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At least 577 records · Page 32

Characterization of X-Ray Diffraction System with a Microfocus X-Ray Source and a Polycapillary Optic

We present here an optimized microfocus x-ray source and polycapillary optic system designed for diffraction of small protein crystals. The x-ray beam is formed by a 5.5mm focal length capillary collimator coupled with a 40 micron x-ray source operating at 46Watts. Measurements of the x-ray flux, the divergence and the spectral characteristics of the beam are presented, This optimized system provides a seven fold greater flux than our recently reported configuration [M. Gubarev, et al., J. of Applied Crystallography (2000) 33, in press]. We now make a comparison with a 5kWatts rotating anode generator (Rigaku) coupled with confocal multilayer focusing mirrors (Osmic, CMF12- 38Cu6). The microfocus x-ray source and polycapillary collimator system delivers 60% of the x-ray flux from the rotating anode system. Additional ways to improve our microfocus x-ray system, and thus increase the x-ray flux will be discussed.

Gubarev, Mikhail↗

Consortium breccia 73255 - Genesis and history of two coarse-grained 'norite' clasts

A study of two clasts of coarse-grained anorthositic-noritic-troctolitic-suite norites from the fragment-laden melt rock 73255 is presented. Both clasts are igneous rocks crystallized from melts that were probably internally generated; clast 27,80 is a cumulate, and the parent magmas of both rocks probably crystallized below the lunar surface. Despite similar history, the parent rocks of the two clasts appear to be derived from distinct magma types: the 27,80 is characterized by plagioclase and orthopyroxene as the major constituents and by a high K, Nb, and Zr content, while the 27,45 type also contains augite and has a low content of K, Nb, and Zr.

James, O. B.↗

Primary igneous carbon in ureilites - Petrological implications

The ureilite meteorites are carbonaceous olivine-pyroxene achondrites. They typically contain up to 4 wt.% carbon (carbonaceous matrix) as graphite, diamond, and lonsdaleite. Shock degradation has effectively obliterated primary textures in the carbonaceous matrix of previously described ureilites, a factor that has hampered efforts to explain the origin of this material. In contrast, the Antarctic ureilite ALHA78019 displays perfectly preserved primary textures in the carbonaceous matrix characterized by euhedral graphite blades intergrown with Fe-Ni metal and sulfide (diamonds are absent). This petrographic feature suggests that most graphite in ureilites originated by crystallization from a C-rich metallic phase. Assuming that fO2 is controlled by C-CO-CO2 reactions, the compositions of silicates and metals in ureilites imply a two-stage redox history. The noble gases and rare earths of ureilites are discussed in light of this model.

Berkely, J. L.↗

Tetravalent chromium doped laser materials and NIR tunable lasers

A method is described to improve and produce purer Cr.sup.4+-doped laser materials and lasers with reduced co-incorporation of chromium in any other valence states, such as Cr.sup.3+, Cr.sup.2+, Cr.sup.5+, and Cr.sup.6+. The method includes: 1) certain crystals of olivine structure with large cation (Ca) in octahedral sites such as Cr.sup.4+:Ca.sub.2GeO.sub.4, Cr.sup.4+:Ca.sub.2SiO.sub.4, Cr.sup.4+:Ca.sub.2Ge.sub.xSi.sub.1-xO.sub.4 (where 0<x<1), and/or 2) high-temperature solution growth techniques that enable the growth of the crystals below the temperature of polymorphic transitions by using low melting point solvent based on oxide, fluoride and/or chloride compounds. Purer Cr.sup.4+-doped laser materials are characterized by a relatively high concentration of Cr.sup.4+-lasing ion in crystalline host that makes these materials suitable for compact high power (thin disk/wedge) NIR laser applications.

Alfano, Robert R.↗

Evaluation of Satellite Remote Sensing Albedo Retrievals over the Ablation Area of the Southwestern Greenland Ice Sheet

MODerate resolution Imaging Spectroradiometer (MODIS) albedo products have been validated over spatially uniform, snow-covered areas of the Greenland ice sheet (GrIS) using the so-called single 'point-to-pixel' method. This study expands on this methodology by applying a 'multiple-point-to-pixel' method and examination of spatial autocorrelation (here using semivariogram analysis) by using in situ observations, high-resolution World- View-2 (WV-2) surface reflectances, and MODIS Collection V006 daily blue-sky albedo over a spatially heterogeneous surfaces in the lower ablation zone in southwest Greenland. Our results using 232 ground-based samples within two MODIS pixels, one being more spatial heterogeneous than the other, show little difference in accuracy among narrow and broad band albedos (except for Band 2). Within the more homogenous pixel area, in situ and MODIS albedos were very close (error varied from −4% to +7%) and within the range of ASD standard errors. The semivariogram analysis revealed that the minimum observational footprint needed for a spatially representative sample is 30 m. In contrast, over the more spatially heterogeneous surface pixel, a minimum footprint size was not quantifiable due to spatial autocorrelation, and far exceeds the effective resolution of the MODIS retrievals. Over the high spatial heterogeneity surface pixel, MODIS is lower than ground measurements by 4-7%, partly due to a known in situ undersampling of darker surfaces that often are impassable by foot (e.g., meltwater features and shadowing effects over crevasses). Despite the sampling issue, our analysis errors are very close to the stated general accuracy of the MODIS product of 5%. Thus, our study suggests that the MODIS albedo product performs well in a very heterogeneous, low-albedo, area of the ice sheet ablation zone. Furthermore, we demonstrate that single 'point-to-pixel' methods alone are insufficient in characterizing and validating the variation of surface albedo displayed in the lower ablation area. This is true because the distribution of in situ data deviations from MODIS albedo show a substantial range, with the average values for the 10th and 90th percentiles being −0.30 and 0.43 across all bands. Thus, if only single point is taken for ground validation, and is randomly selected from either distribution tails, the error would appear to be considerable. Given the need for multiple in-situ points, concurrent albedo measurements derived from existing AWSs, (low-flying vehicles (airborne or unmanned) and high-resolution imagery (WV-2)) are needed to resolve high sub-pixel variability in the ablation zone, and thus, further improve our characterization of Greenland's surface albedo.

Ablation zone↗

The DC-8 Submillimeter-Wave Cloud Ice Radiometer

An airborne radiometer is being developed to demonstrate the capability of radiometry at submillimeter-wavelengths to characterize cirrus clouds. At these wavelengths, cirrus clouds scatter upwelling radiation from water vapor in the lower troposphere. Radiometric measurements made at multiple widely spaced frequencies permit flux variations caused by changes in scattering due to crystal size to be distinguished from changes in cloud ice content. Measurements at dual polarizations can also be used to constrain the mean crystal shape. An airborne radiometer measuring the upwelling submillimeter-wave flux should then able to retrieve both bulk and microphysical cloud properties. The radiometer is being designed to make measurements at four frequencies (183 GHz, 325 GHz, 448 GHz, and 643 GHz) with dual-polarization capability at 643 GHz. The instrument is being developed for flight on NASA's DC-8 and will scan cross-track through an aircraft window. Measurements with this radiometer in combination with independent ground-based and airborne measurements will validate the submillimeter-wave radiometer retrieval techniques. The goal of this effort is to develop a technique to enable spaceborne characterization of cirrus, which will meet a key climate measurement need. The development of an airborne radiometer to validate cirrus retrieval techniques is a critical step toward development of spaced-based radiometers to investigate and monitor cirrus on a global scale. The radiometer development is a cooperative effort of the University of Colorado, Colorado State University, Swales Aerospace, and Jet Propulsion Laboratory and is funded by the NASA Instrument Incubator Program.

Walter, Steven J.↗

Genesis of recent silicic magmatism in the Medicine Lake Highland, California - Evidence from cognate inclusions found at Little Glass Mountain

Sparse, granular inclusions of early-formed minerals found within the Little Glass Mountain rhyolite flows in northern California are shown to provide a means of characterizing the physical conditions, at depth, beneath the Medicine Lake Highland during the latest phase of volcanic activity. Mineral compositions, in combination with thermodynamic calculations and experiments, suggest crystalization at a pressure of 5,200 bars within a 966-836 C temperature range; implying that mineral segregation and equilibration occurred at a depth of 15-18 km beneath the surface. In addition, mass balance calculations indicate that the Medicine Lake flow is a close approximation to the parental magma for the latest silicic lavas.

Mertzman, S. A.↗

SSME - Materials and Methods for Addressing High-Pressure Hydrogen Embrittlement

From the humid, corrosion-friendly atmosphere of KSC, to the extreme heat of ascent, to the cold vacuum of space, the Space Shuttle faced one hostile environment after another. One of those harsh environments the hydrogen environment existed within the shuttle itself. Liquid hydrogen was the fuel that powered the shuttle s complex, powerful, and reusable main engine. Hydrogen provided the high specific impulse the bang per pound of fuel needed to perform the shuttle s heavy lifting duties. Hydrogen, however, was also a potential threat to the very metal of the propulsion system that used it. The diffusion of hydrogen atoms into a metal can make it more brittle and prone to cracking a process called hydrogen embrittlement. This effect can reduce the toughness of carefully selected and prepared materials. A concern that exposure to hydrogen might encourage crack growth was present from the beginning of the Space Shuttle Program, but the rationale for using hydrogen was compelling. This paper outlines the material characterization, anomaly resolution, and path to understanding of hydrogen embrittlement on superalloys through the course of the SSME program. Specific examples of nickel alloy turbine housings and single crystal turbine blades are addressed. The evolution of fracture mechanics analytical methods is also addressed.

Matejczk, Daniel↗

Peology and Geochemistry of New Paired Martian Meteorites 12095 and LAR 12240

The meteorites LAR 12095 and LAR 12240 are believed to be paired Martian meteorites and were discovered during the Antarctic Search for Meteorites (ANSMET) 2012-2013 Season at Larkman Nunatak. The purpose of this study is to characterize these olivine-phyric shergottites by analyzing all mineral phases for major, minor and trace elements and examining their textural relationships. The goal is to constrain their crystallization history and place these shergottites among other Martian meteorites in order to better understand Martian geological history.

Funk, R. C.↗

Pyroclastics Northeast of Gassendi Crater: Discovery/Characteristics/Implications

In our ongoing effort to better understand lunar volcanism on the Moon, we are investigating pyroclastic deposits in the Gassendi region. Interest in pyroclastics has remained high due to the availability of high-resolution data (LRO, Kaguya), which is used to build on previous remote sensing studies [e.g., 1, 2, 3] and also extensive studies of lunar pyroclastic glasses [4, 5]. Analyses conducted in the laboratory of pyroclastic spheres from several deposits show that this volcanic material had a greater depth of origin and lesser fractional crystallization than mare basalts [e.g., 4, 6]. Data indicates that pyroclastic glasses are the best examples of primitive materials on the Moon, and they are important for both characterizing the lunar interior and as a starting place for under-standing the origin and evolution of lunar basaltic magmatism [2].

Giguere, T. A.↗

Electron Beam Damage in Apatite: Limitations for SKα Measurements of S6+/∑S

In magmatic systems, the availabil- ity of excess oxygen that can react with multivalent elements such as Fe and S to change their charge (oxi- dation of Fe2+ to Fe3+ or reduction of S6+ to S2-) is characterized by a parameter called the oxygen fugacity (ƒO2). The ƒO2 controls the availability of these ions and consequently the minerals—and the chemistry of those minerals—that crystallize from a melt. Mineral mode and chemistry control how magmas evolve, and given that ƒO2 varies by many orders of magnitude on different planets [2], understanding the ƒO2 of a mag- ma is critical to relating observations about a magma to the body on which it forms. The mineral apatite was long thought to only incor- porate S6+ in a coupled substitution for P5+, but recently natural apatites with S2- were identified in lunar mare basalts that crystallized at low ƒO2 [3]. This suggests that apatite can be used as a monitor of ƒO2 assuming that one can 1) measure S6+/∑S (S6+ over total sulfur), and 2) determine some partitioning relationship be- tween apatite and melt for S6+ and S2-. The most common method for measuring S6+/∑S is X-ray Absorption Near-Edge Spectroscopy (XANES), but given the limited access to synchrotron facilities, it is wise to explore the potential of other methods for measuring S6+/∑S. One such possible method relies upon the shift in energy of the sulfur K-α peak on the electron microprobe. However, apatite is subject to well-documented beam damage [4, 5], so it is neces- sary to evaluate under what conditions can reliable S6+ ethod.

de Chizelle, J. Kuhn↗

Shuttle Mission STS-50: Orbital Processing of High-Quality CdTe Compound Semiconductors Experiment: Final Flight Sample Characterization Report

The Orbital Processing of High-Quality Doped and Alloyed CdTe Compound Semiconductors program was initiated to investigate, quantitatively, the influences of gravitationally dependent phenomena on the growth and quality of bulk compound semiconductors. The objective was to improve crystal quality (both structural and compositional) and to better understand and control the variables within the crystal growth production process. The empirical effort entailed the development of a terrestrial (one-g) experiment baseline for quantitative comparison with microgravity (mu-g) results. This effort was supported by the development of high-fidelity process models of heat transfer, fluid flow and solute redistribution, and thermo-mechanical stress occurring in the furnace, safety cartridge, ampoule, and crystal throughout the melting, seeding, crystal growth, and post-solidification processing. In addition, the sensitivity of the orbital experiments was analyzed with respect to the residual microgravity (mu-g) environment, both steady state and g-jitter. CdZnTe crystals were grown in one-g and in mu-g. Crystals processed terrestrially were grown at the NASA Ground Control Experiments Laboratory (GCEL) and at Grumman Aerospace Corporation (now Northrop Grumman Corporation). Two mu-g crystals were grown in the Crystal Growth Furnace (CGF) during the First United States Microgravity Laboratory Mission (USML-1), STS-50, June 24 - July 9, 1992.

Larson, David J.↗

Measuring the spacecraft and environmental interactions of the 8-cm mercury ion thrusters on the P80-1 mission

The subject interface measurements are described for the Ion Auxiliary Propulsion System (IAPS) flight test of two 8-cm thrusters. The diagnostic devices and the effects to be measured include: 1) quartz crystal microbalances to detect nonvolatile deposition due to thruster operation; 2) warm and cold solar cell monitors for nonvolatile and volatile (mercury) deposition; 3) retarding potential ion collectors to characterize the low energy thruster ionic efflux; and 4) a probe to measure the spacecraft potential and thruster generated electron currents to biased spacecraft surfaces. The diagnostics will also assess space environmental interactions of the spacecraft and thrusters. The diagnostic data will characterize mercury thruster interfaces and provide data useful for future applications.

Power, J. L.↗

Effects of temperature on remotely sensed mineral absorption features

The present paper provides the results from a series of laboratory experiments which were conducted to investigate the variable spectral behavior of diagnostic Fe(++) crystal field absorptions in common rock-forming minerals as a function of temperature. The general goal of the study is to refine existing techniques of mineralogic and chemical characterization, based on specific optical behavior which has been measured and correlated in a systematic way. It is pointed out that the presented work, taken together with a number of recent studies, provides new information on the manner in which specific features of mafic minerals combine in rocks and soil spectra, taking into account also variations of identification and subsequent interpretation as a function of planetary surface temperature. The obtained results are directly applicable to interpretation of remotely sensed data for many solar system objects, particularly Mars, asteroids, the moon, earth, and Mercury.

Singer, R. B.↗

Glycolonitrile oligomerization: structure of isolated oxazolines, potential heterocycles on the early earth

A study of glycolonitrile polymerization has led to the isolation and characterization of two 2,5-dihydro-4-aminooxazoles, 4 and 5. Previous reports have misassigned these structures as s-triazines or pyrimidines. X-ray diffraction analysis of crystals of 4 and an acetylated oxazole derivative of 5 (6) confirm the proposed structures. Ab initio computations are used to assess the relative thermodynamic stability of three trimer isomers (an s-triazine, an aminohydroxypyrimidine, and an aminooxazoline), and the results indicate that 4 is a novel kinetic product. Mechanistic considerations rationalize kinetic oxazole formation over the more customary triazine or pyrimidine trimers.

Non-NASA Center↗

Synthesis of Two New Group 13 Benzoato-Chloro Complexes: A Structural Study of Gallium and Indium Chelating Carboxylates

Two new heteroleptic chelated-benzoato gallium (III) and indium (III) complexes have been prepared and structurally characterized. The molecular structures of [GaCl2(4-Mepy)2(O2CPh)]4-Mepy (1) and [InCl(4-Mepy)2(O2CPh)2]4-Mepy (2) have been determined by single-crystal x-ray diffraction. The gallium compound (1) is a distorted octahedron with cis-chloride ligands co-planar with the chelating benzoate and the 4-methylpyridines trans to each other. This is the first example of a Ga(III) structure with a chelating benzoate. The indium compound (2) is a distorted pentagonal bipyramid with two chelating benzoates, one 4-methylpyridine in the plane and a chloride trans to the other 4-methylpyridine. The indium bis-benzoate is an unusual example of a seven-coordinate structure with classical ligands. Both complexes, which due to the chelates, could also be described as pseudo-trigonal bipyramidal, include a three-bladed motif with three roughly parallel aromatic rings that along with a solvent of crystallization and electron-withdrawing chloride ligand(s) stabilize the solid-state structures.

Duraj, Stan A.↗

Impact Shock Origin of Diamonds in Ureilite Meteorites

The origin of diamonds in ureilite meteorites is a timely topic in planetary geology as recent studies have proposed their formation at static pressures >20 GPain a large planetary body, like diamonds formed deep within the Earth ́s mantle. We investigated fragments of three diamond-bearing ureilites (two from the Almahata Sitta polymict ureilite and one from the NWA 7983 main group ureilite). In NWA7983 we found an intimate association of large monocrystalline diamonds (up to atleast 100 μm), nanodiamonds, nanographite, and nanometric grains of metallic iron,cohenite, troilite and likely schreibersite. The diamonds show a striking texture pseudo morphing inferred original graphite laths.The silicates in NWA 7983 recorda high degree of shock metamorphism. The presence of both large mono crystalline diamonds and nano diamonds in a highly shocked ureilite can be explained by catalyzed transformation from graphite during an impact shock event characterized by peak pressures possibly as low as 15 GPa for relatively long duration (on the scale of few seconds). The formation of “large” (as opposed to nano-) diamond crystals could have been enhanced by the catalytic effect of metallic Fe-Ni-C liquid coexisting with graphite. We found no evidence that formation of micrometer(s)sized diamonds or associated Fe-S-P phases in ureilites require high static pressures and long formation times. It is unlikely that any of the diamonds in ureilites formed in bodies as large as Mars or Mercury.

Fabrizio Nestola↗

Thermal desorption of metals from tungsten single crystal surfaces

After a short review of experimental methods used to determine desorption energies and frequencies the assumptions underlying the theoretical analysis of experimental data are discussed. Recent experimental results on the flash desorption of Cu, Ag, and Au from clean, well characterized W (110) and (100) surfaces are presented and analyzed in detail with respect to the coverage dependence. The results obtained clearly reveal the limitations of previous analytical methods and of the experimental technique per se (such as structure and phase changes below and in the temperature region in which desorption occurs).

Bauer, E.↗