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At least 559 records · Page 31

Environmental Monitoring Report, Salmon, Mississippi, Site 2019

This report presents the monitoring results for groundwater and surface water samples collected in October 2019 by the U.S. Department of Energy (DOE) Office of Legacy Management for the Salmon, Mississippi, Site. The U.S. Atomic Energy Commission (AEC), a predecessor agency to DOE, conducted a series of underground detonations in the Tatum Salt Dome beneath the Salmon site between 1964 and 1970 to study seismic signatures. Groundwater sampling at the site is conducted to monitor shallow groundwater that became contaminated during AEC use of the site, contamination within the shot cavity, and contamination in the Aquifer 5 injection well. Surface water sampling is conducted to ensure no contaminants are leaving the site.

54 ENVIRONMENTAL SCIENCES↗

Zero-Valent Iron Permeable Reactive Barrier to Remediate Volatile Organic Compounds in Groundwater - 20209

The US DOE-SRS, the US EPA, and the South Carolina Department of Health and Environmental Control determined it was appropriate to perform a non-time critical removal action at the P-Area Groundwater Operable Unit at the SRS to reduce the mass and downgradient transport of trichloroethylene in the P-Area groundwater plume. Contaminated groundwater discharges to a nearby stream, Steel Creek, within the SRS boundaries, resulting in trichloroethylene concentrations above the maximum contaminant level. Impact to surface water is limited in areal extent and supported by recently collected characterization data. The P-Area Groundwater Operable Unit encompasses the groundwater beneath an industrial area within SRS, P Area, where the P-Reactor once operated. The boundaries of the P-Area Groundwater Operable Unit extend northwest to Steel Creek, northeast toward PAR Pond, and southeast to Meyers Branch. Groundwater in the Upper Three Runs Aquifer of the P-Area Groundwater Operable Unit has been impacted by reactor and facility operations between 1954 and 1991, including tritium and volatile organic compounds. The P-Area surface units contributing to groundwater contamination were remediated as part of the P-Area Operable Unit in 2011. The P-Reactor closure is one of the first of its kind in the DOE Complex and is one of only a few full-sized production reactors in the US to undergo completion of final closure activities. The nature and extent of groundwater contamination was determined using a variety of investigative approaches such as groundwater monitoring wells, direct-push technology, and surface water samples. Groundwater contamination associated with trichloroethylene is primarily exhibited in a narrow plume that extends from the source area at P-Reactor and west to Steel Creek. Maximum contaminant level exceedances in groundwater occur over an area of ∼6.9 hectares for trichloroethylene with concentrations as high as 7.7 milligrams per liter. To the west of the P-Area facility area, the trichloroethylene groundwater plume is controlled by a buried geologic feature, assumed to be an old stream bed, that further narrows the groundwater plume in what has been designated as the 'neck area.' This narrowing of the groundwater plume provides an ideal location for a treatment barrier. The non-time critical removal action alternative chosen is to install a zero-valent iron permeable reactive barrier within the neck area of the trichloroethylene groundwater plume, perpendicular to groundwater flow direction. This technology will provide a treatment barrier that will reduce trichloroethylene groundwater concentrations by 90% and has an anticipated useful life of at least 25 years. A pre-design investigation was performed in the neck area to confirm site lithology, hydrogeology, geochemistry, and extent of trichloroethylene contamination prior to a final design. A treatability study, conducted as part of the pre-design investigation, indicated that the subsurface and groundwater in the PArea Groundwater Operable Unit is compatible with the zero-valent iron and will not lead to excessive buildup from mineralization/precipitation or biofouling. Probabilistic modeling was conducted using field and laboratory data to determine the expected performance of the zero-valent iron permeable reactive barrier. The model simulations indicated that a 3.81-centimeter thick barrier would provide greater than 90% reduction of trichloroethylene groundwater concentration. The final design of the zero-valent iron permeable reactive barrier is a barrier that will extend 80.5 linear meters in a 'zigzag' orientation to best transect the trichloroethylene plume and account for varying groundwater flow. The barrier will be installed from 13.7 meters below ground surface to 41.1 meters below ground surface for 65.8 linear meters and from 13.7 meters below ground surface to 36.6 meters below ground surface for 14.6 linear meters, the base of which is 'keyed' into a low permeability zone. The barrier is designed to a thickness of 10.2 centimeters, which was determined to reduce the trichloroethylene groundwater concentrations by greater than 90% with a safety factor of 2.67. A total of approximately 689 metric tons of zero-valent iron will be injected through 22 injection wells spaced 3.66 meters apart, using guar to suspend the zero-valent iron. Zero-valent iron permeable reactive barrier construction will be monitored through 23 installed resistivity receivers offset 7.32 meters from the zerovalent iron permeable reactive barrier. The zero-valent iron will be energized with a low-voltage 100 Hertz signal during injection and will be monitored using the resistivity receivers to ensure complete coalescence of the zero-valent iron permeable reactive barrier. The zero-valent iron was sized to have a hydraulic conductivity greater than the natural subsurface, thus promoting groundwater flow through the barrier. As contaminated groundwater contacts the zero-valent iron, volatile organic compounds, including trichloroethylene, are immediately degraded to harmless compounds such as ethylene. The performance of the zero-valent iron permeable reactive barrier will be monitored using three upgradient monitoring well clusters, six downgradient monitoring well clusters, and four in-wall monitoring wells. The in-wall monitoring wells will indicate immediate reduction of trichloroethylene mass in the groundwater and allow analyses of the zero-valent iron permeable reactive barrier health. (authors)

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Black Carbon in Estuarine and Coastal Ocean Dissolved Organic Matter

Black carbon (BC) in ultrafiltered high-molecular-weight DOM (UDOM) was measured in surface waters of Delaware Bay, Chesapeake Bay and the adjacent Atlantic Ocean (USA) to ascertain the importance of riverine and estuarine DOM as a source of BC to the ocean. BC comprised 5-72% of UDOM-C (27+/-l7%) and on average 8.9+/-6.5% of dissolved organic carbon (DOC) with higher values in the turbid region of the Delaware Estuary and lower yields in the river and coastal ocean. The spatial and seasonal distributions of BC along the salinity gradient of Delaware Bay suggest that the higher levels of BC in surface water UDOM originated from localized sources, possibly from atmospheric deposition or released from resuspended sediments. Black carbon comprised 4 to 7% of the DOC in the coastal Atlantic Ocean, revealing that river-estuary systems are important exporters of colloidal BC to the ocean. The annual flux of BC from Delaware Bay UDOM to the Atlantic Ocean was estimated at 2.4x10(exp 10) g BC yr(exp -1). The global river flux of BC through DOM to the ocean could be on the order of 5.5x1O(exp 12)g BC yr (exp -1). These results support the hypothesis that the DOC pool is the intermediate reservoir in which BC ages prior to sedimentary deposition.

Mannino, Antonio↗

Characterizing the diverse hydrogeology underlying rivers and estuaries using new floating transient electromagnetic methodology

We report the hydrogeology below large surface water features such as rivers and estuaries is universally under-informed at the long reach to basin scales (tens of km+). This challenge inhibits the accurate modeling of fresh/saline groundwater interfaces and groundwater/surface water exchange patterns at management-relevant spatial extents. Here we introduce a towed, floating transient electromagnetic (TEM) system (i.e. FloaTEM) for rapid (up to 15 km/h) high resolution electrical mapping of the subsurface below large water bodies to depths often a factor of 10 greater than other towed instruments. The novel FloaTEM system is demonstrated at a range of diverse 4th through 6th-order riverine settings across the United States including 1) the Farmington River, near Hartford, Connecticut; 2) the Upper Delaware River near Barryville, New York; 3) the Tallahatchie River near Shellmound, Mississippi; and, 4) the Eel River estuary, on Cape Cod, near Falmouth, Massachusetts. Airborne frequency-domain electromagnetic and land-based towed TEM data are also compared at the Tallahatchie River site, and streambed geologic scenarios are explored with forward modeling. A range of geologic structures and pore water salinity interfaces were identified. Process-based interpretation of the case study data indicated FloaTEM can resolve varied sediment-water interface materials, such as the accumulation of fines at the bottom of a reservoir and permeable sand/gravel riverbed sediments that focus groundwater discharge. Bedrock layers were mapped at several sites, and aquifer confining units were defined at comparable resolution to airborne methods. Terrestrial fresh groundwater discharge with flowpaths extending hundreds of meters from shore was also imaged below the Eel River estuary, improving on previous hydrogeological characterizations of that nutrient-rich coastal exchange zone. In summary, the novel FloaTEM system fills a critical gap in our ability to characterize the hydrogeology below surface water features and will support more accurate prediction of groundwater/surface water exchange dynamics and fresh-saline groundwater interfaces.

54 ENVIRONMENTAL SCIENCES↗

Development of a computer-aided procedure for the national program of inspection of dams

An effort was undertaken to determine the utility of ERTS-1 MSS data, together with automatic data processing (ADP) techniques, to detect and locate surface water, and transfer the related technology to the Texas Water Rights Commission (TWRC). A test site was selected, ERTS-1 MSS and ancillary data obtained, and existent ADP classification programs applied. During the course of this effort a linear discriminant function was developed. The results were evaluated for potential candidates for a transferable procedure. A computer-aided technique using a linear discriminant function was selected and recommended, for inclusion in an operational system, which met detection and location criteria. Specifically, evaluation of the selected computer-aided procedure for the test site resulted in the detection of 100 percent of areas of surface water 10 acres or greater in areal extent and the geographic location of areas classified as water to a positional accuracy of 1000 feet or closer. The procedure was recommended for inclusion in an operational computer-aided procedure for transfer to TWRC.

Source record↗

Sulfur Geochemistry Destabilizes Population Oscillations of Wild Rice ( Zizania palustris )

Abstract Elevated inputs of sulfate to freshwater systems can increase sulfide concentrations in anoxic soils and subsequently destabilize aquatic plant populations, but the interactions between sulfate, other geochemical cycles, and interannual plant population cycles are poorly understood. Increased sulfate loading increases mineralization of nitrogen from litter, but the sulfide produced during this process can limit nitrogen uptake by plants. In some cases, iron may mitigate sulfide's impacts on plants by precipitating iron sulfide. We examined the interannual effects of sulfate loading on mesocosm populations of wild rice, an emergent aquatic plant that undergoes population oscillations and is sensitive to sulfide. Using experimental mesocosms with self‐perpetuating populations, we investigated how population dynamics respond to manipulations of surface water sulfate (10 mg L −1 or 300 mg L −1 ), sediment iron (4.3 mg g −1 or 10.9 mg g −1 dry weight), and shoot litter (present or removed). Populations exposed to constant 10 mg L −1 sulfate concentrations had stable biomass oscillations of approximately 3‐year periods, consistent with previous studies that demonstrated litter‐driven oscillations in nitrogen availability. Populations exposed to 300 mg L −1 sulfate concentrations produced fewer and smaller seeds and declined to extinction in 6 years or less. We did not find a strong effect of iron loading or litter removal on wild rice biomass or seed production. Our observations show the potential of elevated surface water sulfate to rapidly destabilize wild rice populations under varying iron and organic carbon concentrations.

59 BASIC BIOLOGICAL SCIENCES↗

Effects of boundary hydraulics, dissolved oxygen, and dissolved organic carbon on growth and death dynamics of aerobic microbes in riverbed dune-induced hyporheic zones

Surface and groundwater interact in the hyporheic zone beneath and adjacent to rivers in the presence of a diverse microbial community. Heterotrophic bacteria mediate a range of environmentally important reactions, yet few studies have quantified bacterial growth and death dynamics in the hyporheic zone, and none have systematically analyzed their response to variations in hydraulic or chemical conditions. Here we used MODFLOW and SEAM3D to simulate hydraulics; dissolved oxygen (DO) and dissolved organic carbon (DOC) transport; and aerobic microbial metabolism, growth, and death in hyporheic zones induced by riverbed dunes. We ran simulations both with and without growth/death processes, and varied hydraulic parameters and DO/DOC boundary concentrations. Microbial biomass reached steady state (t = 3 days) in every simulation, at which time there was greater biomass and DOC biodegradation rates in the hyporheic flowcell (300% and 85% higher for the base case, respectively) when accounting for microbial growth dynamics. This occurred as microbial biomass tailored its spatial distribution to the availability of DO and DOC, demonstrating the importance of simulating growth/death processes. Biomass generally increased with hyporheic flow cell area as upwelling groundwater decreased. When varying surface water DO and DOC source concentrations relative to the base case, the greatest effect on biomass occurred when increasing DOC and decreasing DO. We determined minimum DO and DOC steady-state concentrations required for microbial growth, but the minimums were not absolute or related by stoichiometry. Increasing DOC created a smaller area of microbes with higher concentrations relative to the base case. Increasing DO slightly increased the area occupied by microbes while keeping the total biomass nearly constant. Overall, microbial growth and death dynamics depend on DO and DOC availability in the hyporheic zone, which is dependent on DOC/DO boundary concentrations and hyporheic flow paths, and in turn the hydraulic interaction between surface water and groundwater.

54 ENVIRONMENTAL SCIENCES↗

The Impacts of Microphysics and Planetary Boundary Layer Physics on Model Simulations of U.S. Deep South Summer Convection

Convection-allowing numerical weather simula- tions have often been shown to produce convective storms that have significant sensitivity to choices of model physical parameterizations. Among the most important of these sensitivities are those related to cloud microphysics, but planetary boundary layer parameterizations also have a significant impact on the evolution of the convection. Aspects of the simulated convection that display sensitivity to these physics schemes include updraft size and intensity, simulated radar reflectivity, timing and placement of storm initi- ation and decay, total storm rainfall, and other storm features derived from storm structure and hydrometeor fields, such as predicted lightning flash rates. In addition to the basic parameters listed above, the simulated storms may also exhibit sensitivity to im- posed initial conditions, such as the fields of soil temper- ature and moisture, vegetation cover and health, and sea and lake water surface temperatures. Some of these sensitivities may rival those of the basic physics sensi- tivities mentioned earlier. These sensitivities have the potential to disrupt the accuracy of short-term forecast simulations of convective storms, and thereby pose sig- nificant difficulties for weather forecasters. To make a systematic study of the quantitative impacts of each of these sensitivities, a matrix of simulations has been performed using all combinations of eight separate microphysics schemes, three boundary layer schemes, and two sets of initial conditions. The first version of initial conditions consists of the default data from large-scale operational model fields, while the second features specialized higher- resolution soil conditions, vegetation conditions and water surface temperatures derived from datasets created at NASA's Short-term Prediction and Operational Research Tran- sition (SPoRT) Center at the National Space Science and Technology Center (NSSTC) in Huntsville, AL. Simulations as outlined above, each 48 in number, were conducted for five midsummer weakly sheared coastal convective events each at two sites, Mobile, AL (MOB) and Houston, TX (HGX). Of special interest to operational forecasters at MOB and HGX were accuracy of timing and placement of convective storm initiation, reflectivity magnitudes and coverage, rainfall and inferred lightning threat.

McCaul, Eugene W., Jr.↗

Comparative Habitability of Transiting Exoplanets

Exoplanet habitability is traditionally assessed by comparing a planet’s semimajor axis to the location of its host star’s “habitable zone,” the shell around a star for which Earth-like planets can possess liquid surface water. The Kepler space telescope has discovered numerous planet candidates near the habitable zone, and many more are expected from missions such as K2, TESS, and PLATO. These candidates often require significant follow-up observations for validation, so prioritizing planets for habitability from transit data has become an important aspect of the search for life in the universe. We propose a method to compare transiting planets for their potential to support life based on transit data, stellar properties and previously reported limits on planetary emitted flux. For a planet in radiative equilibrium, the emitted flux increases with eccentricity, but decreases with albedo. As these parameters are often unconstrained, there is an “eccentricity-albedo degeneracy” for the habitability of transiting exoplanets. Our method mitigates this degeneracy, includes a penalty for large-radius planets, uses terrestrial mass–radius relationships, and, when available, constraints on eccentricity to compute a number we call the “habitability index for transiting exoplanets” that represents the relative probability that an exoplanet could support liquid surface water. We calculate it for Kepler objects of interest and find that planets that receive between 60% and 90% of the Earth’s incident radiation, assuming circular orbits, are most likely to be habitable. Finally, we make predictions for the upcoming TESS and James Webb Space Telescope missions.

Planet and satellite surfaces↗

Sustaining On-going Risk Communication at the Riverton, Wyoming, Processing Site - 20310

An environmental risk assessment report has been completed to provide an updated assessment regarding current site conditions for the Riverton, Wyoming, Processing site. Argonne National Laboratory conducted the assessment in collaboration with the U.S Department of Energy (DOE) Office of Legacy Management (LM) and the Northern Arapaho Natural Resources Office (NANRO). The data quality objectives process conducted confirmed that data from plants growing on the Riverton site would be useful and would address an outstanding concern. Data available from site soil, groundwater, and surface water were also used in the assessment in conjunction with the new plant data. A plant survey was then conducted in 2018 to identify the plants at the Riverton site with known traditional Native American cultural uses for sampling and analysis. Laboratory analysis was conducted on the plant samples for the contaminants of concern. Samples were collected from plants growing on the groundwater plume area of the site, and the same was done for eight other areas not affected by the groundwater plume but still within the institutional control boundary. These eight areas served as reference areas for this study. This human health and ecological assessment update provide the quantitative risk information that was qualitatively addressed in a 1995 Risk Assessment Report on plants, livestock, and surface water exposures at the Riverton site [1]. The conditions at the Riverton site are protective of human health and the environment given the results of the update, in combination with past completed remedial action and ongoing monitoring activities and IC implementation. (authors)

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Subtropical Gyre Variability as Seen from Satellites

A satellite multi-sensor approach is used to analyse the biological response of open ocean regions of the subtropical gyres to changes in physical forcing. Thirteen years (1998-2010) of SeaWiFS chlorophyll a (Chl-a), combined with concurrent satellite records of sea-surface temperature (SST) and sea level height, were analysed to investigate the seasonal and interannual variability of Chl-a concentration within these immense so-called ocean deserts. The seasonal variability of Chl-a within the gyres is driven mostly by the warming/cooling of surface waters. Summer warming promotes shallower mixed layers and lower Chl-a due to a reduction of vertical mixing and consequently a decrease in nutrient supply. The opposite happens during the winter cooling period. Therefore, long-term trends in SST have the potential to cause an impact on the interannual variability of Chl-a. Our analyses show that, during the 13 whole years of SeaWiFS data record, the North Pacific, Indian Ocean, and North Atlantic gyres experienced a decrease in Chl-a of 9%, 12%, and 11%, respectively, with corresponding SST increases of 0.27 C, 0.42 C, and 0.32 C. The South Pacific and South Atlantic gyres also showed warming trends but with weak positive trends in Chl-a that are not statistically significant. We hypothesize that the warming of surface waters in these two gyres are counterbalanced by other interacting physical and biological driving mechanisms, as indicated in previous studies.

Signorini, Sergio R.↗

Solvation of furfural at metal–water interfaces: Implications for aqueous phase hydrogenation reactions

Metal–water interfaces are central to understanding aqueous-phase heterogeneous catalytic processes. However, the explicit modeling of the interface is still challenging as it necessitates extensive sampling of the interfaces’ degrees of freedom. Herein, we use ab initio molecular dynamics (AIMD) simulations to study the adsorption of furfural, a platform biomass chemical on several catalytically relevant metal–water interfaces (Pt, Rh, Pd, Cu, and Au) at low coverages. We find that furfural adsorption is destabilized on all the metal–water interfaces compared to the metal–gas interfaces considered in this work. This destabilization is a result of the energetic penalty associated with the displacement of water molecules near the surface upon adsorption of furfural, further evidenced by a linear correlation between solvation energy and the change in surface water coverage. To predict solvation energies without the need for computationally expensive AIMD simulations, we demonstrate OH binding energy as a good descriptor to estimate the solvation energies of furfural. Using microkinetic modeling, we further explain the origin of the activity for furfural hydrogenation on intrinsically strong-binding metals under aqueous conditions, i.e., the endothermic solvation energies for furfural adsorption prevent surface poisoning. In conclusion, our work sheds light on the development of active aqueous-phase catalytic systems via rationally tuning the solvation energies of reaction intermediates.

aqueous-phase hydrogenation↗

Independent Review of Groundwater Remediation Strategy for Hexavalent Chromium and RDX Groundwater Plumes at Los Alamos National Laboratory (Rev. 1)

Site operations at the Los Alamos National Laboratory (LANL) resulted in the release of oxidized chromium, Cr(VI), into Sandia Canyon from cooling tower effluent from 1956 until 1972. The chromium traveled with the surface water approximately 3 miles downstream before migrating below ground surface. Chromium concentrations exceed 50 μg/L in the upper portion of the aquifer. Another LANL groundwater plume of concern is associated with RDX (Royal Demolition Explosives, 1,3,5-trinitro-1,3,5-triazine). Between 1951 and 1996, RDX was released to the mesa-top facilities' process water outfall, adjacent and underlying soils, and alluvial sediments, along with surface water in Cañon de Valle. Between 2000 and 2010, two remedial actions were deployed, removing much of the near-surface RDX, however, recharge due to precipitation has transported RDX into the perched-intermediate zone and into the regional aquifer. The report documents an independent technical review by scientists from the Department of Energy (DOE) Network of National Laboratories for Environmental Management and Stewardship (NNLEMS) to provide recommendations for potential near term actions to address and optimize remediation for both the Cr(VI) and RDX plumes. The proposed near-term remedial actions include design of pump and treat systems for Cr(VI) and monitoring and study for natural attenuation for RDX. The review assesses existing data, conceptual and numerical modeling, and it recommends a technical integration process to support identifying and implementing strategic, effective and efficient remedies. The DOE Environmental Management Los Alamos Field Office (EM-LA) and their cleanup contractor Newport News Nuclear-BWTX, LLC Los Alamos (N3B) provided the information required for the review. Interviews were also conducted with regulators to obtain the full spectrum of technical, regulatory and scientific perspectives. The independent review team was impressed by the capabilities, experiences, innovativeness, and insightfulness of the technical representatives from both the regulator, the New Mexico Environment Department (NMED) and N3B. Incorporation of vadose zone flow pathways in the conceptual site model (CSM) and configuring the numerical modeling for the site was generally state-of-the-practice (or better). This could be considered state-of-the-art by addressing uncertainties related to spatial extent of hydraulic windows. The reviews from the regulators were thorough and often provided useful concepts for consideration and future/study resolutions. The overarching consensus recommendation of independent review team is that the LANL groundwater plumes should be addressed in context of the emerging "management of complex sites" paradigm.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Going With the Flow: Sedimentary Evolution of the Jezero Western Fan, Mars

Sedimentary fans developed at the mouths of Martian valleys have been interpreted as the deposits of sustained surface water flow on early Mars building either fluvial fan systems or deltas into standing bodies of water. Whilst much insight has been gleaned from orbital observations, it is only possible to constrain the character, relative timing and persistence of ancient aqueous activity on Mars through detailed on-the-ground interrogation of sedimentary successions built during fan growth. A prominent sedimentary fan deposit at the western margin of Jezero crater – the Western fan – has been interpreted from orbital data/observations to be a river delta that prograded into an ancient lake basin during the Late Noachian-Early Hesperian epochs on Mars (~3.6-3.8 Ga). The Western fan deposit forms a point-sourced depositional system developed at the mouth of Neretva Vallis, a valley system that is incised across the crater rim and has an extensive extra-crater catchment draining over diverse ancient geological units in Nili Planum. The mechanism of crater rim breaching remains unconstrained. Between 2022 and 2023, the Mars 2020 Perseverance rover explored the Western fan, with the objective of characterizing its paleoenvironmental context and collecting a diverse suite of sedimentary rock samples for return to Earth via the Mars Sample Return mission. Perseverance has now completed her traverse across the Western fan having commenced in the distal downstream sectors exposed at the erosional front of the fan and then crossing across its upper exposed surface toward the fan apex region near the mouth of Neretva Vallis. This transect provides a unique window into a Martian sediment routing system at a time when climate conditions permitted the flow of surface water. In this contribution, we review the overall sedimentary architecture of the fan and develop a model for its evolution based on detailed mapping of lithofacies changes across the fan. A first-order synoptic overview is presented.

Mars 2020↗

The Three Sources of Gas in the Comae of Comets

Surface water ice on a comet nucleus is the major source of coma gas. Dust, entrained by coma gas, fragments and vaporizes, forming a second, distributed source of coma gas constituents. Ice species more volatile than water ice below the surface of the nucleus are a third source of coma gas. Vapors from these ices, produced by heat penetrating into the nucleus, diffuse through pores outward into the coma. The second and third sources provide minor, but sometimes easily detectible, gaseous species in the coma. We present mixing ratios of observed minor coma constituents relative to water vapor as a function of heliocentric and cometocentric distances and compare these ratios with model predictions, assuming the sources of the minor species are either coma dust or volatile ices in the nucleus.

Three Sources Comets↗

Stone Content Influence on Land Surface Model Simulation of Soil Moisture and Evapotranspiration at Reynolds Creek Watershed

Considerable advancement in spatiotemporal resolution of remote sensing and ground-based measurements has enabled refinement of parameters used in land surface models for simulating surface water fluxes. However, land surface modeling capabilities are still inadequate for accurate representation of subsurface properties and processes, which continue to limit the accuracy of land surface model simulation. Our objective in this study was to examine the performance of the variously parameterized Noah-Multiphysics (Noah-MP) land surface model and to improve simulations of evapotranspiration (ET) and soil moisture dynamics in stony soils using verification from eddy covariance ET and in-situ soil moisture data. Meteorological and eddy covariance data from the Lower Sheep sub-catchment within the Reynolds Creek Experimental Watershed in Southwestern Idaho were employed to drive Noah-MP and to assess simulation results. We evaluated the performance of Noah-MP considering four different scenarios: (1) A one-layer soil profile with Noah-MP default soil hydraulic parameters, followed by five-layer soil profiles using -(2) Noah-MP default soil hydraulic parameters -(3) soil hydraulic parameters derived from a pedotransfer function using field observations, and -(4) hydraulic parameters from (3) which also accounted for stone content in each layer. Each modeling experiment was forced with the same set of initial conditions, atmospheric input and vegetation parameters. Our results indicated that enhanced representation of soil profile properties and stone content information noticeably improve the Noah-MP land surface model simulation of soil moisture content and evapotranspiration.

Land surface models, Soil hydrology, Noah-MP, Evap↗