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At least 577 records · Page 32

Improvement to Air2Air™ Technology to Reduce Fresh-Water Evaporative Cooling Loss at Coal-Based Thermoelectric Power Plants

This program was undertaken to enhance the manufacturability, constructability, and cost of the Air2Air™ Water Conservation and Plume Abatement Cooling Tower, giving a validated cost basis and capability. Air2Air™ water conservation technology recovers a portion of the traditional cooling tower evaporate. The Condensing Module provides an air-to-air heat exchanger above the wet fill media, extracting the heat from the hot saturated moist air leaving in the cooling tower and condensing water. The rate of evaporate water recovery is typically 10% - 25% annually, depending on the cooling tower location (climate). This program improved the efficiency and cost of the Air2Air™ Water Conservation Cooling Tower capability, and led to the first commercial sale of the product, as described.

20 FOSSIL-FUELED POWER PLANTS↗

New Adsorbents for Vehicle Exhaust and Evaporative Emission Control

Vehicle cold start hydrocarbon emissions occur before the exhaust catalyst warm up. Therefore, we have to trap/adsorb the hydrocarbons and hold them until the catalyst warms up to light off temperatures. There are many zeolite adsorbents that can adsorb cold start exhaust hydrocarbons but they desorb them before the catalyst lights off. The adsorbent required for this purpose should be able to adsorb the hydrocarbons and hold them (not desorb at temperatures below 250 to 300°C) until the catalyst warms up to light off temperature (-300°C) so that the catalyst will be ready to oxidize the hydrocarbons when they are desorbed. Vehicle evaporative fuel vapors, which consists of diurnal (due to daily temperature cycles), running loss (due to tank fuel heating by engine heat), and refueling gasoline vapors, are trapped/adsorbed in an activated carbon canister. When the engine is running, the trapped vapors are purged (desorbed) and consumed in engine combustion. The purging is accomplished by drawing ambient air through the canister using engine manifold vacuum. If the activated carbon canister is not purged or cleaned properly, the hydrocarbons will breakthrough in subsequent loading, which results in evaporative hydrocarbon emissions into the atmosphere.

99 GENERAL AND MISCELLANEOUS↗

Results of Hg Speciation Testing on Tank 38 and 2H Evaporator Overhead Tank (OHT-1) Materials

The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The seventh shipment of samples was designated to include two Tank 38 (2H Evaporator System Drop Tank) samples: a surface sample (HTF-38-15-48) and a variable depth sample taken at 265” (HTF-38-15-50). The third sample submitted was from the 2H Evaporator Overhead Tank (OHT) #1. All samples were received by SRNL on May 11, 2015. The OHT-1 was not placed in the SRNL Shielded Cells but was instead placed in a refrigerator in 773-A, B-wing upon receipt and kept at 4°C. The Tank 38 samples were left in their stainless steel dip bottles until they were opened and an aliquot of each diluted 1:10 with Eurofins deionized water on June 1, 2015. Following initial dilution in the Shielded Cells, the diluted Tank 38 samples were immediately moved to refrigeration and kept in the dark until prepared for shipment to Eurofins.

54 ENVIRONMENTAL SCIENCES↗

Results of HG Speciation Testing on Tank 43 and 2H Evaporator Overhead Tank (OHT-2) Materials

The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The eighth shipment of samples was designated to include two Tank 43 (2H Evaporator System Feed Tank) samples: a surface sample (HTF-43-15-52) and a variable depth sample taken at 161” (HTF-43-15-54). The third sample submitted was from the 2H Evaporator Overhead Tank (OHT) #2. All samples were received by SRNL on May 11, 2015. The OHT-2 was not placed in the SRNL Shielded Cells but was instead placed in a refrigerator in 773-A, B-wing upon receipt and kept at 4°C. The Tank 43 samples were left in their stainless steel dip bottles until they were opened and an aliquot of each diluted 1:10 with Eurofins deionized water on June 3, 2015. Following initial dilution in the Shielded Cells, the diluted Tank 43 samples were immediately moved to refrigeration and kept in the dark until prepared for shipment to Eurofins.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Addressing Water Consumption of Evaporative Coolers with Greywater

Evaporative coolers (ECs) provide significant gains in energy efficiency compared to vapor compression air conditioners, but simultaneously have significant onsite water demand. This can be a major barrier to deployment in areas of the world with hot and arid climates. To address this concern, this study determined where in the world evaporative cooling is suitable, the water consumption of ECs in these cities, and the potential that greywater can be used reduce the consumption of potable water in ECs. ECs covered 69percent of the cities where room air conditioners are may be deployed, based on comfort conditions alone. The average water consumption due to ECs was found to be 400 L/household/day in the United States and Australia, with the potential for greywater to provide 50percent this amount. In the rest of the world, the average water consumption was 250 L/household/day, with the potential for greywater to supply 80percent of this amount. Home size was the main factor that contributed to this difference. In the Mediterranean, the Middle East, Northern India, and the Midwestern and Southwestern United States alkalinity levels are high and water used for bleeding will likely contribute significantly to EC water consumption. Although technically feasible, upfront costs for household GW systems are currently high. In both developed and developing parts of the world, however, a direct EC and GW system is cost competitive with conventional vapor compression air conditioners. Moreover, in regions of the world that face problems of water scarcity the benefits can substantially outweigh the costs.

25 ENERGY STORAGE↗

Reevaluation Of The Risk Of Solids Formation In The 2h Evaporator System

Savannah River Remediation (SRR) Tank Farm Engineering requested further technical assistance from the Savannah River National Laboratory (SRNL) to reassess the risk of solids formation in the 2H Evaporator system following feed tank and drop tank blending operations conducted between 12/15/2018 and 1/6/2019. OLI aqueous electrolyte model simulations were completed for three variable-depth, post-blending liquid waste samples collected from Tank 43 on 1/27/2019. The purpose of the new simulations is to provide guidance to SRR on a recommended maximum overhead-to-feed volume ratio to avoid unwanted solids formation upon restart of the 2H Evaporator.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Permanganate Oxidation of Actual Defense Waste Processing Facility (DWPF) Slurry Mix Evaporator Condensate Tank (SMECT) and Offgas Condensate Tank (OGCT) Samples to Remediate Glycolate

Savannah River Remediation (SRR) tasked Savannah River National Laboratory (SRNL) to examine glycolate destruction in radioactive samples emulating the proposed process. Experiments with radioactive Defense Waste Processing Facility (DWPF) condensates were performed to demonstrate the oxidation of glycolate using sodium permanganate. One test each was performed for Off-Gas Condensate Tank (OGCT) and Slurry Mix Evaporator Condensate Tank (SMECT) samples received. Condensates were blended with Recycle Collection Tank (RCT) heel simulant and Slurry Mix Evaporator (SME) product containing glycolate to represent typical RCT compositions with estimated nominal entrainment of glycolate. A permanganate to glycolate (P/G) molar ratio targeting 5.7 decreased sample glycolate concentration below Ion Chromatography (IC), glycolate method reporting limits in less than 2 hours for the OGCT sample and in less than 8 hours for the SMECT sample.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the April 2022 Tank Farm 2H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the April 2022 2H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization Results for the March 2023 Tank Farm 2H Evaporator Overhead Sample

On an annual basis, Savannah River Mission Completion (SRMC) provides 2H and 3H evaporator overhead samples to Savannah River National Lab (SRNL) to be analyzed per Section 5.2 of the Effluent Treatment Project (ETP) Waste Compliance Plan (WCP) and the Waste Acceptance Criteria (WAC). This report presents characterization results for the March 2023 2H evaporator overhead sample. The sample was clear and colorless with no visible solids. The results provide measurements for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), and iodine-129 ( 129 I) with the radionuclide concentration limits specified by the WAC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Life Expectancy of Evaporating Capillary Bridges Predicted by Tertiary Creep Modeling

The evaporation of capillary bridges is experimentally investigated at the microscale through a three-grain capillary cluster. This setting provides the minimum viable description of Haines jumps during evaporation, that is, capillary instabilities stemming from air entry into a saturated granular material. The displacement profile of a meniscus is obtained via digital image correlation for different grain materials, geometries, and separations. While it is well known that Haines jumps are triggered at the pore throat, we find that these instabilities are of three types depending on the separation. We also provide a temporal characterization of Haines jumps; we find that they are accurately described, as tertiary creep instabilities, by Voight’s relation, similarly to landslides and volcanic eruptions. This finding extends the description of capillary instabilities beyond their onset predicted by Laplace equilibrium. Our contribution also paves the way for a microscopically-informed description of desiccation cracks, of which Haines jumps are the precursors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Explosive Chromospheric Evaporation and Warm Rain in a C3.1 Flare Observed by IRIS, Hinode/EIS, and RHESSI

IRIS and EIS observed a GOES C3.1 flare in stare mode on 2014 March 15. The GOES flare started at 00:21:35 and peaked at 00:26:30 UT. The IRIS slit pointed near the center of the flare, while the EIS slit pointed 35{sup ′′} to its west. About 4 minutes before the GOES flare start, the IRIS C ii and Si iv intensities became (and remained) greater than their pre-flare averages, indicating that the flare had begun and that the chromosphere and transition region were involved. IRIS first detected blueshifted Fe xxi emission at 00:22:42 UT, by which time the C ii and Si iv intensities had increased by factors around 100 and their profiles were redshifted. Simultaneous, cospatial blueshifted Fe xxi emission with redshifted C ii and Si iv emission indicates explosive chromospheric evaporation. EIS spectra reveal Fe xxiii emission that is too weak to measure velocities, and intensity enhancements by factors about 1.7 in the Fe xiv and Fe xvi emission. Lines from both of these coronal ions show redshifts ≈9 km s{sup −1} around 00:24:00 UT, and the Fe xiv 264.7/274.2 intensity ratio reveals an increase of n {sub e} from (1.03±0.20)×10{sup 9} before to (3.58±0.68)×10{sup 9} cm{sup −3} during the flare. The redshifted coronal line emission and increased n {sub e} are consistent with warm rain falling and accumulating in the remote area observed by EIS. A fit to the RHESSI hard X-ray spectrum yields a nonthermal energy injection rate of 4.9×10{sup 26} erg s{sup −1}, from which we estimate a HXR beam energy flux range consistent with explosive evaporation.

79 ASTRONOMY AND ASTROPHYSICS↗

Distillation-based Droplet Modeling of Non-Ideal Oxygenated Gasoline Blends: Investigating the Role of Droplet Evaporation on PM Emissions

In some studies, a relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from vehicles equipped with spark ignition engines. The fundamental cause of the PM increase seen for moderate ethanol concentrations is not well understood. Ethanol features a greater heat of vaporization (HOV) than gasoline and also influences vaporization by altering the liquid and vapor composition throughout the distillation process. A droplet vaporization model was developed to explore ethanol's effect on the evaporation of aromatic compounds known to be PM precursors. The evolving droplet composition is modeled as a distillation process, with non-ideal interactions between oxygenates and hydrocarbons accounted for using UNIFAC group contribution theory. Predicted composition and distillation curves were validated by experiments. Detailed hydrocarbon analysis was applied to fuel samples and to distillate fractions, and used as input for the initial droplet composition. With composition calculated throughout the distillation, the changing HOV and other physical properties can be found using reference data. The droplet can thus be modeled in terms of energy transfer, which in turn provides the transient mass transfer, droplet temperature, and droplet diameter. Model predictions suggest that non-ideal vapor-liquid equilibrium along with an increase in HOV can alter the droplet composition evolution. Results predict that the presence of ethanol causes enrichment of the higher boiling fractions (T90+) in the aromatic components as well as lengthens the droplet lifetime. A simulation of the evaporation process in a transient environment as experienced within an engine cylinder predicts a decrease in mixing time of the heaviest fractions of the fuel prior to spark initiation, possibly explaining observations linking ethanol to PM.

02 PETROLEUM↗

A coupled ground heat flux–surface energy balance model of evaporation using thermal remote sensing observations

Abstract. One of the major undetermined problems in evaporation (ET) retrieval using thermal infrared remote sensing is the lack of a physically based ground heat flux (G) model and its integration within the surface energy balance (SEB) equation. Here, we present a novel approach based on coupling a thermal inertia (TI)-based mechanistic G model with an analytical surface energy balance model, Surface Temperature Initiated Closure (STIC, version STIC1.2). The coupled model is named STIC-TI. The model is driven by noon–night (13:30 and 01:30 local time) land surface temperature, surface albedo, and a vegetation index from MODIS Aqua in conjunction with a clear-sky net radiation sub-model and ancillary meteorological information. SEB flux estimates from STIC-TI were evaluated with respect to the in situ fluxes from eddy covariance measurements in diverse ecosystems of contrasting aridity in both the Northern Hemisphere and Southern Hemisphere. Sensitivity analysis revealed substantial sensitivity of STIC-TI-derived fluxes due to the land surface temperature uncertainty. An evaluation of noontime G (Gi) estimates showed 12 %–21 % error across six flux tower sites, and a comparison between STIC-TI versus empirical G models also revealed the substantially better performance of the former. While the instantaneous noontime net radiation (RNi) and latent heat flux (LEi) were overestimated (15 % and 25 %), sensible heat flux (Hi) was underestimated (22 %). Overestimation (underestimation) of LEi (Hi) was associated with the overestimation of net available energy (RNi−Gi) and use of unclosed surface energy balance flux measurements in LEi (Hi) validation. The mean percent deviations in Gi and Hi estimates were found to be strongly correlated with satellite day–night view angle difference in parabolic and linear pattern, and a relatively weak correlation was found between day–night view angle difference versus LEi deviation. Findings from this parameter-sparse coupled G–ET model can make a valuable contribution to mapping and monitoring the spatiotemporal variability of ecosystem water stress and evaporation using noon–night thermal infrared observations from future Earth observation satellite missions such as TRISHNA, LSTM, and SBG.

Bhattacharya, Bimal K.↗

Evaporant feed device facilitates flash vapor deposition process in vacuum

Mechanism using a helix sequentially feeds prescribed amounts of metal charges into an evaporation boat used for flash vapor deposition of the evaporants onto a substrate in a vacuum chamber. The helix is advanced by external manual controls extending through sealed feed- through devices into the chamber wall.

Hermann, W. A.↗

Reflectance of evaporated rhenium and tungsten films in the vacuum ultraviolet from 300 to 2000 A.

Discussion of the dependence of the reflectance of Re and W on the substrate temperature during deposition, film thickness, and aging during exposure to air. Re and W of 99.99% purity were evaporated with a 6-kW fine-focused electron gun and deposited on glass and fused quartz plates of various temperatures ranging from 40 to 500 C. With Re, films of highest reflectance were obtained by evaporation onto unheated substrates, whereas with W, heating of the substrate greatly increased the reflectance of the deposited films. For both metals, the reflectance losses during extended exposure to air remained rather small, indicating that the oxide films formed on both film materials at room temperature were very thin.

Cox, J. T.↗

Properties of vacuum-evaporated boron films

The work on the properties of thin boron films made by vacuum evaporation of elemental boron using an electron beam as the energy source is reported. The program aimed at characterizing the properties of vacuum evaporated films. The work was directed toward those variables considered to be important in affecting the tensile strength of the boron films. In general, the thickness of the films was less than 0.002 in. The temperature of the substrate on which the boron was condensed was found to be most important. Three distinctly different forms of boron deposit were produced. Although the transition temperature was not sharply defined, at substrate temperatures of less than approximately 600 deg C the boron deposits were amorphous to X-ray. If the substrate were highly polished, the deposits were black and mirror-like. For substrates with coefficients of thermal expansion close to that of boron, the deposits were then continuous and uncracked. The studies suggest that the potential continues to exist for film-type composites to have both high strength and high modulus.

Feakes, F.↗

Evaporative segregation in 80% Ni-20% Cr and 60% Fe-40% Ni alloys

An analytical approach is outlined to calculate the evaporative segregation behavior in metallic alloys. The theoretical predictions are based on a 'normal' evaporation model and have been examined for Fe-Ni and Ni-Cr alloys. A fairly good agreement has been found between the predicted values and the experimental results found in the literature.

Gupta, K. P.↗