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DOE OSTI2019

Magnetism of Complex Oxide Interfaces

This chapter reviews theoretical studies focused on interfaces or heterostructures of complex oxides such as perovskite transition-metal oxides (TMO). It describes examples of such theoretical studies of TMO interfaces employing a variety of methods. The chapter explains theoretical work at the interfaces of a ferroelectric and a magnetic manganite and provides rules to judge the type of coupling between the spins at opposite sides of the interfaces. It shows how the electric field of the ferroelectric component affects the electronic density of the other component, typically a metallic manganite, thus altering its transport properties and sometimes even inducing a phase transition. The chapter explores the puzzling exchange bias effect is addressed for the interfaces involving a ferromagnet on one side and a G-type antiferromagnetic state on the other. If the interfacial carrier density is modulated away from the region, the ferromagnetism and transport will become worse.

Okamoto, Satoshi↗

DOE OSTI2019

Shear Behavior of Bedded Salt Interfaces under Direct Shear Loading

Bedded salt contains interfaces between the host salt and other in situ materials such as clay seams, or different impurities such as anhydrite or polyhalite in contact with the salt. These inhomogeneities are thought to have first-order effects on the closure of nearby drifts and potential roof collapses. Despite their importance, characterizations of the peak shear strength and residual shear strength of interfaces in salt are extremely rare in the published literature. This paper presents results from laboratory experiments designed to measure the mechanical behavior of a bedding interface or clay seam as it is sheared. The series of laboratory direct shear tests reported in this paper were performed on several samples of materials from the Permian Basin in New Mexico. These tests were conducted at numerous normal and shear loads up to the expected in situ pre-mining stress conditions. Tests were performed on samples with a halite/clay contact, a halite/anhydrite contact, a halite/polyhalite contact, and on plain salt samples without an interface for comparison. Intact shear strength values were determined for all of the test samples along with residual values for the majority of the tests. The results indicated only a minor variation in shear strength, at a given normal stress, across all samples. This result was surprising because sliding along clay seams is regularly observed in the underground, suggesting the clay seam interfaces should be weaker than plain salt. Post-test inspections of these samples noted that salt crystals were intrinsic to the structure of the seam, which probably increased the shear strength as compared to a typical clay seam.

58 GEOSCIENCES↗

DOE OSTI2020

Coupling CTH to Linear Acoustic Propagation across an Air-Earth Interface

The interface between the Earth and the atmosphere forms a strong contrast in material properties. As such, numerical issues can arise when simulating an elastic wavefield across such a boundary when using a numerical simulation scheme. This is exacerbated when two different simulation codes are coupled straddling that interface. In this report we document how we implement the coupling of CTH, a nonlinear shock physics code, to a linearized elastic/acoustic wave propagation algorithm, axiElasti, across the air-earth interface. We first qualitatively verify that this stable coupling between the two algorithms produces expected results with no visible effects of the coupling interface. We then verify the coupling interface quantitatively by checking consistency with results from previous work and with coupled acoustic-elastic seismo-acoustic source inversions in three earth materials.

58 GEOSCIENCES↗

DOE OSTI2023

Energy Services Interface: Requirements Document

This energy services interface (ESI) requirements document represents a process step in the path for creating an ESI specification, which will describe the technical characteristics of an ESI. This document outlines the concepts that need to be covered in the ESI specification, such as principal functions of the ESI, grid services communicated through the ESI, and the ESI lifecycle. It provides context for the Department of Energy’s (DOE’s) Grid Modernization Laboratory Consortium (GMLC) to engage industry participants in the development of the ESI specification. To do this, it describes the desired contents of the ESI specification and provides examples of the type of material that needs to be included in it. The purpose of the ESI specification is to define the requirements that are to be addressed in information and communications technology (ICT) interface standards for enabling the integration of a facility containing responsive distributed energy resources (DER facility) to an electric system consistent with the fundamental ESI principles. In this context, a DER facility may consist of a single DER with a communicating controller or may be as complex as a microgrid campus with several buildings and many DERs. The ESI specification is not a technical interface standard, but the requirements in the specification can be used to check that existing, augmented, or new interface standards meet the interoperability requirements of the ESI concept, which is explained further in this document. In this way, the ESI specification can be used to guide standards advancement work in multiple standards development organizations. To explain the scope of the ESI specification, this ESI requirements document provides examples of situations (or illustrative applications) for using an ESI to coordinate DER flexibility for grid operations. These examples originate from foundational work for describing common grid-DER service agreements that are anticipated to be supported using this interface.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2024

Emergent Phenomena at Mott Interfaces – a Time- and Depth-Resolved Approach (Final Technical Report)

This is the final technical report for Award DE-SC0019297, Emergent Phenomena at Mott Interfaces – a Time- and Depth-Resolved Approach. This research program aimed to address the scientific questions related to the emergence and control of non-equilibrium electronic phases of matter in strongly correlated Mott oxides and their interfaces. We were focusing specifically on exploiting the interfaces in heterostructures and superlattices, containing Mott oxides CaMnO 3 and LaNiO 3 because in such systems, precise control of electronic and magnetic structure in the ground state can be achieved through dimensionality, heterostructuring, interface termination, and lattice strain. We utilized advanced x-ray spectroscopic and scattering techniques, to investigate these phenomena. Additionally, we used intense THz electric-field pulses generated by a femtosecond laser to directly modify the electronic structure and magnetic states of the ultrathin LaNiO 3 and CaMnO 3 layers in such heterostructures, with the objectives of disentangling, understanding, and harnessing control over the intricate competing interactions responsible for two-dimensional magnetism and metal-insulator transition at the interfaces.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Protein-Nanoparticle Interactions Govern the Interfacial Behavior of Polymeric Nanogels: Study of Protein Corona Formation at the Air/Water Interface

Biomedical applications of nanoparticles require a fundamental understanding of their interactions and behavior with biological interfaces. Protein corona formation can alter the morphology and properties of nanomaterials, and knowledge of the interfacial behavior of the complexes, using in situ analytical techniques, will impact the development of nanocarriers to maximize uptake and permeability at cellular interfaces. In this study we evaluate the interactions of acrylamide-based nanogels, with neutral, positive, and negative charges, with serum-abundant proteins albumin, fibrinogen, and immunoglobulin G. The formation of a protein corona complex between positively charged nanoparticles and albumin is characterized by dynamic light scattering, circular dichroism, and surface tensiometry; we use neutron reflectometry to resolve the complex structure at the air/water interface and demonstrate the effect of increased protein concentration on the interface. Surface tensiometry data suggest that the structure of the proteins can impact the interfacial properties of the complex formed. These results contribute to the understanding of the factors that influence the bio-nano interface, which will help to design nanomaterials with improved properties for applications in drug delivery.

Traldi, Federico (ORCID:0000000161251012)↗

DOE OSTI2019

Interface Science Using Ambient Pressure Hard X-ray Photoelectron Spectroscopy

The development of novel in situ/operando spectroscopic tools has provided the opportunity for a molecular level understanding of solid/liquid interfaces. Ambient pressure photoelectron spectroscopy using hard X-rays is an excellent interface characterization tool, due to its ability to interrogate simultaneously the chemical composition and built-in electrical potentials, in situ. In this work, we briefly describe the “dip and pull” method, which is currently used as a way to investigate in situ solid/liquid interfaces. By simulating photoelectron intensities from a functionalized TiO2 surface buried by a nanometric-thin layer of water, we obtain the optimal photon energy range that provides the greatest sensitivity to the interface. We also study the evolution of the functionalized TiO2 surface chemical composition and correlated band-bending with a change in the electrolyte pH from 7 to 14. Our results provide general information about the optimal experimental conditions for characterizing the solid/liquid interface using the “dip and pull” method, and the unique possibilities offered by this technique.

Favaro, Marco (ORCID:0000000235028332)↗

DOE OSTI2022

Real-Sim Interface: Enabling Multi-resolution Simulation and X-in-the-Loop Development for Connected and Automated Vehicles

We report connected and automated vehicles (CAVs) can bring safety, mobility, and energy benefits to transportation systems. Ideally, CAV applications would be fully evaluated and validated prior to real-world implementation. However, many technical challenges in both software and hardware hinder the process. To comprehensively evaluate all aspects of CAV applications, an integrated evaluation environment is needed with various simulation tools from different domains. In the current literature, there lacks a well-developed interface to enable multi-resolution simulation of vehicle, traffic, virtual environment, and hardware-in-the-loop (HIL) simulation. In this work, a modular and flexible interface is developed to enable multi-resolution vehicle and traffic co-simulation for CAV applications. This interface is built upon Oak Ridge National Laboratory’s (ORNL’s) Real-Sim approach, can support various simulation tools and real-time X-in-the-loop (XIL) simulations, and is based on network communication protocols. The network communication delays are analyzed for simultaneous connection of up to 20 simulators. Then, two example applications are studied to demonstrate the potential usage of the Real-Sim interface: (1) a centralized merging scenario where the dynamics of two ego vehicles are emulated with detailed vehicle and powertrain dynamics models and (2) a signal-controller-in-the-loop (SCIL) evaluation where one intersection of the simulated traffic scenario is controlled by a physical signal controller. This Real-Sim interface is a tool that allows researchers to bring real, tangible hardware and software into simulated environments to comprehensively evaluate and support a wide variety of CAV applications.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2023

A General Method for Estimating Zonal Transmission Interface Limits from Nodal Network Data: Preprint

Capacity expansion models for the electric power system often employ zonal (rather than nodal) resolution, necessitating estimates of aggregate power transfer limits across the interfaces between model zones. Interface limits between planning areas are sometimes published, but they are not generalizable to arbitrary zone shapes. There is thus a need for a reproducible method for estimating interface transfer limits (ITLs) between user-defined zones directly from nodal transmission system data. Here, we present a simple method for estimating ITLs using a DC power flow approximation via the power transfer distribution factor (PTDF) matrix. Linear optimization is performed to identify the distribution of power flows that maximizes the total flow on interface-crossing lines, subject to individual line ratings, limits on bus injection/withdrawal, and the relationships among flows, injections, and withdrawals imposed by the PTDF matrix. We demonstrate the application of the method on a 134-zone ~65000-bus system, and we explore the influence of flow direction, contingency level, and zone size on the estimated ITLs. There is significant heterogeneity in the ratio of the ITL to the sum of interface-crossing line ratings, which highlights the importance of accounting for the physical constraints on power flows imposed by Kirchhoff's laws when estimating zonal ITLs.

17 WIND ENERGY↗

NASA NTRS1972

Mechanics of load transfer at the fiber/matrix interface

Methods for measuring and predicting interface bond stresses and interface bond strength are described. Geometric and material variables which influence interface stress and interface bond strength are identified. The dependence of composite fracture surface characteristics on bond strength is illustrated. Parameters for selecting constituents to yield specified interface bond strength are recommended.

Chamis, C. C.↗

NASA NTRS1975

Space tug/shuttle interface compatibility study. Volume 1: Executive summary

Shuttle interfaces required for space tug accommodation are primarily involved with supporting and servicing the tug during launch countdown, flight, and postlanding; deploying and retrieving the tug on orbit; and maintaining control over the tug when it is in or near the orbiter. Each of these interface areas was investigated to determine the best physical and operational method of accomplishing the required functions, with an overriding goal of establishing simple and flexible orbiter interface requirements suitable for tug, tug payloads, IUS and other cargo. It is concluded the orbiter payload accommodations and the MSFC baseline tug are generally interface compatible. Specific minor changes to tug and orbiter interfaces were identified to provide full compatibility. A system concept for supporting and deploying tug from orbiter is described.

Source record↗

NASA NTRS1974

Mechanics of load transfer at the interface

The mechanism of load transfer from matrix to fiber though the interface and, as a consequence, the effects of the interface on composite structural integrity are discussed. Specifically, the present work deals with the role of interfacial bonding in composite strength, the dependence of fracture surface on interface bond strength, and methods of measuring and predicting the stress at the interface, the microresidual stress, and load condition effects on the interface bond. The possibility of designing composites with specified bond properties is examined. Many of these effects are illustrated graphically to indicate general trends and to illustrate significant points. The discussion is based on theoretical considerations and is supplemented with pertinent experimental data.

Chamis, C. C.↗

NASA NTRS1975

A model for the origin of solar wind stream interfaces

The basic variations in solar wind properties that have been observed at 'stream interfaces' near 1 AU are explained by a gas dynamic model in which a radially propagating stream, produced by a temperature variation in the solar envelope, steepens nonlinearly while moving through interplanetary space. The region thus identified with the stream interface separates the ambient solar wind from the fresh hot material originally in the stream. However, the interface regions given by the present model are thicker than most stream interfaces observed in the solar wind, a fact suggesting that some additional physical process may be important in determining that thickness. Variations in the density, speed, or Alfven pressure alone appear not to produce streams with such an interface.

Hundhausen, A. J.↗

NASA NTRS1975

Tug and payload-to-Orbiter interface requirements

This paper presents results of a study to identify, evaluate, and develop Tug plus payload-to-Orbiter accommodation requirements. Interface areas include structural, mechanical, fluids, environmental, avionics, and safety. Each interface area was investigated to determine the best physical and operational method of accomplishing the required functions with an overriding goal of establishing sample and flexible interface requirements suitable for Tug, Tug payloads, and other cargo. The recommended system for supporting the Tug and its payload from the Orbiter employs a cylindrical load-carrying structure called a deployment adapter that has a rotational capability for Tug deployment. The design and operation of the deployment adapter and other peripheral interface equipment such as crew compartment monitor and control panels and cargo bay fluid and electrical interface panels are discussed.

Bock, E. H.↗

NASA NTRS1975

Tug payload interfaces

Some conclusions reached during the IUS/Tug payload requirements compatibility study are presented. This study is concerned with all prospective Tug-payload interfaces, including detailed analysis of low-earth orbit, geosynchronous, and interplanetary missions. Tug payload requirements are discussed and summarized as to operational requirements, structural/mechanical interface, avionics interfaces, fluids interface, and environment. The shuttle impacts created by Tug/payload interfaces are examined and presented in tabular form. Major conclusions are that all payloads in the mission model can be suitably and inexpensively accommodated by the Tug and the Shuttle if standardized integration equipment is employed, that multiple payloads pose no significant integration challenge, and that a relatively small inventory of integration equipment is required to support all prospective payloads.

Runge, F.↗

NASA NTRS1976

An interface between a datametrics 1085A manometer and a Hewlett-Packard 2100S computer

A hardware/software interface designed to mate a Datametrics models 1085A electronic manometer to a Hewlett-Packard (HP) model 2100S computer is described. The software driver operates in the basic control system (BCS) and requires 173 words of memory; the hardware interface uses an HP data source interface (DSI) card which requires one computer input/output channel. Results obtained by incorporating this interface into a data acquisition system indicate that the interface operates successfully.

Hillard, M. E., Jr.↗

NASA NTRS1977

Surface charge kinetics near metal-dielectric interfaces exposed to kilovolt electron flux

Interfaces between dielectric films and grounded metallic boundaries were exposed, in vacuum, to monoenergic electron fluxes having energies up to 22 keV. Two principal concerns were the measuring of the charge distributions on dielectrics and the determining of causes of flashovers, events where dielectric surface charges abruptly transfer to the metallic structures. Surface charges are perturbed within 10 mm of interfaces. Perturbations are relatively small except within about 3 mm of the interface. The probability of flashover was found to be related to microscopic imperfections in the interfaces. As flashovers occur in an exposed metal substrate, points become burned into the dielectric along the slit. As these points develop, the probability of flashover increases greatly. An interface which is highly immune to flashover was formed by covering a dielectric film with a 1.5-mm-thick aperture plate which exposes the film through a machined opening.

Robinson, J. W.↗

NASA NTRS1978

Solar wind stream interfaces

Results are presented for a superposed epoch analysis of discontinuous solar wind interfaces. The average time-space profiles of stream interfaces are discussed with reference to fluid properties (flow speed, pressure ridge, density, electron and proton temperatures) and kinetic properties (electron core and halo, flow speed fluctuations, electron heat flux, alpha particles). Other aspects of stream interfaces are described, such as the persistence of individual interfaces, shock associations, the sector boundaries of the interplanetary magnetic field, and sudden impulses in the geomagnetic field. Interface position is considered in terms of the observed temperature jump. A conceptual model of high-speed stream evolution is proposed.

Gosling, J. T.↗