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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Can Greener Cyrene Replace NMP for Electrode Preparation of NMC 811 Cathodes?

N-methyl-2-pyrrolidone (NMP) is the normally used solvent for cathode processing in lithium battery field. However, its high toxicity attracted more and more environmental scrutiny and was restricted by many chemical legislations in industry applications. So, it is necessary to find a greener and safer alternative to replace it. Dihydrolevoglucosenone (Cyrene), a newly reported green dipolar aprotic solvent, has very similar solvent properties as NMP, making it a very attractive candidate. The possibility to use Cyrene to replace NMP for NMC 811 cathode fabrication was studied. Although PVDF binder has very poor solubility in Cyrene at room temperature, increasing temperature can significantly change this. High temperature (above 80 °C) electrode processing with Cyrene gives promising performance, which is comparable to the conventional NMP fabricated electrode. A proof of principle was provided: Cyrene can be a good green alternative to replace NMP. So, the positive results reported here may also lead to a search for more Cyrene-like green solvents that have a higher solubility for PVDF, or of PVDF-like binders that are more soluble in Cyrene, to help making the electrode processing much greener.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Production and purification of research scale 161 Tb using cation-exchange semi-preparative HPLC for radiopharmaceutical applications

Terbium-161 ( 161 Tb) is emerging as a promising radionuclide for cancer therapy due to its favorable nuclear properties that are similar to clinically established lutetium-177 ( 177 Lu) along with its therapeutic edge arising from the higher number of Auger and conversion electrons per decay. These low energy electrons result in higher cytotoxicity within a short range of the decaying nuclei to enhance therapeutic efficacy. Despite these promising characteristics, a significant challenge remains in the lack of a domestic 161 Tb supply in the United States, which poses an obstacle to the advancement of 161 Tb-based radiopharmaceutical research and development. Here, this study developed a reliable cation-exchange high-performance liquid chromatography-based method for purification of reactor-produced 161 Tb at quantities suitable to support research and preclinical studies. The purified 161 Tb product showed high radionuclidic purity with excellent radiochemical purity, and the successful labeling studies with the DOTA chelator and DOTA-TATE peptide demonstrated the effective incorporation of the purified 161 Tb into radiopharmaceuticals designed for targeted cancer therapy.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2025

Preparation of 1,3-Dihydroxyphenazine

The ability to effectively store energy produced by intermittent renewable sources is a critical challenge for chemists and materials scientists. Redox flow batteries (RFB), which generate current by the flow of electrons between dissolved redox active compounds in separate solutions, are envisioned as a method to store renewable energy at the electrical grid scale. The best known examples of RFBs are driven by redox active metal or main group complexes. Within the past decade, redox active organic molecules have begun to be used in the construction of RFBs with high cell potential and cycle stability, at economical price points. Of particular interest are substituted dihydroxy phenazines, a class of heterocycles, that have recently been used as an anolyte for aqueous organic RFBs. Recent work indicates that different regioisomers of dihydroxyphenazine show dramatically different solubility and stability under electrochemical cycling conditions. Of particular interest was 1,3-dihydroxyphenazine (1,3-DHP), which showed greater than 1.5 M solubility in 2M KOH and excellent electrochemical stability. Current methods of producing 1,3-DHP, however, are low yielding and cumbersome. In the article proposal that follows, we offer an improved method of producing 1,3-DHP at high purity and moderate yield. The method detailed below was used by the Materials Engineering Research Facility (MERF) at Argonne National Lab to deliver more than 1.5 kg of this compound for use in the construction of aqueous organic RFBs.

Dzwiniel, Trevor [Argonne National Laboratory (ANL↗
DOE OSTI2020

Sample Preparation for 3D Characterization of Irradiated Fuel

Thorough characterization of nuclear fuel is essential when striving to understand its microstructural evolution in response to varying irradiation conditions. A detailed understanding of the microstructural evolution of irradiated fuel can be useful when predicting the fuel’s response to off-normal conditions and related phenomena such as high burnup fuel fragmentation (HBFF) and fission gas release. This sort of characterization and the study of complex phenomena like HBFF that are related to fuel performance are an important part of the US Department of Energy Office of Nuclear Energy’s Advanced Fuels Campaign (AFC). Multiple characterization techniques are commonly used to perform post-irradiation examination (PIE) analysis on an irradiated fuel sample, but many of these techniques are limited to the 2D surface analysis of the fuel pellet. Although there is a lot of useful information to be gained by analyzing the fuel pellet surface, a 2D analysis provides only an approximation of the nature of the material’s features, such as porosity and grain structure. Therefore, it is critical to analyze the 3D structure of the material, as materials exist and respond to conditions in all three dimensions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

LANL's Contribution to the Design and Preparation of the ANL Bubble Experiment #2

In collaboration with Argonne National Laboratory (ANL), Los Alamos National Laboratory (LANL) is assisting in the design and development of portions of the second ANL Bubble Experiment to be performed in late 2020 at ANL. The ANL Bubble Experiment, as called in this report, is a series of direct electron irradiations of a uranyl sulfate solution to produce radiolysis-induced gas bubbles of hydrogen and oxygen. The gas bubbles formed in the solution enhance mixing and heat transfer. The study of the dynamics, shape, and size of radiolysis-induced gas bubbles is of great importance to understand and characterize the thermal and fluid behavior of the solution, especially for the solution based, neutron-induced fission production technique for Mo-99. During the first experiment performed in 2014, ANL’s 35 MeV electron linear accelerator provided average powers of 6, 12, and 15 kW using a rastered beam to homogeneously heat the 15 x 15 x 80-cm uranyl-sulfate solution. Gas bubble size, shape, velocity, solution temperature, and hydrogen and oxygen concentrations were recorded during the irradiations. The details of the experimental setup and results for the first experiment are described in the ANL reports, Design and Construction of Experiment for Direct Electron Irradiation of a Uranyl Sulfate Solution: Bubble Formation and Thermal Hydraulics Studies and Experimental Results for Direct Electron Irradiation of a Uranyl Sulfate Solution: Bubble Formation and Thermal Hydraulics Studies. The purpose of this report is to describe the issues and lessons learned associated with the first experiment and elaborate on designs to improve and obtain more accurate experimental results for the upcoming experiment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Application of the Recharge Estimation Tool (RET) to Prepare Spatially and Temporally Variable Recharge Boundary Conditions for Hanford Site Composite Analysis Vadose Zone Models

This environmental calculation file (ECF) describes the development of a tool for translating recharge estimates into readable input for STOMP© (Subsurface Transport Over Multiple Phases) vadose zone models primarily supporting the vadose zone (VZ) facets of the updated Hanford Site Composite Analysis (CA) and the Hanford Site Cumulative Impact Evaluation (CIE). The recharge estimates are spatiotemporally variable and are produced by the Recharge Evolution Tool (RET) described in Hanford Site-wide Natural Recharge Boundary Condition for Groundwater Models (ECF-HANFORD-15-0019). Outputs from the RET are given in Esri’s™ feature class format with yearly estimates and associated metadata encapsulated in file geodatabase objects. For STOMP models, the translated output is a text file in the format of an input boundary condition card, consistent with STOMP software requirements. The text file contains assimilated spatiotemporal recharge estimates produced by the RET. The tool discussed in this document will be referred to as the “RET2STOMP” tool.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Preparation of Mesophase Pitch Feedstock for Carbon Fiber

A filtration process of the low cost mesophase pitch developed by Advanced Carbon Products, LLC (ACP) was developed. The mesophase pitch was melt spun into fiber at the University of Kentucky Center for Applied Energy Research (UKY), and converted to carbon fiber. The melt spinning process was moderately stable, but resulted in some void structure in the green fibers. The tensile properties of the resulting carbon fibers, after graphitization heat treatment, were tested yielding a modulus value of approximately 560 GPa or 81 MSI. This demonstrated that a high modulus graphitic carbon fiber is certainly possible from the ACP 20 mesophase pitch. For future work, a better balance between the softening point temperature, the spinning temperature, and filtering must be met to reduce the volatiles generated in the pitch during spinning. This would reduce voids in the fiber, facilitate spinning, and generate finer, higher performance graphitic fiber.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Preparing Distribution Utilities for Utility-Scale Storage and Electric Vehicles: A Novel Analytical Framework

Emerging distributed energy resources (DERs)—such as solar photovoltaics (PV), battery energy storage systems (BESS), and electric vehicles (EVs)—are expected to increase substantially in India in the coming years following policy-driven targets of the Government of India to modernize its electricity system, reduce greenhouse gas emissions (GHGs), and improve air quality. These emerging technologies can pose challenges to distribution utilities, forcing overhauls in planning and operational practices. They can also create challenges in power system infrastructure planning and cause more frequent system operational violations (e.g., network voltage bounds and loading thresholds) if not properly integrated. The impacts on the localized power distribution grid from these emerging technologies manifest in increased infrastructure investments and erratic shifts in demand patterns. These impacts are not yet well understood, and analytic solutions are not readily available. To address these challenges, the National Renewable Energy Laboratory (NREL), in collaboration with BSES Rajdhani Power Ltd. (BRPL), developed an advanced power distribution system impact analysis framework of BRPL’s distribution system. This framework helps analyze the readiness of the power distribution network to accommodate emerging technologies and the potential opportunities they might introduce. The framework has been predominantly set up to evaluate distributed PV, BESS, and EVs. In this collaboration between NREL and BRPL, we developed and evaluated the framework on two distribution feeders in the BRPL territory for various scenarios of BESS and EVs. BESS are evaluated for their effectiveness on the grid to mitigate present and future feeder overloading scenarios, and they are subsequently analyzed for their costs compared to the costs of traditional upgradation measures. Scenarios include assessing the effects of EV density on grid infrastructure upgrades and interlinking EV management with BESS integration.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Charged Microdroplets in Air: Characterization and Use in Surface Functionalization and Nanomaterials Preparation (Final Technical Report)

The major theme of this project is the exploration of ions and charged droplets in the open air. The specific goals are (1) focusing ions in the open air, (2) separating and measuring the sizes of charged droplets, (3) examining chemical reactions occurring within droplets, (4) examining chemical reactions occurring between charged droplets and chemical vapors, and (5) characterizing surfaces post droplet deposition. The analysis of ions in the open air greatly simplifies instrumentation as it removes the need for large, costly vacuum pumps. Major strides in this project include the sizing of electrospray droplets using structured illumination microscopy, 3D printed drift tube ion mobility (both standalone and coupled with mass spectrometry), and accelerated Suzuki reactions in Leidenfrost droplets.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Proposal to use the DOE-STD-3009-2014 Methodology to Prepare the Documented Safety Analysis (DSA) for Research Reactor Nuclear Facilities

Sandia National Laboratories (SNL) personnel operate a low power research reactor (the Annular Core Research Reactor, or ACRR), and a zero-power critical experiment assembly referred to as CX. In accordance with 10 CFR 830, Subpart B, Appendix A, the acceptable methodology for developing a Documented Safety Analysis (DSA) for DOE nuclear reactors is the Nuclear Regulatory Commission’s (NRC’s) Regulatory Guide 1.70 (RG 1.70). RG 1.70 does not address certain areas required by 10 CFR 830 and expected by DOE (e.g., full facility hazard analysis).Thus, the current DSAs for SNL’s reactor nuclear facilities are based on RG 1.70, but also of necessity supplemented by DOE-STD-3009-94 methods. SNL personnel, in consultation with the National Nuclear Security Administration (NNSA) Sandia Field Office (SFO), have concluded that an alternate methodology is preferred to RG 1.70. The details of the proposal, and the reasons motivating its development, are discussed in the order described below. The proposed alternate methodology will be applicable to the ACRR and the CX (i.e., it will be applicable to nuclear facilities in which a reactor and/or a critical assembly will be operated).

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2021

Preparing Distribution Utilities for the Future - Evolving Customer Consumption in Renewable Rich Grids: A Novel Analytical Framework

The research collaboration between NREL and BYPL focuses on the challenges caused by renewable integration into the power grid at large. Since the challenges and opportunities vary depending on the point of interconnection (distribution or transmission) the research team identified two tracks for research as listed below: 1. Power procurement - This research track focuses on the challenges and opportunities caused by GW scale renewable integration at the transmission level. Specifically, this track focuses on the contribution that utility-scale renewable energy procurement provides to distribution utilities, both from energy and capacity perspectives. In this track of research, utility customers are only considered as traditional (one-directional) consumers of energy. 2. Distributed energy resources - This research track focuses on the challenges and opportunities caused by many small-scale distributed renewable resource integrations at the distribution systems. At the power distribution level, distribution utilities may face not only new solar energy technologies, but also battery energy storage and electric vehicles as well. These three technologies (solar PV, battery energy storage, and electric vehicles) combined, pose unique challenges to distribution utilities. This track focuses on assessing the net-load evolution that distribution utilities observe as these emerging technologies make their way to the grid.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Low-Activity Waste Glass Standards Preparation and Characterization for Calibration of Analytical Instruments

A matrix of seven low-activity waste (LAW) glasses was fabricated and characterized to be used by the Hanford Waste Treatment and Immobilization Plant (WTP) as analytical instrument calibration and matrix interference standards when measuring LAW glass compositions. The matrix of glasses was designed to represent the range of LAW glass compositions that will be generated by the WTP. Samples from each of the seven glasses were measured with electron probe microanalysis (EPMA), ion chromatography (IC), and bulk inductively coupled plasma mass spectroscopy (ICP-MS) to determine the variability and accuracy across batches and within individually poured glass bar samples. High relative percent differences and standard deviations were calculated for components with low concentrations due to instrument detection limits. IC and ICP-MS percent differences and standard deviations were higher at low component concentrations. Otherwise, variability in measured compositions from IC and ICP-MS was generally lower than measurements from EPMA, with the exclusion of Cl, F, Si, and B. Overall, the two methods proved comparable and complementary. From EPMA, IC, and ICP-MS data, volatile elements were underrepresented compared to batched compositions, which suggested loss of these elements during melting. EPMA data was statistically analyzed to evaluate homogeneity within single bars and whole compositions for each of the seven glasses. Most of the variability within glass compositions occurred at the bar-to-bar level; however, no clear systematic trends were observed. Based on these analyses, when using these glasses as reference material, it is recommended that the overall mean and variance of each composition be used for performing instrument calibrations and analytical corrections.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Preparing Distribution Utilities for the Future - Unlocking Demand-Side Management Potential: A Novel Analytical Framework

The balance of supply and demand in the power systems has traditionally been served solely through generation and network capacity planning and operations. However, with increased requirements for flexibility due to the uptake in variable renewable generation sources such as wind and solar there is a need to increased demand-side flexibility. In addition, there are increased communications and flexibility capabilities emerging on the demand-side from the adoption of advanced metering infrastructures and smart meter deployment and intelligent loads such as smart thermostats and schedulable white goods (e.g. dishwashers and washing machines). Unlocking demand-side flexibility can bring system benefits from peak load reduction bringing about generation capacity and network upgrade deferral, to reducing demand and more efficient utilization of generation and network capacity. Unlocking demand-side flexibility is an evolving process for utilities and solutions must be tailored to each specific customer group. Demand-side management (DSM) is a broad set of tools that can include demand response (both dispatchable and non-dispatchable), energy efficiency and distributed energy resources and demand-side technologies. The National Renewable Energy Laboratory (NREL), in collaboration with BSES Rajdhani Power Ltd. (BRPL) and Deloitte, examined the potential of DSM in BRPL’s service territory, developing detailed information on customer classes and willingness to participate in DSM. The study developed modeling frameworks for load analysis and the analysis tools to assess the potential of time-of-use tariffs in motivating customers to reduce their peak period energy consumption. The study shows that BRPL customers, specifically their domestic customers, are willing to participate in DSM programs and that time-of-use pricing can help BRPL reduce their peak demand and help unlock demand-side flexibility.

24 POWER TRANSMISSION AND DISTRIBUTION↗