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At least 559 records · Page 31

To bin or not to bin: Does binning in multiplicity reliably suppress unwanted volume fluctuations?

Here, in this study, we examine the effect of the so-called Centrality Bin Width Correction (CBWC) on the measurement of (net-)proton number cumulants in nucleus-nucleus collisions. We present an analytically tractable model, which includes correlations between multiplicity and proton number similar to those generated by the decay of baryon resonances. Within this model, we analyze the circumstances under which the CBWC method correctly removes the undesired effects of volume or impact parameter fluctuations. Additionally, we explore situations where the method fails and produces misleading results.

Critical point↗

PV backsheets survey protocol: A framework for geo-spatial field surveys for bulk material characterization and reliability analysis applied across 41 PV systems

As widespread adoption of photovoltaic (PV) technologies continues, understanding the lifetime of modules is paramount to the viability of the industry as an environmentally conscious alternative to traditional energy generation. Although power degradation can affect the total energy production of a module over its lifetime, module safety failures necessitate the removal of a module leading to a loss of not only the particular asset, but the earning potential of the device. Therefore, it is critical to ensure that the components that provide essential safety functions for PV module operate for their entire rated lifetime. PV backsheets provide necessary electrical insulation to the completed device and failure of this component is cause for a immediate removal of the module. Degradation of the PV module backsheet has led to module safety failures in large-scale installations, costing millions of dollars in damages and lost potential revenue. The spatio-temporal degradation of fielded PV modules is important to study in order to identify which modules within installations are experiencing the greatest exposure conditions and in turn have the highest chance of failure. This paper describes a comprehensive field survey protocol developed for monitoring PV module backsheet performance using solely non-destructive methods in commercial PV fields. The protocol establishes a field naming convention, sampling method, data handling requirements, and measurement procedures. By ensuring consistent data collection practices, the field survey protocol enables research groups to obtain data of uniform quality on backsheet performance over multiple years and locations. In this study, the developed protocol was implemented at forty-one PV sites. Eight different types of airside layer backsheet materials including poly(vinylidene fluoride) (PVDF), acrylic PVDF, poly(tetrafluoroethylene-co-hexafluoropropylene-co-vinylidene fluoride) (THV), poly(vinyl fluoride) (PVF), poly(ethylene terephthalate) (PET), fluoroethylene vinyl ether (FEVE), polyethylene naphthalate (PEN), and glass were identified using attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. The field survey results show that the spatial distribution of degradation indicators are non-uniform within a particular module, individual site, and across site locations. The degradation of PV modules increased in severity for modules mounted at the edge of rows (across a field) and near the junction box (within a module). This study demonstrates the sensitivity of material performance to exposure length across different materials and climates.

14 SOLAR ENERGY↗

Enhanced Switching Reliability of Hf 0.5 Zr 0.5 O 2 Ferroelectric Films Induced by Interface Engineering

Ferroelectric materials have been widely researched for applications in memory and energy storage. Among these materials and benefiting from their excellent chemical compatibility with complementary metal–oxide–semiconductor (CMOS) devices, hafnia-based ferroelectric thin films hold great promise for highly scaled semiconductor memories, including nonvolatile ferroelectric capacitors and transistors. However, variation in the switched polarization of this material during field cycling and a limited understanding of the responsible mechanisms have impeded their implementation in technology. Here, we show that ferroelectric Hf 0.5 Zr 0.5 O 2 (HZO) capacitors that are nearly free of polarization “wake-up”─a gradual increase in switched polarization as a function of the number of switching cycles─can be achieved by introducing ultrathin HfO 2 buffer layers at the HZO/electrodes interface. High-resolution transmission electron microscopy (HRTEM) reveals crystallite sizes substantially greater than the film thickness for the buffer layer capacitors, indicating that the presence of the buffer layers influences the crystallization of the film (e.g., a lower ratio of nucleation rate to growth rate) during postdeposition annealing. This evidently promotes the formation of a polar orthorhombic (O) phase in the as-fabricated buffer layer samples. Synchrotron X-ray diffraction (XRD) reveals the conversion of the nonpolar tetragonal (T) phase to the polar orthorhombic (O) phase during electric field cycling in the control (no buffer) devices, consistent with the polarization wake-up observed for these capacitors. The extent of T–O transformation in the nonbuffer samples is directly dependent on the duration over which the field is applied. Here these results provide insight into the role of the HZO/electrodes interface in the performance of hafnia-based ferroelectrics and the mechanisms driving the polarization wake-up effect.

36 MATERIALS SCIENCE↗

Pipe Parity Analysis of Seawater Desalination in the United States: Exploring Costs, Energy, and Reliability via Case Studies and Scenarios of Emerging Technology

As climate change-induced variables exacerbate water scarcities, the use of seawater reverse osmosis (SWRO) membrane desalination technology for treating seawater could potentially provide a long-term drought-proof source of drinking water. This study carried out a technoeconomic assessment (TEA) for three SWRO desalination plants in the U.S. and one in Israel to set baselines for the cost and energy consumption for seawater desalination. In addition, a breakeven curve for implementing SWRO desalination was estimated in relation to the cost of water conservation measures to meet drought-induced reduction of the traditional water supply. The results show that the cost of SWRO water production scales with the plant capacity while energy intensity is not dramatically different across the plants. The higher cost in some U.S. plants is due to high capital investment, including land acquisition and permitting. Variations in plant capacity utilization have the greatest impact on the levelized cost of water (LCOW) over the plant service life, suggesting the importance of reducing fouling and maintenance-related downtime. Scenario analysis of fixed labor cost reduction through process automation indicates investments in automation and sensing technology could result in long-term savings. Breakeven analysis shows the decision to adopt SWRO is highly dependent on the local cost associated with water conservation to meet water supply reduction. Moreover, a small reduction in SWRO cost can influence a shift toward the adoption of SWRO over water conservation measures. Incorporation of future water demand, water conservation potential, and water stress data around the nation indicates SWRO desalination could be an important contributor to the future municipal drinking water portfolio in the U.S.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗