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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Affinity of LDR Organics to Cementitious Materials: Sorption and Leaching Tests

SRNL is working to identify and test the physiochemical interactions of organic contaminants of potential concern with minerals in grout/cementitious materials. Organic species may interact with cementitious minerals including slag, fly ash, cement, and other components/dopants like carbon in fly ash. The identification of such interactions will support the solidification process design, performance assessments for the chemicals of concern, and a proposed Resource Conservation and Recovery Act (RCRA) treatment variance the technology-based treatment standard specified for the Land Disposal Restriction (LDR) organics associated with Hanford tank waste. In FY24, a list of the 132 reasonably expected to be present LDR organics associated with Hanford tank waste (RPP-RPT-63493, Rev 1a) was screened by functional groups, octanol-water partitioning coefficients, and detection frequency in Hanford tank waste samples. A subset of 10 compounds spanning the identified properties were tested using sorption and leachate tests. These compounds were subject to traditional batch sorption tests and leaching tests on/from Cast Stone cementitious material with and without activated carbon (a potential organic adsorption additive). The tests have been completed and analysis is underway but as yet currently unavailable. The analytical results (and conclusions) will be included in a forthcoming revision to this report as soon as they are available

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Affinity of LDR Organics to Cementitious Materials: Sorption and Leaching Tests

SRNL is working to identify and test the physiochemical interactions of organic contaminants of potential concern with minerals in grout/cementitious materials. Organic species may interact with cementitious minerals including slag, fly ash, cement, and other components/dopants like carbon in fly ash. The identification of such interactions will support the solidification process design, performance assessments for the chemicals of concern, and a proposed Resource Conservation and Recovery Act (RCRA) treatment variance specified for the Land Disposal Restriction (LDR) organics associated with Hanford tank waste. Inably expected to be present LDR organics associated with Hanford tank waste (RPP-RPT-63493, Rev 1a) was screened by functional groups, octanol-water partitioning coefficients, and detection frequency in Hanford tank waste samples. A subset of 10 compounds, spanning the identified properties, were tested using sorption and leachate tests. These compounds were subjected to traditional batch sorption tests and leaching tests on/from Cast Stone cementitious material with and without activated carbon (a potential organic adsorption additive). The interactions between organic compounds were observed in traditional batch sorption and modified Toxic Characteristic Leaching Procedure (TCLP) leachate tests for a surrogate Cast Stone material with and without an activated carbon addition. Specifically, phthalic acids (negatively charged) and 4-chloroaniline (polar) sorbed strongly to unmodified Cast Stone and a group of 3 phenolic compounds (2,4,6-Trichlorophenol, Pentachlorophenol, o-Cresol) were sorbed to and were retained by Cast Stone with a 1% activated carbon amendment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

GeV–TeV Counterparts of SS 433/W50 from Fermi -LAT and HAWC Observations

The extended jets of the microquasar SS 433 have been observed in optical, radio, X-ray, and recently very-high-energy γ-rays by High Altitude Water Cerenkov (HAWC). The detection of HAWC γ-rays with energies as great as 25 TeV motivates searches for high-energy γ-ray counterparts in the Fermi-Large Area Telescope (LAT) data in the 100 MeV–300 GeV band. In this paper, we report on the first joint analysis of Fermi-LAT and HAWC observations to study the spectrum and location of γ-ray emission from SS 433. Our analysis finds common emission sites of GeV-to-TeV γ-rays inside the eastern and western lobes of SS 433. The total flux above 1 GeV is $\sim 1\times {10}^{-10}\,{\mathrm{cm}}^{-2}\,{{\rm{s}}}^{-1}$ in both lobes. The γ-ray spectrum in the eastern lobe is consistent with inverse Compton emission by an electron population that is accelerated by jets. To explain both the GeV and TeV flux, the electrons need to have a soft intrinsic energy spectrum, or undergo a quick cooling process due to synchrotron radiation in a magnetized environment.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1972

Application of ecological, geological and oceanographic ERTS-1 imagery to Delaware's coastal resources planning

The author has identified the following significant events. Coastal vegetation species appearing in the ERTS-1 image taken of the Southern Coast of Delaware, during orbit 333 on August 16, 1972, have been correlated with ground truth vegetation maps, and imagery obtained from high altitude RB-57 and U-2 overflights. The vegetation maps of the entire Delaware Coast were prepared using data collected on foot, in small boats, and from low altitude aircraft. Multispectral analysis of high altitude RB-57 and U-2 photographs indicated that five vegetation species could be clearly discriminated from 60,000 feet altitude, including: (1) salt marsh cord grass (Spartina alterniflora); (2) salt marsh hay and spike grass (Spartina patens and Distichlis spicata); (3) reed grass (Phragmites communis); (4) high tide bush and sea myrtle (Iva species and Baccharus halimifolia); and (5) a group of fresh water species found in impounded areas built to attract water fowl. Major Spartina alterniflora and Spartina patens communities within the tidal marshes can be identified in the ERTS-1 imagery. Phragmites, and other species however, occur in smaller, more dispersed groupings and are difficult to discriminate within the resolution capability of the ERTS-1 scanner. Similarly, major impounded areas, built to attract water fowl can be detected; however, mosquito drainage ditches, covering many of Delaware's marshes, are too narrow and not long enough to be resolved by ERTS-1 sensors. High-marsh and dune communities dominated by high tide bush (Iva frutescens) and sea myrtle (Baccharus halimifolia) can be distinguished from adjacent maritime forest and beach grass communities.

Klemas, V.↗
NASA NTRS1977

Remote water-monitoring system

General-purpose, water-quality sampling process detects microorganisms and integrates sampling, sample preservation, and sample analysis. System overcomes difficulties in correlation of surface measurements with remote measurements and minimizes human error in handling of samples and instrumentation.

Grana, D. C.↗
NASA NTRS1975

Investigation of remote sensing to detect near-surface groundwater on irrigated lands

The application of remote sensing techniques was studied for detecting areas with high water tables in irrigated agricultural lands. Aerial data were collected by the LANDSAT-1 satellite and aircraft over the Kansas/Bostwick Irrigation District in Republic and Jewell Counties, Kansas. LANDSAT-1 data for May 12 and August 10, 1973, and aircraft flights (midday and predawn) on August 10 and 11, 1973, and June 25 and 26, 1974, were obtained. Surface and water table contour maps and active observation well hydrographs were obtained from the Bureau of Reclamation for use in the analysis. Results of the study reveal that LANDSAT-1 data (May MSS band 6 and August MSS band 7) correlate significantly (0.01 level) with water table depth for 144 active observation wells located throughout the Kansas/Bostwick Irrigation District. However, a map of water table depths of less than 1.83 meters prepared from the LANDSAT-1 data did not compare favorably with a map of seeped lands of less than 1.22 m (4 feet) to the water table. Field evaluation of the map is necessary for a complete analysis. Analysis of three fields on a within or single-field basis for the 1973 LANDSAT-1 data also showed significant correlation results.

Ryland, D. W.↗
NASA NTRS1976

Applications of space technology to developing nations

The use of imagery from the Landsat spacecraft for the monitoring and management of natural resources in developing countries is discussed. The Landsat imagery can be used to make cartographic maps at scales of 1:250,000 which meet the US National Map Accuracy Standards, providing a means of map updating to correct for river meanders or changing shorelines. The Landsat data can also be used in defining and measuring agricultural areas, identifying pest breeding areas, and monitoring irrigation practices and crop performance. Total volume estimates can be obtained in many cases for surface bodies of water, and subsurface water supplies can be detected from changes in vegetation in some instances.

Freden, S. C.↗
NASA NTRS1977

Null-balancing microwave radiometer

Device performs absolute temperature measurements over range of 0 to 300 degrees Kelvin. Stability of device approaches 0.1 degrees Kelvin. Potential uses include detecting oil slicks on water and determining cloud water content and water vapor content of atmosphere.

Hardy, W. N.↗
NASA NTRS1979

Using Landsat digital data to detect moisture stress

A technique utilizing transformed Landsat digital data for detection of agricultural drought was empirically defined during the 1976 South Dakota drought. During 1977, the procedure was expanded to the Great Plains for evaluation as a technique for detecting and monitoring vegetative water stress over large areas. The technique, Green Index Number (GIN), uses Landsat digital data from 5 by 6 nautical mile sampling frames (segments) to indicate when the vegetation within the segment is undergoing drought. At known growth stages for wheat, segments were classified as drought or non-drought areas. The remote-sensing-based information was compared to a weekly ground-based index (Crop Moisture Index) provided by the United States Department of Commerce. This comparison demonstrated a high degree of agreement between the 18-day remote sensing technique and the ground-based weekly data. Maps based on GIN of parts of the USSR and Australia were produced with a two-week lag and later compared with other crop assessments of crop conditions in these areas. These maps were judged to be in general agreement with the other data sources.

Thompson, D. R.↗
NASA NTRS1982

A different type of maser star

A systematic survey of short-period, semiregular variable stars has been made resulting in the detection of six new water masers. Of the 14 short-period maser stars now known, nine are classified as SRb variables. All are very late spectral type SRb's, typically M7, while the overwhelming majority of normal SRb stars is M4 to M6. Their 2.2-11 micron color indices are among the lowest of any known maser stars. They are presumably less dusty as well. Four of the SRb stars and two of the remainder do not obey the correlation between period and velocity spread of the emission features that is found for the Mira and long-period, semiregular variables. Finally, high galactic latitudes dominate; 13 of the 14 are in excess of 13 deg, and nine of these are greater than 25 deg. These facts suggest that the short-period semiregular variables - particularly in SRb stars - may be a very different type of maser star than the Mira and long-period semiregular variables.

Dickinson, D. F.↗
NASA NTRS1982

Discrimination of growth and water stress in wheat by various vegetation indices through a clear a turbid atmosphere

Reflectance data were obtained over a drought-stressed and a well-watered wheat plot with a hand-held radiometer having bands similar to the MSS bands of the LANDSAT satellites. Data for 48 clear days were interpolated to yield reflectance values for each day of the growing season, from planting until harvest. With an atmospheric path radiance model and LANDSAT-2 calibration data, the reflectance were used to simulate LANDSAT digital counts (not quantized) for the four LANDSAT bands for each day of the growing season, through a clear (approximately 100 km meteorological range) and a turbid (approximately 10 km meteorological range) atmosphere. Several ratios and linear combinations of bands were calculated using the simulated data, then assessed for their relative ability to discriminate vegetative growth and plant stress through the two atmospheres. The results show that water stress was not detected by any of the indices until after growth was retarded, and the sensitivity of the various indices to vegetation depended on plant growth stage and atmospheric path radiance.

Jackson, R. D.↗