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At least 559 records · Page 31

A Perspective into Operando Methods for Probing Catalytic Interfaces

Rational design of electrocatalysts for (photo)electrochemical (PEC) processes like hydrogen and oxygen evolution and CO2 reduction reactions is aided by the recent improvements in capabilities of operando measurements, where morphology, composition, and/or function are probed during active catalysis. Through operando microscopy and spectroscopy, structure, catalytic microenvironment, oxidation state, adsorbates, and products can be measured to gain a better understanding of catalyst behavior and suggest possible improvements. Visualizing evolving catalyst morphologies, surface compositions, and electrochemical behavior also helps address many fundamental research questions for a better understanding of catalytic mechanisms. Correlating morphology with chemical identity or functional behavior using a variety of innovative microscopy methods is particularly promising for guiding development of next generation catalysts, and there are also many recent examples of using AI and robotics tools to innovate and speed development. In this Perspective, advances made over the past few years in operando imaging of catalysts relevant to solar fuels will be explored, followed by an outlook on technological developments in instrumentation, sample design, and computational power that may be applied to this field.

Catalysts↗

From binary to quinary: The rationale and development of GaInAsSbBi for mid- and long-wave infrared sensing applications

Given the added complexity in flux calibration and composition evaluation inherent to quinary alloy growth, what motivates compounding the challenges of III–V-Bi growth with the goal of producing a quinary alloy of GaInAsSbBi for mid- and long-wave infrared sensing applications? Each elemental constituent provides some additional design freedom to achieve the ultimate goal of producing a lattice-matched, bulk random alloy mid-wave infrared III–V material with smooth surface morphology and high optoelectronic quality to enable high performance elevated operating temperatures. Here, this paper reviews the evolution of Bi-containing semiconductor research, focusing on mid- and long-wave infrared materials and highlighting key research findings that motivated the decisions to accept the added complexity in going from binaries like InAs or InSb, to InAsBi, to InAsSbBi, and, finally, to GaInAsSbBi to meet the performance demands of advanced infrared sensing applications.

Webster, Preston T. [Air Force Research Laboratory↗

Theoretical horizontal-branch evolution

The general features of the theoretical evolution of canonical horizontal-branch (HB) stars are briefly reviewed with specific emphasis on the track morphology in the HR diagram and the determination of the globular cluster helium abundance. The observational evidence for the occurrence of semiconvection is discussed together with some remaining theoretical uncertainty.

Sweigart, Allen V.↗

Mechanical response and microstructure evolution from multiaxial stress relaxation in textured zircaloy nuclear cladding

Modern energy markets provide motivation for nuclear reactors to increase operational flexibility and load following capacity of existing reactor designs. The operational power changes result in fuel pellet expansion and contraction resulting in pellet-cladding mechanical interaction (PCMI) and high cladding stresses that are strongly related to stressed corrosion cracking (SCC) which can lead to fuel rod failure. This work aims to quantify the stress fields in cladding with a focus on multiaxial stress relaxation response from an imposed strain and the resulting microstructure changes in textured zircaloy claddings. Stress relaxation tests resulting in multiaxial stress fields are performed to measure the material response of Zircaloy-4 nuclear cladding. Multiple experiments using samples from the same piece of cladding are performed so samples with the same processing history may be removed at strategic points throughout mechanical testing for microstructure characterization. The microstructure evolution is analyzed with mechanical response to evaluate the static recovery impact on crystallographic texture and grain morphology. Experiments are performed at Idaho National Laboratory using an experimental device capable of applying internal pressure and independent axial load to commercial nuclear cladding at elevated temperatures with stress- or strain-controlled experimental capability. X-ray diffraction and electron backscatter diffraction are used for microstructure analysis. Rheological models are used to visualize the multiaxial stress-strain relationships and isolate elastic, plastic, and viscoplastic material properties for analysis.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Quasar number density evolution

A simple model of quasar number density evolution is presented based on the occurrence of quasar-like radio galaxies (i.e., strong optical emission lines and type 2 radio morphology) exclusively in regions of low galaxy and intergalactic medium (IGM) density. This suggests a limit for the IGM density of 10 to the -4th (+ or - 1) per cu cm below which quasars are allowed to form and above which they are not allowed. In the recent past (z not greater than 1), the inferred quasar environments are the outskirts of clusters and near the centers of groups of galaxies. However, models of rich cluster evolution consistent with current X-ray observations predict gas densities of less than 10 to the -4th per cu cm in cluster cores in the more distant past (z between 1 and 5). This suggests that quasars were allowed to form in the cores of rich clusters at those epochs, which explains both the rich absorption spectra of high-redshift quasars and the absence of clusters surrounding quasars at lower redshift.

Stocke, J. T.↗

Evolution of large shield volcanoes on Venus

We studied the geologic history, topographic expression, and gravity signature of 29 large Venusian shield volcanoes with similar morphologies in Magellan synthetic aperture radar imagery. While they appear similar in imagery, 16 have a domical topographic expression and 13 have a central depression. Typical dimensions for the central depression are 150 km wide and 500 m deep. The central depressions are probably not calderas resulting from collapse of a shallow magma chamber but instead are the result of a corona-like sagging of a previously domical volcano. The depressions all have some later volcanic filling. All but one of the central depression volcanoes have been post-dated by geologic features unrelated to the volcano, while most of the domical volcanoes are at the top of the stratigraphic column. Analysis of the gravity signatures in the spatial and spectral domains shows a strong correlation between the absence of post-dating features and the presence of dynamic support by an underlying plume. We infer that the formation of the central depressions occurred as a result of cessation of dynamic support. However, there are some domical volcanoes whose geologic histories and gravity signatures also indicate that they are extinct, so sagging of the central region apparently does not always occur when dynamic support is removed. We suggest that the thickness of the elastic lithosphere may be a factor in determining whether a central depression forms when dynamic support is removed, but the gravity data are of insufficient resolution to test this hypothesis with admittance methods.

Herrick, Robert R.↗

Groundwater sapping valleys: Experimental studies, geological controls and implications to the interpretation of valley networks on Mars

An integrated approach using experimental laboratory models, field studies of terrestrial analogs, and remote studies of terrestrial field sites were applied to the goals of understanding the nature and morphology of valley networks formed by groundwater sapping. In spite of problems with scaling, the experimental studies provide valuable insights into concepts relating to the initiation, development, and evolution of valleys by groundwater sapping. These investigations are also aimed at developing geomorphic criteria for distinguishing valleys formed by surface runoff from those formed by groundwater sapping processes. Channels that were field classified as sapping vs. runoff were successfully distinguished using statistical analysis of their respective morphologies; therefore, it may be possible to use similar techniques to interpret channel genesis on Mars. The terrestrial and flume studies provide the ground truth dataset which can be used (and will be during the present year) to help interpret the genesis of valley networks on Mars.

Kochel, R. Craig↗

Cometary spectroscopy and imaging

The objective is to investigate the spectroscopic and morphological characteristics of comets and selected minor planets over a wide range of heliocentric distances as they may suggest or constrain models of cometary processes, their formation environments and evolution. Direct images of all observable comets and 300-800 nm spectra of the brighter ones are obtained on a monthly basis with a charge coupled device spectrograph-camera. The direct images may be used for astrometry, photometry, and studies of coma and tail morphology. In some cases, anisotropic dust emission can provide information on the nucleus spin vector. Spectra may provide data on strengths of the principle emission for comparison of gas/dust ratios of a large sample of comets. Long integrations of minor planets in comet-like and nearby orbits are made to search for faint comae.

Larson, Stephen M.↗

A novel xylosylated fucoglucuronan in Penium reveals structural parallels to rhamnogalacturonan-I and its broad evolutionary footprint in lower plants

Green algae inhabit aquatic environments across the planet and play a crucial role in sustaining the global ecosystem. Ancestors of some Charophytes adapted to terrestrial conditions and eventually evolved into land plants. Extant green algae have inherited traits from their ancestors and evolved into their current morphological and chemical forms, as reflected by their cell walls with distinct shapes and compositions. To illuminate the evolution of plant cell walls and bridge the gap between green algae and land plants, we investigated the charophyte Penium margaritaceum, a close relative of terrestrial plants. We discovered a previously unknown polysaccharide in both its culture medium and cell wall. This polysaccharide, termed xylosylated fucoglucuronan (XFG), possesses a rhamnogalacturonan-I (RG-I)-like backbone composed of repeating [-3-α-Fucp-(1,4)-α-GlcpA-] disaccharides that are extensively xylosylated and acetylated. Surveying approximately 20 non-vascular plants revealed that XFG and RG-I (or related structures) first emerge in certain Chlorophyceae and subsequently co-occur throughout lineages along the evolutionary trajectory to bryophytes, thereby bridging aquatic green algae to early land plants. The striking structural parallels between XFG, RG-I, and ulvan suggest a shared evolutionary origin, offering new insight into how plant cell walls adapted during the transition from marine to freshwater environments and ultimately to land.

Algae↗

Effects of sample bias on adhesion of magnetron sputtered Cr coatings on SiC

Swelling of SiC at 300 C due to in-service neutron irradiation causes tensile residual stresses in coatings which are expected to adversely affect the performance of coated SiC composite fuel cladding for light water reactors. Matching the coating swelling with the substrate, a solution common for thermal expansion, is not practical in the case of neutron irradiation. Biasing samples during magnetron sputtering deposition induces compressive residual stress which may counteract this. In this study, chromium coatings were deposited on SiC by DC magnetron sputtering with no external heating at bias voltages of –50V, –75V, and –100V. The effects of the bias voltage on morphology, residual stress, microstrain, texture, and adhesion are shown. The low deposition temperature resulted in the coating microstructure evolution following an energetic particle bombardment dominated trend. Additionally, at the two lower bias voltages knock-on implantation dominated increasing the residual stress and microstrain while at the highest bias voltage, thermal spike migration allowed for defect relaxation. When the knock-on induced compressive residual stress exceeded 0.8 GPa microcrack formation in the SiC substrate decreased coating adhesion. While no microcracks formed at the lowest bias voltage, insufficient atomic mobility during coating growth lead to voids forming in the coating. A balance is needed to form void-free coatings that have high compressive residual stress.

36 MATERIALS SCIENCE↗

Multi-messenger dynamic imaging of laser-driven shocks in water using a plasma wakefield accelerator

Understanding dense matter hydrodynamics is critical for predicting plasma behavior in environments relevant to laser-driven inertial confinement fusion. Traditional diagnostic sources face limitations in brightness, spatiotemporal resolution, and in their ability to detect relevant electromagnetic fields. In this work, we present a dual-probe, multi-messenger laser wakefield accelerator platform combining ultrafast X-rays and relativistic electron beams at 1 Hz, to interrogate a free-flowing water target in vacuum, heated by an intense 200 ps laser pulse. This scheme enables high-repetition-rate tracking the evolution of the interaction using both particle types. Betatron X-rays reveal a cylindrically symmetric shock compression morphology assisted by low-density vapor, resembling foam-layer-assisted fusion targets. The synchronized electron beam detects time-evolving electromagnetic fields, uncovering charge separation and ion species differentiation during plasma expansion – phenomena not captured by photons or hydrodynamic simulations. We show that combining both probes provides complementary insights spanning kinetic to hydrodynamic regimes, highlighting the need for hybrid physics models to accurately predict fusion-relevant plasma behavior.

imaging techniques↗

Nondiffractive beam shaping for enhanced optothermal control in metal additive manufacturing

High thermal gradients and complex melt pool instabilities involved in powder bed fusion–based metal additive manufacturing using focused Gaussian-shaped beams often lead to high porosity, poor morphological quality, and degraded mechanical performance. We show here that Bessel beams offer unprecedented control over the spatiotemporal evolution of the melt pool in stainless steel (SS 316L) in comparison to Gaussian beams. Notably, the nondiffractive nature of Bessel beams enables greater tolerance for focal plane positioning during 3D printing. We also demonstrate that Bessel beams significantly reduce the propensity for keyhole formation across a broad scan parameter space. High-speed imaging of the melt pool evolution and solidification dynamics reveals a unique mechanism where Bessel beams stabilize the melt pool turbulence and increase the time for melt pool solidification, owing to reduced thermal gradients. Consequently, we observe a distinctively improved combination of high density, reduced surface roughness, and robust tensile properties in 3D-printed test structures.

36 MATERIALS SCIENCE↗

Viscous relaxation of impact craters on icy planetary surfaces - Determination of viscosity variation with depth

Spacecraft images show that the icy Galilean satellites have surfaces with very low topographic relief. Impact craters on Ganymede and Callisto are anomalously shallow and are characterized by sharp well-defined rims and domed floors. These morphological characteristics can be explained by viscous relaxation of topography on an icy crust in which the viscosity is uniform or decreases with depth. Under these conditions, large craters relax more rapidly than small craters, therefore explaining a possible underabundance of large craters. Viscous relaxation on an icy crust that is thin compared to the crater diameter or on a thick icy crust in which viscosity increases with depth could not produce this crater morphology and would result in the more rapid relaxation of small craters rather than large craters. The results of this study suggest that more detailed analysis of relaxing impact crater morphology may resolve the rate of viscosity decrease with depth and so provide evidence on the interior thermal evolution of icy planetary bodies.

Parmentier, E. M.↗

HEAO 2 X-ray observations of clusters of galaxies

A summary of results of Einstein satellite observations of clusters of galaxies is provided, and X-ray luminosities or upper limits for 27 clusters are reported. Newly reported clusters with interesting morphologies are presented, and a brief discussion of the data in relation to theories of cluster formation and evolution is given.

Ulmer, M. P.↗

Impact Cratering: A Critical Jovian Icy Moons Science Objective

Impact craters perform two vital functions in planetary history and evolution. They date the surface. They probe the interior. Voyager and Galileo based studies reveal that impact crater morphology is fundamentally different on icy and rocky bodies. Also, differences have been discovered among the icy satellites that are probably related to thermal state of the ice shell. Much of this is related to the strong temperature dependence of ice rheology on temperature, and the much weaker strength of ices in general. Depth diameter studies of impact craters show very clear breaks associated with morphologic transitions. In fact, some larger craters appear to be shallower than smaller craters. These transitions may be related to rheologic transitions at depth within the outer icy shells. Unfortunately, only a few of the larger impact craters can be mapped topographically and some of these were not observed at high resolution. It is therefore highly desirable to determine the shapes of larger impact features on these satellites.

Schenk, P. M.↗

Lunar and Planetary Science XXXV: Impacts on Mars and Earth

The session "Impacts on Mars and Earth" included the following reports:A Timescale for Major Events in Early Mars Crustal Evolution; Impact Craters in Arabia Terra, Mars; Ancient Giant Basin/Aquifer System in the Arabia Region, Mars; Small Crater Morphology Within Gusev Crater and Isidis Planitia: Evidence for Widespread Secondaries on Mars; Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries; Asymmetric Ramparts of Secondary Craters in Cerberus, Mars: Interpretation and Implications for Local Stratigraphy; Depth to Diameter Relationships of Craters in the High Latitudes (70 -80 ) of Mars: Implications for Geologic History of Those Areas; Impact Cratering on Mars: Search for Target Influence on Morphology; Starting Conditions for Hydrothermal Systems Underneath Martian Craters: Hydrocode Modeling; Impact-induced Hydrothermal System at the Sudbury Crater: Duration, Temperatures, Mechanics, and Biological Implications; Major and Trace Element Variations in Impact Crater Clay from Chicxulub, Lonar, and Mistastin, Implications for the Martian Soil; Stable Isotopes and Hydrothermal Fluid Source in the Yaxcopoil-1 Borehole, Chicxulub Impact Structure, Mexico; and Chicxulub Impact Melts: Geochemical Signatures of Target Lithology Mixing and Post-Impact Hydrothermal Fluid Processes.

Source record↗

The Dense, Warm Interstellar Medium (D-WIM): Unravelling a New Phase of the ISM A PRIMA FIR Probe Mission Project

We propose a study of the Dense Warm Interstellar Medium (D-WIM) via the two fine structure lines of ionized nitrogen (\NII). This new phase of the interstellar medium (ISM) has density 10 $\cmv \le n(e) \le$ 100 $\cmv$, and has effectively been identified throughout much of the Milky Way and in nearby galaxies. :The unexpected conditiosn in the D-WIM immediately raise important questions both about this phase of the ISM and its relationship to the ISM as a while. These include: what is the structure of the D-WIM -- e.g. filling factor, distribution, and morphology?; what is the origin of the D-WIM?; what supports its ionization and what is its evolution given huge overpressure relative to the $\ge$ 100 times more diffuse Warm Ionized Medium (WIM)?; what is its possible relationship to stars - is it the the remnants of very old HII regions that were produced by clusters of masive stars? The PRIMA survey requires a coverage of a large fraction of the plane, plus selected regions at high galactic latitudes. A sensitivity of 10$^{-9}$ $Wm^{-2}sr^{-1}$ would be highly desirable. A spectral resolution $R$ of 10$^4$ will isolate individual spectral features. $R$ = 10$^3$ would be acceptable to measure the total intensity. This PRIMA survey could be part of a broader survey of the ISM, and include a number of other important ISM tracers such as [CII] 158 \um, [OI] 63 \um\ and [OI] 146 \um, depending on wavelength coverage of the instrument. The sensitivity requirement for study of the D-WIM is likely more stringent than for the other lines, and may require special consideration for successful implementation as well as for determining the area that can be observed.

Lis, Dariusz↗

The separate effect of halo mass and stellar mass on the evolution of massive disc galaxies

ABSTRACT We analyse a sample of massive disc galaxies selected from the fourth-generation Sloan Digital Sky Survey/Mapping Nearby Galaxies at Apache Point Observatory survey to investigate how the evolution of these galaxies depends on their stellar and halo masses. We applied a semi-analytic spectral fitting approach to the data from different regions in the galaxies to derive several of their key physical properties. From the best-fitting model results, together with direct observables such as morphology, colour, and the Mgb/〈Fe〉 index ratio measured within 1Re, we find that for central galaxies both their stellar and halo masses have a significant influence in their evolution. For a given halo mass, galaxies with higher stellar mass accumulate their stellar mass and become chemically enriched earlier than those with smaller stellar mass. Furthermore, at a given stellar mass, galaxies living in more massive haloes have longer star formation time-scales and are delayed in becoming chemically enriched. In contrast, the evolution of massive satellite galaxies is mostly determined by their stellar mass. The results indicate that both the assembled halo mass and the halo assembly history impact the evolution of central galaxies. Our spatially resolved analysis indicates that only the galaxy properties in the central region (0.0–0.5Re) show the dependencies described above. This fact supports a halo-driven formation scenario since the galaxies’ central regions are more likely to contain old stars formed along with the halo itself, keeping a memory of the halo formation process.

Zhou, Shuang (ORCID:0000000289996814)↗