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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

A Treatment of Measurements of Heptane Droplet Combustion Aboard MSL-1

Results of measurements on the burning of free n-heptane droplets (that is, droplets without fiber supports) performed in Spacelab during the flights of the first Microgravity Science Laboratory (MSL-1) are presented. The droplet combustion occurred in oxidizing atmospheres which were at an ambient temperature within a few degrees of 300 K. A total of 34 droplets were burned in helium-oxygen atmospheres having oxygen mole fractions ranging from 20 to 50 percent, at pressures from 0.25 to 1.00 bar. In addition, four droplets were burned in air at 1.00 bar, bringing the total number of droplets for which combustion data were secured to 38; two of these four air tests were fiber-supported to facilitate comparisons with other fiber-support experiments, results of which also are given here. Initial diameters of free droplets ranged from about 1 to 4 mm. The primary data obtained were histories of droplet diameters, recorded in backlight on 35 mm film at 80 frames per second, and histories of flame diameters, inferred from emissions through a narrow-band interference filter centered at the 310 micron OH chemiluminescent ultraviolet band, recorded at 30 frames per second by a intensified-array camera. These data are reported here both in raw form and in a smoothed form with estimated error bars. In addition, summaries are presented of measured burning-rate constants, final droplet diameters, and final flame diameters. Both diffusive and radiative extinctions were exhibited under different conditions. Although some interpretations are reported and conclusions drawn concerning the combustion mechanisms, the principal intent of this report is to provide a complete, documented data set for future analysis.

Ackerman, M. D.↗
NASA NTRS1983

Numerical solution of the problem of flame propagation by the use of the random element method

A numerical, grid-free algorithm is presented for one-dimensional reaction-diffusion model of laminar flame propagation in premixed gases. It is based on the random element method we developed for the analysis of diffusional processes. The effect of combustion is taken into account by applying the principle of fractional steps to separate the process of diffusion, modeled by the random walk of computational elements, from the exothermic effects of chemical reaction, monitoring their strength. The validity of the algorithm is demonstrated by application to flame propagation problems for which exact solutions exist. The flame speed evaluated by its use oscillates around the exact value at a relatively small amplitude, while the temperature and species concentration profiles are self-correcting in their convergence to the exact solution. A satisfactory resolution is obtained by the use of quite a small number of computational elements which automatically adjust their distribution of fit sharp gradients.

Ghoniem, A. F.↗
NASA NTRS2002

Great (Flame) Balls of Fire! Structure of Flame Balls at Low Lewis-number-2 (SOFBALL-2)

Everyone knows that an automobile engine wastes fuel and energy when it runs with a fuel-rich mixture. 'Lean' burning, mixing in more air and less fuel, is better for the environment. But lean mixtures also lead to engine misfiring and rough operation. No one knows the ultimate limits for lean operation, for 'weak' combustion that is friendly to the environment while still moving us around. This is where the accidental verification of a decades-old prediction may have strong implications for designing and running low-emissions engines in the 21st century. In 1944, Soviet physicist Yakov Zeldovich predicted that stationary, spherical flames are possible under limited conditions in lean fuel-air mixtures. Dr. Paul Ronney of the University of Southern California accidentally discovered such 'flame balls' in experiments with lean hydrogen-air mixtures in 1984 during drop-tower experiments that provided just 2.2 seconds of near weightlessness. Experiments aboard NASA's low-g aircraft confirmed the results, but a thorough investigation was hampered by the aircraft's bumpy ride. And stable flame balls can only exist in microgravity. The potential for investigating combustion at the limits of flammability, and the implications for spacecraft fire safety, led to the Structure of Flame Balls at Low Lewis-number (SOFBALL) experiment flown twice aboard the Space Shuttle on the Microgravity Sciences Laboratory-1 (MSL-1) in 1997. Success there led to the planned reflight on STS-107. Flame balls are the weakest fires yet produced in space or on Earth. Typically each flame ball produced only 1 watt of thermal power. By comparison, a birthday candle produces 50 watts. The Lewis-number measures the rate of diffusion of fuel into the flame ball relative to the rate of diffusion of heat away from the flame ball. Lewis-number mixtures conduct heat poorly. Hydrogen and methane are the only fuels that provide low enough Lewis-numbers to produce stable flame balls, and even then only for very weak, barely flammable mixtures. Nevertheless, under these conditions flame balls give scientists the opportunity to test models in one of the simplest combustion experiments possible. SOFBALL-2 science objectives include: Improving our understanding of the flame ball phenomenon; Determining the conditions under which flame balls exist; Testing predictions of flame ball lifetimes; Acquiring more precise data for critical model comparison.

Ronney, Paul↗
NASA NTRS1953

Effect of Diffuser Design, Diffuser-exit Velocity Profile and Fuel Distribution on Altitude Performance of Several Afterburner Configurations

An investigation was conducted in the NACA Lewis altitude wind tunnel to improve the altitude performance and operational characteristics of an afterburner primarily by modifying the diffuser-exit velocity profile by changes in diffuser design and by changing the fuel distribution and the flame holder. Twenty configurations, consisting of combinations of six diffuser geometries, six flame-holder types, and twelve fuel systems, were investigated. Data were obtained over a range of afterburner fuel-air ratios at diffuser-inlet total pressures from 2750 to 620 pounds per square foot. Changes in fuel distribution affected the fuel-air ratio at which peak combustion efficiency occurred as well as the efficiency level. Screeching combustion, which was most prevalent at low altitudes and medium-to-high fuel-air ratios, imposed a restriction on the operable range of a number of configurations.

Diffusers, Subsonic↗
NASA NTRS1999

Gravitational Influences on Flame Propagation Through Non-Uniform Premixed Gas Systems

Flame propagation through non-uniformly premixed gases occurs in several common combustion situations. As summarized in a previous conference paper, non-uniform premixed gas combustion has received scant attention compared to the more usual limiting cases of diffusion or uniformly premixed flames. It is the goal of this research to further our knowledge of layered combustion, in which a fuel concentration gradient exists normal to the direction of flame spread, in particular by focusing on the role that gravity plays. Gravity can affect flame propagation in at least three ways: through a hydrostatic pressure gradient, by altering the initial distribution of fuel vapor, and through buoyantly induced flows once ignition has occurred. An understanding of the phenomena involved is important to fire safety, especially aboard spacecraft since no microgravity data exist. The data obtained will also be useful to verify theoretical models of this problem, which are easier to implement if buoyancy is neglected.

Miller, Fletcher J.↗
NASA NTRS2001

Gravitational Influences on Flame Propagation through Non-Uniform, Premixed Gas Systems

Flame propagation through non-uniformly premixed (or layered) gases has importance both in useful combustion systems and in unintentional fires. As summarized previously, non-uniform premixed gas combustion receives scant attention compared to the more usual limiting cases of diffusion or uniformly premixed flames, especially regarding the role gravity plays. This paper summarizes our progress on furthering the knowledge of layered combustion, in which a fuel concentration gradient exists normal to the direction of flame spread. We present experimental and numerical results for flame spread through propanol-air layers formed near the flash point temperature (25 C) or near the stoichiometric temperature (33 C). Both the model and experimental results show that the removal of gravity results in a faster spreading flame, by as much as 80% depending on conditions. This is exactly the opposite effect as that predicted by an earlier model reported. We also found that having a gallery lid results in faster flame spread, an effect more pronounced at normal gravity, demonstrating the importance of enclosure geometry. Also reported here is the beginning of our spectroscopic measurements of fuel vapor.

Miller, Fletcher J.↗
NASA NTRS2003

Gravitational Influences on Flame Propagation Through Non-Uniform, Premixed Gas Systems

Flame propagation through non-uniformly premixed (or layered) gases has importance both in useful combustion systems and in unintentional fires. As summarized recently and in previous Microgravity Workshop papers, non-uniform premixed gas combustion receives scant attention compared to the more usual limiting cases of diffusion or uniformly premixed flames, especially regarding the role gravity plays. This paper summarizes our recent findings on gravitational effects on layered combustion along a floor, in which the fuel concentration gradient exists normal to the direction of flame spread. In an effort to understand the mechanism by which the flames spread faster in microgravity (and much faster, in laboratory coordinates, than the laminar burning velocity for uniform mixtures), we have begun making pressure measurements across the spreading flame front that are described here. Earlier researchers, testing in 1g, claimed that hydrostatic pressure differences could account for the rapid spread rates. Additionally, we present the development of a new apparatus to study flame spread in free (i.e., far from walls), non-homogeneous fuel layers formed in a flow tunnel behind an airfoil that has been tested in normal gravity.

Miller, Fletcher J.↗
NASA NTRS1991

Combustion of unsupported methanol/dodecanol mixture droplets at low gravity

Experiments are reported on the combustion of free or unsupported methanol/dodecanol mixture droplets in a reduced gravity environment. The experiments were conducted in a drop tower. The Grashof number (based on drop diameter) in the moving frame of reference was on the order of 10 exp -5 for the period of droplet burning. Combustion of the mixture droplets was characterized by a multi-stage process indicative of diffusion controlled burning. The flame was not visible during the first stage because of the lighting used, but was visible (and spherical) in the final stage. The results suggested that the mixture droplets did not extinguish. By contrast, methanol droplets consistently extinguished. Microexplosions were not observed for mixtures with initial concentrations of equal volumes of methanol and dodecanol. However, most of the droplets containing initially 75 percent (by volume) of methanol exploded. The initiation of microexplosion, as defined by the occurrence of homogeneous nucleation within the droplet, is explained by comparing the calculated nonlinear variation of superheat limit with composition for a methanol/dodecanol mixture with the boiling point of dodecanol.

Yang, J. C.↗
NASA NTRS1999

Diffusive and Radiative Transport in Fires (DARTFire): Opposed-Flow Flame Spread in Low-Velocity Flows

For flames spreading into a low-velocity flow that can only be obtained in microgravity, we have observed behavior that is different from that which is obtained at higher velocities where radiative effects are unimportant and species transport is relatively fast. Unfortunately, lack of a large body of low-gravity flame spread experimental data inhibits progress in developing an understanding of the physics of low-velocity, opposed-flow flame spread phenomena. Recent DARTFire sounding rocket experimental studies though, coupled with developing theory and modelling, have allowed some strides in understanding to be made, on which we report here. Four launches to date have resulted in six experiments for opposed-flow flame spread over a thick PMMA sample. During the 6 min microgravity period, the PMMA samples were ignited, and steady flame spread was studied under varied flow velocity, oxidizer atmospheric conditions, and, because radiative heat transfer is so important in these slowly spreading flames, external radiant flux. These were the first attempts at such experimental control and measurement in microgravity. A recent reflight of the Solid Surface Combustion Experiment (SSCE) has demonstrated, as modelling predicts, that for the thick fuel of the DARTFire experiment, flame spread in a quiescent environment is a transient process evolving from ignition to extinction on the order of 600 s (Altenkirch et al., 1999). Further study then of the effects of radiation in the very low-velocity opposing flows is of interest in understanding the transition from steady, sustained spread to the unsteady evolution to extinction as the opposing flow is reduced further and eventually removed.

Altenkirch, R. A.↗
NASA NTRS2001

The Cool Flames Experiment

A space-based experiment is currently under development to study diffusion-controlled, gas-phase, low temperature oxidation reactions, cool flames and auto-ignition in an unstirred, static reactor. At Earth's gravity (1g), natural convection due to self-heating during the course of slow reaction dominates diffusive transport and produces spatio-temporal variations in the thermal and thus species concentration profiles via the Arrhenius temperature dependence of the reaction rates. Natural convection is important in all terrestrial cool flame and auto-ignition studies, except for select low pressure, highly dilute (small temperature excess) studies in small vessels (i.e., small Rayleigh number). On Earth, natural convection occurs when the Rayleigh number (Ra) exceeds a critical value of approximately 600. Typical values of the Ra, associated with cool flames and auto-ignitions, range from 104-105 (or larger), a regime where both natural convection and conduction heat transport are important. When natural convection occurs, it alters the temperature, hydrodynamic, and species concentration fields, thus generating a multi-dimensional field that is extremely difficult, if not impossible, to be modeled analytically. This point has been emphasized recently by Kagan and co-workers who have shown that explosion limits can shift depending on the characteristic length scale associated with the natural convection. Moreover, natural convection in unstirred reactors is never "sufficiently strong to generate a spatially uniform temperature distribution throughout the reacting gas." Thus, an unstirred, nonisothermal reaction on Earth does not reduce to that generated in a mechanically, well-stirred system. Interestingly, however, thermal ignition theories and thermokinetic models neglect natural convection and assume a heat transfer correlation of the form: q=h(S/V)(T(bar) - Tw) where q is the heat loss per unit volume, h is the heat transfer coefficient, S/V is the surface to volume ratio, and (T(bar) - Tw ) is the spatially averaged temperature excess. This Newtonian form has been validated in spatially-uniform, well-stirred reactors, provided the effective heat transfer coefficient associated with the unsteady process is properly evaluated. Unfortunately, it is not a valid assumption for spatially-nonuniform temperature distributions induced by natural convection in unstirred reactors. "This is why the analysis of such a system is so difficult." Historically, the complexities associated with natural convection were perhaps recognized as early as 1938 when thermal ignition theory was first developed. In the 1955 text "Diffusion and Heat Exchange in Chemical Kinetics", Frank-Kamenetskii recognized that "the purely conductive theory can be applied at sufficiently low pressure and small dimensions of the vessel when the influence of natural convection can be disregarded." This was reiterated by Tyler in 1966 and further emphasized by Barnard and Harwood in 1974. Specifically, they state: "It is generally assumed that heat losses are purely conductive. While this may be valid for certain low pressure slow combustion regimes, it is unlikely to be true for the cool flame and ignition regimes." While this statement is true for terrestrial experiments, the purely conductive heat transport assumption is valid at microgravity (mu-g). Specifically, buoyant complexities are suppressed at mu-g and the reaction-diffusion structure associated with low temperature oxidation reactions, cool flames and auto-ignitions can be studied. Without natural convection, the system is simpler, does not require determination of the effective heat transfer coefficient, and is a testbed for analytic and numerical models that assume pure diffusive transport. In addition, mu-g experiments will provide baseline data that will improve our understanding of the effects of natural convection on Earth.

Pearlman, Howard↗
NASA NTRS2001

Outwardly Propagating Flames at Elevated Pressures

Spherical, outwardly-propagating flames of CH4-O2-inert and H2-O2-inert mixtures were experimentally studied in a high pressure apparatus. Stretch-free flame speeds and Markstein lengths were extracted for a wide range of pressures and equivalence ratios for spherically-symmetric, smooth flamefronts and compared to numerical computations with detailed chemistry and transport, as well as existing data in the literature. Wrinkle development was examined for propagating flames that were unstable under our experimental conditions. Hydrodynamic cells developed for most H2-air and CH4-air flames at elevated pressures, while thermal-diffusive instabilities were also observed for lean and near-stoichiometric hydrogen flames at pressures above atmospheric. Strategies in suppressing or delaying the onset of cell formation have been assessed. Buoyancy effects affected sufficiently off-stoichiometric CH4 mixtures at high pressures.

Law, C. K.↗
NASA NTRS1995

Dynamics and structure of turbulent premixed flames

In earlier work (Mantel & Bilger, 1994) the structure of the turbulent premixed flame was investigated using statistics based on conditional averaging with the reaction progress variable as the conditioning variable. The DNS data base of Trouve and Poinsot (1994) was used in this investigation. Attention was focused on the conditional dissipation and conditional axial velocity in the flame with a view to modeling these quantities for use in the conditional moment closure (CMC) approach to analysis of kinetics in premixed flames (Bilger, 1993). Two remarkable findings were made: there was almost no acceleration of the axial velocity in the flame front itself; and the conditional scalar dissipation remained as high, or higher, than that found in laminar premixed flames. The first finding was surprising since in laminar flames all the fluid acceleration occurs through the flame front, and this could be expected also for turbulent premixed flames at the flamelet limit. The finding gave hope of inventing a new approach to the dynamics of turbulent premixed flames through use of rapid distortion theory or an unsteady Bernoulli equation. This could lead to a new second order closure for turbulent premixed flames. The second finding was contrary to our measurements with laser diagnostics in lean hydrocarbon flames where it is found that conditional scalar dissipation drops dramatically below that for laminar flamelets when the turbulence intensity becomes high. Such behavior was not explainable with a one-step kinetic model, even at non-unity Lewis number. It could be due to depletion of H2 from the reaction zone by preferential diffusion. The capacity of the flame to generate radicals is critically dependent on the levels of H2 present (Bilger, et al., 1991). It seemed that a DNS computation with a multistep reduced mechanism would be worthwhile if a way could be found to make this feasible. Truly innovative approaches to complex problems often come only when there is the opportunity to work close at hand with the (in this case numerical) experimental data. Not only can one spot patterns and relationships in the data which could be important, but one can also get to know the limitations of the technique being used, so that when the next experiment is being designed it will address resolvable questions. A three-year grant from the Australian Research Council has enabled us to develop a small capability at the University of Sydney to work on DNS of turbulent reacting flow, and to analyze data bases generated at CTR. Collaboration between the University of Sydney and CTR is essential to this project and finding a workable modus operandum for this collaboration, given the constraints involved, has been a major objective of the past year's effort. The overall objectives of the project are: (1) to obtain a quantitative understanding of the dynamics of turbulent premixed flames at high turbulence levels with a view to developing improved second order closure models; and (2) to carry out new DNS experiments on turbulent premixed flames using a carefully chosen multistep reduced mechanism for the chemical kinetics, with a view to elucidating the laser diagnostic findings that are contrary to the findings for DNS using one-step kinetics. In this first year the objectives have been to make the existing CTR data base more accessible to coworkers at the University of Sydney, to make progress on understanding the dynamics of the flame in this existing CTR data base, and to carefully construct a suitable multistep reduced mechanism for use in a new set of DNS experiments on turbulent premixed flames.

Bilger, R. W.↗
NASA NTRS1991

Effect of gravity on the stability and structure of lean hydrogen-air flames

Detailed, time-dependent, 2D numerical simulations with full hydrogen-oxygen chemistry are used to investigate the effects of gravity on the stability and structure of laminar flames in lean, premixed hydrogen-air mixtures. The calculations show that the effects of gravity becomes more important as the lean flammability limit is approached. In a 12 percent hydrogen-air mixture, gravity plays only a secondary role in determining the multidimensional structure of the flame with the stability and structure of the flame controlled primarily by the thermo-diffusive instability mechanism. However, in leaner hydrogen-air mixtures gravity becomes more important. Upward-propagating flames are highly curved and evolve into a bubble rising upwards in the tube. Downward-propagating flames are flat or even oscillate between structures with concave and convex curvatures. The zero-gravity flame shows only cellular structures. Cellular structures which are present in zero gravity can be suppressed by the effect of buoyancy for mixtures leaner than 11 percent hydrogen. These observations are explained on the basis of an interaction between the processes leading to buoyancy-induced Rayleigh-Taylor instability and the thermo-diffusive instability.

Patnaik, G.↗
NASA NTRS1985

On the determination of laminar flame speeds from stretched flames

The effects of stretch on the determination of the laminar flame speed are experimentally studied by using the positively-stretched stagnation flame and negatively-stretched bunsen flame, and by using lean and rich mixtures of methane, propane, butane, and hydrogen with air whose effective Lewis numbers are either greater or less than unity. Results demonstrate that flame speed determination can be influenced by stretch through two factors: (1) Preferential diffusion which tends to increase or decrease the flame temperature and burning rate depending on the effective Lewis number, and (2) Flow divergence which causes the flame speed to assume higher values when evaluated at the upstream boundary of the preheat zone instead of the reaction zone. Recent data on flame speed including the present ones are then examined from the unified viewpoint of flame stretch, leading to satisfactory resolution of the discrepancies between them. The present study also proposes a methodology of determining the laminar flame speeds by using the stagnation flame and linearly extrapolating the data to zero stretch rate.

Wu, C. K.↗
NASA NTRS1984

Combustion characteristics in the transition region of liquid fuel sprays

A number of important effects were observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NO(x) formation. Unfortunately, because of differences in experimental facilities and limitations in the ranges of experimental data, a unified description of these transition region effects is not available at this time. Consequently, a fundamental experimental investigation was initiated to study the effect of droplet size, size distribution, and operating parameters on these transition region phenomena in a single well controlled spray combustion facility.

Cernansky, N. P.↗
NASA NTRS1986

Combustion characteristics in the transition region of liquid fuel sprays

A number of important effects have been observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NOx formation. A monodisperse aerosol generator has been used to form and deliver a well controlled liquid fuel spray to the combustion test section where measurements of ignition energy have been made. The ignition studies were performed on monodisperse n-heptane sprays at atmospheric pressure over a range of equivalence ratios and droplet diameters. A capacitive discharge spark ignition system was used as the ignition source, providing independent control of spark energy and duration. Preliminary measurements were made to optimize spark duration and spark gap, optimum conditions being those at which the maximum frequency or probability of ignition was observed. Using the optimum electrode spacing and spark duration, the frequency of ignition was determined as a function of spark energy for three overall equivalence ratios (0.6, 0.8, and 1.0) and for initial droplet diameters of 25, 40, 50, 60, and 70 micro m.

Cernansky, N. P.↗
NASA NTRS1990

Near-limit flame structures at low Lewis number

The characteristics of premixed gas flames in mixtures with low Lewis numbers near flammability limits were studied experimentally using a low-gravity environment to reduce buoyant convection. The behavior of such flames was found to be dominated by diffusive-thermal instabilities. For sufficiently reactive mixtures, cellular structures resulting from these instabilities were observed and found to spawn new cells in regular patterns. For less reactive mixtures, cells formed shortly after ignition but did not spawn new cells; instead these cells evolved into a flame structure composed of stationary, apparently stable spherical flamelets. Experimental observations are found to be in qualitative agreement with elementary analytical models based on the interaction of heat release due to chemical reaction, differential diffusion of thermal energy and mass, flame front curvature, and volumetric heat losses due to gas and/or soot radiation.

Ronney, Paul D.↗
NASA NTRS2003

Cool Flames in Propane-Oxygen Premixtures at Low and Intermediate Temperatures at Reduced-Gravity

The Cool Flame Experiment aims to address the role of diffusive transport on the structure and the stability of gas-phase, non-isothermal, hydrocarbon oxidation reactions, cool flames and auto-ignition fronts in an unstirred, static reactor. These reactions cannot be studied on Earth where natural convection due to self-heating during the course of slow reaction dominates diffusive transport and produces spatio-temporal variations in the thermal and thus species concentration profiles. On Earth, reactions with associated Rayleigh numbers (Ra) less than the critical Ra for onset of convection (Ra(sub cr) approx. 600) cannot be achieved in laboratory-scale vessels for conditions representative of nearly all low-temperature reactions. In fact, the Ra at 1g ranges from 10(exp 4) - 10(exp 5) (or larger), while at reduced-gravity, these values can be reduced two to six orders of magnitude (below Ra(sub cr)), depending on the reduced-gravity test facility. Currently, laboratory (1g) and NASA s KC-135 reduced-gravity (g) aircraft studies are being conducted in parallel with the development of a detailed chemical kinetic model that includes thermal and species diffusion. Select experiments have also been conducted at partial gravity (Martian, 0.3gearth) aboard the KC-135 aircraft. This paper discusses these preliminary results for propane-oxygen premixtures in the low to intermediate temperature range (310- 350 C) at reduced-gravity.

Pearlman, Howard↗