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DOE OSTI2023

Lightning Rings and Gravity Waves: Insights Into the Giant Eruption Plume From Tonga's Hunga Volcano on 15 January 2022

Abstract On 15 January 2022, Hunga Volcano in Tonga produced the most violent eruption in the modern satellite era, sending a water‐rich plume at least 58 km high. Using a combination of satellite‐ and ground‐based sensors, we investigate the astonishing rate of volcanic lightning (>2,600 flashes min −1 ) and what it reveals about the dynamics of the submarine eruption. In map view, lightning locations form radially expanding rings. We show that the initial lightning ring is co‐located with an internal gravity wave traveling >80 m s −1 in the stratospheric umbrella cloud. Buoyant oscillations of the plume's overshooting top generated the gravity waves, which enhanced turbulent particle interactions and triggered high‐current electrical discharges at unusually high altitudes. Our analysis attributes the intense lightning activity to an exceptional mass eruption rate (>5 × 10 9 kg s −1 ), rapidly expanding umbrella cloud, and entrainment of abundant seawater vaporized from magma‐water interaction at the submarine vent.

58 GEOSCIENCES↗

DOE OSTI2022

The Use of Acoustic Cavitation to Recovery High-Assay Low-Enriched Uranium (HALEU) form TRISO Fuel Particles

Recent interest in advanced nuclear reactor concepts such as small modular reactor (SMR), micro reactor or versatile test reactor (VTR) has increased the demand for high-assay, low-enriched uranium (HALEU). The sustainable management of this resource is integral to successful resurgence of nuclear energy in the United States. The High Temperature Gas-Cooled Reactor (HTGR) concept is a prime candidate for deployment of the new fleet of SMRs, and it will become very important to have a simple and cost-effective technology to recover HALEU from short-burned, defective, or off-specification TRISO fuel particles. We have attempted to harness the high energetics of sonochemistry to penetrate the TRISO fuel particles and recover HALEU via acidic leaching. While the TRISO fuel particle design is inherently “bulletproof,” (due to the silicon carbide (SiC) layer), ultrasonic irradiation may hold the key to convenient access to its valuable contents. Sonochemistry is a field of chemistry based on acoustic cavitation, which is the formation, growth, and collapse of bubbles in liquid media.1,2 The oscillating bubble formation is produced by irradiation of a liquid media with sound waves. Literature reports indicate that collapsing bubbles induced by cavitation produces intense local heating, high pressures, and short lifetimes.1 These localized hot spots reach temperatures of ˜5000 K, pressures approaching 500 atm, and heating and cooling rates exceeding 100 K/s.1 The large temperature and pressure differentials deliver high-energy heating and microscopic explosive shock waves to a liquid media or liquid/solid interface. Cavitation at the surface of a solid in solution induces a deformation in the bubble cavity upon collapse. This deformation reinforces the bubble structure and sends a fast-moving stream of liquid through the cavity at the surface with velocities greater than 100 m/s.3 These energetic impacts have demonstrated an ability to penetrate or simply destroy the SiC shell surrounding the uranium fuel kernel during prolonged exposures to the high-power acoustic waves. Some preliminary results demonstrating HALEU recovery using sonochemistry techniques will be reported.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NASA NTRS1997

The Evolving Universe: Structure and Evolution of the Universe Roadmap 2000-2020

The Roadmap for the Structure and Evolution of the Universe (SEU) theme embraces three fundamental, scientific quests: (1) To explain structure in the Universe and forecast our cosmic destiny. (2) To explore the cycles of matter and energy in the evolving Universe. (3) To examine the ultimate limits of gravity and energy in the Universe. These quests are developed into six, focused research campaigns addressing the objectives of one or more quests: Identify dark matter and learn how it shapes galaxies and systems of galaxies; Find out where and when the chemical elements were made; Understand the cycles in which matter, energy, and magnetic field are exchanged between stars and the gas between stars; Discover how gas flows in disks and how cosmic jets are formed; Identify the sources of gamma-ray bursts and high-energy cosmic rays; and Measure how strong gravity operates near black holes and how it affects the early Universe. These campaigns lead to a portfolio of future major missions of strong scientific and popular appeal, strongly endorsed by the scientific community and which has undergone significant initial study. Some of these missions are in a state of readiness that makes ideal candidates for the present Office of Space Science Strategic Plan; others may well feature in the next Strategic Plan. Each provides a golden scientific opportunity to advance our understanding of the Universe. Our highest priority science objectives are addressed by five Observatory Class Missions, unranked by science, but in approximate order of readiness: A high-energy gamma-ray facility that will observe relativistic jets and study the sources of cosmic gamma ray bursts; An ultra-sensitive X-ray telescope, optimized for spectroscopy, to examine the hot gas linked with clusters of galaxies, the disks around black holes, and supernova explosions; A large, radio telescope in deep space to map central regions of distant quasars and perform astrometric investigations; An orbiting gravitational coalescing, massive black holes and test how gravity waves distort spacetime; A pair of Earth-orbiting, optical telescopes that will detect flashes of light produced when ultra high-energy cosmic rays impact the upper atmosphere so as to determine their arrival directions and energies. A new program for supporting pertinent international collaboration is strongly endorsed and maintaining a strong Explorer program is important. The flexibility to exploit exceptional opportunities, such as attaching payloads to space station, should also be acquired. A strong technology development program must be initiated now to enable this mission set.

Source record↗

DOE OSTI2021

Geodyn Material Library: Pseudocap models for dry porous tocks

This report describes the second edition of the Pseudocap Strength models for porous rocks implemented in GEODYN material library. The first model was developed in 2007 and calibrated for concrete. Then, the model parameters were calibrated based on triaxial tests reported for limestones and sandstones of various porosities. In these models some key parameters were chosen as functions of the reference porosity,Φ. Since then multiple modifications were implemented in the model, therefore, it has been recalibrated for some common porous materials such as limestones, sandstones, alluvium, tuffs and granite. Two types of models are described in this repot. The first type (called Pseudocap Model or PM) is for rocks from a specific location. Parameters were calibrated for several specific geologic materials. The second type (called Generic Pseudocap Model or GPM) is useful for the sites where only basic information (rock type, porosity) is available. Generic models include built-in correlations between porosities and other mechanical properties observed for certain rock types. The models of both types were validated by comparing not only to quasi-static triaxial tests for these materials but also to shock Hugoniot data and spherical explosion data for some materials. All models were derived in the frame of isotropic plasticity. They are designed to be used in explicit finite element/difference codes. Tangent stiffness tensor is not provided but can be calculated numerically for the model to be used in implicit finite element codes. For an isotropic material the stress can be decomposed into volumetric and deviatoric parts. The volumetric part is modeled using an Equation of state (EOS) which calculates the pressure and the bulk sound speed as functions of the internal specific energy and density. Here a simple, Mie-Gruneisen EOS is presented, but tabulated EOS (LEOS) provided by the library can be used as well. The stress is limited by the yield surface which depends on three invariants of the stress tensor and specific internal energy. In addition, to capture the strain-rate dependence a simple multiplier is used for the yield surface which depends on the equivalent plastic strain rate. The failure surface (the ultimate yield, Y f , defined later) is chosen in the Hoek-Brown form, commonly used in rock mechanics. It includes measurable parameters such as Unconfined Compressive Strength (UCS) as well as scale parameters characterizing the quality of the rock such as GSI (Geologic Strength Index). Thus, even though the model is calibrated for small samples it offers a way to extrapolate the strength to the field scale using geological characterization of the rock mass. The model captures effects of brittle-ductile transition in rocks by introducing a cap multiplier to the yield function. The rate of dilatancy (bulking) is proportional to the slope of the yield surface affected by the cap. Therefore, it takes place only at low confinements when the pressure is less than the brittle-ductile transition pressure, P BD . On the contrary, the porous compaction takes place at pressures higher than P BD . The cap moves as the porosity is compacted or new porosity is generated due to dilatancy. The porous compaction is modeled using an evolution equation which includes deviatoric stress so that the onset of compaction corresponds to the cap surface. The model captures effects of shear-enhanced compaction which is an important for porous rocks. Section 2 describes the modeling framework and Section 3 presents the model calibration procedure. Section 4 compares experimental data for various rocks versus model predictions. The model parameters used for this comparison are given in Appendix. The files with material constants are available with the latest GEODYN material library distribution.

58 GEOSCIENCES↗

DOE OSTI2025

NFPA Distributed Energy Resources Safety Training (DERST) For Emergency Responders

The National Fire Protection Association, with support from the Department of Energy, executed a multi-year initiative to develop, enhance, and disseminate Distributed Energy Resources Safety Training (DERST) tools for U.S. emergency responders. As Distributed Energy Resources (DER)—such as solar photovoltaics, battery energy storage systems (ESS), electric vehicles (EVs), and associated infrastructure—become increasingly prevalent, the NFPA identified a critical need for up-to-date standardized, accessible, and effective safety training tailored for the fire service and related public safety professionals. The project delivered a comprehensive suite of educational resources to improve responders’ abilities to safely manage DER-related incidents. This included: • Revised Modular Training Courses: Updated classroom-based DER safety courses, now modular and accessible nationwide through fire academies and the North American Fire Training Directors (NAFTD) network. • Live Burn Testing & Research: A full-scale controlled burn of a DER-equipped residential structure provided real-world data and insights, forming the basis for updated best practices. • A Gamified Simulation Tool – Firefighters Incident Response Simulation Tool (FIRST): A first-of-its-kind, multiplayer, scenario-based simulation using the Unreal Engine 5.0 to train responders in a realistic virtual, multi-DER incident environment. • Field Familiarization Software Tools & Prop Guide: Digital DER field familiarization evolutions software guide and a prop development manual to support field-based DER training exercises, enhancing responders' hands-on familiarity with DER infrastructure and collaboration on virtual incident responses. • National Dissemination Strategy: Strategic partnerships with NAFTD, Vector Solutions, and others enabled wide-scale distribution, with over 5,000 departments accessing resources and 1,100+ departments adopting the simulator in the first seven months. Also provided a web portal for easy access to all training and simulation programs developed under this grant for the U.S. responder community. Key findings from the project—particularly from the burn test—led to paradigm shifts in fire response tactics. For example, traditional approaches to garage fires may be hazardous if DERs are present, due to explosive off gassing and thermal runaway risks. The new training emphasizes scene assessment, stand-off approaches, thermal imaging verification, and careful post-incident cooling of DER components to prevent reignition. This initiative has had a significant national impact, raising awareness, enhancing preparedness, and supporting safer DER incident response practices. Significant engagement from the media, public safety organizations, and PBS coverage has further amplified the reach and adoption of NFPA’s DER safety training, tools, and simulations.

14 SOLAR ENERGY↗

DOE OSTI2021

Effects of non-thermal termolecular chemistry on detonation development in hydrogen (H2) / methane (CH4) - air mixtures

In combustion simulations, it is usually assumed that highly-energized collision complexes (either radical or stable species) formed in exothermic reactions are always under thermal equilibrium as they evolve through competing networks of reactions. However, in practical flames, non-trivial amounts of reactive radicals such as H, O and OH are present apart from O2. As a result, collisions of these reactive species with the energized collision complexes have been shown in recent studies to induce non-thermal reactivity. These studies have also demonstrated that such non-thermal reactions can be suitably represented in macroscopic kinetics models as chemically termolecular reactions. The present work was focused on identifying and quantifying the effects of including such reactions on the evolution of an initial deflagration front to a developing detonation in H2/CH4-air mixtures under boosted internal combustion (IC) engine conditions. Specifically, fully resolved simulations, with and without non-thermal reactivity, were performed for a constant volume reactor containing stoichiometric H2/CH4-air mixture. It was found that inclusion of termolecular chemistry resulted in a delayed onset of end-gas auto-ignition. Concurrently, the developing detonation intensity was observed to be significantly higher. Chemical explosive mode analysis (CEMA) was performed to identify the dominant species/reactions responsible for the observed variation in the results.

Detonation↗

NASA NTRS2018

Next-Generation NASA Earth-Orbiting Relay Satellites: Fusing Optical and Microwave Communications

NASA is currently considering architectures and concepts for the generation of relay satellites that will replace the Tracking and Data Relay Satellite (TDRS) constellation, which has been flying since 1983. TDRS-M, the last of the second TDRS generation, launched in August 2017, extending the life of the TDRS constellation beyond 2030. However, opportunities exist to re-engineer the concepts of geosynchronous Earth relay satellites. The needs of the relay satellite customers have changed dramatically over the last 34 years since the first TDRS launch. There is a demand for greater bandwidth as the availability of the traditional RF spectrum for space communications diminishes and the demand for ground station access grows. The next generation of NASA relay satellites will provide for operations that have factored in these new constraints. In this paper, we describe a heterogeneous constellation of geosynchronous relay satellites employing optical and RF communications. The new constellation will enable new optical communications services formed by user-to-space relay, space relay-to-space relay and space relay-to-ground links. It will build upon the experience from the Lunar Laser Communications Demonstration from 2013 and the Laser Communications Relay Demonstration to be launched in 2019.Simultaneous to establishment of the optical communications space segment, spacecraft in the TDRS constellation will be replaced with RF relay satellites with targeted subsets of the TDRS capabilities. This disaggregation of the TDRS service model will allow for flexibility in replenishing the needs of legacy users as well as addition of new capabilities for future users. It will also permit the U.S. government access to launch capabilities such as rideshare and to hosted payloads that were not previously available.In this paper, we also explore how the next generation of Earth relay satellites provides a significant boost in the opportunities for commercial providers to the communications space segment. For optical communications, the backbone of this effort is adoption of commercial technologies from the terrestrial high-bandwidth telecommunications industry into optical payloads. For RF communications, the explosion of software-defined radio, high-speed digital signal processing technologies and networking from areas such as 5G multicarrier will be important. Future commercial providers will not be limited to a small set of large aerospace companies. Ultimately, entirely government-owned and -operated satellite communications will phase out and make way for commercial business models that satisfy NASA's satellite communications requirements. The competition being provided by new entrants in the space communications business may result in a future in which all NASA communications needs can be satisfied commercially.

Space Communications↗

NASA NTRS2018

Next-Generation NASA Earth-Orbiting Relay Satellites: Fusing Microwave and Optical Communications

NASA is currently considering architectures and concepts for the generation of relay satellites that will replace the Tracking and Data Relay Satellite (TDRS) constellation, which has been flying since 1983. TDRS-M, the last of the second TDRS generation, launched in August 2017, extending the life of the TDRS constellation beyond 2030. However, opportunities exist to re-engineer the concepts of geosynchronous Earth relay satellites. The needs of the relay satellite customers have changed dramatically over the last 34 years since the first TDRS launch. There is a demand for greater bandwidth as the availability of the traditional RF spectrum for space communications diminishes and the demand for ground station access grows. The next generation of NASA relay satellites will provide for operations that have factored in these new constraints. In this paper, we describe a heterogeneous constellation of geosynchronous relay satellites employing optical and RF communications. The new constellation will enable new optical communications services formed by user-to-space relay, space relay-to-space relay and space relay-to-ground links. It will build upon the experience from the Lunar Laser Communications Demonstration from 2013 and the Laser Communications Relay Demonstration to be launched in 2019.Simultaneous to establishment of the optical communications space segment, spacecraft in the TDRS constellation will be replaced with RF relay satellites with targeted subsets of the TDRS capabilities. This disaggregation of the TDRS service model will allow for flexibility in replenishing the needs of legacy users as well as addition of new capabilities for future users. It will also permit the U.S. government access to launch capabilities such as rideshare and to hosted payloads that were not previously available. In this paper, we also explore how the next generation of Earth relay satellites provides a significant boost in the opportunities for commercial providers to the communications space segment. For optical communications, the backbone of this effort is adoption of commercial technologies from the terrestrial high-bandwidth telecommunications industry into optical payloads. For RF communications, the explosion of software-defined radio, high-speed digital signal processing technologies and networking from areas such as 5G multicarrier will be important. Future commercial providers will not be limited to a small set of large aerospace companies. Ultimately, entirely government-owned and -operated satellite communications will phase out and make way for commercial business models that satisfy NASAs satellite communications requirements. The competition being provided by new entrants in the space communications business may result in a future in which all NASA communications needs can be satisfied commercially.

Space Communications↗

NASA NTRS1994

The heating of nova ejecta by radioactive decays of the beta-unstable nuclei

Recent nucleosynthesis and hydrodynamic calculations of the consequences of accretion onto massive ONeMg white dwarf stars show that under certain circumstances significant amounts of the beta-unstable nuclei can be produced and ejected by the resulting explosion. We use these calculations as a guide in order to obtain the conditions under which the heating of the ejected material by the nonthermal electrons and positrons produced by the decays of the beta-unstable nuclei is sufficient to overcome the cooling from adiabatic expansion and lead to the production of X-ray-emitting coronal gas. These conditions are as follows: (1) a mass fraction for Na-22 of the order of 10(exp -3) or greater, (2) an expansion velocity in the range approximately 10(exp 2) - 10(exp 3) km/s, (3) a photospheric radius of approximately 10(exp 14) cm, (4) if the density distribution in the atmosphere satisfies a power law, then the exponent must be less than 3 for heating to overcome adiabatic cooling. Both the simulations of the outburst and the model atmosphere fits to the observed energy distributions, however, imply that the exponent is greater than or = 3 during the early phases of the outburst. Nevertheless, for a value of the exponent of 2, we predict the time when hot coronal gas can form during the expansion phases of the envelope.

Pistinner, Shlomi↗

NASA NTRS1989

Large space antenna concepts for ESGP

It is appropriate to note that 1988 marks the 100th anniversary of the birth of the reflector antenna. It was in 1888 that Heinrich Hertz constructed the first one, a parabolic cylinder made of sheet zinc bent to shape and supported by a wooden frame. Hertz demonstrated the existence of the electromagnetic waves that had been predicted theoretically by James Clerk Maxwell some 22 years earlier. In the 100 years since Hertz's pioneering work the field of electromagnetics has grown explosively: one of the technologies is that of remote sensing of planet Earth by means of electromagnetic waves, using both passive and active sensors located on an Earth Science Geostationary Platform (ESEP). For these purposes some exquisitely sensitive instruments were developed, capable of reaching to the fringes of the known universe, and relying on large reflector antennas to collect the minute signals and direct them to appropriate receiving devices. These antennas are electrically large, with diameters of 3000 to 10,000 wavelengths and with gains approaching 80 to 90 dB. Some of the reflector antennas proposed for ESGP are also electrically large. For example, at 220 GHz a 4-meter reflector is nearly 3000 wavelengths in diameter, and is electrically quite comparable with a number of the millimeter wave radiotelescopes that are being built around the world. Its surface must meet stringent requirements on rms smoothness, and ability to resist deformation. Here, however, the environmental forces at work are different. There are no varying forces due to wind and gravity, but inertial forces due to mechanical scanning must be reckoned with. With this form of beam scanning, minimizing momentum transfer to the space platform is a problem that demands an answer. Finally, reflector surface distortion due to thermal gradients caused by the solar flux probably represents the most challenging problem to be solved if these Large Space Antennas are to achieve the gain and resolution required of them.

Love, Allan W.↗

DOE OSTI2024

Prospects for direct detection of black hole formation in neutron star mergers with next-generation gravitational-wave detectors

A direct detection of black hole formation in neutron star mergers would provide invaluable information about matter in neutron star cores and finite temperature effects on the nuclear equation of state. We study black hole formation in neutron star mergers using a set of 190 numerical relativity simulations consisting of long-lived and black-hole-forming remnants. The postmerger gravitational-wave spectrum of a long-lived remnant has greatly reduced power at a frequency 𝑓 greater than 𝑓 peak , for 𝑓 ≳ 4 kHz, with 𝑓 peak ∈ [2.5,4] kHz. On the other hand, black-hole-forming remnants exhibit excess power in the same large 𝑓 region and manifest exponential damping in the time domain characteristic of a quasinormal mode. We demonstrate that the gravitational-wave signal from a collapsed remnant is indeed a quasinormal ringing. We report on the opportunity for direct detections of black hole formation with next-generation gravitational-wave detectors such as Cosmic Explorer and Einstein Telescope and set forth the tantalizing prospect of such observations up to a distance of 100 Mpc for an optimally oriented and located source with an SNR of 4.

Astronomy & Astrophysics↗

DOE OSTI2022

Vapor-Phase Aggregation of Cerium Oxide Nanoparticles in a Rapidly Cooling Plasma

Local conditions, such as temperature and oxygen availability, have a pronounced effect on the formation and evolution of fallout following a nuclear explosion. While the behavior of nuclear-relevant materials such as uranium has begun to be explored under a wider range of environments, little is known about the behavior of plutonium. Here, using cerium as a surrogate, we track the vapor-phase aggregation of cerium oxide nanoparticles created in a plasma flow reactor under conditions of controlled temperature at two different oxygen fugacities. In situ optical emission spectroscopy is used to measure the variations in the spectral intensity of atomic and molecular species with temperature and oxygen content. We find that the relative rate of gas-phase oxidation of cerium is highly dependent on both temperature and local redox conditions within the flow reactor, to the extent that doubling the oxygen availability effectively doubles the amount of vapor-phase cerium monoxide at high temperatures (>2000 K). Condensed cerium oxide nanoparticles are also collected and analyzed ex situ via transmission electron microscopy and grazing-incidence small-angle X-ray scattering to determine their elemental composition, crystal structure, and size distribution. The size and morphology of the condensed nanoparticles are independent of local redox conditions, forming the same crystal type with the same size distribution regardless of oxygen availability. Postcondensation particle evolution, however, is found to be predominantly driven by temperature, with the average particle size increasing as particles cool and subsequently aggregate. These results expand our understanding of the chemical and physical behavior of refractory oxides that form during the early stages of fallout formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Predicted Melt Curve and Liquid Shear Viscosity of RDX up to 30 GPa

Recent grain-scale simulations of HMX and TATB have shown that predictions for hot spot formation in high explosives are particularly sensitive to accurate determinations of the pressure-dependent melt curve and the shear viscosity of the liquid phase. These physics terms are poorly constrained beyond ambient pressure for the explosive RDX. Here we adopt an all-atom modeling approach using molecular dynamics (MD) simulations to predict the melt curve of RDX near to detonation conditions (30 GPa) and determine the shear viscosity of the liquid as a function of temperature and pressure above the melt curve. Phase-coexistence simulations were used to determine the melt curve, which is predicted to vary by almost 1100 K as the pressure increases from 0 GPa to 30 GPa. Equilibrium MD simulations and the Green-Kubo formalism were used to obtain the pressure-temperature-dependent shear viscosity. The shear viscosity of RDX is predicted to be of similar magnitude to the viscosity of TATB at low GPa-range pressures, and to be roughly an order of magnitude lower than the viscosity of HMX. The temperature dependence of the shear viscosity is Arrhenius at a given pressure, and the exponential pre-factor and activation term exhibit a strong, yet complicated, pressure dependence. An empirical pressure-temperature dependent function for RDX shear viscosity is developed that simultaneously captures a wide range of MD predictions while taking an analytic form that extrapolates smoothly beyond the fitted regime. The relative strength of the pressure and temperature dependencies of these two physics terms is found to be of similar magnitude for RDX, HMX, and TATB, which motivates incorporating these results in future RDX grain-scale modeling.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Experimental and theoretical analysis of carbon driven detonation waves in a heterogeneously premixed Rotating Detonation Engine

Coal dust explosions can be hazardous; however, they can also generate a significant rise in stagnation pressure if adequately harnessed. Rotating detonation combustors seek to take advantage of the stagnation pressure rise phenomenon in a more sustained and controlled manner via confinement to a physical annulus, leading to increased overall thermodynamic efficiency. Here this investigation presents an analysis of detonations fueled by Carbon Black, a solid particulate consisting of virtually pure carbon molecules and lean Hydrogen-Air mixtures. It is realized that with the addition of Carbon Black, an increase of lean mixture detonability and detonation velocities extending the operating limit over that of a pure hydrogen-air mixture is experienced. For all testing conditions, the total equivalence ratio is held at φ = 1, while the fuel mixture's carbon mass fraction is increased from 0 to 0.7 while the hydrogen is decreased. Detonation wave velocities are extracted from high-speed imaging through applying a Discrete Fourier Transform algorithm to determine changes to the wave speed as Carbon Black particles are introduced. As a result, due to the addition of Carbon Black as an auxiliary fuel source, detonations were formed instead of deflagrations in operating conditions where one would expect deflagrations at the same hydrogen-air equivalence ratios without Carbon Black addition. The detonation formation provides evidence that the coal particles are reacting within the detonation wave in a large enough capacity to support a detonation wave within the annulus. Furthermore, the wave speed is shown to increase with the additional of carbon particles. At a constant global equivalence ratio, the detonation wave velocities were found to decrease with hydrogen's incremental replacement with coal particles. Whereby, through a theoretical comparison of the heat of combustion as computed from the experimentally derived detonation wave velocities, a linear relationship of the two was shown to exist. Therefore, the heat of combustion has the potential to describe an operational limit to sustaining a detonation wave.

42 ENGINEERING↗

DOE OSTI2020

Spherically expanding flame in silane–hydrogen–nitrous oxide–argon mixtures

The effect of silane addition on the laminar flame speed ($S^0_u$) of flames propagating in hydrogen–nitrous oxide–argon mixtures has been investigated experimentally for the first time using the spherically expanding flame technique in a constant volume combustion chamber. Replacing hydrogen by silane and maintaining the equivalence ratio constant, much higher flame speeds, explosion peak pressures, and pressure rise coefficients were measured. A previously developed detailed reaction model has been updated based on ab initio thermodynamic properties calculations and collision limit violation analysis. The improved reaction model demonstrates encouraging performance in predicting the flame speed, with a mean absolute error below 11%. To explain the effect of silane addition on the flame dynamics, a number of parameters have been calculated including OH and H rate of production, heat release rate per reaction, and sensitivity coefficient on . The dynamics of freely propagating flames in SiH 4 –H 2 –N 2 O–Ar mixtures is essentially controlled by reactions of the H–O–N chemical system: N 2 O+H=N 2 +OH, OH+H 2 =H 2 O+H, and N 2 O(+M)=N 2 +O(+M). Whereas silane addition does not influence much the rate of production of OH, it significantly modifies that of H with a number of pyrolytic chemical pathways of silicon hydrides, such as SiH+H 2 =SiH 2 +H and Si+H 2 =SiH+H, which act as sink of H atom as they proceed in the backward direction. The reactions forming SiO(s) and SiO 2 (s), such as SiO+OH=SiO 2 (s)+H and 2SiO=2SiO(s), are exothermic and significantly contribute to the temperature increase. The adiabatic, constant pressure flame temperature for mixture containing silane is significantly higher, up to several 100’s K. The increase of induced by silane addition seems to be mostly related to the large increase of the flame temperature which leads to higher energy release rate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Air-coupled tsunamis generated from impacts and airbursts: Our understanding before Hunga-Tonga Hunga-Ha'apai

The effort to prevent or mitigate the effects of an impact on Earth is known as planetary defense. A significant component of planetary defense research involves risk assessment. Much of our understanding of the risk from near-Earth objects comes from the geologic record in the form of impact craters, but not all asteroid impacts are crater-forming events. Small asteroids explode before reaching the surface, generating an airburst, and most impacts into the ocean do not penetrate the water to form a crater in the sea floor. The risk from these non-crater-forming ocean impacts and airbursts is difficult to quantify and represents a significant uncertainty in our assessment of the overall threat. We are currently working to better understand impact scenarios that can generate dangerous tsunamis. One of the suggested mechanisms for the production of asteroid–generated tsunamis is by direct coupling of the pressure wave to the water, analogous to the means by which a moving weather front can generate a meteotsunami. To test this hypothesis, we ran a series of airburst simulations and provided time-resolved pressure and wind profiles to use as source functions for tsunami models. We used the CTH hydrocode to model the various airburst scenarios to compare to the results of other simulations and provide time dependent boundary conditions as input to shallow-water wave propagation codes. The strongest and most destructive meteotsunamis are generated by atmospheric pressure oscillations with amplitudes of only a few hPa1 (mbar), corresponding to changes in sea level of a few cm. The resulting wave is strongest when there is a resonance between the ocean and the atmospheric forcing. A Proudman resonance takes place when the atmospheric disturbance’s translational speed (U) equals the longwave phase speed $\sqrt{gh}$ of shallow water wave. Coupling is strongest when the Froude number (Fr=U/c) is unity. A weather front propagates much slower than the speed of sound, so meteotsunamis are most common and dangerous in shallow bodies of water such as the Mediterranean Sea or Lake Michigan. By contrast, the blast wave from an airburst or crater-forming impact propagates at a speed faster than a tsunami in the deepest ocean, and a Proudman resonance cannot be achieved even though the overpressures are orders of magnitude greater. However, blast wave profiles are N-waves in which a sharp shock wave leading to overpressure is followed by a more gradual rarefaction to a much longer-duration underpressure phase. Even though the blast outruns the water wave it is forcing, the tsunami should continue to be driven by the out-of-resonance gradient associated with the suction phase, which may depend strongly on the details of the airburst or impact scenario. The open question is whether there are any conditions under which such an airburst-driven tsunami can be dangerous enough to contribute to the overall impact risk. We have also identified other potential mechanisms for airburst-generated tsunamis: 1) reaction force at the surface from the plume ejected into space, which carries significant momentum, 2) expanding toroidal vortices at the surface, which travel more slowly than the shock wave and can generate a Proudman resonance in relatively shallow ocean (such as continental shelf), and 3) steam explosion from seawater ablation by a “Type II” (Libyan Desert Glass-type) airburst in which the hot vapor jet descends to the surface. On January 15, 2022, the Hunga-Tonga Hunga-Ha’apai volcano, located approximately 60 km north of Tongatapu, the main island of Tonga, violently erupted with a powerful explosion, culminating the period of volcanic activity that started in December of 2021. This event and resulting tsunamis provided an existence proof for the air pressure wave coupling mechanism we proposed. It also suggests that it can be stronger and more significant over much greater distances than we contemplated, leading to global tsunamis associated with impact events on land as well as in the water. Large atmospheric explosions generate global Lamb waves with larger amplitudes, longer periods, and slower speeds than the local and regional blast waves we modeled prior to that event. This paper reviews our analysis and modeling of airburst-driven tsunamis prior to the 2022 Hunga-Tonga Hunga-Ha’apai tsunami, which was the subject of two presentations at the 2023 Planetary Defense Conference and is the subject of another paper currently in preparation.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1994

Explosion Calculations of SN1087

Explosion calculations of SNT1987A generate pictures of Rayleigh-Taylor fingers of radioactive Ni-56 which are boosted to velocities of several thousand km/s. From the KAO observations of the mid-IR iron lines, a picture of the iron in the ejecta emerges which is consistent with the "frothy iron fingers" having expanded to fill about 50% of the metal-rich volume of the ejecta. The ratio of the nickel line intensities yields a high ionization fraction of greater than or equal to 0.9 in the volume associated with the iron-group elements at day 415, before dust condenses in the ejecta. From the KAO observations of the dust's thermal emission, it is deduced that when the grains condense their infrared radiation is trapped, their apparent opacity is gray, and they have a surface area filling factor of about 50%. The dust emission from SN1987A is featureless: no 9.7 micrometer silicate feature, nor PAH features, nor dust emission features of any kind are seen at any time. The total dust opacity increases with time even though the surface area filling factor and the dust/gas ratio remain constant. This suggests that the dust forms along coherent structures which can maintain their radial line-of-sight opacities, i.e., along fat fingers. The coincidence of the filling factor of the dust and the filling factor of the iron strongly suggests that the dust condenses within the iron, and therefore the dust is iron-rich. It only takes approximately 4 x 10(exp -4) solar mass of dust for the ejecta to be optically thick out to approximately 100 micrometers; a lower limit of 4 x 10(exp -4) solar mass of condensed grains exists in the metal-rich volume, but much more dust could be present. The episode of dust formation started at about 530 days and proceeded rapidly, so that by 600 days 45% of the bolometric luminosity was being emitted in the IR; by 775 days, 86% of the bolometric luminosity was being reradiated by the dust. Measurements of the bolometric luminosity of SN1987A from 1000 - 1800 days are based on 10 micrometers and 20 micrometers photometry and rely on the suppositions that the IR emission is a greybody (proven to be true by the KAO observations at 615 and 775 days) and that the dust temperature drops to and remains at 150 K. The late time bolometric luminosity is stronger than that expected from the radioactive decay of Co-56, Co-57, Ti-44, and Na-22 and the possibility of an embedded compact object will be discussed.

Wooden, Diane H.↗

DOE OSTI2021

Following nuclei through nucleosynthesis: A novel tracing technique

Astrophysical nucleosynthesis is a family of diverse processes by which atomic nuclei undergo nuclear reactions and decay to form new nuclei. The complex nature of nucleosynthesis, which can involve as many as tens of thousands of interactions between thousands of nuclei, makes it difficult to study any one of these interactions in isolation using standard approaches. In this work, we present a new technique, nucleosynthesis tracing, that we use to quantify the relative fraction of nuclear abundances that pass through individual nuclear reaction, decay, and fission processes at any point during nucleosynthesis. Here, we apply this technique to study fission and β – decay as they occur in the rapid neutron capture (r) process of nucleosynthesis.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗