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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS2024

Impact of Spaceflight on Earth’s Atmosphere: Climate, Ozone, and the Upper Atmosphere

In order to eliminate potential risk from the lack of scientific understanding and resolve the current inability to assess how a rapidly growing space industry will affect Earth’s atmosphere, a well-defined research effort is recommended. As demonstrated in the white paper “Impacts of Spaceflight on the Global Atmosphere: Current Understanding, Knowledge Gaps, NASA’s Role, and Roadmap", we must improve our ability to model and observe rocket engine combustion, far field rocket plume evolution, impacts on the upper atmosphere, global launch impacts, reentry gas and aerosol production, far field reentry plume evolution, and global reentry impacts. The highly successful Atmospheric Chemistry of Combustion Emissions Near the Tropopause (ACCENT) program serves as a model for the proposed effort. ACCENT was a multiagency research program that included observation and modeling of rocket plumes and played a critical role to remove the threat of regulatory action against the Space Shuttle’s solid rocket motors. A similar effort today would be a combination of remote, in situ, and laboratory measurements that feed into model development and assessment of future launch and reentry emissions.

Ozone Layer↗
NASA NTRS1983

A quasi-continuous record of atmospheric opacity at lambda = 1.1 mm over 34 days at Mauna Kea Observatory

A quasi-continuous record of atmospheric attenuation is obtained. The data were gathered during a 24-day period in September and October 1982 and a 10-day period in December of that year. The opacity is arrived at by measuring the thermal emission of the atmosphere over a bandwidth of approximately 300 MHz. Using an experimental relationship established by Zammit and Ade (1981), opacity measurements at 1.1 mm are converted to the precipitable water vapor column overhead. With the precipitable water vapor, estimates of opacity due to water vapor can be made for other mm and FIR wavelengths. These estimates require model absorption curves for the atmosphere.

De Zafra, R. L.↗
DOE OSTI2023

Quantitative Characterization of Hyper-Local Atmospheric Greenhouse Gas Sources

Atmospheric greenhouse gas (GHG) emissions are often characterized using stationary, tower-based sensors. Ground based sensors reside in the turbulent boundary layer and are subject to intense concentration impulses from hyper-local (<100m) point sources of emissions. These high frequency spikes are often filtered out in broader emission flux studies, losing valuable information about how hyper-local sources influence receptors. In this study, we investigated how empirical atmospheric data can be used to locate and quantify a concurrently measured hyper-local point source in a dense urban setting. An eddy covariance style tower and a low-cost sensor tower were deployed in various locations around an urban, hyper-local CO2/CH4 emissions source (a continuously measured restaurant exhaust vent). A model using different processing and statistical techniques was built to examine the most effective procedures for source isolation, directional location, and emission quantification. Using excess concentrations above a minimum baseline, we identify the source using bivariate polar plots and quantify the relationship between source size, receptor distance, and statistical proxies. Furthermore, we find that varying statistical thresholds allows for identification of less influential sources which are drowned out by larger or closer sources. Finally, we show that large sources can be effectively characterized using low-cost sensors, a valuable outcome informing how networks for monitoring larger areas could be implemented. This work may provide a basis for source identification and monitoring protocols for networks that feature sensors influenced by hyper-local point sources, subject to site-specific assumptions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1995

An overview of the SABER experiment for the TIMED mission

The Sounding of the Atmosphere Using Broadband Emission Radiometry (SABER) experiment has been selected for flight on the Thermosphere-Ionosphere-Mesosphere Energetics and Dynamics (TIMED) mission expected to fly in the latter part of this decade. The primary science goal of SABER is to achieve fundamental and important advances in understanding of the energetics, chemistry, and dynamics, in the atmospheric region extending from 60 km to 180 km altitude, which has not been comprehensively observed on a global basis. This will be accomplished using the space flight proven experiment approach of broad spectral band limb emission radiometry. SABER will scan the horizon in 12 selected bands ranging from 1.27 microns to 17 microns wavelength. The observed vertical horizon emission profiles will be mathematically inverted in ground data processing to provide vertical profiles with 2 km vertical resolution, of temperature, O3, H2O, NO, NO2, CO, and CO2. SABER will also observe key emissions needed for energetics studies at 1.27 microns (O2((sup 1)delta)), 2 microns (OH(v = 7,8,9)) 1.6 microns (OH(v = 3,4,5)), 4.3 microns (CO2(v(sub 3))) 5.3 microns (NO) 9.6 microns (O3), and 15 microns (CO2(v(sub 2))). These measurements will be used to infer atomic hydrogen and atomic oxygen, the latter inferred three different ways using only SABER observations. Measurements will be made both night and day over the latitude range from the southern to northern polar regions.

Mlynczak, Martin G.↗
DOE OSTI2022

Super-Large-Scale Hierarchically Porous Films Based on Self-Assembled Eye-Like Air Pores for High-Performance Daytime Radiative Cooling

Metal-free polymer daytime radiative cooling coatings with hierarchical eye-like air pores are proposed and fabricated with a super-large-scale film-stretching method. The hierarchically porous film (HPF) can be further coated with polymethyl methacrylate (PMMA) micro-hemispheres, forming coated HPF (cHPF), which do not dramatically change the optical or thermal properties. The cHPF is slightly better with a lower solar absorptivity (2.4%) and a higher thermal emissivity over the atmospheric transparency window (90.1%). The low solar absorptivity is due to the strong scattering of the hierarchical eye-like air pores, while the molecular vibrations and the focusing effect of the PMMA micro-hemispheres contribute to the high emissivity. Further, an average mid-day temperature reduction of 7.92 °C is achieved relative to the air temperature, and the average cooling power reaches 116.0 W m -2 , which are much better than the cooling performances of the commercial cooling cushion. During the day, the cHPF-covered simulated building is up to 6.47 and 4.84 °C cooler than the ambient and the white painted counterpart, respectively. The film is durable and resistant to chemical etching, and very promising to use globally, especially in warm and tropical regions.

36 MATERIALS SCIENCE↗
NASA NTRS2015

Using Satellite Observations to Evaluate the AeroCOM Volcanic Emissions Inventory and the Dispersal of Volcanic SO2 Clouds in MERRA

Simulation of volcanic emissions in climate models requires information that describes the eruption of the emissions into the atmosphere. While the total amount of gases and aerosols released from a volcanic eruption can be readily estimated from satellite observations, information about the source parameters, like injection altitude, eruption time and duration, is often not directly known. The AeroCOM volcanic emissions inventory provides estimates of eruption source parameters and has been used to initialize volcanic emissions in reanalysis projects, like MERRA. The AeroCOM volcanic emission inventory provides an eruptions daily SO2 flux and plume top altitude, yet an eruption can be very short lived, lasting only a few hours, and emit clouds at multiple altitudes. Case studies comparing the satellite observed dispersal of volcanic SO2 clouds to simulations in MERRA have shown mixed results. Some cases show good agreement with observations Okmok (2008), while for other eruptions the observed initial SO2 mass is half of that in the simulations, Sierra Negra (2005). In other cases, the initial SO2 amount agrees with the observations but shows very different dispersal rates, Soufriere Hills (2006). In the aviation hazards community, deriving accurate source terms is crucial for monitoring and short-term forecasting (24-h) of volcanic clouds. Back trajectory methods have been developed which use satellite observations and transport models to estimate the injection altitude, eruption time, and eruption duration of observed volcanic clouds. These methods can provide eruption timing estimates on a 2-hour temporal resolution and estimate the altitude and depth of a volcanic cloud. To better understand the differences between MERRA simulations and volcanic SO2 observations, back trajectory methods are used to estimate the source term parameters for a few volcanic eruptions and compared to their corresponding entry in the AeroCOM volcanic emission inventory. The nature of these mixed results is discussed with respect to the source term estimates.

OMI SO2↗
DOE OSTI2020

Life cycle greenhouse gas emissions and energy use of polylactic acid, bio-derived polyethylene, and fossil-derived polyethylene

Bioplastics recently have become an attractive, viable, and popular alternative to conventional petroleum-based plastics, with the hope that replacing fossil-derived plastics with renewable alternatives will reduce greenhouse gas (GHG) emissions and fossil energy consumption (FEC). The bioplastic industry is encouraging creative designs and enhanced properties such as biodegradability, which is considered a sustainable solution for waste plastic management. However, biodegradability also means that carbon in the product is emitted to the atmosphere as GHG emissions. In this paper, a life cycle analysis (LCA) of biodegradable polylactic acid (PLA) and bio-polyethylene (bio-PE) plastics was conducted to understand the environmental effects of these bioplastics from feedstock production to product end-of-life (EOL). In particular, emissions from biodegradability (EOL emissions) are accounted for. The results were compared to those of conventional fossil-based plastics such as high-density polyethylene (HDPE) and low-density polyethylene (LDPE). Results showed that the lowest GHG emissions (-1.0 and 1.7 kg CO 2 e per kg for bio-PE and PLA with no biodegradation, respectively) and FEC (29 and 46 MJ per kg of bio-PE and PLA, respectively) were achieved with bio-derived plastics, particularly bio-PE plastic. However, despite the benefits of biogenic carbon uptake, when landfill and composting emissions were considered for the PLA pathway, the life cycle emissions of PLA increase significantly, from 16% to 163% depending on the biodegradation condition, compared to the case where there is no degradation in the landfill. This study also contributed to understand the effects on the GHG emissions of biodegradability in landfill and composting scenarios, regional electricity mix, and plastics manufacturing technologies. (C) 2020 The Authors. Published by Elsevier Ltd.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1986

Microwave emission and scattering from Earth surface and atmosphere

Nonlinear Electromagnetic (EM) wave interactions with the upper atmosphere were investigated during the period 15 December 1985 to 15 June 1986. Topics discussed include: the simultaneous excitation of ionospheric density irregularities and Earth's magnetic field fluctuations; the electron acceleration by Langmuir wave turbulence; and the occurrence of artificial spread F. The role of thermal effects in generating ionospheric irregularities by Whistler waves, intense Quasi-DC electric fields, atmospheric gravity waves, and electrojets was investigated. A model was developed to explain the discrete spectrum of the resonant ultralow frequency (ULF) waves that are commonly observed in the magnetosphere.

Kong, J. A.↗
NASA NTRS1994

The determination of electron densities in the solar atmosphere from the 1718.56 A/1486.51 A emission-line ratio in N IV

The theoretical electron density sensitive emission-line ratio R = I(1718.56 a)/I(1486.51 A) in N IV is presented for a range of N(sub e)(approximately equals 10(exp 10) - 10(exp 12)/cu cm) applicable to higher density solar plasmas, such as active regions. A comparison of these calculations with the observed values of R of several solar features obtained with the Naval Research Laboratory's S082B spectrograph on board Skylab reveals general agreement between theory and observation at pointings just above the limb, where line blends with N IV 1718.56 A should be insignificant, which provides experimental support for the accuracy of the line ratio calculations.

Keenan, F. P.↗
NASA NTRS1994

Model atmospheres and radiation of magnetic neutron stars: Anisotropic thermal emission

We investigate the anisotropy of the thermal radiation emitted by a surface element of a neutron star atmosphere (e.g., by a polar cap of a radio pulsar). Angular dependences of the partial fluxes at various photon energies, and spectra at various angles are obtained for different values of the effective temperature T(sub eff) and magnetic field strength B, and for different directions of the magnetic field. It is shown that the local radiation of the magnetized neutron star atmospheres is highly anisotropic, with the maximum flux emitted in the magnetic field direction. At high B the angular dependences in the soft X-ray range have two maxima, a high narrow peak along B and a lower and broader maximum at intermediate angles. The radiation is strongly polarized, the modulation of the degree of polarization due to the rotation of the neurtron star may be much higher than that for the radiative flux. The results obtained are compared with recent ROSAT observations of the thermal-like radiation from the radio pulsars PSR 1929+10 and PSR J0437-4715.

Pavlov, G. G.↗
DOE OSTI2022

Opinion: Coordinated development of emission inventories for climate forcers and air pollutants

Emissions into the atmosphere of fine particulate matter, its precursors, and precursors to tropospheric ozone impact not only human health and ecosystems, but also the climate by altering Earth's radiative balance. Accurately quantifying these impacts across local to global scales historically and in future scenarios requires emission inventories that are accurate, transparent, complete, comparable, and consistent. In an effort to better quantify the emissions and impacts of these pollutants, also called short-lived climate forcers (SLCFs), the Intergovernmental Panel on Climate Change (IPCC) is developing a new SLCF emissions methodology report. This report would supplement existing IPCC reporting guidance on greenhouse gas (GHG) emission inventories, which are currently used by inventory compilers to fulfill national reporting requirements under the United Nations Framework Convention on Climate Change (UNFCCC) and new requirements of the Enhanced Transparency Framework (ETF) under the Paris Agreement starting in 2024. We review the relevant issues, including how air pollutant and GHG inventory activities have historically been structured, as well as potential benefits, challenges, and recommendations for coordinating GHG and air pollutant inventory efforts. We argue that, while there are potential benefits to increasing coordination between air pollutant and GHG inventory development efforts, we also caution that there are differences in appropriate methodologies and applications that must jointly be considered.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1986

Microwave remote sensing: Active and passive. Volume 3 - From theory to applications

Aspects of volume scattering and emission theory are discussed, taking into account a weakly scattering medium, the Born approximation, first-order renormalization, the radiative transfer method, and the matrix-doubling method. Other topics explored are related to scatterometers and probing systems, the passive microwave sensing of the atmosphere, the passive microwave sensing of the ocean, the passive microwave sensing of land, the active microwave sensing of land, and radar remote sensing applications. Attention is given to inversion techniques, atmospheric attenuation and emission, a temperature profile retrieval from ground-based observations, mapping rainfall rates, the apparent temperature of the sea, the emission behavior of bare soil surfaces, the emission behavior of vegetation canopies, the emission behavior of snow, wind-vector radar scatterometry, radar measurements of sea ice, and the back-scattering behavior of cultural vegetation canopies.

Ulaby, F. T.↗
DOE OSTI2024

Contribution of Microorganisms with the Clade II Nitrous Oxide Reductase to Suppression of Surface Emissions of Nitrous Oxide

The sources and sinks of nitrous oxide, as control emissions to the atmosphere, are generally poorly constrained for most environmental systems. Initial depth-resolved analysis of nitrous oxide flux from observation wells and the proximal surface within a nitrate contaminated aquifer system revealed high subsurface production but little escape from the surface. Further, to better understand the environmental controls of production and emission at this site, we used a combination of isotopic, geochemical, and molecular analyses to show that chemodenitrification and bacterial denitrification are major sources of nitrous oxide in this subsurface, where low DO, low pH, and high nitrate are correlated with significant nitrous oxide production. Depth-resolved metagenomes showed that consumption of nitrous oxide near the surface was correlated with an enrichment of Clade II nitrous oxide reducers, consistent with a growing appreciation of their importance in controlling release of nitrous oxide to the atmosphere. Our work also provides evidence for the reduction of nitrous oxide at a pH of 4, well below the generally accepted limit of pH 5.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1995

Soot Aerosols in the Atmosphere: Contributions by Aircraft

Interest in the distribution of black carbon (soot) aerosol (BCA) in the atmosphere is based on the following: (1) Because BCA has the highest absorption cross section of any compound know, it can absorb solar radiation to cause atmospheric warming; (2) Because BCA is a strong adsorber of gases, it can catalyze heterogeneous chemical reactions to modify the chemical composition of the atmosphere; (3) If aircraft emission is the major source of BCA, it can serve as an atmospheric tracer of aircraft exhaust. We collect BCA particles as small as 0.02 micrometers by wires mounted on both the DC-8 and ER-2 aircraft. After return to the laboratory, the wires are examined with a field emission scanning electron microscope to identify BCA particles by their characteristics morphology, Typically, BCA exists in the atmosphere as small particles of complex morphology. The particle sizes at the source are measured in tens of Angstrom units; after a short residence time in the atmosphere, individual particles coalesce to loosely packed agglomerates of typical dimensions 0.01 to 0.1 micrometer. We approximate the size of each BCA aggregate by that of a sphere of equivalent volume. This is done by computing the volume of a sphere whose diameter is the mean between averaged minimum and maximum dimensions of the BCA particle. While this procedure probably underestimates the actual surface area, it permits us to compare BCA size distributions among themselves and with other types of aerosols.

Pueschel, R. F.↗
NASA NTRS2004

Analysis of Temperature and Wind Measurements from the TIMED Mission: Comparison with UARS Data

We report on an analysis of temperature and wind data based respectively on measurements with the SABER (Sounding of the Atmosphere using Broadband Emission Radiometry) and TIDI (TIMED Doppler Interferometer) instruments on the TIMED (Thermosphere-Ionosphere-Mesosphere-Energetics and Dynamics) mission. Comparisons are made with corresponding results obtained from the HRDI (High Resolution Doppler Imager), MLS (Microwave Limb Sounder) and CLAES (Cryogenic Limb Array Etalon Spectrometer) instruments on the UARS (Upper Atmosphere Research Satellite) spacecraft. The TIMED and UARS instruments have important common and uncommon properties in their sampling of the data as a function local solar time. For comparison between the data from the two satellite missions, we present the derived diurnal tidal and zonal-mean variations of temperature and winds, obtained as functions of season, latitude, and altitude. The observations are also compared with results from the Numerical Spectral Model (NSM).

Huang, Frank↗
NASA NTRS1993

Artificial auroras in the upper atmosphere. I - Electron beam injections

The Atlas-1 Spacelab payload's Space Experiments with Particle Accelerators generated artificial electron beams for the stimulation of auroral emissions at southern auroral latitudes. Optical measurements were made by the Shuttle Orbiter's onboard TV cameras, as well as by the Atmospheric Emissions Photometric Imager (in both white light and the 427.8 nm N2(+) emission line). Shuttle-based auroral imaging furnished a novel perspective on the artificial auroras; the emissions were traced from 295 km to the 110 km level along the curved magnetic-field lines.

Burch, J. L.↗