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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31

Energy Optimization of Light and Heavy-Duty Vehicle Cohorts of Mixed Connectivity, Automation and Propulsion System Capabilities via Meshed V2V-V2I and Expanded Data Sharing (Final Scientific and Technical Report)

Vehicle connectivity and automated driving technologies individually have the potential to decrease energy consumption and/or increase safety on light, medium or heavy duty vehicles to varying degrees depending on the traffic infrastructure and specific driving scenarios. Due to advances in sensing, perception and computing power, research and development emphasis in the mobility sector has shifted away from connectivity. Prior research has shown that driving automation with the absence of connectivity can in certain circumstances increase energy consumption. The effectiveness of synergizing connectivity and driving automation technologies is the focus of this work, specifically applied to vehicle cohorts of mixed composition, light and heavy duty, and powertrains ranging from all electric to conventional internal combustion engine. The project team is led by Michigan Technological University (MTU) and partnered with AVL Mobility Technologies Inc. (AVL), Borg Warner (BW), Traffic Technology Services (TTS), American Center for Mobility (ACM) and Navistar (NAV). The main thrusts for the team are to develop a micro-traffic simulation environment with specific VD&PT system attributes and CAV capabilities, 2) field a vehicle test fleet of mixed classification, propulsion and CAV capacity, 3) develop artificial intelligence (AI) and machine learning (ML) based multi-agent optimization methods for various traffic infrastructures, 4) integrate the virtual environment and the optimization methods then deploy the system as a CAV hardware in the loop (HiL) for the vehicle test fleet and 5) conduct closed track and public road testing to validate simulation and demonstrated energy and mobility improvements at multiple scales. For a cohort of mixed vehicles, the team will demonstrate a reduction of energy consumption of 10-50% at intersection, arterial roadway and limited access highway scenarios through connectivity and automation in simulation and at a closed test track. The energy reduction objectives of the project are summarized in Table 1, indicating the infrastructure and over what distances are relevant considered. Single scenario energy reductions are not relevant and thus, the research team took the approach to vary parameters associated with the infrastructure, vehicle cohort composition and dynamic behavior to generate energy consumption distributions for both unconnected and connected scenarios.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

STTR Phase I: Microfluidic Printing of High Performance Microgrids for High Efficiency, Flexible Organic Light Emitting Diodes Technical Report

Electroninks has been approached, and received strong interest from customers including chemical companies, device integrators, and final device producers. We have gained substantial customer traction in diverse markets as detailed in our Phase I report, and are currently sampling customers in the US, as well as Asia which is where the consumer/industry electronics supply chain is primarily positioned. The results reported here combined with our customer traction to date encourage us to apply for the Phase II stage of this work with the goal to advance the commercialization of our metal grids and particle free conductive inks.

LeMieux, PhD, Melbs↗

Building a Framework to Understand Transition Metals' Behavior in Euxinic Conditions (Final Technical Report)

This project focuses first and foremost on metal sulfide geochemistry and mineralogy as controlled by a complex matrix of environmental factors. The principal investigator’s group aim to illuminate the metal-sulfide reaction mechanisms, rates, and pathways through systematic experimentation and data collection and analyzing the relationships between the characteristics of the produced metal sulfide solid-phase/aqueous complexes and the environmental factors. This understanding is essential for obtaining a full picture of the complex cycling patterns of single or multi metal species in sulfidic environments ranging from deep-see basins, hydrothermal vents, inland seas, terrestrial water bodies, to engineered remediation systems. The specific goal of this past project was to illuminate the reaction mechanisms and kinetics of metal anions and sulfide in mixed metal cation-metal anion-sulfide systems under various aqueous conditions (which resembled a range of naturally occurring euxinic settings). For the period of this contract, we investigated the molybdenum-iron-sulfide system, with an emphasis on the conditions that caused solid phase formation. We focused on quantifying the mobility/sequestration of molybdenum under each experimental condition and identified the changes of valence states for each involved element (i.e., Mo, Fe, and S) in the precipitate. We also proposed pathways for the electron transfer that occurred in aqueous chemistry. The major analytical tools used for this study include UV-visible light spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and synchrotron-based X-ray absorption spectroscopy (access gained through facility proposals to the Canadian Light Source). The biggest finding of this project was that besides pH, the iron-sulfur chemistry has a dominant control of the thiolation kinetics and subsequent reduction of Mo(VI), which are likely prerequisites of molybdenum sequestration in anoxic conditions. The results have been written up as manuscript by the end of this project (see Phillips et al.). The experimental results of this project may be critical for advancing our understanding of (1) basic chemistry involving transition metals and reduced sulfur species, (2) the validity of certain geochemical proxies, and (3) the stability and evolution of euxinic geochemical environments. It is noted that the basic results obtained through this project also have implications for Mo-S cluster-based catalyst development in inorganic chemistry and materials sciences.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Low-Cost, High-Performance Electrochromic Devices (Final Technical Report)

The project goals were to develop low-cost electrochromic (EC) devices with organic dyes to pass ASTM E2141. The low-cost was also attributed to the simplified structure of these devices where capital equipment costs and process complexity to produce them was significantly reduced.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Microdroplet Electrospray Localized Laser Printing and Sintering of Nanoparticles for Passivating, Carrier-Selective Contacts (Final Technical Report)

In this project, the team used a nanoparticle electrospray laser deposition (NELD) process developed at the University of Central Florida (UCF) to address current limitations of passivating, carrier-selective contact technologies for crystalline silicon (c-Si) photovoltaic (PV) cells. The NELD process was used to print low bulk line resistivity Ag contacts directly onto transparent conductive oxides (TCOs), like indium tin oxide (ITO), for hydrogenated amorphous silicon (a-Si:H) based c-Si heterojunction (SHJ) cells without any subsequent contact firing step needed.

14 SOLAR ENERGY↗

Characterization of Contact Degradation in Crystalline Silicon Photovoltaic Modules (Final Technical Report)

In this project, the aim was to develop highly-automated metrology methods that can provide more insights into degradation and failure, while still relying on the types of measurements the PV industry and RD communities are comfortable with (e.g., I – V and EL). In particular, our focus was to develop techniques to better understand contact and interconnect degradation in crystalline silicon (c-Si) PV modules and apply those techniques to conventional and emerging c-Si cell architectures and cell interconnection technologies.

14 SOLAR ENERGY↗

Quantitative, trait-based microbial ecology to accurately model the impacts of nitrogen deposition on soil carbon cycling in the Anthropocene (Final Technical Report)

Atmospheric nitrogen pollution has altered fundamental soil processes, challenging our understanding of the extent to which soils will continue to sequester carbon and slow the pace of future environmental change. While most evidence shows that increases in soil nitrogen have enhanced carbon storage in temperate forests, it remains unclear whether these effects will persist as nitrogen pollution continues to decline. Moreover, there remains uncertainty as to why some forests gain more carbon in response to nitrogen pollution than others. At the heart of this knowledge gap is a failure to link nitrogen–induced shifts in microbial biodiversity with gains or losses in their functional ability to decompose, assimilate, and ultimately stabilize soil carbon. Given that this uncertainty impedes the ability of predictive models to project future soil carbon stocks, there is a critical need to determine how key microbial traits drive soil carbon responses to nitrogen pollution. As such the goals of this project were to: (1) Quantify variation in taxon–specific and community–level microbial traits across gradients in microbial community composition, mycorrhizal symbioses, and nitrogen availability. (2) Integrate empirical data into a novel predictive framework that enhances our ability to project the regional soil carbon consequences of historical nitrogen pollution in temperate forests.

54 ENVIRONMENTAL SCIENCES↗

Multifunctional Optical Outcouplers for Efficient and Stable White OLEDs (Final Technical Report)

Replacing fluorescence by phosphorescence in OLED-based solid-state lighting can realize the Department of Energy’s efficiency target of 83% Internal Quantum Efficiency (IQE). The principal challenge, however, is to fix the poor stability of phosphorescent blue OLEDs. To address this, we have fabricated novel plasmonic architectures that improve device stability by decreasing the exciton lifetime of the emitters without drastically decreasing the light extraction efficiency. We describe the impact on stability of these structures in high efficiency blue phosphorescent OLEDs. Although the benefit is appreciable, we find that targeting ‘bright’ triplets on phosphorescent emitter molecules is an incomplete solution, and that it is also necessary to stabilize ‘dark’ triplets formed in the host and blocking layers. We demonstrate substantial improvements in stability using the latter approach, and conclude with a discussion of potential approaches to managing dark triplets in OLEDs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The University of Virginia, Theoretical High Energy Physics (Final Technical Report)

We summarize research performed in the final reporting period of grant DE-SC0007984 for University of Virginia, Theoretical High Energy Physics. Progress was made on studying quantum mechanical effects in the showering of high energy particles inside a quark-gluon plasma, on the effects of extra dimensions on gravitational waves, and on expanding the use of what is known as the "worldline" formalism in quantum field theory.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Effects of hurricane disturbance and increased temperature on carbon cycling and storage of a Puerto Rican forest: a mechanistic investigation of above- and belowground processes (Final Technical Report)

The overall goal of the Tropical Responses for Altered Climate Experiment (TRACE) is to assess the effects of increasing temperature on tropical plant and soil carbon fluxes and storage as the forest recovers from major hurricane disturbance that occurred in September 2017. Ultimately, we aimed to reduce uncertainty and increase confidence with which tropical forests are represented in Earth System models to make more accurate global forecasts of future climate. We focused on both above- and belowground processes and explored temperature controls over critical aspects of carbon and nutrient cycling for tropical plants, soil, and microbes. TRACE is located in a wet tropical forest in the Luquillo Experimental Forest close to the USDA Forest Service Sabana Field Research Station in Luquillo, Puerto Rico. The warming treatment consists of six 4.7 m diameter plots. Three of the plots receive infrared warming and three have the same infrastructure but are not warmed (using ‘dummy’ heaters). Each plot was monitored from 2018-2023 to investigate two major questions: 1) Are there legacy effects of prior warming on forest recovery following hurricane disturbance? 2) Will the trajectory of forest recovery following disturbance be affected by warmer temperatures? Concurrent soil incubation experiments were conducted to enable more controlled mechanistic investigations of temperature response on microbial function. In sum, our goal was to use this novel climate manipulation experiment (the only of its kind in any tropical forest) and once-in-a-lifetime chance to assess how temperature and hurricane disturbance interact to affect coupled biogeochemical cycling in a tropical forest.

54 ENVIRONMENTAL SCIENCES↗

Microbial metabolic dependency and its impacts on the soil carbon cycle (Final Technical Report, DE-SC0016364)

The terrestrial biosphere contains a large fraction of global carbon (C) and nearly 70% of the organic C in terrestrial systems is found in soils. Global changes in atmospheric CO 2 , temperature, precipitation, and ecosystem N inputs, will impact primary production and carbon inputs to soils, but it remains difficult to predict soil responses to these environmental conditions. Our ability to predict C-cycle responses to global change remains limited by unexplained variability within the terrestrial C-cycle. Our difficulty in predicting responses of the soil C-cycle to environmental change suggests a need for a greater understanding of the biotic mechanisms that govern soil C-transformations. Changes in microbial community structure and function have been proposed to impact soil processes, but mechanistic connections between microbial activity and C-cycle transformations remain poorly described. We assembled an interdisciplinary team to conduct cross-scale examination of microbial contributions to C-cycle dynamics and C-fate in soils. We investigated microbial contributions to soil C-transformations using a suite of complementary isotopic techniques including DNA-Stable Isotope Probing (DNA-SIP), metagenomic-SIP, metabolomic-SIP, proteomic-SIP, and microspatial analysis of soil organic C. These techniques were deployed in experiments that tested fundamental assumptions that underlie terrestrial C-cycle models. We characterized the functional characteristics of soil microorganisms responsible for major C-transformations in soil, evaluated the metabolic and ecological interactions that underlie soil C-cycle dynamics, and evaluated the degree to which these interactions impact rates of C mineralization and stabilization in soils.

54 ENVIRONMENTAL SCIENCES↗

RADWIND Project Final Technical Report

The Rural Area Distributed Wind Integration Network Development (RADWIND) Project (January 2020-April 2023) was undertaken by NRECA Research, a not-for-profit subsidiary of NRECA focused on underwritten research, with the support of DOE. The project was part of the Wind Energy Technologies Office’s (WETO’s) Wind Integration for Rural Economic Development (WIRED) program, which was developed out of an October 2018 workshop in which NRECA participated in. RADWIND’s end of project goal was “to raise awareness of distributed wind as a solution for the energy, resiliency, and economic development needs of electric cooperatives, and to provide resources and information that reduce barriers and lower costs for co-ops seeking to deploy distributed wind. Through this project, NRECA Research seeks to establish a national distributed wind presence for and by NRECA’s members that delivers these benefits and plans to communicate NRECA’s members that properly deployed distributed wind can be a bankable technology option for rural America.”

17 WIND ENERGY↗

Physics of the thermal quench in MST tokamak plasmas (Final Technical Report)

This project at the University of Wisconsin-Madison targeted measurements in tokamak plasmas in the Madison Symmetric Torus (MST) to help elucidate the physics of the tokamak disruption. We intended to focus on the thermal quench, during which energy is lost from the plasma in a very short time. Understanding and ultimately mitigating the thermal quench are among the highest priority research thrusts for ITER, a large international fusion experiment presently under construction. The measurements in MST exploited an advanced set of diagnostics for internal measurements with high time resolution, targeting linear and nonlinear magnetohydrodynamic (MHD) activity as well as the electron temperature and density profiles. We also exploited other features of the MST device, including very flexible power supplies for the toroidal magnetic field and toroidal plasma current that are capable of producing almost arbitrary waveforms. While the work funded by this project was purely experimental, we continued and expanded an existing collaboration with UW-Madison experts in nonlinear MHD computational modeling of tokamak plasmas. That modeling incorporated realistic, experimentally measured parameters. The results of the modeling were anticipated to deepen considerably our understanding of the experimental measurements, and in turn, the experimental measurements were anticipated to help validate the modeling results. The science of transients such as disruptions is one of the highest priority research areas in the U.S. and international fusion programs. The work carried out in this project was targeted to help advance the science of tokamak disruptions which will in turn contribute to the success of ITER.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Biomimetic Light Harvesting Complexes Based on Self-Assembled Dye-DNA Nanostructures (Final Technical Report)

A fundamental limitation in the development of artificial molecular light harvesting structures is that generally if one places pigment molecules close enough to achieve very high energy transfer efficiency and absorbance cross section, the dyes interact in such a way that self-quenching occurs. This limits both the optical cross section and the overall efficiency of light capture in such systems. Nature overcomes this problem and achieves efficient energy transfer without self-quenching by controlling the environment, vibration characteristics, orientation and dynamics of the pigments involved in light harvesting. Natural light harvesting systems have evolved highly intricate chromophore architectures of protein-bound organic molecules that absorb and funnel solar energy with high efficiency and fast transfer rates using elegant excitonic circuitries. Nature achieves this precise control over the properties of pigment complexes by using specific proteins as templates to guide the formation of very well-defined pigment aggregates, groups of pigment molecules that are in close enough contact to undergo excitonic interactions resulting in new electronic properties that were not present in the monomer. In synthetic systems, pigment aggregates are well known, and J-aggregates and H-aggregates have been long studied for their unique properties. In Nature, the chlorosomes of green bacteria form what appear to be classical J-aggregates and the light harvesting complexes of purple nonsulfur bacteria form ring structures that have many of the properties of J-aggregates such as a red-shifted absorbance spectrum and excited states that are delocalized over multiple pigment molecules. These photosynthetic systems leverage the spectral and enhanced transport properties of J-like aggregates to achieve fast exciton transport within the antenna and thus high light-harvesting efficiency. The close interaction of the pigments results in substantial electronic coupling that lifts the degeneracy of excitonic states and therefore modifies the absorption and emission spectra of the monomer. In the case of J-aggregation, lower energy excitonic states acquire significant oscillator strength, resulting in a characteristic bathochromic shift of the absorption and fluorescence and often superradiant delocalized exciton states.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

The Atlantic Multidecadal Oscillation: Key Drivers and Climate Impacts (Final Technical Report)

The goal of this project was to investigate the Atlantic multidecadal variability (AMV) using a hierarchical modeling framework to advance our process-level understanding on the respective roles of, and the feedback between, the key drivers of the AMV, in particular the ocean circulation associated with the Atlantic meridional overturning circulation and stochastic atmospheric forcing, primarily due to the North Atlantic Oscillation. The focus was primarily on the AMV due to natural variability, but the investigation will be extended to the possible modulation on the main characteristics of AMV under external climate forcing. Furthermore, we examined the impact of the AMV, with a special emphasis on the possible augmentation of predictability the AMV may bring to the regional weather and climate of North America, Western Europe, and the Arctic. Under this goal, we have published 15 peer-reviewed journal papers, and presented our results in more than 30 conferences over the project duration.

58 GEOSCIENCES↗

Physics of the Aurora: Laboratory Measurements of Electron Acceleration by Inertial Alfven Waves (Final Technical Report)

The physics of the aurora is one of the foremost unsolved problems of space physics. The mechanisms responsible for accelerating electrons that precipitate onto the ionosphere are not fully understood. For more than three decades, particle interactions with Alfven waves have been proposed as a possible means for accelerating electrons and generating auroras. Due to the limitations of spacecraft conjunction studies and other multi-spacecraft approaches, it is unlikely that it will ever be possible, through spacecraft observations alone, to confirm definitively the proposed electron acceleration mechanism by making simultaneous measurements of both the accelerated electrons and the inertial Alfven wave responsible for the acceleration. Here, we show laboratory measurements of the resonant transfer of energy from Alfven waves to electrons under conditions relevant to the auroral zone. Experiments are performed by launching Alfven waves and simultaneously recording the electron velocity distribution. Numerical simulations and analytical theory support that the measured energy transfer process produces accelerated electrons capable of reaching auroral energies. The experiments, theory, and simulations demonstrate a clear causal relationship between Alfven waves and accelerated electrons that directly cause auroras.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Collaborative Research: Particle Simulation of Collisionless Magnetic Reconnection Under Finite Guide Field (Final Technical Report)

The project investigated 3-D linear instabilities of Harris current sheet under a realistic ion-to-electron mass ratio and a finite guide field. The excitation and 3-D properties of lower hybrid drift instability (LHDI), along with two new instabilities were demonstrated. The report presents the nonlinear properties of current sheet instabilities by employing Gyrokinetic electron and Fully kinetic ion (GeFi) particle simulation code. The GeFi simulation results are compared with fully kinetic PIC simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗