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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32

Tuning the surface energy of fluorinated diamond-like carbon coatings via plasma immersion ion implantation plasma-enhanced chemical vapor deposition with 1,1,1,2-tetrafluoroethane

Here, we demonstrate an environmentally friendly and scalable method to create fluorine-doped diamond-like carbon (F-DLC) coatings using plasma immersion ion implantation plasma-enhanced chemical vapor deposition (PIII-PECVD) with 1,1,1,2-tetrafluoroethane. F-DLC films tend to have low wettability and good mechanical flexibility, which make them suitable for applications in biomedical devices and antibiofouling surfaces. We report on the effects of fluorine incorporation on the surface chemistry, surface energy, and morphology of these coatings, showing that our method is effective in increasing the fluorine content in the F-DLC up to 40%. We show that the addition of fluorine leads to a decrease in surface energy, which is consistent with a reduction in surface wettability.

Contact angle↗

Fabrication and durability characterization of superhydrophobic and lubricant-infused surfaces

Hypothesis: Practical applications of non-wetting surfaces require good mechanical durability in the wet environments for which they are intended to be used. Durability of non-wetting surfaces is influenced by the surface features, interaction with the functionalization agent, and the lubricant properties that can be tuned independently to identify optimal combination. Experiments: In this study, superhydrophobic and lubricant-infused surfaces are fabricated on copper tubes using chemical etching and electrodeposition texturing techniques, six different functionalizing agents, and five different infused lubricants. Through 180 fabrication combinations and 102 durability tests, each parameter is systematically studied for contributions to initial non-wetting behavior and its durability in heated, wet environment, under high-energy water jet impingement, and under accelerated flow conditions. Findings: Among the adsorbing and curing functionalization agents investigated, n-Hexadecyl mercaptan that belongs to the sulfhydryl group and Sylgard-184, respectively, showed high durability in heated water immersion and under jet impingement tests. For lubricant-infused surfaces, lubricants with high surface tension demonstrated high durability in heated water immersion test, whereas durability in hydrodynamic conditions is closely correlated to lubricant viscosity. Results showed that a lubricant-infused surface will maintain its non-wetting properties in dropwise condensation conditions for approximately 1.5 years.

36 MATERIALS SCIENCE↗

CO 2 -Soluble Nonionic Surfactants for Enhanced CO 2 Storage via In Situ Foam Generation

Geologic carbon storage (GCS) is a rapidly evolving technology with the potential to reduce the environmental impact of fos-sil fuels. Saline aquifers, which comprise a sandstone matrix with brine in the pores, make up much of the pore space availa-ble for CO 2 storage in the United States. When CO 2 is injected in saline aquifers, however, capillary fingering occurs and only a small percentage of the pore space is filled with CO 2 . This is due to the low viscosity of CO 2 , which is roughly ten times less viscous than brine. To address this problem, we tested the ability of inexpensive, commercially available nonionic surfactants to be dissolved in the injected CO 2 and increase the apparent viscosity of CO 2 by generating CO 2 -in-water foams in situ.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Density Measurements of Various Molten Sodium, Magnesium, Potassium, and Uranium Chloride Salt Compositions Using Neutron Imaging

With an increased interest in the use of molten salts for energy generation, obtaining thermophysical properties of salt mixtures becomes critical for the understanding of salt performance and behavior. Density is one of the significant thermophysical properties of salt systems. This work presents the density measurement of molten chloride salt mixtures using neutron imaging. This work was performed at the Oak Ridge National Laboratory High-Flux Isotope Reactor. Here, resulting densities as a function of temperature for different molten chloride salts from this work were compared with calculated values using Redlich–Kister modeling. Agreement between the calculated and measured values was within 1–10%, with the exception of the ternary UCl 3 –NaCl–KCl salt that showed a 32% discrepancy between several literature reports; however, the results did align well with another neutron radiography article. Analysis of the radiographs suggests that microbubbles in the ternary mixture might have biased the density measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Integration of the fundamental knowledge on solvent-packing interactions into the multiscale framework for column scale design and optimization

The interfacial area, also known as the effective mass transfer area, is a key factor for determining the mass transfer for carbon dioxide (CO 2 ) capture via the chemical absorption process in a packed column, and thus the overall capture efficiency of the packed column. Most of the widely used empirical and semi-empirical models for interfacial area were derived indirectly through absorption mass transfer with simplifications based on fast chemical kinetics. This report presents the comprehensive unique multiscale approach to develop a surrogate model for effective mass transfer area in structured packed columns that accounts local hydrodynamics as well as variation in physical properties, and changes in solid surface characteristics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of gravity on liquid phase sintering

The unique conditions offered by the earth orbital environment in material processing involving both solid and liquid phases, such as liquid phase sintering, were studied. An experimental development program involving both test and theoretical work was initiated. Experimental work using material combinations selected such that maximum information about the effect of gravity can be derived has been conducted. Wetting of the solid phase by the liquid during sintering is an important phenomenon in liquid phase sintering, and gravity has influence on both capillary phenomenon and density segregation; hence, material combinations were selected such that these two effects can be suitably studies. The experimental work is meant to form the basis for similar comparative work done under low-g conditions. The part of the model dealing with the capillary phenomenon, as related to liquid phase sintering and the effect of gravity on it, suggest that gravity will have negligible effect on the Bond number and that the cohesive force is dependent on both the amount of liquid phase and the angle of contact.

Mookherji, T.↗

Methods for an investigation of the effect of material components on the mechanical characteristics of glass-fiber-reinforced plastics

The materials used in the production of glass reinforced plastics are discussed. Specific emphasis is given to matrix polyester materials, the reinforcing glass materials, and aspects of specimen preparation. Various methods of investigation are described, giving attention to optical impregnation and wetting measurements and the gravimetric determination of the angle of contact. Deformation measurements and approaches utilizing a piezoelectric device are also considered.

Willax, H. O.↗

The stability of the axially symmetric pendent drop

The axially symmetric pendent drop as it occurs in three different physical settings is analyzed: Problem A with constant pressure and a fixed circular opening (the siphon); Problem B with constant volume and a fixed circular opening (the medicine dropper); and Problem C with prescribed volume and a constant angle of contact with a horizontal plate. As examples, the results are verified. For Problem B it is shown that if the opening is small enough to support a stable pendent drop with a bulge, then as the exposed volume is increased, stable pendent drops with both a neck and a bulge will be formed. For Problem C it is shown that with increasing volume the profile curves for the family of stable pendent drops will develop an inflection point before instability arises.

Wente, H. C.↗

The determination of minority carrier lifetimes in direct band-gap semiconductors by monitoring intensity-modulated luminescence radiation

When an extrinsic, direct band-gap semiconductor sample is irradiated by photons of an energy higher than the energy of the band gap between valence and conduction bands, excess electron-hole pairs are generated which, while diffusing through the sample, produce luminescence via radiative recombination. If, furthermore, the intensity of the impinging beam of photons is modulated sinusoidally, the luminescence radiation escaping from the sample will be phase shifted with respect to the original photon beam in a characteristic way. It will be shown that by measuring the phase shift at different modulation frequencies, the Shockley-Read-Hall lifetime of minority carriers may be ascertained. The method is nondestructive inasmuch as there is no need to fabricate p-n junctions or Ohmic contacts, nor is it necessary to remove already existing Ohmic contacts of angle lap the surface, etc., procedures often needed when determining lifetimes with the scanning electron microscope (in which case a p-n junction must be present).

Von Roos, O.↗

Application of optical and photomechanical techniques in the study of mechanical joints

A fiber-optic technique and the conventional photoelastic technique were applied to the investigation of pin-loaded specimens which simulate pin joints and bolted joints. The angle of contact between the pin and the hole was measured by these techniques and compared with finite element results. The stress distributions obtained form the otoelastic response were also compared with the finite element results. Such comparisons are needed to verify the finite element model and to assess the role of important joint variables such as friction.

Prabhakaran, R.↗

An Evaluation of Structural Analysis Methodologies for Space Deployable Structures

Benchmarks are introduced for evaluating the performance of numerical simulations of space deployable structures. These benchmarks embody the key challenges of interest to future large space deployable structures, including large angle motion, contact between flexible bodies, and the presence of both soft and stiff mechanical components. The benchmarks were used in companion studies to evaluate the ADAMS multibody dynamics code, the LS-Dyna nonlinear finite element code, and the Sierra large-scale parallel nonlinear finite element code. In the past, only multibody codes would have been considered for this application. This study found that all three codes could be used for these benchmarks, a finding that may lead to larger scale, higher fidelity simulations in the future.

Mobrem, Mehran↗

The Unrealized Potential of Superhydrophobic Substrates in Advanced Life Support Systems

Nearly all water processing equipment aboard spacecraft is to a large extent controlled by capillary forces arising from substrate wetting conditions. Superhydrophobic wetting conditions provide an essentially passive means to keep water away from certain substrates providing a level of no-moving-parts phase separation and control. This work presents a host of non-wetting aqueous microgravity capillary fluidics phenomena arising from interactions with easily fabricated superhydrophobic substrates. The value of such phenomena for potential life support applications aboard spacecraft is clear, especially for substrate properties that are thermally robust, corrosion resistant, and self-cleaning for both long- and short term applications. Large length scale low-g demonstrations of the phenomena are provided in HD video format for the extensive drop tower tests conducted. The broader crosscutting impacts to numerous fluids processing operations for life support are discussed. Current practical applications addressed in light of superhydrophobicity include urine-processing, water recovery, fire safety, and others.

Superhydrophoic↗

Materials for Cryogenic Propellant Dewetting

The purpose of this experiment campaign is to find materials or surface coatings that repel ("dewet") cryogenic propellants. This presentation summarizes progress up to this point.

contact angle↗

Recursive forward dynamics for multiple robot arms moving a common task object

Recursive forward dynamics algorithms are developed and presented for an arbitrary number of robot arms moving a commonly held object. The multiarm forward dynamics problem is to find the angular accelerations at the joints and the contact forces that the arms impart to the task object. The problem also involves finding the acceleration of this object. The multiarm forward dynamics solutions provide a thorough physical and mathematical understanding of the way several arms behave in response to a set of applied joint moments. Such an understanding simplifies and guides the subsequent control design and experimentation process. The forward dynamics algorithms also provide the necessary analytical foundation for conducting analysis and simulation studies. The multiarm algorithms are based on the filtering and smoothing approach recently advanced for single-arm dynamics, and they can be built up modularly from the single-arm algorithms. The algorithms compute recursively the joint angle accelerations, the contact forces, and the task-object accelerations. Algorithms are also developed to evaluate in closed form the linear transformations from the active joint moments to the joint angle accelerations, to the task object accelerations, and to the task-object contact forces. A possible computing architecture is presented as a precursor to a more complete investigation of the computational performance of the dynamics algorithms.

Rodriguez, Guillermo↗

Recursive forward dynamics for multiple robot arms moving a common task object

Recursive forward dynamics algorithms are developed for an arbitrary number of robot arms moving a commonly held object. The multiarm forward dynamics problem is to find the angular accelerations at the joints and the contact forces that the arms impart to the task object. The problem also involves finding the acceleration of this object. The multiarm forward dynamics solutions provide a thorough physical and mathematical understanding of the way several arms behave in response to a set of applied joint moments. Such an understanding simplifies and guides the subsequent control design and experimentation process. The forward dynamics algorithms also provide the necessary analytical foundation for conducting analysis and simulation studies. The multiarm algorithms are based on the filtering and smoothing approach recently advanced for single-arm dynamics, and they can be built up modularly from the single-arm algorithms. The algorithms compute recursively the joint-angle accelerations, the contact forces, and the task-object accelerations. Algorithms are also developed to evaluate in closed form the linear transformations from the active joint moments to the joint-angle accelerations, to the task-object accelerations., and to the task-object contact forces. A possible computing architecture is presented as a precursor to a more complete investigation of the computational performance of the dynamics algorithms.

Rodriguez, G.↗

Landing impact studies of a 0.3-scale model air cushion landing system for a Navy fighter airplane

An experimental study was conducted in order to determine the landing-impact behavior of a 0.3-scale, dynamically (but not physically) similar model of a high-density Navy fighter equipped with an air cushion landing system. The model was tested over a range of landing contact attitudes at high forward speeds and sink rates on a specialized test fixture at the Langley aircraft landing loads and traction facility. The investigation indicated that vertical acceleration at landing impact was highly dependent on the pitch angle at ground contact, the higher acceleration of approximately 5g occurring near zero body-pitch attitude. A limited number of low-speed taxi tests were made in order to determine model stability characteristics. The model was found to have good pitch-damping characteristics but stability in roll was marginal.

Leland, T. J. W.↗