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At least 577 records · Page 32

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DOE OSTI2017

ENERGETIC PARTICLE TRANSPORT ACROSS THE MEAN MAGNETIC FIELD: BEFORE DIFFUSION

Current particle transport models describe the propagation of charged particles across the mean field direction in turbulent plasmas as diffusion. However, recent studies suggest that at short timescales, such as soon after solar energetic particle (SEP) injection, particles remain on turbulently meandering field lines, which results in nondiffusive initial propagation across the mean magnetic field. In this work, we use a new technique to investigate how the particles are displaced from their original field lines, and we quantify the parameters of the transition from field-aligned particle propagation along meandering field lines to particle diffusion across the mean magnetic field. We show that the initial decoupling of the particles from the field lines is slow, and particles remain within a Larmor radius from their initial meandering field lines for tens to hundreds of Larmor periods, for 0.1–10 MeV protons in turbulence conditions typical of the solar wind at 1 au. Subsequently, particles decouple from their initial field lines and after hundreds to thousands of Larmor periods reach time-asymptotic diffusive behavior consistent with particle diffusion across the mean field caused by the meandering of the field lines. We show that the typical duration of the prediffusive phase, hours to tens of hours for 10 MeV protons in 1 au solar wind turbulence conditions, is significant for SEP propagation to 1 au and must be taken into account when modeling SEP propagation in the interplanetary space.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2017

Skill of ship‐following large‐eddy simulations in reproducing MAGIC observations across the northeast P acific stratocumulus to cumulus transition region

Abstract During the Marine ARM GPCI Investigation of Clouds (MAGIC) in October 2011 to September 2012, a container ship making periodic cruises between Los Angeles, CA, and Honolulu, HI, was instrumented with surface meteorological, aerosol and radiation instruments, a cloud radar and ceilometer, and radiosondes. Here large‐eddy simulation (LES) is performed in a ship‐following frame of reference for 13 four day transects from the MAGIC field campaign. The goal is to assess if LES can skillfully simulate the broad range of observed cloud characteristics and boundary layer structure across the subtropical stratocumulus to cumulus transition region sampled during different seasons and meteorological conditions. Results from Leg 15A, which sampled a particularly well‐defined stratocumulus to cumulus transition, demonstrate the approach. The LES reproduces the observed timing of decoupling and transition from stratocumulus to cumulus and matches the observed evolution of boundary layer structure, cloud fraction, liquid water path, and precipitation statistics remarkably well. Considering the simulations of all 13 cruises, the LES skillfully simulates the mean diurnal variation of key measured quantities, including liquid water path (LWP), cloud fraction, measures of decoupling, and cloud radar‐derived precipitation. The daily mean quantities are well represented, and daily mean LWP and cloud fraction show the expected correlation with estimated inversion strength. There is a −0.6 K low bias in LES near‐surface air temperature that results in a high bias of 5.6 W m −2 in sensible heat flux (SHF). Overall, these results build confidence in the ability of LES to represent the northeast Pacific stratocumulus to trade cumulus transition region.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2016

Strain Control of Oxygen Vacancies in Epitaxial Strontium Cobaltite Films

The ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the deliberate control of important defects, oxygen vacancies. Here, strontium cobaltite (SrCoOx) is used to demonstrate that epitaxial strain is a powerful tool for manipulating the oxygen vacancy concentration even under highly oxidizing environments and at annealing temperatures as low as 300 degrees C. By applying a small biaxial tensile strain (2%), the oxygen activation energy barrier decreases by approximate to 30%, resulting in a tunable oxygen defi cient steady-state under conditions that would normally fully oxidize unstrained cobaltite. These strain-induced changes in oxygen stoichiometry drive the cobaltite from a ferromagnetic metal towards an antiferromagnetic insulator. The ability to decouple the oxygen vacancy concentration from its typical dependence on the operational environment is useful for effectively designing oxides materials with a specific oxygen stoichiometry.

Petrie, Jonathan R.↗

DOE OSTI2024

Zero-Strain Metal-Insulator Transition by the Local Fluctuation of Cation Dimerization

The coupled electronic and structural transitions in metal-insulator transition (MIT) hinder ultrafast switching and ultimate endurance. Decoupling these transitions and achieving a zero-strain electronic MIT can overcome the fundamental limitations of MIT in solid materials. Here, this study demonstrates that iso-valent Ti dopants in supercooled VO 2 epitaxial films cause MIT with minimal hysteresis without changing unit-cell volume and crystal symmetry. The Ti dopants in the VO 2 lattice locally alter the configuration of V-V pairs, where the long-range ordering in V-V pairs is disrupted, and the nano-domains of V-V dimers are formed. Strikingly, these local V-V dimers persist even above the electronic transition temperature (T MI ), facilitating the zero-strain electronic MIT with nanoscale structural heterogeneity. The geometrically compatible interface between insulating and metallic phases drastically enhances switching speed and endurance during electrically and optically driven zero-strain MIT. In conclusion, this discovery offers a fresh perspective on the scientific understanding of MIT and the improved functionality in terms of device speed and reliability by decoupling electronic and structural transitions.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Crossing the Oxo‐Peroxo Wall for Selective Electrochemical Epoxidation

Electrochemical oxidation in water requires the formation of reactive oxygen species to be able to oxidize unsaturated hydrocarbons to epoxides, aldehydes, and ketones. These reactions, broadly classified as alternative oxidation reactions (AOR), directly compete with the prevalent oxygen evolution reaction (OER). In molecular catalysis, the Oxo-Wall dictates a transition from a stable oxo intermediate (OER active) to a meta-stable metal-oxo (OER inactive) generally occurs. In this work on heterogeneous catalysis, the same Oxo-Wall applies, however, a meta-stable oxo preferentially coordinates with lattice oxygen to form a more stable surface peroxo intermediate. A universal free energy onset of this process is identified at 3.39 eV under electrochemical activation in water and show that it is completely decoupled from the OER oxo species. Such decoupling gives rise to a new region of oxygen reactivity relevant for AOR where a selective oxidation of the unsaturated C-C bonds is predicted to occur instead of OER. A distinct AOR overpotential volcano is constructed and identify recently reported electrocatalysts, including palladium-platinum for propylene epoxidation and silver-nickel for ethylene epoxidation, along with others such as TiO 2 and CuO. Broader implications and limitations of electrochemical AOR are discussed, highlighting their potential to enable electrochemically enhanced thermal catalysis.

Electrocatalysis↗

DOE OSTI2019

Dopant-Dependent Increase in Seebeck Coefficient and Electrical Conductivity in Blended Polymers with Offset Carrier Energies

The strong and counterproductive interrelationship of thermoelectric parameters remains a bottleneck to improving thermoelectric performance, especially in polymer-based materials. In this paper, we decouple the electrical conductivity and Seebeck coefficient, achieving increases in at least one of these two parameters while the other is maintained or slightly increased as well. This is done using an alkylthio-substituted polythiophene (PQTS12) as additive in poly(bisdodecylquaterthiophene) (PQT12) with tetrafluorotetracyanoquinodimethane (F4TCNQ) and nitrosyl tetrafluoroborate (NOBF4) as dopants. The power factor increased two orders of magnitude with the PQTS12 additive at constant doping level. Using a second pair of polymers, poly(2,5-bis(3-dodecylthiophen-2-yl)thieno[3,2-b]thiophene (PBTTTC12) and poly(2,5-bis(3-dodecylthiothiophen-2-yl)thieno[3,2-b]thiophene, (PBTTTSC12), with higher mobilities, we also observed the decoupling of the Seebeck coefficient and electrical conductivity, and achieved higher power factor. Distinguished from recently reported works, these two sets of polymers possess very closely offset carrier energy levels (0.05 ~ 0.07 eV), and the microstructure, assessed using grazing incidence X-ray scattering, and mobility evaluated in field-effect transistors, was not adversely affected by the blending. Experiments, calculations and simulations are consistent with the idea that blending and doping polymers with closely-spaced energy levels and compatible morphologies to promote carrier mobility favors increased power factors.

42 ENGINEERING↗

DOE OSTI2018

Transport properties of disordered two‐dimensional complex plasma crystal

In this study, we numerically investigate the transport properties of a two‐dimensional ( 2D ) complex plasma crystal using diffusion of coplanar dust lattice waves. In the limit where the Hamiltonian interactions can be decoupled from the non‐Hamiltonian effects, we identify two distinct types of wave transport: Anderson‐type delocalization and long‐distance excitation. We use a recently developed spectral approach to evaluate the contribution of the Anderson problem and compare it to the results of the simulation. The benefit of our approach to transport problems is twofold. First, we employ a highly tuneable macroscopic hexagonal crystal, which exhibits many‐body interactions and allows for the investigation of transport properties at the kinetic level. Second, the analysis of the transport problem in 2D is provided using an innovative spectral approach, which avoids the use of scaling and boundary conditions. The comparison between the analytically predicted and numerically observed wave dynamics allows for the study of important characteristics of this open system. In our simulations, we observe long‐distance lattice excitation, which occurs around lattice defects even when the initial perturbation does not spread from the centre to the exterior of the crystal. In the decoupled Hamiltonian regime, this many‐body effect can be attributed to the dust lattice interaction with the plasma environment.

Kostadinova, E. G.↗

DOE OSTI2016

Estimating heterotrophic respiration at large scales: challenges, approaches, and next steps

Heterotrophic respiration (HR), the aerobic and anaerobic processes mineralizing organic matter, is a key carbon flux but one impossible to measure at scales significantly larger than small experimental plots. This impedes our ability to understand carbon and nutrient cycles, benchmark models, or reliably upscale point measurements. Given that a new generation of highly mechanistic, genomic-specific global models is not imminent, we suggest that a useful step to improve this situation would be the development of "Decomposition Functional Types" (DFTs). Analogous to plant functional types (PFTs), DFTs would abstract and capture important differences in HR metabolism and flux dynamics, allowing models to efficiently group and vary these characteristics across space and time. We argue that DFTs should be initially informed by top-down expert opinion, but ultimately developed using bottom-up, data-driven analyses, and provide specific examples of potential dependent and independent variables that could be used. We present and discuss an example clustering analysis to show how model-produced annual HR can be broken into distinct groups associated with global variability in biotic and abiotic factors, and demonstrate that these groups are distinct from already-existing PFTs. A similar analysis, incorporating observational data, could form a basis for future DFTs. Finally, we suggest next steps and critical priorities: collection and synthesis of existing data; more in-depth analyses combining open data with high-performance computing; rigorous testing of analytical results; and planning by the global modeling community for decoupling decomposition from fixed site data. These are all critical steps to build a foundation for DFTs in global models, thus providing the ecological and climate change communities with robust, scalable estimates of HR at large scales.

carbon cycle↗

DOE OSTI2016

Thermofield duality for higher spin Rindler Gravity

In this paper, we study the Thermo-field realization of the duality between the Rindler-AdS higher spin theory and O(N) vector theory. The CFT represents a decoupled pair of free O(N) vector field theories. It is shown how this decoupled domain CFT is capable of generating the connected Rindler-AdS background with the full set of Higher Spin fields.

1/N Expansion↗

DOE OSTI2016

CP violation in heavy MSSM Higgs scenarios

We introduce and explore new heavy Higgs scenarios in the Minimal Supersymmetric Standard Model (MSSM) with explicit CP violation, which have important phenomenological implications that may be testable at the LHC. For soft supersymmetry-breaking scales M S above a few TeV and a charged Higgs boson mass M H + above a few hundred GeV, new physics effects including those from explicit CP violation decouple from the light Higgs boson sector. However, such effects can significantly alter the phenomenology of the heavy Higgs bosons while still being consistent with constraints from low-energy observables, for instance electric dipole moments. To consider scenarios with a charged Higgs boson much heavier than the Standard Model (SM) particles but much lighter than the supersymmetric particles, we revisit previous calculations of the MSSM Higgs sector. We compute the Higgs boson masses in the presence of CP violating phases, implementing improved matching and renormalization-group (RG) effects, as well as two-loop RG effects from the effective two-Higgs Doublet Model (2HDM) scale M H ± to the scale M S . Here, we illustrate the possibility of non-decoupling CP-violating effects in the heavy Higgs sector using new benchmark scenarios named.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2023

Large U(1) charges from flux breaking in 4D F-theory models

We study the massless charged spectrum of U(1) gauge fields in F-theory that arise from flux breaking of a nonabelian group. The U(1) charges that arise in this way can be very large. In particular, using vertical flux breaking, we construct an explicit 4D F-theory model with a U(1) decoupled from other gauge sectors, in which the massless/light fields have charges as large as 657. This result greatly exceeds prior results in the literature. We argue heuristically that this result may provide an upper bound on charges for light fields under decoupled U(1) factors in the F-theory landscape. We also show that the charges can be even larger when the U(1) is coupled to other gauge groups.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2019

Cosmology with a very light Lμ - Lτ gauge boson

In this study, we explore in detail the cosmological implications of an abelian $L_\mu-L_\tau$ gauge extension of the Standard Model featuring a light and weakly coupled $Z'$. Such a scenario is motivated by the longstanding $\sim \, 4 \sigma$ discrepancy between the measured and predicted values of the muon's anomalous magnetic moment, $(g-2)_\mu$, as well as the tension between late and early time determinations of the Hubble constant. If sufficiently light, the $Z'$ population will decay to neutrinos, increasing the overall energy density of radiation and altering the expansion history of the early universe. We identify two distinct regions of parameter space in this model in which the Hubble tension can be significantly relaxed. The first of these is the previously identified region in which a $\sim \, 10-20$ MeV $Z'$ reaches equilibrium in the early universe and then decays, heating the neutrino population and delaying the process of neutrino decoupling. For a coupling of $g_{\mu-\tau} \simeq (3-8) \times 10^{-4}$, such a particle can also explain the observed $(g-2)_{\mu}$ anomaly. In the second region, the $Z'$ is very light ($m_{Z'} \sim 1\,\text{eV}$ to $\text{MeV}$) and very weakly coupled ($g_{\mu-\tau} \sim 10^{-13}$ to $10^{-9}$). In this case, the $Z'$ population is produced through freeze-in, and decays to neutrinos after neutrino decoupling. Across large regions of parameter space, we predict a contribution to the energy density of radiation that can appreciably relax the reported Hubble tension, $\Delta N_{\rm eff} \simeq 0.2$.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2016

Light stop mass limits from Higgs rate measurements in the MSSM: Is MSSM electroweak baryogenesis still alive after all?

We investigate the implications of the Higgs rate measurements from Run 1 of the LHC for the mass of the light scalar top partner (stop) in the Minimal Supersymmetric Standard Model (MSSM). We focus on light stop masses, and we decouple the second, heavy stop and the gluino to the multi-TeV range in order to obtain a Higgs mass of ~125 GeV. We derive lower mass limits for the light stop within various scenarios, taking into account the effects of a possibly light scalar tau partner (stau) or chargino on the Higgs rates, of additional Higgs decays to undetectable “new physics”, as well as of non-decoupling of the heavy Higgs sector. Under conservative assumptions, the stop can be as light as 123 GeV. Relaxing certain theoretical and experimental constraints, such as vacuum stability and model-dependent bounds on sparticle masses from LEP, we find that the light stop mass can be as light as 116 GeV. Lastly, our indirect limits are complementary to direct limits on the light stop mass from collider searches and have important implications for electroweak baryogenesis in the MSSM as a possible explanation for the observed matter-antimatter asymmetry of the Universe.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2024

Celestial gluon amplitudes from the outside in

We show that, given a two-dimensional realization of the celestial OPE in self-dual Yang-Mills, we can find a scalar source around which scattering amplitudes replicate correlation functions computed from the 2D ‘gluon’ operators in a limit where a dynamic massless scalar decouples. We derive conditions on the two-dimensional three-point correlation function so that such a source exists and give two particular examples of this construction, one in which gluons are constructed from vertex operators in the semiclassical limit of Liouville theory and another in which the soft gluons arise from generalized free fields. Finally, we identify a bulk dual to the level of the boundary Kac-Moody algebra and discuss moving beyond the decoupling limit.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2019

Shift-symmetric spin-1 theories

We study interacting massive spin-1 theories in de Sitter (dS) and anti-de Sitter (AdS) space that possess shift symmetries parametrized by (A)dS Killing vectors. We show how they emerge from the massless limit of massive spin-2 theories on (A)dS space. In the case of massive gravity, the corresponding spin-1 theory realizes a symmetry breaking pattern that takes two copies of the (A)dS isometry group down to a diagonal subgroup. By taking the flat space limit of this theory, we find a new symmetry of the decoupling limit of massive gravity in flat space. This symmetry acts on the vector modes, is parametrize by an antisymmetric tensor, and fixes the nonlinear structure of the scalar-vector sector of the decoupling limit.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2021

Factorized class $\mathrm{S}$ theories and surface defects

It is known that some theories of class S are actually factorized into multiple decoupled nontrivial four-dimensional $\mathcal{N}$ = 2 It is known that some theories of class S are actually factorized into multiple decoupled nontrivial four-dimensional $\mathcal{N}$ = 2 superconformal SU(2) QCD, describing this factorized theory as a class S theory of type A 3 on a five-punctured sphere with a twist line. Separately, we also present explicit checks that the Coulomb branch of a putative factorized class S theory has the expected product structure, in two examples.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2019

Renormalization and BRST Symmetry in Donaldson–Witten Theory

The presence of a BRST symmetry in topologically twisted gauge theories makes a precise analysis of these theories feasible. While the global BRST symmetry suggests that correlation functions of BRST exact observables vanish, this decoupling might be obstructed due to a contribution from the boundary of field space. Motivated by divergent BRST exact observables on the Coulomb branch of Donaldson–Witten theory, we put forward a new prescription for the renormalization of correlation functions on the Coulomb branch. This renormalization is based on the relation between Coulomb branch integrals and integrals over a modular fundamental domain and establishes that BRST exact observables indeed decouple in Donaldson–Witten theory.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2018

Air turbulence characteristics at multiple sites in and above the Amazon rainforest canopy

Atmospheric turbulence characteristics within and above rain forest canopies are investigated at several sites located in the Amazon region of Brazil. Turbulence data provided by bi- and three-dimensional sonic anemometers, which were deployed at heights ranging from near the forest floor to about 80 m, are analyzed to describe the principal features of atmospheric turbulence, sensible heat flux (H), and components of the turbulent kinetic energy (TKE) budget equation. The analyses focused on weak (WW) and strong (SW) wind conditions to achieve the research objectives of evaluating the turbulence structure above and below the rain forest canopy and estimating the degree of coupling between air layers above the forest and deep in the canopy. Turbulence statistical moments show that atmospheric eddies, generated above the canopy, hardly penetrate the region below 0.5h (h is the canopy height). Forest-atmosphere exchanges of heat differ depending on the observed wind regimes. Sensible heat fluxes decrease with canopy depth for SW conditions and are approximately constant with the height for WW above the canopy. Sensible heat flux profiles reveal a transition layer (around 0.6h) which sometimes exchanges heat with the upper and sometimes with the lower forest canopy, depending on time of day and weather conditions. TKE balance results show that during the daytime period in SW conditions the shear production is at least an order of magnitude greater than the buoyancy above the forest canopy. This turbulence, however, is practically all dissipated in the region above 0.5h. Thus, the air layer from the soil surface to 0.5h is largely decoupled from the upper part of the forest canopy. This feature of having the bottom of the canopy mostly decoupled from the air aloft in the dense and tall rain forest can exert control on the residence times and turbulent transport of plant-emitted gases out of the forest canopy.

54 ENVIRONMENTAL SCIENCES↗