, detonation cycles featuring idealized non-uniform Hz/air mixtures were analyzed using a two-dimensional Navier-Stokes computational fluid dynamics code with detailed chemistry. Mixture non-uniformities examined included axial equivalence ratio gradients, transverse equivalence ratio gradients, and partially fueled tubes. Three different average test section equivalence ratios were studied; one stoichiometric, one fuel lean, and one fuel rich. All mixtures were detonable throughout the detonation tube. Various mixtures representing the same average test section equivalence ratio were shown to have specific impulses within 1% of each other, indicating that good fuel/air mixing is not a prerequisite for optimal detonation tube performance under conditions investigated.

Perkins, H. Douglas↗

Mach 0.3 Burner Rig Facility at the NASA Glenn Materials Research Laboratory

This Technical Memorandum presents the current capabilities of the state-of-the-art Mach 0.3 Burner Rig Facility. It is used for materials research including oxidation, corrosion, erosion and impact. Consisting of seven computer controlled jet-fueled combustors in individual test cells, these relatively small rigs burn just 2 to 3 gal of jet fuel per hour. The rigs are used as an efficient means of subjecting potential aircraft engine/airframe advanced materials to the high temperatures, high velocities and thermal cycling closely approximating actual operating environments. Materials of various geometries and compositions can be evaluated at temperatures from 700 to 2400 F. Tests are conducted not only on bare superalloys and ceramics, but also to study the behavior and durability of protective coatings applied to those materials.

Fox, Dennis S.↗

Deposit formation and heat transfer in hydrocarbon rocket fuels

An experimental research program was undertaken to investigate the thermal stability and heat transfer characteristics of several hydrocarbon fuels under conditions that simulate high-pressure, rocket engine cooling systems. The rates of carbon deposition in heated copper and nickel-plated copper tubes were determined for RP-1, propane, and natural gas using a continuous flow test apparatus which permitted independent variation and evaluation of the effect on deposit formation of wall temperature, fuel pressure, and fuel velocity. In addition, the effects of fuel additives and contaminants, cryogenic fuel temperatures, and extended duration testing with intermittent operation were examined. Corrosion of the copper tube surface was detected for all fuels tested; however, plating the insides of the tubes with nickel reduced deposit formation and eliminated corrosion in most cases. The lowest rates of carbon deposition were obtained for natural gas, and the highest rates were obtained for propane. Forced-convection heat transfer film coefficients were satisfactorily correlated using a Nusselt-Reynolds-Prandtl number equation for all the fuels tested.

Giovanetti, A. J.↗

A Materials Compatibility and Thermal Stability Analysis of Common Hydrocarbon Fuels

A materials compatibility and thermal stability investigation was conducted using five common liquid hydrocarbon fuels and two structural materials. The tests were performed at the NASA Glenn Research Center Heated Tube Facility under environmental conditions similar to those encountered in regeneratively cooled rocket engines. Scanning-electron microscopic analysis in conjunction with energy dispersive spectroscopy (EDS) was utilized to characterize the condition of the tube inner wall surface and any carbon deposition or corrosion that was formed during selected runs. Results show that the carbon deposition process in stainless steel tubes was relatively insensitive to fuel type or test condition. The deposition rates were comparable for all fuels and none of the stainless steel test pieces showed any signs of corrosion. For tests conducted with copper tubing, the sulfur content of the fuel had a significant impact on both the condition of the tube wall and carbon deposition rates. Carbon deposition rates for the lowest sulfur fuels (2 ppm) were slightly higher than those recorded in the stainless steel tubes with no corrosion observed on the inner wall surface. For slightly higher sulfur content (25 ppm) fuels, nodules that intruded into the flow area were observed to form on the inner wall surface. These nodules induced moderate tube pressure drop increases. The highest sulfur content fuels (400 ppm) produced extensive wall pitting and dendritic copper sulfide growth that was continuous along the entire tube wall surface. The result of this tube degradation was the inability to maintain flow rate due to rapidly increasing test section pressure drops. Accompanying this corrosion were carbon deposition rates an order of magnitude greater than those observed in comparable stainless steel tests. The results of this investigation indicate that trace impurities in fuels (i.e. sulfur) can significantly impact the carbon deposition process and produce unacceptable corrosion levels in copper based structural materials.

Meyer, M. L.↗

Effect of Flame Stabilizer Design on Performance and Exhaust Pollutants of a Two-Row Swirl-Can Combustor Operated to Near-Stoichiometric Conditions

Emissions and performance characteristics were determined for two full annulus modular combustors operated to near stoichiometric fuel air ratios. The tests were conducted to obtain stoichiometric data at inlet air temperatures from 756 to 894 K and to determine the effects of a flat plate circular flame stabilizer with upstream fuel injection and a contraswirl flame stabilizer with downstream fuel injection. Levels of unburned hydrocarbons were below 0.50 gram per kilogram of fuel for both combustors and thus there was no detectable difference in the two methods of fuel injection. The contraswirl flame stabilizer did not produce the level of mixing obtained with a flat plate circular flame stabilizer. It did produce higher levels of oxides of nitrogen, which peaked at a fuel air ratio of 0.037. For the flat plate circular flame stabilizer, oxides of nitrogen emission levels were still increasing with fuel air ratio to the maximum tested value of 0.045.

Biaglow, James A.↗

Gaseous fuel reactors for power systems

Gaseous-fuel nuclear reactors have significant advantages as energy sources for closed-cycle power systems. The advantages arise from the removal of temperature limits associated with conventional reactor fuel elements, the wide variety of methods of extracting energy from fissioning gases, and inherent low fissile and fission product in-core inventory due to continuous fuel reprocessing. Example power cycles and their general performance characteristics are discussed. Efficiencies of gaseous fuel reactor systems are shown to be high with resulting minimal environmental effects. A technical overview of the NASA-funded research program in gaseous fuel reactors is described and results of recent tests of uranium hexafluoride (UF6)-fueled critical assemblies are presented.

Kendall, J. S.↗

Nuclear thermal propulsion test facility requirements and development strategy

The Nuclear Thermal Propulsion (NTP) subpanel of the Space Nuclear Propulsion Test Facilities Panel evaluated facility requirements and strategies for nuclear thermal propulsion systems development. High pressure, solid core concepts were considered as the baseline for the evaluation, with low pressure concepts an alternative. The work of the NTP subpanel revealed that a wealth of facilities already exists to support NTP development, and that only a few new facilities must be constructed. Some modifications to existing facilities will be required. Present funding emphasis should be on long-lead-time items for the major new ground test facility complex and on facilities supporting nuclear fuel development, hot hydrogen flow test facilities, and low power critical facilities.

Allen, George C.↗

Minimum fuel mode evaluation

The minimum fuel mode of the NASA F-15 research aircraft is designed to minimize fuel flow while maintaining constant net propulsive force (FNP), effectively reducing thrust specific fuel consumption (TSFC), during cruise flight conditions. The test maneuvers were at stabilized flight conditions. The aircraft test engine was allowed to stabilize at the cruise conditions before data collection initiated; data were then recorded with performance seeking control (PSC) not-engaged, then data were recorded with the PSC system engaged. The maneuvers were flown back-to-back to allow for direct comparisons by minimizing the effects of variations in the test day conditions. The minimum fuel mode was evaluated at subsonic and supersonic Mach numbers and focused on three altitudes: 15,000; 30,000; and 45,000 feet. Flight data were collected for part, military, partial, and maximum afterburning power conditions. The TSFC savings at supersonic Mach numbers, ranging from approximately 4% to nearly 10%, are in general much larger than at subsonic Mach numbers because of PSC trims to the afterburner.

Orme, John S.↗

Study of Rapid-Regression Liquefying Hybrid Rocket Fuels

A report describes experiments directed toward the development of paraffin-based hybrid rocket fuels that burn at regression rates greater than those of conventional hybrid rocket fuels like hydroxyl-terminated butadiene. The basic approach followed in this development is to use materials such that a hydrodynamically unstable liquid layer forms on the melting surface of a burning fuel body. Entrainment of droplets from the liquid/gas interface can substantially increase the rate of fuel mass transfer, leading to surface regression faster than can be achieved using conventional fuels. The higher regression rate eliminates the need for the complex multi-port grain structures of conventional solid rocket fuels, making it possible to obtain acceptable performance from single-port structures. The high-regression-rate fuels contain no toxic or otherwise hazardous components and can be shipped commercially as non-hazardous commodities. Among the experiments performed on these fuels were scale-up tests using gaseous oxygen. The data from these tests were found to agree with data from small-scale, low-pressure and low-mass-flux laboratory tests and to confirm the expectation that these fuels would burn at high regression rates, chamber pressures, and mass fluxes representative of full-scale rocket motors.

Zilliac, Greg↗

The N.A.C.A. Photographic Apparatus for Studying Fuel Sprays from Oil Engine Injection Valves and Test Results from Several Researches

Apparatus for recording photographically the start, growth, and cut-off of oil sprays from injection valves has been developed at the Langley Memorial Aeronautical Laboratory. The apparatus consists of a high-tension transformer by means of which a bank of condensers is charged to a high voltage. The controlled discharge of these condensers in sequence, at a rate of several thousand per second, produces electric sparks of sufficient intensity to illuminate the moving spray for photographing. The sprays are injected from various types of valves into a chamber containing gases at pressures up to 600 pounds per square inch. Several series of pictures are shown. The results give the effects of injection pressure, chamber pressure, specific gravity of the fuel oil used, and injection-valve design, upon spray characteristics.

Beardsley, Edward G↗

Evaluation of the micro-carburetor

A prototype sonic, variable-venturi automotive carburetor was evaluated for its effects on vehicle performance, fuel economy, and exhaust emissions. A 350 CID Chevrolet Impala vehicle was tested on a chassis dynamometer over the 1975 Federal Test Procedure, urban driving cycle. The Micro-carburetor was tested and compared with stock and modified-stock engine configurations. Subsequently, the test vehicle's performance characteristics were examined with the stock carburetor and again with the Micro-carburetor in a series of on-road driveability tests. The test engine was then removed from the vehicle and installed on an engine dynamometer. Engine tests were conducted to compare the fuel economy, thermal efficiency, and cylinder-to-cylinder mixture distribution of the Micro-carburetor to that of the stock configuration. Test results show increases in thermal efficiency and improvements in fuel economy at all test conditions. Improve fuel/air mixture preparation is implied from the information presented. Further improvements in fuel economy and exhaust emissions are possible through a detailed recalibration of the Micro-carburetor.

Weiss, M. F.↗

Evaluation of a staged fuel combustor for turboprop engines

Proposed EPA emission regulations require emission reduction by 1979 for various gas turbine engine classes. Extensive combustion technology advancements are required to meet the proposed regulations. The T56 turboprop engine requires CO, UHC, and smoke reduction. A staged fuel combustor design was tested on a combustion rig to evaluate emission reduction potential in turboprop engines from fuel zoning. The can-type combustor has separately fueled-pilot and main combustion zones in series. The main zone fueling system was arranged for potential incorporation into the T56 with minor or no modifications to the basic engine. Three combustor variable geometry systems were incorporated to evaluate various airflow distributions. Emission results with fixed geometry operation met all proposed EPA regulations over the EPA LTO cycle. CO reduction was 82 percent, UHC reduction was 96 percent, and smoke reduction was 84 percent. NOx increased 14 percent over the LTO cycle. At high power, NOx reduction was 40 to 55 percent. This NOx reduction has potential application to stationary gas turbine powerplants which have different EPA regulations.

Verdouw, A. J.↗

Fuel Efficient Strategies for Reducing Contrail Formations in United States Air Space

This paper describes a class of strategies for reducing persistent contrail formation in the United States airspace. The primary objective is to minimize potential contrail formation regions by altering the aircraft's cruising altitude in a fuel-efficient way. The results show that the contrail formations can be reduced significantly without extra fuel consumption and without adversely affecting congestion in the airspace. The contrail formations can be further reduced by using extra fuel. For the day tested, the maximal reduction strategy has a 53% contrail reduction rate. The most fuel-efficient strategy has an 8% reduction rate with 2.86% less fuel-burnt compared to the maximal reduction strategy. Using a cost function which penalizes extra fuel consumed while maximizing the amount of contrail reduction provides a flexible way to trade off between contrail reduction and fuel consumption. It can achieve a 35% contrail reduction rate with only 0.23% extra fuel consumption. The proposed fuel-efficient contrail reduction strategy provides a solution to reduce aviation-induced environmental impact on a daily basis.

Sridhar, Banavar↗

Metallized Gelled Propellants Combustion Experiments in a Pulse Detonation Engine

A series of combustion tests were performed with metallized gelled JP 8/aluminum fuels in a Pulse Detonation Engine (PDE). Nanoparticles of aluminum were used in the 60 to 100 nanometer diameter. Gellants were also of a nanoparticulate type composed of hydrocarbon alkoxide materials. Using simulated air (a nitrogen-oxygen mixture), the ignition potential of metallized gelled fuels with nanoparticle aluminum was investigated. Ignition of the JP 8/aluminum was possible with less than or equal to a 23-wt% oxygen loading in the simulated air. JP 8 fuel alone was unable to ignite with less than 30 percent oxygen loaded simulated air. The tests were single shot tests of the metallized gelled fuel to demonstrate the capability of the fuel to improve fuel detonability. The tests were conducted at ambient temperatures and with maximal detonation pressures of 1340 psia.

Palaszewski, Bryan↗