Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “surface mass variations”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Heat transfer in the tip region of a rotor blade simulator

In gas turbines, the blades of axial turbine stages rotate in close proximity to a stationary peripheral wall. Differential expansion of the turbine wheel, blades, and the shroud causes variations in the size of the clearance gap between blade tip and stationary shroud. The necessity to tolerate this differential thermal expansion dictates that the clearance gap cannot be eliminated altogether, despite accurate engine machining. Pressure differences between the pressure and suction sides of a blade drives a flow through the clearance gap. This flow, the tip leakage flow, is detrimental to engine performance. The primary detrimental effect of tip leakage flow is the reduction of turbine stage efficiency, and a second is the convective heat transfer associated with the flow. The surface area at the blade tip in contact with the hot working gas represents an additional thermal loading on the blade which, together with heat transfer to the suction and pressure side surface area, must be removed by the blade internal cooling flows. Experimental results concerned with the local heat transfer characteristics on all surfaces of shrouded, rectangular cavities are reported. A brief discussion of the mass transfer system used is given.

Chyu, M. K.↗
NASA NTRS1989

The inverse gravimetric problem in gravity modelling

One of the main purposes of geodesy is to determine the gravity field of the Earth in the space outside its physical surface. This purpose can be pursued without any particular knowledge of the internal density even if the exact shape of the physical surface of the Earth is not known, though this seems to entangle the two domains, as it was in the old Stoke's theory before the appearance of Molodensky's approach. Nevertheless, even when large, dense and homogeneous data sets are available, it was always recognized that subtracting from the gravity field the effect of the outer layer of the masses (topographic effect) yields a much smoother field. This is obviously more important when a sparse data set is bad so that any smoothing of the gravity field helps in interpolating between the data without raising the modeling error, this approach is generally followed because it has become very cheap in terms of computing time since the appearance of spectral techniques. The mathematical description of the Inverse Gravimetric Problem (IGP) is dominated mainly by two principles, which in loose terms can be formulated as follows: the knowledge of the external gravity field determines mainly the lateral variations of the density; and the deeper the density anomaly giving rise to a gravity anomaly, the more improperly posed is the problem of recovering the former from the latter. The statistical relation between rho and n (and its inverse) is also investigated in its general form, proving that degree cross-covariances have to be introduced to describe the behavior of rho. The problem of the simultaneous estimate of a spherical anomalous potential and of the external, topographic masses is addressed criticizing the choice of the mixed collection approach.

Sanso, F.↗
NASA NTRS1993

Research on Earth's rotation and the effect of atmospheric pressure on vertical deformation and sea level variability

The work done under NASA grant NAG5-485 included modelling the deformation of the earth caused by variations in atmospheric pressure. The amount of deformation near coasts is sensitive to the nature of the oceanic response to the pressure. The PSMSL (Permanent Service for Mean Sea Level) data suggest the response is inverted barometer at periods greater than a couple months. Green's functions were constructed to describe the perturbation of the geoid caused by atmospheric and oceanic loading and by the accompanying load-induced deformation. It was found that perturbation of up to 2 cm are possible. Ice mass balance data was used for continental glaciers to look at the glacial contributions to time-dependent changes in polar motion, the lod, the earth's gravitational field, the position of the earth's center-of-mass, and global sea level. It was found that there can be lateral, non-hydrostatic structure inside the fluid core caused by gravitational forcing from the mantle, from the inner core, or from topography at the core/mantle or inner core/outer core boundaries. The nutational and tidal response of a non-hydrostatic earth with a solid inner core was modeled. Monthly, global tide gauge data from PSMSL was used to look at the 18.6-year ocean tide, the 14-month pole tide, the oceanic response to pressure, the linear trend and inter-annual variability in the earth's gravity field, the global sea level rise, and the effects of post glacial rebound. The effects of mantle anelasticity on nutations, earth tides, and tidal variation in the lod was modeled. Results of this model can be used with Crustal Dynamics observations to look at the anelastic dissipation and dispersion at tidal periods. The effects of surface topography on various components of crustal deformation was also modeled, and numerical models were developed of post glacial rebound.

Wahr, John↗
NASA NTRS2010

The Hot Horizontal-Branch Stars in omega Centauri

Context. UV observations of some massive globular clusters have revealed a significant population of stars hotter and fainter than the hot end of the horizontal branch (HB), the so-called blue hook stars. This feature might be explained either by the late hot flasher scenario where stars experience the helium flash while on the white dwarf cooling curve or by the progeny of the helium-enriched sub-population recently postulated to exist in some clusters. Previous spectroscopic analyses of blue hook stars in co Cen and NGC 2808 support the late hot flasher scenario, but the stars contain much less helium than expected and the predicted C, N enrichment could not be verified. Aims. We compare observed effective temperatures, surface gravities, helium abundances, and carbon line strengths (where detectable) of our targets stars to the predictions of the two scenarios. Methods. Moderately high resolution spectra of hot HB stars in the globular cluster omega-Cen were analysed for radial velocity variations, atmospheric parameters and abundances using LTE and non-LTE model atmospheres. Results. We find no evidence for close binaries among our target stars. All stars below 30 000 K are helium-poor and very similar to HB stars observed in that temperature range in other globular clusters. In the temperature range 30000 K to 50000 K we find that 28% of our stars are helium-poor (log ((sup n)He/(sup n )H)< - 1.6), while 72% have roughly solar or super-solar helium abundance (log ((sup n)He/(sup n )H) >/= -1.5). We also find carbon enrichment strongly correlated with helium enrichment, with a maximum carbon enrichment of 3% by mass. Conclusions. The strong carbon enrichment in tandem with helium enrichment is predicted by the late hot flasher scenario, but not by the helium-enrichment scenario. We conclude that the helium-rich HB stars in omega-Cen cannot be explained solely by the helium-enrichment scenario invoked to explain the blue main sequence.

Moehler, S.↗
NASA NTRS2014

New Martian Meteorite Is One of the Most Oxidized Found to Date

As of 2013, about 60 meteorites from the planet Mars have been found and are being studied. Each time a new Martian meteorite is found, a wealth of new information comes forward about the red planet. The most abundant type of Martian meteorite is a shergottite; its lithologies are broadly similar to those of Earth basalts and gabbros; i.e., crustal igneous rocks. The entire suite of shergottites is characterized by a range of trace element, isotopic ratio, and oxygen fugacity values that mainly reflect compositional variations of the Martian mantle from which these magmas came. A newly found shergottite, NWA 5298, was the focus of a study performed by scientists within the Astromaterials Research and Exploration Science (ARES) Directorate at the Johnson Space Center (JSC) in 2012. This sample was found in Morocco in 2008. Major element analyses were performed in the electron microprobe (EMP) laboratory of ARES at JSC, while the trace elements were measured at the University of Houston by laser inductively coupled plasma mass spectrometry (ICPMS). A detailed analysis of this stone revealed that this meteorite is a crystallized magma that comes from the enriched end of the shergottite spectrum; i.e., trace element enriched and oxidized. Its oxidation comes in part from its mantle source and from oxidation during the magma ascent. It represents a pristine magma that did not mix with any other magma or see crystal accumulation or crustal contamination on its way up to the Martian surface. NWA 5298 is therefore a direct, albeit evolved, melt from the Martian mantle and, for its lithology (basaltic shergottite), it represents the oxidized end of the shergottite suite. It is thus a unique sample that has provided an end-member composition for Martian magmas.

Hui, Hejiu↗
NASA NTRS2021

Effect of Preconditioning on Post-Soldering Failures in Tantalum Capacitors

Soldering have a strong effect on performance and reliability of most surface mount technology components, including tantalum capacitors. High quality tantalum capacitors are likely the only type of components where soldering simulation is the first step during screening. Nevertheless, post-soldering failures of tantalum capacitors do happen and require additional analysis. Popcorning is a well-known effect in plastic encapsulated microcircuits (PEM) and it occurs also in chip tantalum capacitors. The sensitivity of parts to the presence of moisture during soldering is characterized by the moisture sensitivity level (MSL); however, contrary to PEMs, there is no standard procedure for establishing MSL for tantalum capacitors, and standard J-STD-020 is applicable partially only. In this work, the effect of absorbed moisture on soldering related degradation and failures in tantalum capacitors have been studied using 22 types of polymer and 11 types of MnO2 cathodes tantalum capacitors including single and multianode parts. The amount of moisture released during soldering has been estimated by measurements of mass and capacitance variations. Results show that moisture uptake in similar parts is approximately two times greater in polymer than in MnO2 capacitors. Cracking of the case and degradation of parameters can occur in both types of parts, but MnO2 capacitors are much more susceptible to catastrophic short circuit failures and their ignition is possible during the first power-on cycle. This type of failure in MnO2 capacitors is lot-related, can occur even at derated voltages and relatively low levels of moisture sorption corresponding to room conditions. Baking before soldering is an effective measure to prevent failures even in lots susceptible to popcorning damage. Recommendations for testing to establish MSL and for baking to reduce the probability of failures are suggested.

tantalum polymer capacitors↗
DOE OSTI2020

A new phenomenological model to describe root-soil interactions based on percolation theory

In his paper on net primary productivity of terrestrial communities predicted from climatological data, Rosenzweig (1968) argued that variability in productivity is well accounted for by (evapo)-transpiration, and that water from transpiration is, on global scales, the most variable component in the photosynthesis reaction. The goal of this paper is to investigate whether variability in plant growth on local scales and within species is primarily related to transpiration under several scenarios including different terrain curvature, slope aspect, soil characteristics, and climate ranges. Here, we test the hypothesis that this relationship exists because root growth into the surface soil layers (0–2 m) tends to follow paths with minima in resistance, which in turn maximizes water flow and nutrient delivery rates that regulate growth. The set of all connected paths with individual pore-to-pore flow resistances less than a critical, percolating, value forms a cluster with mass fractal dimensionality, d f . We propose that roots follow paths through the 2D percolation cluster, defining the set of all optimal flow paths, making the 2D value of d f from percolation relevant to root fractal dimensionality. The tortuosity of such optimal paths as defined in percolation theory should then relate root length to root radial extent, linking the parameters of root tortuosity and plant productivity. Our analysis of large data sets across species implies that root radial extent and tree height are both proportional to cumulative transpiration until trees approached maximum height, and their growth rates are proportional to the transpiration rate, not to the moisture content. Local variations in tree height as functions of the variables investigated appear generally consistent with deduced variations in transpiration. Here this correlation is investigated more closely in the context of studies addressing individual tree species.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Jets from shocked metal surfaces with grooves: Missing experiments

Many studies have investigated the mass outflows generated when a planar shock transits an imperfect (“defected”) metal surface, where the defects are symmetric triangular or sinusoidal grooves. Yet a fundamental question remains unanswered: how does the quantity of outflow mass and its maximum velocity vary as a function of the groove cross-sectional aspect ratio? We identify two sets of missing experiments that must be addressed to answer the question. The aspect ratio (groove depth over width) is equivalently represented by θ, the cross sectional half angle, or by η 0 k, the amplitude multiplied by an effective wavenumber. Low θ (high η 0 k) grooves comprise the first set of missing experiments, which are necessary to determine the validity of theoretical predictions of the nonlinear regime (η 0 k ≥ 1, θ < 57.5°). The second set of missing experiments are those in which the volume of the groove (or equivalently, the axial cross-sectional area) has been held constant as θ or η 0 k are varied. Such experiments are necessary to independently measure the effects of variations in groove volume and groove aspect ratio on the resulting jets.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

Comparative Evaluation of the Ability of the MYNN‐EDMF PBL Scheme in WRF Model to Reproduce Near Surface Wind Speed Over Different Topographical Types

Abstract This study systematically evaluates the performance of the Mellor‐Yamada‐Nakanishi‐Niino‐Eddy‐Diffusion‐Mass‐Flux planetary boundary layer (PBL) scheme within the Weather Research and Forecasting (WRF) model in simulating near‐surface wind speeds across various topographies in New York State (NYS). Simulated wind speeds are compared with in‐situ measurements from 22 surface sites, grouped into six topographic categories: continental plain (CT), lakeside (LS), river valley (RV), Long Island (LI), Block Island (BI), and offshore ocean (OO). A quantitative evaluation based on Relative Euclidean Distance shows that wind speeds at the OO site are the most accurately reproduced, followed by those at LI sites, while the model performs less accurately for the remaining topographic groups. Wind speeds over CT sites tend to be overestimated by approximately 1 m/s, although their diurnal variability (DV) is well captured. In contrast, the model underestimates wind DV at LS, RV, LI, and BI sites, with the largest biases occurring at LI and BI, resulting in underestimated daytime wind speed and/or overestimated nighttime wind speed. The OO winds exhibit minimal diurnal variation, accurately captured by our WRF model. The surface wind diurnal variation is closely linked to PBL development. Among the indicators of PBL development, surface potential temperature biases most strongly correlate with wind speed biases. Our WRF model faces challenges in capturing the distinctions between winds influenced by local circulations and those over continental plains, and the significantly stronger winds at OO compared to BI. Potential causes for these biases are discussed, offering pathways for improving surface wind simulations in future.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Jets from shocked metal surfaces with grooves: Missing experiments

Many studies have investigated the mass outflows generated when a planar shock transits an imperfect (“defected”) metal surface, where the defects are symmetric triangular or sinusoidal grooves. Yet a fundamental question remains unanswered: how does the quantity of outflow mass and its maximum velocity vary as a function of the groove cross-sectional aspect ratio? We identify two sets of missing experiments that must be addressed to answer the question. The aspect ratio (groove depth over width) is equivalently represented by θ, the cross-sectional half angle, or by η 0 k, the amplitude multiplied by an effective wavenumber. Low θ (high η 0 k) grooves comprise the first set of missing experiments, which are necessary to determine the validity of theoretical predictions of the nonlinear regime (η 0 k ≥ 1, θ < 57.5°). The second set of missing experiments are those in which the volume of the groove (or equivalently, the axial cross-sectional area) has been held constant as θ or η 0 k are varied. Such experiments are necessary to independently measure the effects of variations in groove volume and groove aspect ratio on the resulting jets.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2019

Seasonal Variations in Atmospheric Composition as Measured in Gale Crater, Mars

The Sample Analysis at Mars (SAM) instrument onboard the Mars Science Laboratory Curiosity rover measures the chemical composition of major atmospheric species (CO2, N2, 40Ar,O2, and CO) through a dedicated atmospheric inlet. We report here measurements of volume mixing ratios in Gale Crater using the SAM quadrupole mass spectrometer, obtained over a period of nearly 5 years (3 Mars years) from landing. The observation period spans the northern summer of MY31 and solar longitude (L(sub S)) of 175° through spring of MY 34, L(sub S) = 12°. This work expands upon prior reports of the mixing ratios measured by SAM QMS in the first 105 sols of the mission. The SAM QMS atmospheric measurements were taken periodically, with a cumulative coverage of four or five experiments per season on Mars. Major observations include the seasonal cycle of CO2, N2, and Ar, which lags approximately 20–40° of L(sub S) behind the pressure cycle driven by CO2 condensation and sublimation from the winter poles. This seasonal cycle indicates that transport occurs on faster timescales than mixing. The mixing ratio of O2 shows significant seasonal and interannual variability, suggesting an unknown atmospheric or surface process at work. The O2 measurements are compared to several parameters, including dust optical depth and trace CH4 measurements by Curiosity. We derive annual mean volume mixing ratios for the atmosphere in Gale Crater: CO2 = 0.951 (±0.003), N2 = 0.0259 (±0.0006), 40Ar = 0.0194 (±0.0004), O2 = 1.61 (±0.09) x 10(exp ‐3), and CO = 5.8 (±0.8) x 10(exp ‐4).

Gale Crater↗
NASA NTRS2013

GRAIL Refinements to Lunar Seismic Structure

Joint interpretation of disparate geophysical datasets helps to reduce drawbacks that can result from analyzing them individually. The Apollo seismic network was situated on the lunar nearside surface in a roughly equilateral triangle having sides approximately 1000 km long, with stations 12/14 nearly co‐located at one corner. Due to this limited geographical extent, near‐surface ray coverage from moonquakes is low, but increases with depth. In comparison, gravity surveys and their resulting gravity anomaly maps have traditionally offered optimal resolution at crustal depths. Gravimetric maps and seismic data sets are therefore well suited to joint inversion, since the complementary information reduces inherent model ambiguity. Previous joint inversions of the Apollo seismic data (seismic phase arrival times) and Clementine‐ or Lunar Prospector‐derived gravity data (mass and moment of inertia) attempted to recover the subsurface structure of the Moon by focusing on hypothetical lunar compositions that explore the density/velocity relationship. These efforts typically search for the best fitting thermodynamically calculated velocity/density model, allowing variables like core size, velocity, and/or composition to vary freely. Seismic velocity profiles previously derived from the Apollo seismic data through inversion of travel times vary both in the depth of the crust and mantle layers, and the seismic velocities and densities assigned to those layers. The lunar mass and moment of inertia likewise only constrain gross variations in the density profile beyond that of a uniform density sphere. As a result, composition and structure models previously obtained by jointly inverting these data retain the original uncertainties inherent in the input data sets. We will perform a joint inversion of Apollo seismic delay times and gravity data collected by the GRAIL lunar gravity mission, in order to recover seismic velocities and density as a function of latitude, longitude, and depth within the Moon. We will relate density to seismic velocity using a linear relationship that is allowed to be depth‐dependent. The corresponding coefficient (B) can reflect a variety of material properties that vary with depth, including temperature and composition. The inversion seeks to recover the set of density, velocity, and B‐coefficient perturbations that minimize (in a least‐squares sense) the difference between the observed and calculated data.

Weber, Renee C.↗
NASA NTRS2014

GRAIL Refinements to Lunar Seismic Structure

Joint interpretation of disparate geophysical datasets helps reduce drawbacks that can result from analyzing them individually. The Apollo seismic network was situated on the lunar nearside surface in a roughly equilateral triangle having sides approximately 1000 km long, with stations 12/14 nearly co-located at one corner. Due to this limited geographical extent, near-surface ray coverage from moonquakes is low, but increases with depth. In comparison, gravity surveys and their resulting gravity anomaly maps have traditionally offered optimal resolution at crustal depths. Gravimetric maps and seismic data sets are therefore well suited to joint inversion, since the complementary information reduces inherent model ambiguity. Previous joint inversions of the Apollo seismic data (seismic phase arrival times) and Clementine- or Lunar Prospector-derived gravity data (mass and moment of inertia) attempted to recover the subsurface structure of the Moon by focusing on hypothetical lunar compositions that explored the density/velocity relationship. These efforts typically searched for the best fitting thermodynamically calculated velocity/density model, and allowed variables like core size, velocity, and/or composition to vary freely. Seismic velocity profiles derived from the Apollo seismic data through travel time inversion vary both in the depth of the crust and mantle layers, and the seismic velocities and densities assigned to those layers. The lunar mass and moment of inertia likewise only constrain gross variations in the density profile beyond that of a uniform density sphere. As a result, composition and structure models previously obtained by jointly inverting these data retain the original uncertainties inherent in the input data sets. We perform a joint inversion of Apollo seismic delay times and gravity data collected by the GRAIL lunar gravity mission, in order to recover seismic velocity and density as a function of latitude, longitude, and depth within the Moon. We relate density (p) to seismic velocity (v) using a depth-dependent linear relationship. The corresponding coefficient (B) can reflect a variety of material properties, including temperature and composition. The inversion seeks to recover the set of p, v, and B perturbations that minimize (in a least-squares sense) the difference between the observed and calculated data.

Weber, Renee C.↗
NASA NTRS1996

Modelling the Soft X-Ray and EUV Emission in Classical Novae: EUVE and ROSAT Observations of V1974 Cygni

We have conducted an extensive analysis of the observability of Classical Novae with the EUVE Lex/B and Al/Ti/C detectors. Predicted count rates have been computed using optically thin, isothermal plasma models for solar and metal-rich compositions, and hot ONeMg white dwarf model atmospheres. We find EUVE to be quite sensitive to both the EUV and soft X-ray emission emitted by the underlying hot white dwarf during novae outbursts, except for the coolest temperatures with very high intervening hydrogen column density. These results are used to interpret the emission detected during the EUVE all-sky survey of Nova Cygni 1992 (approx. = V1974 Cyg), 279-290 days after visual maximum. We find the best fit to the observed emission from V1974 Cyg arises from a hot ONeMg white dwarf with surface temperature approx. 4 x l0(exp 5) K and a mas of approx. 1.2 solar mass, and derive an interstellar hydrogen column density of approx. 3 x 10(exp 21)/sq cm. Virtually all this emission arises from supersoft X-rays rather than the EUV. We also report the detection of V1974 Cyg with the EUVE Deep Survey detector at 549 days after visual maximum. This observation is compatible with the above properties, indicating that the mechanism responsible for the soft X-ray emission, connected with the underlying white dwarf, had not yet entirely turned off. We also present analysis of a ROSAT PSPC observation which is contemporaneous with the EUVE survey observations; this independently confirms the high column density we derived from the EUVE survey observation. Light curves for the EUVE and ROSAT observations are presented. Statistical tests for variability show that all of these observations are indeed highly variable over various time scales. The EUVE survey data shows one day variations, the EUVE DS data show approx. 30 minute fluctuations, while the ROSAT data vary rapidly on time scales of seconds. The EUVE data shows no periodic variability on any time scale. The implications of the rapid variability are briefly discussed.

Stringfellow, Guy S.↗
NASA NTRS1994

Spectral variations in the low-mass X-ray binary 4U 0614+09

We report the X-ray spectra of a binary 4U 0614+09 observed with EXOSAT on five different occasions in 1984 and 1986. In four observations in 1984, the source intensity was 'low' compared to its intensity in the 1986 observation. The source was steady on timescales of 10 to 1000 s in each of the 1984 observations but highly variable during the 1986 variations. The best-fit spectral models for the continuum are a blackbody spectrum plus an emission from a Comptonized region. In addition, a component due to reflection from a cold disk around the source was needed as an absorbiton edge due to cold or ionized iron was seen near 7 keV with good significance in most of the spectra, particularly in the 'low' state. The relation of the hardness ratios with intensity follow the behavior seen in the 'Atoll' sources. We have studied the behavior of the hardness ratios with the variations in the parameters of the best-fit spectral models. Most of the variability is associated with the blackbody component thought to arise from the boundary layer on the surface of the neutron star. During the 'high' state in 1986, the blackbody temperature is higher, its size smaller, and its contribution significantly greater than in the 'low' state. The other notable difference between the two states is the lower opacity in the Comptonized region, and a significantly higher absorption in the 'high' state. A weak line emission (equivalent width = 10 to 40 eV) is detected during the 'high' state. The line energy lies between 6 and 7 keV wh ich implies its origin from ionized iron.

Singh, K. P.↗
NASA NTRS2012

A Near-Infrared and Thermal Imager for Mapping Titan's Surface Features

Approximately 10% of the solar insolation reaches the surface of Titan through atmospheric spectral windows. We will discuss a filter based imaging system for a future Titan orbiter that will exploit these windows mapping surface features, cloud regions, polar storms. In the near-infrared (NIR), two filters (1.28 micrometer and 1.6 micrometer), strategically positioned between CH1 absorption bands, and InSb linear array pixels will explore the solar reflected radiation. We propose to map the mid, infrared (MIR) region with two filters: 9.76 micrometer and 5.88-to-6.06 micrometers with MCT linear arrays. The first will map MIR thermal emission variations due to surface albedo differences in the atmospheric window between gas phase CH3D and C2H4 opacity sources. The latter spans the crossover spectral region where observed radiation transitions from being dominated by thermal emission to solar reflected light component. The passively cooled linear arrays will be incorporated into the focal plane of a light-weight thin film stretched membrane 10 cm telescope. A rad-hard ASIC together with an FPGA will be used for detector pixel readout and detector linear array selection depending on if the field-of-view (FOV) is looking at the day- or night-side of Titan. The instantaneous FOV corresponds to 3.1, 15.6, and 31.2 mrad for the 1, 5, and 10 micrometer channels, respectively. For a 1500 km orbit, a 5 micrometer channel pixel represents a spatial resolution of 91 m, with a FOV that spans 23 kilometers, and Titan is mapped in a push-broom manner as determined by the orbital path. The system mass and power requirements are estimated to be 6 kg and 5 W, respectively. The package is proposed for a polar orbiter with a lifetime matching two Saturn seasons.

Aslam, S.↗
NASA NTRS2019

The Distribution, Composition, and Particle Properties of Mars Mesospheric Aerosols: an Analysis of CRISM Visible/near-IR Limb Spectra with Context from Near-Coincident MCS and MARCI Observations

The Compact Reconnaissance Imaging Spectral Mapper (CRISM) onboard the Mars Reconnaissance Orbiter (MRO) obtains pole-to-pole observations (i.e., full MRO orbits) of vertical profiles for visible/near-IR spectra (λ=0.4–4.0 μm), which are ideally suited to identifying the composition and particle sizes of Mars ice and dust aerosols over 50–100 km altitudes in the Mars mesosphere. Within the coverage limitations of the CRISM limb data set, a distinct compositional dichotomy is found in Mars mesospheric ice aerosols. CO2 ice clouds appear during the aphelion period of Mars orbit (Solar Longitudes, Ls∼0–160°) at low latitudes (∼20S–10N) over specific longitude regions (Meridiani, Valles Marineris) and at typical altitudes of 55–75 km. Apart from faint water ice hazes below 55 km, mesospheric H2O ice clouds are primarily restricted to the perihelion orbital range (Ls∼160 – 350°) at northern and southern mid-to-low latitudes with less apparent longitudinal dependences. Mars mesospheric CO2 clouds are presented in CRISM spectra with a surprisingly large range of particle sizes (cross section weighted radii, Reff=0.3 to 2.2 μm). The smaller particle sizes (Reff ≤1 μm) appear concentrated near the spatial (latitude and altitude) boundaries of their global occurrences. CRISM spectra of mesospheric CO2 clouds also show evidence of iridescence, indicating very narrow particle size distributions (effective variance, Veff∼0.03) and so very abrupt CO2 cloud nucleation. Furthermore, these clouds are sometimes accompanied by altitude coincident peaks in 1.27 μm O2 dayglow, which indicates very dry, cold regions of formation. Mesospheric water ice clouds generally exhibit small particle sizes (Reff=0.1–0.3 μm), although larger particle sizes (Reff=0.4–0.7 μm) appear infrequently. On average, water ice cloud particle sizes decrease with altitude over 50–80 km in the perihelion mesosphere. Water ice mass appears similar in clouds over a large range of observed cloud particle sizes, with particle number densities increasing to ∼10 cm−3 for Reff=0.2 μm. Near coincident Mars Climate Sounder (MCS) temperature and aerosol profile measurements for a subset of CRISM mesospheric aerosol measurements indicate near saturation (H2O and CO2) conditions for ice clouds and distinct mesospheric temperature increases associated with mesospheric dust loading. Dayside (3 pm) mesospheric CO2 clouds with larger particle sizes (Reff ≥0.5 μm) scatter surface infrared emission in MCS limb infrared radiances, as well as solar irradiance in the MCS solar band channel. Scattering of surface infrared emission is most strikingly presented in nighttime (3 am) MCS observations at 55–60 km altitudes, indicating extensive mesospheric nighttime CO2 clouds with considerably larger particle sizes (Reff∼7 μm). Mesospheric CO2 ice clouds present cirrus-like waveforms over extensive latitude and longitude regions (10°×10°), as revealed in coincident Mars Color Imager (MARCI) nadir imaging. Solar tides, gravity waves, and the large orbital variation of the extended thermal structure of the Mars atmosphere influence all of these behaviors. Mesospheric dust aerosols appear infrequently over the non-global (planet encircling) dust storm era of the CRISM limb data set (2009–2016), and exhibit smaller particle sizes (Reff=0.2–0.7 μm) relative to dust in the lower atmosphere. One isolated case of an aphelion (Ls=96°) mesospheric dust layer with large dust particle sizes (Reff ∼2 μm) over Syria Planum may reflect high altitude, non-local transport of dust over elevated regions.

Clancy, Todd R.↗
DOE OSTI2022

Impacts of phase state and water content on secondary organic aerosol formation and partitioning (Final Technical Report)

Secondary organic aerosols (SOA) account for a major fraction of particulate matter in the atmosphere, affecting climate, air quality, and public health. SOA formation and evolution are highly complex processes involving both chemical reactions and transport of molecules in air, at particle surfaces, and within particles. The state of the matter, or “phase state,” comprising SOA can vary from a liquid, over an amorphous semi-solid, to a glassy solid, depending on chemical composition, water content, relative humidity (RH), and temperature. The occurrence of glassy and amorphous semi-solid states can pose limitations on the rate of transport of molecules, affecting gas-particle interactions and challenging the treatment of SOA in atmospheric models. The objective of this project was to improve fundamental understanding of the interplay of the phase state of particles and water content on the evolution of SOA formation. We have developed a method to estimate the glass transition temperature (T g ) of organic compounds to predict the phase state and viscosity of SOA. This method has been applied to high resolution mass spectrometry data of various types of SOA, achieving a good agreement with viscosity measurements. In addition, the viscosity estimation method was implemented into a regional model CMAQ to simulate diel and seasonal variations of SOA phase state over the U.S. Applying kinetic multilayer modeling, we analyzed laboratory experiments and ARM field measurements (e.g., HI-SCALE) on kinetic limitations of amine uptake. We have also conducted numerical simulations to estimate equilibration timescales of SOA partitioning. Overall, we have evaluated the impacts of phase state and water content on SOA lifecycle that should contribute to reducing the uncertainty of SOA representation in regional climate and air quality predictions. The project has yielded 17 publications, in which DE-SC0018349 is explicitly acknowledged. Please see the list of publications as below, followed by summary of research activities.

54 ENVIRONMENTAL SCIENCES↗